Maximum Permissible Exposure Limits Research Articles

Organic-inorganic hybrid ZIF-8/MXene/cellulose-based textiles with improved antibacterial and electromagnetic interference shielding performance

Despite the tremendous efforts on developing antibacterial wearable textile materials containing Ti3C2Tx MXene, the singular antimicrobial mechanism, poor antibacterial durability, and oxidation susceptibility of MXene limits their applications. In this context, flexible multifunctional cellulosic textiles were prepared via layer-by-layer assembly of MXene and the in-situ synthesis of zeolitic imidazolate framework-8 (ZIF-8). Specifically, the introduction of highly conductive MXene enhanced the interface interactions between the ZIF-8 layer and cellulose fibers, endowing the green-based materials with outstanding synergistic photothermal/photodynamic therapy (PTT/PDT) activity and adjustable electromagnetic interference (EMI) shielding performance. In-situ polymerization formed a MXene/ZIF-8 bilayer structure, promoting the generation of reactive oxygen species (ROS) while protecting MXene from oxidation. The as-prepared smart textile exhibited excellent bactericidal efficacy of >99.99 % against both Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) after 5 min of NIR (300 mW cm−2) irradiation which is below the maximum permissible exposure (MPE) limit. The sustained released Zn2+ from the ZIF-8 layer achieved a bactericidal efficiency of over 99.99 % within 48 h without NIR light. Furthermore, this smart textile also demonstrated remarkable EMI shielding efficiency (47.7 dB). Clearly, this study provides an elaborate strategy for designing and constructing multifunctional cellulose-based materials for a variety of applications.

An NIR-II-photoresponsive CoSnO3 nanozyme for mild photothermally augmented nanocatalytic cancer therapy.

The main challenges of nanozyme-based tumor catalytic therapy (NCT) lie in the unsatisfactory catalytic activity accompanied by a complex tumor microenvironment (TME). A few nanozymes have been designed to possess both enzyme-like catalytic activities and photothermal properties; however, the previously reported nanozymes mainly utilize the inefficient and unsafe NIR-I laser, which has a low maximum permissible exposure limit and a limited penetration depth. Herein, we report for the first time an all-in-one strategy to realize mild NIR-II photothermally amplified NCT by synthesizing amorphous CoSnO3 nanocubes with efficient triple enzyme-like catalytic activities and photothermal conversion properties. The presence of Co2+ and Sn4+ endows CoSnO3 nanocubes with the triple enzyme-like catalytic activities, not only achieving enhanced reactive oxygen species (ROS) generation through the Co2+-mediated peroxidase-like catalytic reaction to generate ˙OH and Sn4+-mediated depletion of overexpressed GSH, but also realizing the catalytic decomposition of endogenous H2O2 for relieving tumor hypoxia. More importantly, the obtained CoSnO3 nanocubes with a high photothermal conversion efficiency of 82.1% at 1064 nm could achieve mild hyperthermia (43 °C), which further improves the triple enzyme-like catalytic activities of the CoSnO3 nanozyme. The synergetic therapeutic efficacy of the NIR-II-responsive CoSnO3 nanozyme through mild NIR-II PTT-enhanced NCT could realize all-in-one multimodal tumor therapy to completely eliminate tumors without recurrence. This study will open a new avenue to explore NIR-II-photoresponsive nanozymes for efficient tumor therapy.

RF-EMF Exposure near 5G NR Small Cells.

Of particular interest within fifth generation (5G) cellular networks are the typical levels of radiofrequency (RF) electromagnetic fields (EMFs) emitted by 'small cells', low-power base stations, which are installed such that both workers and members of the general public can come in close proximity with them. In this study, RF-EMF measurements were performed near two 5G New Radio (NR) base stations, one with an Advanced Antenna System (AAS) capable of beamforming and the other a traditional microcell. At various positions near the base stations, with distances ranging between 0.5 m and 100 m, both the worst-case and time-averaged field levels under maximized downlink traffic load were assessed. Moreover, from these measurements, estimates were made of the typical exposures for various cases involving users and non-users. Comparison to the maximum permissible exposure limits issued by the International Commission on Non-Ionizing Radiation Protection (ICNIRP) resulted in maximum exposure ratios of 0.15 (occupational, at 0.5 m) and 0.68 (general public, at 1.3 m). The exposure of non-users was potentially much lower, depending on the activity of other users serviced by the base station and its beamforming capabilities: 5 to 30 times lower in the case of an AAS base station compared to barely lower to 30 times lower for a traditional antenna.

The potential ‘blue light hazard’ from LED headlamps

Many dental personnel use light-emitting diode (LED) headlamps for hours every day. The potential retinal ‘blue light hazard’ from these white light headlamps is unknown. MethodsThe spectral radiant powers received from direct and indirect viewing of an electronic tablet, an LED curing light, a halogen headlamp, and 6 brands of LED headlamps were measured using integrating spheres attached to fiberoptic spectroradiometers. The spectral radiant powers were measured both directly and indirectly at a 35 cm distance, and the maximum daily exposure times (tMAX) were calculated from the blue weighted irradiance values. ResultsThe headlamps emitted very different radiant powers, emission spectra, and color temperatures (K). The total powers emitted at zero distance ranged from 47 mW from the halogen headlamp to 378 mW from the most powerful LED headlamp. The color temperatures from the headlamps ranged from 3098 K to 7253 K. The tMAX exposure times in an 8 h day when the headlamps were viewed directly at a distance of 35 cm were: 810 s from the halogen headlamp, 53 to 220 s from the LED headlamps, and 62 s from the LED curing light. Light from the LED headlamps that was reflected back from a white reference tile 35 cm away did not exceed the maximum permissible exposure time for healthy adults. Using a blue dental dam increased the amount of reflected blue light, but tMAX was still greater than 24 h. ConclusionsWhite light LED headlamps emit very different spectra, and they all increase the retinal ‘blue light hazard’ compared to a halogen source. When the headlamps were viewed directly at a distance of 35 cm, the ‘blue light hazard’ from some headlamps was greater than from the LED curing light (tMAX = 62 s). Depending on the headlamp brand, tMAX could be reached after only 53s. The light from the LED headlamps that was reflected back from a white surface that was 35 cm away did not exceed the maximum permissible ocular exposure limits for healthy adults. Clinical relevanceReflected white light from dental headlamps does not pose a blue light hazard for healthy adults. Direct viewing may be hazardous, but the hazard can be prevented by using the appropriate blue-light blocking glasses.

Measurement and Assessment of Exposure to 50 Hz Magnetic Fields from Common Home Electrical Appliances

In this twenty first century, man is exposed to a very high amount of magnetic fields in his environment. This is mainly due to the ubiquitous use of electricity and other technological devices, which are the major sources of magnetic field pollution. The effect of magnetic field exposure on health problems and safety risk of people is continually being investigated. A number of international organizations have formulated guidelines on limits to the value of the generated magnetic field. This work provides information on the amount of 50 Hz magnetic field created by some common home electrical appliances, and compare results obtained with permissible exposure limit by The International Commission on Non-Ionising Radiation Protection (ICNIRP) for the public. The home electrical appliances investigated include electric cooker, hair dryer, toaster, kettle, fan, microwave oven, electric iron, voltage stabilizer, etc. Measurements were carried out with the aid of a magnetic field strength meter, at a distance of 3 cm to 75 cm from the appliances. Results showed that the magnetic field varies with distance from the appliances (by quarter of a meter, most become negligible), the power consumption of the appliance, the age of the appliance, and the product (manufacturer) of the appliance. Also, appliances with electromagnets, coils and electric motors produce more magnetic fields than appliances with heating elements. At a distance of 3 cm from the appliances, the highest value of magnetic field obtained was 85.5 µT and the lowest value of the magnetic field obtained was 4.28 µT. The overall results obtained indicate that the magnetic field strengths are lower than the maximum permissible exposure limit (100 µT) recommended by ICNIRP for members of the public, and therefore, will not lead to any significant exposure risk. In conclusion, in-expensive measures of reducing magnetic field exposure are recommended.

Hybrid Laser-LED Transmitter With Closed-Loop Beam-Steering Control for Indoor Optical Wireless Communication

In this paper, we demonstrate a hybrid Laser-LED transmitter module for indoor optical wireless communication with closed-loop, non-mechanical beam steering capability. The hybrid transmitter module consists of a near infrared laser diode for data communication and white LED array for illumination, combined on a diffuser surface. Dual-axis non-mechanical beam steering of the laser beam is implemented using two off-centered liquid lenses. The diffused laser beam directed towards the receiver is steered over an angular range of −7.6 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">o</sup> to 7.6 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">o</sup> (−1.7 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">o</sup> to 2.6 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">o</sup> ) along the horizontal (vertical) axes spanning −200 to 200 mm (−44 to 67 mm) at the receiver placed 1.5-meter from the transmitter. M-QAM/OFDM in combination with adaptive bit-and power-loading is utilized to achieve a total data throughput of 5.15 Gbps for the diffused laser beam with steering. Laser intensity levels as measured at the receiver plane are kept below the maximum permissible exposure limit for indoor usage across the entire beam steering range. Closed-loop beam steering is also demonstrated by scanning the transmitted laser beam horizontally, measuring the signal strength using a low bandwidth photodetector and locking the laser beam to the receiver position for data-communication. Such hybrid transmitters offer the benefit of decoupling the data communication and illumination requirements of the indoor optical link, thereby tailoring the individual light emitter's performance to specific use-case.

Towards Transabdominal Functional Photoacoustic Imaging of the Placenta: Improvement in Imaging Depth Through Optimization of Light Delivery

Functional photoacoustic imaging of the placenta could provide an innovative tool to diagnose preeclampsia, monitor fetal growth restriction, and determine the developmental impacts of gestational diabetes. However, transabdominal photoacoustic imaging is limited in imaging depth due to the tissue’s scattering and absorption of light. The aim of this paper was to investigate the impact of geometry and wavelength on transabdominal light delivery. Our methods included the development of a multilayer model of the abdominal tissue and simulation of the light propagation using Monte Carlo methods. A bifurcated light source with varying incident angle of light, distance between light beams, and beam area was simulated to analyze the effect of light delivery geometry on the fluence distribution at depth. The impact of wavelength and the effects of variable thicknesses of adipose tissue and muscle were also studied. Our results showed that the beam area plays a major role in improving the delivery of light to deep tissue, in comparison to light incidence angle or distance between the bifurcated fibers. Longer wavelengths, with incident fluence at the maximum permissible exposure limit, also increases fluence within deeper tissue. We validated our simulations using a commercially available light delivery system and ex vivo human placental tissue. Additionally, we compared our optimized light delivery to a commercially available light delivery system, and conclude that our optimized geometry could improve imaging depth more than 1.6×, bringing the imaging depth to within the needed range for transabdominal imaging of the human placenta.

Analysis of model for assessing the road train movement stability

In this paper, we conduct a mathematical analysis of the model of ensuring the road trains movement stability by changing the design of coupling devices to determine the critical characteristic parameters of the road trains, which result in the loss of en-route directional stability under external action. The concept of the model was to separate the process of yawing of the road trains and its elements (due to external perturbing action) on the highway into several typical stages. The main parameters of the stages (the displacement amplitude and rotation angle of the road trains elements in relation to the driving direction) were determined based on the initial conditions of the road trains movement, the force and duration of the external action. The most dangerous areas of external action application to the road trains were determined in this paper. The maximum permissible exposure limit should not exceed 0.5–1.0% of the road trains trailer momentum, with duration having the greater effect than the amount of impact. The results obtained can be used in mechanical engineering to improve the road trains performance.

Beam steering in a narrow-beam phosphor down-converted white light visible light communication link using transmitter lens decentering.

Indoor visible light communication (VLC) systems with narrow beams can achieve practical few-meters-long wireless optical links. Such links can operate at low power levels and high data rate for supporting point-to-point or multipoint communication. The narrow-beam VLC links can, however, benefit from beam steering to support mobility of user equipment and cater to multiple users. Simple beam-steering techniques with minimal changes to the existing optical hardware are required to enable widespread adoption of beam steering in VLC links. We study the performance of a simple transmitter-lens-decenter-based beam-steering scheme in a VLC link, utilizing a phosphor down-converted blue laser transmitter. The beam-steering angle and hence the receiver coverage depend on the transmitter lens decenter and the choice of the transmitter and receiver lens's focal lengths. Optical ray tracing is used to quantify the collection efficiency achievable with beam steering, choose a suitable receiver lens, and understand the role of off-axis aberration in the system performance. In our experimental implementation, the transmitter lens decentering technique results in a maximum steering angle of 7.1°. This corresponds to a receiver coverage of 30 cm per cm of transmitter lens decenter for a fixed link length of 300 cm. The measured on-axis white light color coordinates of (0.286, 0.253) is found to shift toward warmer white colors with beam steering. The on-axis illuminance level of ∼19lux decreases slightly with beam steering and is found to be below the maximum permissible exposure limit for indoor illumination. We also quantify the data communication performance as a function of beam steering using on-off modulated data. Bit-error rates below the forward error correction limit are obtained for receiver coverage diameter of 75 cm and 60 cm for 1.25 Gbps and 1.5 Gbps data rates, respectively.

Range-gated active short-wave infrared imaging for rain penetration

A fixed wavelength optical parametric amplifier laser was constructed to create nanosecond pulsed light at 1527 nm for eye-safe range gated active short-wave infrared (SWIR) imaging. The laser pulse is generated using a Nd:YAG operating at 1064 nm to pump a potassium titanyle arsenate crystal in a single-pass geometry, resulting in ≈85 mJ at up to 28 Hz at 1527 nm with a pulse duration of ∼8 ns. The SWIR imager can be gated in as short as a 70-ns window (active time) with time steps as small as 5 ns (e.g., 0 to 70 ns and 5 to 75 ns). This allows for significant weather penetration by reducing the contribution from back-scattered photons reaching the receiver from scattering along the path prior to the imaging target. In addition, by converting to 1527 from 1064 nm, the maximum permissible exposure limit for eye-safety is ≈4 orders of magnitude larger, allowing for higher fluences without risk of injury. NEXRAD weather data along the line-of-sight were utilized to facilitate atmospheric propagation modeling via MODTRAN to retrieve an estimate of the path transmittance during testing. The integrated system herein is shown to extend imaging ranges with improvement factors of ≈2.5–3.1 × during periods of rain. An image of a water tower at a 10-km range was generated with visibilities between 3 and 4 km during testing.

In vivo combined virtual histology and vascular imaging with dual-wavelength photoacoustic remote sensing microscopy

Histological evaluation of tissues is currently a lengthy process that typically precludes intraoperative margin assessment. While numerous approaches have aimed to address the need for intraoperative virtual histology, none have yet proved sufficiently efficacious. We demonstrate the use of a new all-optical imaging modality, photoacoustic remote sensing (PARS), capable of virtual histopathological imaging, while simultaneously providing visualization of microvasculature in both freshly resected tissues and live animal subjects. We demonstrate high resolutions of 0.44µm and 1.2µm for 266-nm and 532-nm excitation wavelengths, respectively, as well as the characterization of maximum permissible exposure limits for both excitation wavelengths.

Pulmonary Alterations Among Workers in a Dental Prosthesis Laboratory: Exploring High Dust Concentrations and Novel Findings of Bacterial Genera in the Workplace to Achieve Improved Control.

To evaluate the pulmonary alterations in workers from a dental prosthesis laboratory and explore dust and bacterial dissemination generated in the laboratory. Spirometry and computerized axial tomography were performed on 67 workers. Dust in workplace air was determined using the filtration-gravimetric method, and bacterial detection was explored using 16S rDNA gene sequencing. Pulmonary alterations were detected in 37% of the workers. Airborne dust concentrations were determined to be higher than the maximum permissible exposure limit, and bacterial detection analysis revealed 23 bacterial genera. The most frequently detected bacterial genus was Sphingomonas sp., which has been described as microbiota associated with disease of the oral cavity. The results of this study highlight the importance of the implementation of biosecurity measures, improvement of ventilation systems, and routine disinfection of dental impressions.

Ultrasmall Semiconducting Polymer Dots with Rapid Clearance for Second Near‐Infrared Photoacoustic Imaging and Photothermal Cancer Therapy

AbstractPhototheranostic agents in the second near‐infrared (NIR‐II) window (1000–1700 nm) are emerging as a promising theranostic platform for precision medicine due to enhanced penetration depth and minimized tissue exposure. The development of metabolizable NIR‐II nanoagents for imaging‐guided therapy are essential for noninvasive disease diagnosis and precise ablation of tumors. Herein, metabolizable highly absorbing NIR‐II conjugated polymer dots (Pdots) are reported for the first time for photoacoustic imaging guided photothermal therapy (PTT). The unique design of low‐bandgap D‐A π‐conjugated polymer (DPP‐BTzTD) together with modified nanoreprecipitation conditions allows to fabricate NIR‐II absorbing Pdots with ultrasmall (4 nm) particle size. Extensive experimental tests demonstrate that the constructed Pdots exhibit good biocompatibility, excellent photostability, bright photoacoustic signals, and high photothermal conversion efficiency (53%). In addition, upon tail‐vein intravenous injection of tumor‐bearing mice, Pdots also show high‐efficient tumor ablation capability with rapid excretion from the body. In particular, both in vitro and in vivo assays indicate that the Pdots possess remarkable PTT performance under irradiation with a 1064 nm laser with 0.5 W cm−2, which is much lower than its maximum permissible exposure limit of 1 W cm−2. This pilot study thus paves a novel avenue for the development of organic semiconducting nanoagents for future clinical translation.

Spatial and temporal assessment of radiofrequency electromagnetic fields emitted by smart meters and smart meter banks in urban environments

This paper describes radiofrequency (RF) electromagnetic field (EMF) measurements in the vicinity of single and banks of advanced metering infrastructure (AMI) smart meters. The measurements were performed in a meter testing and distribution facility as well as in-situ at five urban locations. The measurements consisted of gauging the RF environment at the place of assessment, evaluating the worst-case electric-field levels at various positions around the assessed AMI meter configuration (spatial assessment), which ranged from a single meter to a bank of 81 m, and calculating the duty cycle of the system, i.e. the fraction of time that the AMI meters were actually transmitting (12-h temporal assessment). Both in-situ and in the meter facility, the maximum field levels at 0.3 m from the meter configurations were 10–13 V/m for a single meter and 18–38 V/m for meter banks with 20–81 m. Furthermore, 6-min average duty cycles of 0.01% (1 m) up to 13% (81-m bank) were observed. Next, two general statistical models (one for a single meter and one for a meter bank) were constructed to predict the electric-field strength as a function of distance to any configuration of the assessed AMI meters. For all scenarios, the measured exposure levels (at a minimum distance of 0.3 m) were well below the maximum permissible exposure limits issued by the International Commission on Non-Ionizing Radiation Protection (ICNIRP), the U.S. Federal Communications Commission (FCC), and the Institute of Electrical and Electronics Engineers (IEEE). Indeed, the worst-case time-average exposure level at a distance of 0.3 m from an AMI installation was 5.39% of the FCC/IEEE and 9.43% of the ICNIRP reference levels.

3D Dental Subsurface Imaging Using Enhanced Truncated Correlation-Photothermal Coherence Tomography

Development of accurate and sensitive dental imaging technologies is a top priority in the pursuit of high-quality dental care. However, while early dental caries detection and routine monitoring of treatment progress are crucial for effective long-term results, current radiographic technologies fall short of this objective due to low sensitivity for small lesions and use of ionizing radiation which is unsuitable for frequent monitoring. Here we demonstrate the first application of enhanced Truncated Correlation-Photothermal Coherence Tomography (eTC-PCT) to dental imaging. eTC-PCT is non-invasive and non-ionizing, operates well below the maximum permissible exposure (MPE) limit, and features 3D subsurface imaging capability with operator controlled axial resolution. We explore the potential of this method for dental applications and demonstrate its capability for depth-resolved tomographic 3D reconstructions of the details and subsurface extent of a variety of dental defects. To this end, in this proof-of-concept study, dental eTC-PCT imaging results, and its sensitivity to dental caries, are discussed in comparison with visual examination, x-rays and micro-CT imaging.

Thermal damage thresholds for multiple-pulse porcine skin laser exposures at 1070 nm

.As solid-state laser technology continues to mature, high-energy lasers operating in the near-infrared (NIR) band have seen increased utilization in manufacturing, medical, and military applications. Formulations of maximum permissible exposure limits establish guidelines for the safe use of these systems for a given set of laser parameters, based on past experimental and analytical studies of exposure thresholds causing injury to the skin and eyes. The purpose of our study is to characterize the skin response to multiple-pulsed laser exposures at the NIR wavelength of 1070 nm, at a constant beam diameter of 1 cm, using anesthetized Yucatan mini-pig subjects. Our study explores three constant total laser-on times of 0.01, 0.1, and 10 s as single- and multiple-pulse sequences. Exposures consisting of 10, 30, and 100 pulses have identical individual pulse durations but different duty cycles in order to include variable degrees of thermal additivity. A plurality of three observers quantifies skin damage with the minimally visible lesion metric, judged at the 1- and 24-h intervals postexposure. Calculation of the median effective dose () provides injury thresholds for all exposure conditions, based on varying laser power across subjects. The results of this study will provide a quantitative basis for the incorporation of multiple-pulsed laser exposure into standards and augment data contained in the existing database.

Evaluation of noise levels in areas and departments of the upper Technological Institute of Guasave

The present experimentation is the evaluation of noise levels in laboratories, classrooms and departments of a Higher Education Institution. Its objective is to identify and evaluate the working conditions to which workers and students are exposed when performing tasks. The study was conducted based on the official Mexican Standard NOM 011-STPS-2001 "Conditions of safety and hygiene in workplaces where noise is generated". Using a TES 1353S sound level meter for 4 weeks, evaluating 16 zones, in 2 periods. As a result, it was obtained that 6 of the 16 zones evaluated exceed the maximum permissible exposure limits. And recording discomfort and lack of concentration in the activities to be carried out on workers and students. As a recommendation, the implementation of periodic medical examinations and personal protective equipment for the personnel, in addition to the evaluation of noise levels in the preventive maintenance of the institution.to make the activities more comprehensive.

Optimal scheduling to minimize noise exposure in an oil and gas field

Noise analysis with different scenarios has been conducted for an oil and gas field to determine whether workers during sandblasting operations were fully protected from high noise to prevent ear injuries and downtime. The main purpose is to minimize noise doses affecting workers through an optimal scheduling algorithm. Data collected from a noise meter was fully evaluated and analyzed in terms of LAeq—A-weighted average energy equivalent sound pressure levels—and Lpk energy peak, in the audible range from 12.5 Hz to 20 kHz based on the one-third octave band frequencies. All noise results were found above the maximum permissible exposure limit 85 dB(A). Another important feature is the sharp rise observed in all weighted levels up to a mean value of 67 dB at low frequency of 80 Hz. A sharp decrease in the high frequency noise levels beyond 8 kHz is also observed. Comparisons between different scenarios are also presented. Additional noise sources such as compressors and air coolers add up an important fraction of the workers’ noise exposure dose and highly contribute to the hearing loss. Finally, a fair scheduling algorithm to optimize noise exposure time by minimizing the noise dose is proposed.

Suprathreshold laser injuries in excised porcine skin for millisecond exposures at 1070 nm

Skin injury response to near-infrared (NIR) laser radiation between the minimum visible lesion threshold and ablation onset is not well understood. This study utilizes a 1070-nm diode-pumped Yb-fiber laser to explore the response of excised porcine skin to high-energy exposures in the suprathreshold injury region without inducing ablation. Concurrent high-speed videography is employed to determine a dichotomous response for three progressive damage categories: observable surface distortion, surface bubble formation due to contained intracutaneous water vaporization, and surface bubble rupture during exposure. Median effective dose (ED50) values are calculated in these categories for 3- and 100-ms pulses with beam diameters (1 / e2) of 3mm (28, 35, and 49 J / cm2) and 7mm (96, 141, and 212 J / cm2), respectively. Double-pulse cases are secondarily investigated. Experimental data are compared with the maximum permissible exposure limits and ablation onset simulated by a one-dimensional multiphysics model. Logistic regression analysis predicted injury events with ∼90 % of accuracy. The distinction of skin response into progressive damage categories expands the current understanding of high-energy laser safety while underlining the unique biophysical effects during induced water phase change in tissue. These results prove to be useful in the diagnosis and treatment of NIR laser injuries.

High light-quality OLEDs with a wet-processed single emissive layer

High light-quality and low color temperature are crucial to justify a comfortable healthy illumination. Wet-process enables electronic devices cost-effective fabrication feasibility. We present herein low color temperature, blue-emission hazards free organic light emitting diodes (OLEDs) with very-high light-quality indices, that with a single emissive layer spin-coated with multiple blackbody-radiation complementary dyes, namely deep-red, yellow, green and sky-blue. Specifically, an OLED with a 1,854 K color temperature showed a color rendering index (CRI) of 90 and a spectrum resemblance index (SRI) of 88, whose melatonin suppression sensitivity is only 3% relative to a reference blue light of 480 nm. Its maximum retina permissible exposure limit is 3,454 seconds at 100 lx, 11, 10 and 6 times longer and safer than the counterparts of compact fluorescent lamp (5,920 K), light emitting diode (5,500 K) and OLED (5,000 K). By incorporating a co-host, tris(4-carbazoyl-9-ylphenyl)amine (TCTA), the resulting OLED showed a current efficiency of 24.9 cd/A and an external quantum efficiency of 24.5% at 100 cd/m2. It exhibited ultra-high light quality with a CRI of 93 and an SRI of 92. These prove blue-hazard free, high quality and healthy OLED to be fabrication feasible via the easy-to-apply wet-processed single emissive layer with multiple emitters.