A ns-pulsed laser operating at 532 nm wavelength has been employed to irradiate micrometric mylar films (1–100 μm) with an attached 0.1 μm Al film on its back face. Protons and light ions have been accelerated by the electric field developed in the non-equilibrium plasma generated by the laser pulse in a vacuum at an intensity of the order of 1010 W/cm2. The Time-of-flight (TOF) technique, using a Faraday cup (ion collector) coupled to a fast storage oscilloscope, has been employed to measure the ion velocity, energy and yield. The yield of plasma-emitted photons has been also evaluated. Two ion collectors have been used in opposite directions to measure the maximum ion acceleration by the TOF data acquired in backward and forward directions and the photon yield as a function of the target thickness. The evaluation of the ion energy distribution has been based on the Coulomb-Boltzmann-Shifted (CBS) distribution function.