Maximum Conversion Efficiency Research Articles

Femtosecond-laser-inscribed cladding waveguides in KTiOPO4 crystal for second-harmonic generation and Y-branch splitters

In this study, the fabrication of straight- and Y-branch-cladding waveguides in KTiOPO4 crystals using femtosecond laser-direct writing is described. The second-harmonic generation (SHG) of green light through the cladding waveguides was realized using a pulsed-wave pump at 1,064 nm. The guiding properties of straight-cladding waveguides fabricated by varying the laser-writing conditions were investigated. The minimum insertion loss was approximately 2.0 dB at 1,064 nm. Confocal micro-Raman spectroscopy was used to investigate the lattice micro-modifications. The maximum SHG conversion efficiency of the straight-cladding waveguide reached 31.4% with a maximum output power of 79.29 mW from an input power of 252.6 mW. The performances of the Y-branch splitters with splitting angles ranging from 0.5° to 2.6° were characterized at 1,064 nm, showing excellent properties, including symmetrical output ends and approximately equal splitting ratios. An SHG conversion efficiency of 13.4% and maximum output power of 33.63 mW were achieved in the Y-branch splitter with a splitting angle of 1.0°. These findings support potential applications in constructing compact-frequency converters by using femtosecond laser-written KTiOPO4 depressed-cladding waveguides.

Design and hardware verification of photovoltaic converter based on adaptive P&O with snubber and BJT circuits

The efficient utilization of renewable energy is a key technology area of high domestic and international concern, and the research and development of DC–DC photovoltaic converters with high conversion efficiency is of great significance for improving performance and reducing the cost of solar power generation systems. In order to improve the conversion efficiency of solar energy, this paper proposes the design of a high-efficiency photovoltaic DC–DC converter with a non-isolated DC–DC converter as the object of the study. Solar power conversion is accomplished by designing a simple and reliable snubber circuit and a triode auxiliary circuit and tracking the maximum power point by combining the perturbation observation method with variable step size. The snubber circuit can effectively suppress the problems of pulse spikes and oscillations, and the triode auxiliary circuit prevents the reverse current and improves the switching speed, which reduces the switching loss and combines with the perturbation observation method with variable step size for fast and stable tracking of the maximum power point. In order to verify the feasibility of the converter, a 600 W prototype is designed. The experimental results show that using the snubber circuit reduces the pulse spike by 4.2 V and the overshoot is reduced by 4.3%. The maximum conversion efficiency is increased by 0.88% with the use of the transistor-assisted circuit, and the tracking efficiency of the MPPT is still stable under cloudy conditions. The maximum conversion efficiency of the prototype is finally measured to be up to 98.12%.

Numerical modelling of an effective perovskite solar cell and PV-module for comparison analysis of organic and inorganic electron transport layers

The demand for energy has increased over the past few decades due to both the industrial sector's rapid development and the world's population growth. As we know, the main source of energy consists primarily of fossil fuels, which are expected to be exhausted very soon. Researchers were therefore urged to locate an alternative source of energy that may substitute for fossil fuels in order to meet the world's growing energy needs. Substitute energy sources, like renewable energy, can be used to reduce reliance on conventional energy. As its irradiance may produce electricity when struck by photovoltaic solar (PV) panels, one of the increasingly prevalent types of energy is solar energy. With the help of capacitance simulator software for solar cells (SCAPS-1D), a thorough study of comparison analysis for the design of more efficient, inexpensive, and non-toxic Ni/Cu2O/MASnI3/PCBM/FTO and Ni/Cu2O/MASnI3/WO3/FTO module configurations of solar cells was carried out, and the PVsyst photovoltaic software package investigated the dependence of solar panels on temperature and irradiation. In order to investigate how altering the electron transport layer (ETL) affects conversion efficiency, this work offers a perovskite solar cell simulation with both organic and inorganic ETLs. The absorber layer of perovskite and the HTL (hole transport layer) are maintained uniformly across all ETL configurations. This particular research takes into account the CH3NH3SnI3 absorber layer with Cu2O as HTL. In order to determine which cell combination has the maximum conversion efficiency, we examine the outcomes of both cell combinations. The SCAPS-1D software is used for all simulation work. The power conversion efficiency (PCE) for organic ETL was found to be 28.79%., in addition to a number of electrical parameters like short-circuit current density (Jsc) of 33.42mA/cm2, open-circuit voltage (Voc) of 1.032V, and fill factor (FF) of 83.43%. For inorganic ETL, PCE was 29.54%, Jsc was 34.28mA/cm2, Voc was 1.033, and fill factor was 83.34%. The optimised layer thickness of HTL was 0.2µm, for ETL it was 0.02µm, and the CH3NH3SnI3 absorber layer was 0.8µm. For a solar module with 72 cells with dimensions of 2.2×1.1m, the results obtained from the simulation of electrical parameters derived from SCAPS-1D were configured in the PVsyst software package for panel performance.

Design of Laser-Powered Opto-Electrical Current Transformer and Its Application in Electrical Automation of Substations

The novel power equipment represented by the Opto-Electrical Current Transformer (OECT) possesses unparalleled advantages compared to traditional Current Transformers (CTs), rendering it with vast potential in power systems. In the design of OECT, this study employs laser power supply and focuses on the overall perspective, particularly the design of the laser power supply module and the optical fiber digital transmission module. The laser power supply module selects a high-power semiconductor laser to provide power to the circuit, incorporating line filters, thermistor resistors, and a laser overcurrent protection circuit. An automatic temperature control circuit based on PI regulation is utilized to stabilize the working temperature of the laser diode (LD). The photoelectric conversion device PPC-6E achieves a maximum photoelectric conversion efficiency of 40%, and the MAX639 DC–DC conversion chip ensures stable output voltage. The optical fiber digital transmission module adopts a circuit composed of multiple NOR gate logic for electro-optical conversion, a low-power driving circuit based on the 74LVC1G07 chip, and the HFBR-2412 photoelectric converter to simplify the circuit board design. To achieve a higher communication baud rate, a quartz multimode optical fiber with a diameter of 62.5 μm is chosen. In the experimental phase, a simulation of high-power AC power with equal turns is conducted. The linearity/temperature test results demonstrate that the designed OECT in this study meets expectations. In the electrical automation test of substations, a comparison between traditional CTs and the designed OECT is carried out using traditional protection algorithms and optical differential protection algorithms. The results indicate that, compared to traditional protection algorithms, the optical differential algorithm using the designed OECT achieves faster protection times.

Theoretical Study of Quantum Efficiency and Spectral Response of Solar Cells

A theoretical study of Quantum Efficiency (QE) and Spectral Response (SR) of solar cells was done in order to suggest ways in which related parameters could be optimized for maximum conversion efficiency of solar cells. Secondary data for the base, emitter and total parameters of QE and SR were obtained. MATLAB was employed in plotting and analysing these data across different diffusion lengths. From the results obtained, it was observed that when the value of the Emitter Diffusion Length (EDL) was varied from 0.3μm to 0.5μm, the emitter and total values of QE increased by about 700% at wavelength 300nm – 400nm. In the case of SR, it was observed that when there was an increase in the Base Diffusion Length (BDL) from 20μm to 50μm, there was an increase of about 26% at wavelength 800nm – 900nm. A rise in the diffusion length was seen to increase both the QE and SR of the cell. Thus, it can be suggested that an increase in the emitter and base diffusion length of a solar cell leads to a decrease in the recombination charges in the cell, giving more time for the charge carriers to exit the cell.

Research on the power generation performance and optimization of thermoelectric generators for recycling remaining cold energy

Compared with extensive research on the power generation of thermoelectric generators (TEGs) under medium-high temperatures, research on power generation for cold energy utilization is still limited. To study the performance and feasibility of low-temperature power generation, this paper combines simulation and experiments for research. Firstly, a simulation model based on actual material parameters is established. Then, a thermoelectric low-temperature power generation experimental platform is established to conduct experimental research on TEG in different temperature zones and temperature differences and compared with simulation results. Finally, optimization research is conducted by changing thermoelectric materials and structures. The research results indicate that the maximum errors between the dates of simulation and experiment in terms of output voltage, conversion efficiency, and exergy efficiency are 11.3 %, 10.57 %, and 10.57 %, respectively. Compared with Bi2Te3, the output voltage, conversion efficiency, and exergy efficiency of CsBi4Te6 are improved by 21.95 %, 34.64 %, and 34.64 %, respectively. The maximum output power and conversion efficiency are linearly related to the output current. The performance is optimal when the thermoelectric unit height is 1.0 mm and the side length is 1.6 mm. This proves the feasibility of TEG application at low temperatures and lays the foundation for low-temperature power generation.

Manipulation of metavalent bonding to stabilize metastable phase: A strategy for enhancing zT in GeSe

AbstractExploration of metastable phases holds profound implications for functional materials. Herein, we engineer the metastable phase to enhance the thermoelectric performance of germanium selenide (GeSe) through tailoring the chemical bonding mechanism. Initially, AgInTe2 alloying fosters a transition from stable orthorhombic to metastable rhombohedral phase in GeSe by substantially promoting p‐state electron bonding to form metavalent bonding (MVB). Besides, extra Pb is employed to prevent a transition into a stable hexagonal phase at elevated temperatures by moderately enhancing the degree of MVB. The stabilization of the metastable rhombohedral phase generates an optimized bandgap, sharpened valence band edge, and stimulative band convergence compared to stable phases. This leads to decent carrier concentration, improved carrier mobility, and enhanced density‐of‐state effective mass, culminating in a superior power factor. Moreover, lattice thermal conductivity is suppressed by pronounced lattice anharmonicity, low sound velocity, and strong phonon scattering induced by multiple defects. Consequently, a maximum zT of 1.0 at 773 K is achieved in (Ge0.98Pb0.02Se)0.875(AgInTe2)0.125, resulting in a maximum energy conversion efficiency of 4.90% under the temperature difference of 500 K. This work underscores the significance of regulating MVB to stabilize metastable phases in chalcogenides.

A generalized model for a triboelectric nanogenerator energy harvesting system

A triboelectric nanogenerator (TENG) energy harvesting system involves at least three components: the mechanical source that inputs mechanical energy to drive TENGs, the TENG device itself as an energy converter, and an external electrical circuit that output the energy from TENGs. Multiple theoretical models have been developed for structural optimization design and maximum power output, yet there has been less emphasis on dynamic modelling of the entire energy harvesting system. This work presents attempts to establish such system-level models that encompass both mechanical and electrical systems. Special consideration is paid to the dynamic contact problem in this generalized model, since dynamic response of impacts can significantly affect the electric outputs. To address contact constraint problems, the penalty function method is utilized to handle non-smoothness and discontinuity. Subsequently, this research specifies how to improve the maximum energy conversion efficiency, and suggest optimal executive strategies for maximizing the energy output through a thorough parametric study. The anticipated outcome is that the generalized model will not only guide optimization design and predict the dynamic characteristics of the energy harvesting system but also assess the potential feasibility of mechanical energy harvesting technology across diverse application domains.

ANALYSIS THE EFFECTIVENESS OF THERMOELECTRIC POWER GENERATION USING WASTE HEAT RECOVERY

Non-renewable energy resources, which account for about 85% of worlds’ energy (68% fossil fuels are used for electric power generation), are getting exhausted rapidly. As predicted by the Institute of Sustainable Energy Policies, by the year 2050, only 33% of non-renewable energy resources will be available for electric power generation. Hence, to meet the required demand, the remaining 67% has to be replaced by renewable energy sources. This demand in electric power generation has to be met by a pollution free, low-cost, clean energy resource, which is the need of the hour. The present research targets towards two main applications for generating power using the biomass energy based resources. They are domestic based application – burning biomass wood and utilizing the heat for generating power, industrial based application – combustion of gasified de-oiled Pongamia cake and utilizing the heat energy for generating power In order to achieve the proposed target, initially, the theoretical modeling on the performance of (Bi2Te3-PbTe) hybrid thermoelectric generator (TEG) composed of n-type Bismuth Telluride - p-type Lead Telluride semiconductor materials has been done. The effect of different performance parameters on the maximum conversion and power efficiencies have been theoretically analyzed by varying the hot side temperature. Key Words: Hybrid Thermoelectric Generator, Electric Power Generation, Graphene Nanoparticles.

Realizing BiCuSeO-based thermoelectric device for ultrahigh carrier mobility through texturation

The thermoelectric conversion technology, as a promising renewable energy technology, enables direct and efficient conversion between electricity and heat. In the past ten years, there has been an increasing curiosity towards oxide thermoelectric materials due to their environmentally friendly nature, low cost, and excellent thermal and chemical stability. However, the intrinsic low carrier mobility of BiCuSeO limits its potential to be a high-performance thermoelectric material. Herein, we propose a dynamic sintering approach to enhance carrier mobility of BiCuSeO. As a result, carrier mobility at room temperature of three-step textured Bi0.94Pb0.06Cu0.97Se1.05O0.95 reaches an ultrahigh value of 13.1 cm2 V−1 s−1, which is the highest reported in the conventional doping of BiCuSeO system. Based on the ultrahigh carrier mobility, the power factor of three-step textured Bi0.94Pb0.06Cu0.97Se1.05O0.95 sample could reached 20 μV cm−1 K−2 near room temperature, and the average power factor of 300–923 K could reach 18.0 μV cm−1 K−2, effectively optimizing the electrical performance throughout the entire test temperature span. As a result, we successfully attain a ZT of ∼ 1.5 at 923 K and a ZTave of 0.89 within the temperature span of 300–923 K for three-step textured Bi0.94Pb0.06Cu0.97Se1.05O0.95 sample. Based on the outstanding performance, we have successfully built a 7-pair thermoelectric device based on three-step textured Bi0.94Pb0.06Cu0.97Se1.05O0.95 paired with the N-type two-step textured Bi2Te2.7Se0.3Cu0.01, which is the first BiCuSeO-based thermoelectric device. The thermoelectric device, exhibits a maximum conversion efficiency of 2.8 % at the temperature difference 215 K and simultaneously achieves a cooling temperature difference of 23.5 K with the hot end at 286 K. This work indicates that texturation is an effective approach for enhancing the carrier mobility of oxide TE materials. Besides, BiCuSeO oxyselenide is promising for pollution-free and cost-effective thermoelectric devices of power generation and cooling, thereby offering potential implications for sustainable energy solutions.

Excellent visible light absorption and ultra-high photoelectric conversion efficiency of two-dimensional (MoSe2)x(MoSTe)1-x mosaic heterostructures

Solar cells are a promising and potentially sustainable energy technology due to their cost-effectiveness, eco-friendliness, and capacity for integration into pliable apparatuses. Developing new photovoltaic materials to achieve higher photovoltaic conversion efficiency is a hot topic in the field of solar cells. In this work, the electronic structures and optical properties of two-dimensional (MoSe2)x(MoSTe)1-x mosaic heterostructures have been studied by density functional theory. Our results show that the mosaic heterostructures retain semiconductors with tunable band gap of 1.14–1.53 eV. With the augmentation of MoSe2 concentration in the mosaic heterostructures, the band gap of the materials has gradually increased. Besides, the mosaic heterostructures exhibit excellent optical absorption in the visible light region. Furthermore, the maximum theoretical photoelectric conversion efficiency of (MoSe2)0.80(MoSTe)0.20 mosaic heterostructure can reach 32.36 %. The tunable band gap, excellent light absorption, and ultra-high photoelectric conversion efficiency of (MoSe2)x(MoSTe)1-x mosaic heterostructures make them candidates for new nanocrystalline thin-film solar cells.

Design and hydrodynamic study of a new pile-based breakwater-OWC device combined system

In order to enhance the conversion efficiency and optimize the hydrodynamic performance of the OWC device, a novel combined system composed of a pile-based OWC chamber and a perforated wave-eliminator is proposed. The schemes with rectangular front wall M1, elliptical front wall M2, M3 are designed. Physical tests and numerical simulations were conducted for the hydrodynamic process under the action of wave of the system with H/d = 0.16, 0.20, 0.24 and L/B = 3.3, 3.8, 4.3, 4.7, 5.2, 5.5, 6.4. The obtained-results show that the system has better energy converting and wave eliminating performance than the other existing systems. Its maximum conversion efficiency ξ is up to 70%, while its transmission coefficient Ct is less than 0.45. Compared to M1 and M2, M3 can improve the efficiency ξ of the system (up to approximately 35%) and reduce the maximum force exerted on the system (up to 10%). When studying the forces on the combined system, the horizontal force (in the direction of wave propagation) can be primarily calculated by considering the force exerted on the chamber. However, when investigating the vertical forces (opposite to gravity) acting on the system, both the OWC chamber and the wave-eliminator need to be considered. The research results can provide valuable references for further design optimization of OWC devices.

Ultralow Glassy Thermal Conductivity and Controllable, Promising Thermoelectric Properties in Crystalline o-CsCu5S3.

We thoroughly investigated the anharmonic lattice dynamics and microscopic mechanisms of the thermal and electronic transport characteristics in orthorhombic o-CsCu5S3 at the atomic level. Taking into account the phonon energy shifts and the wave-like tunneling phonon channel, we predict an ultralow κL of 0.42 w/mK at 300 K with an extremely weak temperature dependence following ∼T-0.33. These findings agree well with experimental values along with the parallel to the Bridgman growth direction. The κL in o-CsCu5S3 is suppressed down to the amorphous limit, primarily due to the unconventional Cu-S bonding induced by the p-d hybridization antibonding state coupled with the stochastic oscillation of Cs atoms. The nonstandard temperature dependence of κL can be traced back to the critical or dominant role of wave-like tunneling of phonon contributions in thermal transport. Moreover, the p-d hybridization of Cu(3)-S bonding results in the formation of a valence band with "pudding-mold" and high-degeneracy valleys, ensuring highly efficient electron transport characteristics. By properly adjusting the carrier concentration, excellent thermoelectric performance is achieved with a maximum thermoelectric conversion efficiency of 18.4% observed at 800 K in p-type o-CsCu5S3. Our work not only elucidates the anomalous electronic and thermal transport behavior in the copper-based chalcogenide o-CsCu5S3 but also provides insights for manipulating its thermal and electronic properties for potential thermoelectric applications.

Effect of defect density, bandgap profile, material composition, thickness, and doping density of the absorber layer on the performance of thin film solar cell based on antimony selenosulfide Sb2(Se1-ySy)3

This article deals with the optimization by simulation of a graded bandgap thin film solar cell based on antimony selenosulfide Sb2(Se1-ySy)3 having the following structure: Front contact/n-ZnO/i-ZnO/p-SbSSe/n-CdS/Back contact. The simulation is performed using SCAPS-1D software. The optimization process includes optimizing the bulk defect density, bandgap profile, material composition, thickness, and doping density of the absorber layer of thin film solar cell based on antimony selenosulfide Sb2(Se1-ySy)3. We found that for a bulk defect density below 1013 cm-3 , using an absorber material with a graded bandgap profile leads to an efficiency of 25.33 % (For a bulk defect density of 1010 cm-3 ) higher than that with a uniform bandgap profile. However, for a bulk defect density of 1013 cm-3 , both profiles provide almost the same maximum solar cell conversion efficiencies of about 13.6 %. Ultimately, for a bulk defect density above 1013 cm-3 , the graded bandgap profile is not useful, and a maximum solar cell conversion efficiency of 10.5 % (For a bulk defect density of 1014 cm-3 ) is achieved with a uniform bandgap profile. These optimization results help to improve the efficiency of low-cost fabricated thin-film solar cells.

High‐Temperature Semiconductor CuO/SiC‐Based Catalyst for Artificial Photosynthesis

AbstractArtificial photosynthesis can convert CO2 and H2O into hydrocarbons via solar energy. However, the extremely low process efficiency is a major obstacle to this application. The photocatalyst is considered to be the key factor to raise the overall solar energy conversion efficiency. Much research focused on co‐catalysts, but less attention has been paid on the high‐temperature semiconductor. Herein, a strategy is proposed involving high‐temperature semiconductor to design target photocatalyst dealing with the artificial photosynthesis at high temperature. Based upon this strategy, a CuO/SiC catalyst with single atom characteristic was designed, prepared and the activity of CO2 photoreduction with H2O was tested in a high temperature environment. Above 150 °C, the catalyst activity was boosted and unprecedented performance values were attained. Under the irradiation condition delivered by a 1000 W Xe light and at 350 °C, the obtained yields of CH4, C2H4, and C2H6 were 2041.4 μmol ⋅ g−1, 15.2 μmol ⋅ g−1, and 63.6 μmol ⋅ g−1, respectively. The overall CO2 conversion reached 24.6 % and the maximum solar energy conversion efficiency was 2.3 % without any sacrificed agents. This strategy will be helpful to overcome the current limitations for the industrialization of artificial photosynthesis and accelerate the related research on photothermal catalysis.

Realizing high conversion efficiency in all-ZrCoSb-based half-Heusler thermoelectric power generators

ZrCoSb-based thermoelectric materials exhibit promising potential for power generation applications due to their high performance in both p- and n-type constituents. In this work, a newly developed all-ZrCoSb-based module achieves a maximum conversion efficiency of ∼9.3 % at a temperature difference of 668 K. This high conversion efficiency is enabled by the enhanced average thermoelectric properties for both types of ZrCoSb-based materials via Bi alloying and Sn/Ni doping. The hole and electron carrier concentrations were tuned to match the theoretically predicted optimized values, contributing to high weight mobility and power factor. Additionally, the increased mass and strain field fluctuations enhance point defect scattering, leading to a significant reduction in the lattice thermal conductivity of ZrCoSb. Consequently, peak zT values of ∼1.2 and ∼1.0 at 973 K were respectively obtained in p-type ZrCo(Sb0.5Bi0.5)0.85Sn0.15 and n-type ZrCo0.85Ni0.15Sb0.5Bi0.5, resulting in high average zT values of ∼0.75 and ∼0.51 in the temperature of 300 to 973 K. This work underscores the significant potential of all-ZrCoSb-based half-Heuslers in waste heat recovery.

Wavelength and angle-dependent third-harmonic generation in epsilon-near-zero indium tin oxide

Third-harmonic generation (THG) is a typical nonlinear optical phenomenon, which has important applications in the field of photoelectric integration. Here we reported the broadband and incident angle-dependent third-harmonic generation from a 350 nm thick indium tin oxide (ITO) film in near-infrared region, and a significant THG enhancement was observed. Moreover, the maximum third-harmonic conversion efficiency at ENZ wavelength is ∼10 times higher than that in non-ENZ region, and the large nonlinear enhancement effect mainly comes from the electric field enhancement under the ENZ condition. Our results highlight the potential applications of ITO in nonlinear optics and provide a promising platform for the development of efficient nonlinear light sources.

Dual Frequency Energy Harvesting System Based on Planar Inverted F-shaped Antenna

<p>With the expansion of Internet of things (IoT) scale and the extension of its application fields, node energy acquisition has become one of the constraints on the development and application of IoT technology. Wireless energy acquisition is faced with the challenge of how to enhance power conversion efficiency under low input power in the broadband range. This study aimed to improve the capability of energy collection and transmission in wireless communication, an efficient dual-frequency energy harvesting system was proposed, moreover a novel dual-frequency planar inverted-f antenna (PIFA) and its energy conversion circuit for Radio frequency (RF) energy harvesting were designed by studying the characteristics of ambient RF energy and antenna. The developed antenna is designed and manufactured for GSM 900mhz or DCS 1.8 GHz to harvest the ambient energy provided by nearby devices. It is proved that the new dual-frequency antenna still has high efficiency when the input power is less than -20 dbm, and can maximize the receiving energy. The system works with an energy conversion and storage module to convert weak signals into required voltages, the simulation and test results show that the maximum conversion efficiency of the prototype is about 65% at 920MHZ and 1.8GHz at -20 dBm input power.</p> <p> </p>

Parametric investigation and RSM optimization of DBD plasma methods (direct & indirect) for H2S conversion in the air

Hydrogen sulfide (H2S) is known as a harmful pollutant for the environment and human health, and its emission control is a high priority. Non-thermal plasma is an effective technology in this field. In this study, for the first time, the performance of direct and indirect H2S plasma conversion methods was compared, optimized, and modeled with the CCD method. H2S was diluted in zero air, and the study investigated the effect of discharge power, relative humidity, total flow rate, initial H2S concentration, and their interactions. ANOVA results showed that the models for H2S conversion efficiency and energy yield were significant and efficient. The direct method achieved a maximum conversion efficiency of 56 % and energy yield of 3.43 g/kWh, while the indirect method produced 68 % conversion efficiency and 1.59 g/kWh energy yield. According to the process optimization results, the direct conversion method is more optimal than the indirect conversion method due to the presence of active species and high-energy electrons in the plasma treatment, and it is a better choice if there are suitable working conditions.

Enhancing Stability and Photovoltaic Performance of Perovskite Solar Cells via 5‐Ammonium Acid Additive

AbstractThe quality of perovskite films plays a fundamental role in determining the performance of perovskite solar cells (PSCs). It is widely recognized that achieving high crystalline quality and minimizing defect density in perovskite films are essential. In this study, the utilization of the multifunctional additive 5‐ammonium acid (5‐AVA) to improve the morphology of perovskite films is proposed. The ‐NH2 and ‐COOH groups in 5‐AVA enable effective coordination with Pb ions and organic ions in perovskite, resulting in the suppression of defect formation and the reduction of non‐radiative recombination losses. Furthermore, the addition of 5‐AVA facilitates a more favorable energy level alignment, thereby enhancing the transfer of carriers between the perovskite layer and transport layers. Consequently, this process contributes to the improvement of the open circuit voltage (VOC) in PSCs. Attributing to the addition of 5‐AVA, the optimized PSCs achieve significantly enhanced performance with a maximum photoelectric conversion efficiency (PCE) of 24.74% and excellent long‐term stability. This work presents a straightforward and effective approach to enhance the performance and long‐term stability of PSCs.