view Abstract Citations (82) References (41) Co-Reads Similar Papers Volume Content Graphics Metrics Export Citation NASA/ADS The Atmosphere of Venus Near HER Cloud Tops. Chamberlain, Joseph W. Abstract The conclusions that one reaches about Venus' atmospheric structure and composition near her cloud tops depend on the theory of line formation adopted to interpret the spectra. Here it is argued that the absorption bands of CO2 are produced through multiple scatterings in an optically thick atmosphere and that consequently our knowledge of that atmosphere is much less precise than is commonly believed. First, the visual data are reviewed to obtain an estimate of the properties of the cloud particles Next the thermal-infrared observations are used to derive some idea of the temperature, T, and its variation with optical depth, r, in the cloud; the degree of uncertainty in these parameters is considerable, but the cloud tops are almost certainly cooler than the region where CO2 absorption occurs. This observational conclusion is interpreted as a natural consequence of the multiple-scattering mechanism of line formation, which alleviates the need for more elaborate models of cloud and haze layers. From the T(r) dependence combined with the rotational temperature of CO2, we can deduce the mean depth, (r), of band formation. (Incidentally, it becomes necessary here to modify the conventional concept of "rotational temperature" to allow for the fact that different lines in a band are formed at different depths and, therefore, different local temperatures) Finally, the radiative-transfer theory of line formation is used to relate (r) to the albedo for single scattering, . Knowing the mean absorption cross-section for the gas, we may then derive the amount of CO1 above depth (r . This indirect method of deriving abundances does not make use of the absolute equivalent widths of absorption. Unfortunately, the chain of deductive reasoning is so long and involves so many poorly known parameters that the CO2 content is exceedingly uncertain. The CO1 equivalent widths and the line profiles are discussed as a means of deriving the amount of collisional broadening and thence the CO2/total-gas ratio. With the present theory the "spectroscopic pressures" are about half the values derived from a number of high-resolution spectra by Spinrad. But since the CO1 content must also be less than Spinrad's values, we can at least reaffirm his important conclusion that CO1 is a minor constituent of Venus' atmosphere. A number of intriguing correlations among observables are examined in the light of this theory. The variation of band strength and rotational with planetary phase have the forms expected. For the phase variation of band strength, an error in an earlier paper is corrected, and it is shown that for weak bands the temperature should change very little with phase Sample values are computed for the relative variation of the equivalent width across the disk at various phase angles; observed values are not yet available for comparison. The sporadic variations of equivalent width, rotational temperatures, and spectroscopic pressures are correlated, according to Spinrad. As interpreted here this correlation suggests that the temperature gradient near the cloud tops is not far from the dry, adiabatic lapse rate, but this conclusion, like so many others, remains imprecise Taking the data literally, we conclude that the near-infrared CO1 bands are formed mostly within the first scale height (about 8 km) below the cloud tops This part of the atmosphere is much more important in producing absorption, because of the multiple scatterings of light, than is the region above the clouds. The theory predicts the correct relative equivalent widths of the different weak bands, which heretofore have paradoxically indicated different CO2 abundances. Interpreting the equivalent widths with the present theory reaffirms Kuiper's conclusion that the carbon and oxygen isotopes are in about the same ratios as on Earth. The water-vapor band recently measured by Bottema, Plummer, and Strong is probably formed mainly above the clouds, unlike the weak CO2 bands With the pressures and temperatures thought to be characteristic of this region, the clouds cannot be composed of H2O. It seems unlikely (but not impossible) that the observations or their interpretation could be in error enough that ice clouds might actually form. Publication: The Astrophysical Journal Pub Date: April 1965 DOI: 10.1086/148207 Bibcode: 1965ApJ...141.1184C full text sources ADS |
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