Matter Content Research Articles

Variability of inherent optical properties of seawater in relation to the concentration and composition of suspended particulate matter in the coastal Arctic waters of western Spitsbergen

Inherent optical properties (IOPs) and characteristics of suspended particles in surface seawater samples were measured in summer months of 2021 and 2022 in Arctic fjords and coastal waters of western Spitsbergen in the Svalbard archipelago. The measured IOPs included the spectral backscattering and scattering coefficients of suspended particulate matter, as well as the spectral absorption coefficients of suspended particulate matter and its non-algal particulate and phytoplankton components. The particulate assemblages were characterized by measuring the mass concentrations of suspended particulate matter (SPM), particulate organic matter (POM), particulate inorganic matter (PIM), and phytoplankton pigments including chlorophyll-a (Chla). The investigated coastal waters exhibit high variability of particulate characteristics and associated IOPs. We observed more than two orders of magnitude variation in SPM and particulate IOPs, and Chla varied from below the detection limit to more than 3 mg m−3. The contribution of organic fraction to SPM (POM/SPM ratio) varied from 0.05 to 0.6, and the Chla/SPM ratio spanned more than three orders of magnitude with a maximum value of the order of 10−3. As a result, the mass-specific optical coefficients, especially the mass-specific backscattering and scattering coefficients of particles and mass-specific absorption coefficient of non-algal particulate matter, exhibit large variations. In addition, our study demonstrates the influences of changes in composition of suspended particulate matter parameterized in terms of POM/SPM and Chla/SPM ratios on IOPs. Various variants of spectral parametrizations of optical coefficients in terms of univariate or multivariable relationships with particulate characteristics are provided. These parameterizations are representative of the investigated coastal Arctic waters in Svalbard region and can be used for better interpretation of optical measurements, both in-situ and remote, in this Arctic environment.

Selection Rules of Linear and Nonlinear Polarization-Selective Absorption in Optically Dressed Matter

Dynamical symmetries of laser-dressed matter determine the selection rules that influence its absorption spectrum. We explore selection rules for polarization-sensitive absorption in Floquet matter, using Floquet group theory in synthetic dimensions. We present comprehensive tables of selection rules that polarization-structured light impose on Floquet dark states and Floquet dark bands. Notably, our tables encompass nonlinear absorption for all nonlinear orders, revealing that different nonlinear orders follow distinct polarization selection rules, potentially leading to polarization-tunable optical filters.

Axially symmetric solutions in Ricci-inverse modified gravity

We investigate a family of axial symmetry solution constructed in general relativity (GR) within the framework of Ricci-inverse (RI) gravity theory. In GR, these solutions admitted closed time-like curves at an instant of time from an initial spacelike hypersurface in a causally well-behaved manner, thus, violates the causality condition. Our aim is to examine these axial symmetry solutions within the context of Ricci-inverse gravity theory to determine whether closed time-like curves still appear in this new gravity theory. We consider two Classes of RI-gravity models: (i) Class-II models defined by a function f=f(R,AμνAμν)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$f=f({\\mathcal {R}}, A^{\\mu \ u }\\,A_{\\mu \ u })$$\\end{document} gravity and (ii) Class-III models defined by f=f(R,A,AμνAμν)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$f=f({\\mathcal {R}},{\\mathcal {A}}, A^{\\mu \ u }\\,A_{\\mu \ u })$$\\end{document}, where Aμν\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$A^{\\mu \ u }$$\\end{document} is the anti-curvature tensor, A=gμνAμν\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\mathcal {A}}=g_{\\mu \ u }\\,A^{\\mu \ u }$$\\end{document} as its scalar, and Rμν\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$R^{\\mu \ u }$$\\end{document} is the Ricci tensor. We are able solved the modified field equations considering these axial symmetry solutions as background in RI-gravity with null radiation as the matter content and the cosmological constant. This confirms that the chosen family of axial symmetry solutions are valid solutions in RI-gravity theory and, consequently, closed time-like curves is still form, analogous to their formation in GR.

Dose increment in ultrashort particle irradiations via coherent stopping power

We present a relativistic self-consistent theory of the coherent stopping power (CSP) of ultradense charged particle beams propagating in a dense matter. CSP corresponds to a collective inelastic collision which adds to the ordinary stopping power of individual particles. Unlike the latter, which depends only on the particles' energy, CSP depends upon many more parameters such as the total charge of the ensemble and its charge density and shape. This paves the way for a broad variety of novel methods to tailor particle absorption and penetration in a dense matter. CSP losses can be explained both by collective excitations of single or multiple molecules and by the emission of coherent Cherenkov radiation. Here we demonstrate that the former mechanism is more relevant than the latter. We find that the coherent energy absorption of subpicosecond particle bunches in water occurs exciting a broad Debye process in the GHz range and an intermolecular stretching vibration mode in the THz region. We generalize the Bethe-Bloch stopping power formula to coherent effects including self-forces, dielectric screening, and absorption by the dense matter. For the sake of a self-consistent dynamical theory including phase space evolution, we have also generalized the Fermi-Eyges theory of particle diffusion to the presence of forces. Nonlinear dynamics is demonstrated, inducing nonlinear dose release, beam self-focusing, and self-enhancement of coherent losses. Given the advent of ultraintense particle sources and their use for biomedical and other relevant applications, our results may be of paramount importance for contemporary and future developments of science and technology. Published by the American Physical Society 2024

Searches for new physics below twice the electron mass with GERDA

A search for full energy depositions from bosonic keV-scale dark matter candidates of masses between 65 and 1021 keV has been performed with data collected during Phase II of the GERmanium Detector Array (Gerda) experiment. Our analysis includes direct dark matter absorption as well as dark Compton scattering. With a total exposure of 105.5 kg years, no evidence for a signal above the background has been observed. The resulting exclusion limits deduced with either Bayesian or Frequentist statistics are the most stringent direct constraints in the major part of the 140–1021 keV mass range. As an example, at a mass of 150 keV the dimensionless coupling of dark photons and axion-like particles to electrons has been constrained to α′/α<8.7×10-24\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\alpha '/\\alpha <8.7~\ imes 10^{-24}$$\\end{document} and gae<3.3×10-12\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$g_\ extrm{ae}<3.3~\ imes 10^{-12}$$\\end{document} at 90% credible interval (CI), respectively. Additionally, a search for peak-like signals from beyond the Standard Model decays of nucleons and electrons is performed. We find for the inclusive decay of a single neutron in 76\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^{76}$$\\end{document}Ge a lower lifetime limit of τn>1.5×1024\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ au _\ extrm{n} > 1.5 \ imes 10^{24}$$\\end{document} years and for a proton τp>1.3×1024\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ au _\ extrm{p} > 1.3 \ imes 10^{24}$$\\end{document} years at 90% CI. For the electron decay e-→νeγ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$e^\ ext {-} \\rightarrow \ u _\ extrm{e} \\gamma $$\\end{document} a lower limit of τe>5.4×1025\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ au _\ extrm{e} > 5.4\ imes 10^{25}$$\\end{document} years at 90% CI has been determined.

Modeling dissolved organic carbon in inland waters using an unmanned aerial vehicles-borne hyperspectral camera

Remote sensing can provide an alternative solution to quantify Dissolved Organic Carbon (DOC) in inland waters. Sensors embedded on Unmanned Aerial Vehicles (UAV) and satellites that can capture the DOC have already shown good relationships between DOC and the Colored Dissolved Organic Matter absorption (aCDOM.) coefficients in specific spectral regions. However, since the signal recorded by the sensors is reflectance-based, DOC estimates accuracy decreases when inverting the aCDOM. coefficients to reflectance. Thus, the main objective is to study the potential of a UAV-borne hyperspectral camera to retrieve the DOC in inland waters and to develop reflectance-based models using UAV and satellite (Landsat-8 OLI and Sentinel-2 MSI) data. Ensemble based systems (EBS) were favored in this study. The EBSUAV calibration results showed that six spectral regions (543.5, 564.5, 580.5, 609.5, 660, and 684 nm) are sensitive to DOC in waters. The EBSUAV test results showed a good concordance between measured and estimated DOC with an R2 = Nash-criterion (NASH) = 0.86, and RMSE (Root Mean Squares Error) = 0.68 mg C/L. The EBSSAT test results also showed a strong concordance between measured and estimated DOC with R2 = NASH = 0.92 and RMSE = 0.74 mg C/L. The spatial distribution of DOC estimates showed no dependency to other optically active elements. Nevertheless, estimates were sensitive to haze and sun glint.

Development of a Small-Sized Urban Cable Conduit Inspection Robot

Cable conduits are crucial for urban power transmission and distribution systems. However, current conduit robots are often large and susceptible to tilting issues, which hampers the effective and intelligent inspection of these conduits. Therefore, there is an urgent need to develop a smaller-sized conduit inspection robot to address these challenges. Based on an in-depth analysis of the characteristics of the cable conduit working environment and the associated functional requirements, this study successfully developed a small-scale urban cable conduit inspection robot prototype. This development was grounded in relevant design theories, simulation analyses, and experimental tests. The test results demonstrate that the robot’s bracing module effectively prevents tilting within the conduit. Additionally, the detection module enables comprehensive 360-degree conduit inspections, and the vacuuming module meets the negative pressure requirements for efficient absorption of dust and foreign matter. The robot has met the expected design goals, effectively enhanced the automation of the cable conduit construction process, and improved the quality control of cable laying.

Incoherent fermionic dark matter absorption with nucleon Fermi motion

We investigate the incoherent regime of the fermionic dark matter absorption by nuclei using the relativistic Fermi gas model and nuclear form factors. With the momentum transfer being roughly equal to the dark matter mass mχ, the incoherent regime contributes significantly to the absorption process for mχ≳100 MeV with a spin-independent operator and for even smaller mass with a spin-dependent one. We also compare the situations for various target nuclei (Xe131, Ge72, Ar40, Ne20, and He4) that are typically used in the dark matter direct detection. A heavier nucleus actually has the advantage of probing the incoherent scattering of the fermionic absorption dark matter. Observing both the coherent and incoherent contributions would be an important justification of the fermionic dark matter absorption. Published by the American Physical Society 2024

Modeling compact objects with quark matter and dark energy: A comparative study of the radial oscillation modes of HESS J1731-347 and PSR J0740+6620

We model the massive pulsar J0740+6620 and the light HESS J1731-347 compact object assuming (i) quark matter and (ii) dark energy stars. Within Einstein’s General Relativity, and assuming objects made of isotropic matter, we adopt analytic equations-of-state for both matter contents. Although the inner composition of the objects is very different in each case, both equations-of-state imply qualitatively very similar mass-to-radius relationships. We compute the spectra of radial equations for all four cases and the corresponding wave functions as well as the large frequency separations. A comparison between the different matter contents is made as well.

Intradermal Delivery of Calcium Hydroxylapatite With Fractionated Ablation.

The absorption of biostimulatory particulate matter following its application to fractional skin defects remains poorly understood, and even less is known about its in vivo impact in terms of tissue integration. The objectives of this study are twofold: (1) to evaluate the potential of calcium hydroxylapatite (CaHA) to penetrate through skin treated with a fractional laser; and (2) to assess the effectiveness of clinical laser scanning microscopy technologies in monitoring the effects of such treatment over time. One area on a volunteer's arm was treated with a fractional erbium laser (Sciton Inc., Palo Alto, CA), while a second area received the same laser treatment followed by CaHA topical application. We used reflectance confocal microscopy (RCM) and multiphoton microscopy (MPM) to noninvasively image beneath the surface of the treated skin to study and monitor the effects of these treatments within 1 h of treatment and at four additional time points over a 6-week period. One hour posttreatment, at different depths beneath the skin surface, MPM and RCM provided similar visualizations of laser-induced channels. In skin treated by both laser and CaHA, these two imaging methods provided complementary information. RCM captured the lateral and depth distribution of CaHA microspheres and were seen as bright spheres as they became incorporated into the healing tissue. MPM, meanwhile, visualized the CaHA microparticles as dark shadow spheres within the laser-induced channels and encroaching healing tissue. Furthermore, MPM provided critical information about collagen regeneration around the microspheres, with the collagen visually marked by its distinct second harmonic generation (SHG) signal. This observational pilot study demonstrates that CaHA, a collagen stimulator used as a dermal filler, can not only be inserted into the dermis after fractional laser treatment but remains in the healing skin for at least 6 weeks posttreatment. The noninvasive imaging techniques RCM and MPM successfully captured the presence of CaHA microspheres mid-dermis during the healing phase. They also demonstrated new collagen production around the microspheres, highlighting the effectiveness of these imaging approaches in monitoring such treatment over time.

Removal of organic matter from food wastewater using anaerobic digestion at low temperatures enhanced by exogenous signaling molecule N-hexanoyl-homoserine lactone enhancement: Insight to extracellular polymeric substances and key functional genes

This experiment aimed to study the effects of adding the exogenous signaling molecule N-hexanoyl-homoserine lactone (C6-HSL) on the anaerobic digestion of food wastewater at low temperature (15 °C). Daily addition of 0.4 μmol C6-HSL increased the average chemical oxygen demand removal from 45.98% to 94.92%, while intermittent addition (adding 2 μmol C6-HSL every five days) increased it from 45.98% to 72.44%. These two modes of C6-HSL addition increased protease and acetate kinase activity by 47.99%/8.04% and 123.26%/127.91% respectively, and increased coenzyme F420 concentrations by 15.79% and 63.16%, respectively. The regulation of loosely bound extracellular polymeric substances synthesis was influenced by C6-HSL, which increased protein and polysaccharide content in sludge. The relative abundance of Firmicutes and Bacteroidetes increased following addition of C6-HSL. After continuous addition of C6-HSL, the relative abundance of related functional genes such as amy, apgM, aceE, and accC increased, indicating that methanogens obtained sufficient substrate. The abundance of glycolysis-related functional genes such as glk, pfk, pgi, tpiA, gap, pgk, gpmA, eno, and pyk increased after the addition of C6-HSL, ensuring the efficient transformation and absorption of organic matter by anaerobic sludge at low temperatures. This study provides new comprehensive insights into the mechanism behind the enhancement of food wastewater anaerobic digestion by C6-HSL at low temperature.

Transient absorption of warm dense matter created by an X-ray free-electron laser

Warm dense matter is at the boundary between a plasma and a condensed phase and plays a role in astrophysics, planetary science and inertial confinement fusion research. However, its electronic structure and ionic structure upon irradiation with strong laser pulses remain poorly understood. Here, we use an intense and ultrafast X-ray free-electron laser pulse to simultaneously create and characterize warm dense copper using L-edge X-ray absorption spectroscopy over a large irradiation intensity range. Below a pulse intensity of 1015 W cm−2, an absorption peak below the L edge appears, originating from transient depletion of the 3d band. This peak shifts to lower energy with increasing intensity, indicating the movement of the 3d band upon strong X-ray excitation. At higher intensities, substantial ionization and collisions lead to the transition from reverse saturable absorption to saturable absorption of the X-ray free-electron laser pulse, two nonlinear effects that hold promise for X-ray pulse-shaping. We employ theoretical calculations that combine a model based on kinetic Boltzmann equations with finite-temperature real-space density-functional theory to interpret these observations. The results can be used to benchmark non-equilibrium models of electronic structure in warm dense matter.

Suitability of different in-water algorithms for eutrophic and absorbing waters applied to Sentinel-2 MSI and Sentinel-3 OLCI data

Optically complex waters present significant challenges for remote sensing due to high concentrations of optically active substances (OASs) and their inherent optical properties (IOPs), as well as the adjacency effect. OASs and IOPs can be derived from atmospheric correction processors’ in-water algorithms applied to data from Sentinel-2 MultiSpectral Instrument (S2 MSI) and Sentinel-3 Ocean and Land Color Instrument (S3 OLCI). This study compared S3 OLCI Level-2 in-water products for Case-2 waters with alternative in-water algorithms derived from ACOLITE, POLYMER, C2RCC, and A4O. Fifty in-water algorithms were evaluated using an extensive match-up dataset from lakes and coastal areas, focusing particularly on small lakes with high colored dissolved organic matter absorption at 442 nm (up to 48 m-1). The Chl a band ratio introduced by Gons et al. (2022) applied to data processed by ACOLITE performed best for S3 OLCI Chl a retrieval (dispersion = 23%, bias = 10%). Gons et al. (2022) band ratio also showed consistent agreement between S3 OLCI and S2 MSI resampled data (intercept of 6.27 and slope of 0.83, close to the 1:1 line); however, lower Chl a values (&amp;lt;20 mg/m3) were overestimated by S2 MSI. When estimating errors associated with proximity to land, S2 MSI Chl a in-water algorithms had higher errors close to the shore (on average 315%) compared to S3 OLCI (on average 150%). Chl a retrieved with POLYMER had the lowest errors close to the shore for both S2 MSI and S3 OLCI data (on average 70%). Total suspended matter (TSM) retrieval with C2RCC performed well for S2 MSI (dispersion 24% and bias −12%). Total absorption was most accurately derived from C2RCC applied to S3 OLCI L1 data (dispersion &amp;lt; 43% and bias &amp;lt; −39%), and it was better estimated than its individual components: phytoplankton, mineral particles, and colored dissolved organic matter absorption. However, none of the colored dissolved organic matter absorption in-water algorithms performed well (dispersion &amp;gt; 59% and bias &amp;lt; −29%).

Effect of Einasto spike and isothermal dark matter density profile on the geometry of wormhole in [formula omitted] gravity

In the present article, we uncover striking properties of traversable wormhole solutions generated under a newly developed f(ℜ,Lm) gravitational theory. Two distinct dark matter density profiles—the Einasto spike and the Pseudo-isothermal model—are employed to demonstrate the existence of stable wormhole geometries with throat radii of 1.18 km and 1.41 km, respectively. Through a rigorous analytical and plot-based survey, we delve deeper into the exotic matter characteristics of these wormhole structures and analyze their matter content in the context of energy conditions. Impressively, both wormhole models exhibit an adiabatic index greater than 1.34 (Γ>43), indicating their inherent stability. What is more, our study of the anisotropy parameter reveals the attractive nature of these wormhole solutions, a crucial property for their potential traversability. This novel work not only broadens our understanding of modified gravity theories but also highlights the remarkable possibilities of traversable wormholes, opening up new avenues in theoretical physics and in the exploration of exotic spacetime geometries.

Migdal-type effect in the dark matter absorption process

We propose a new mechanism of absorption of dark matter particles in atoms which resembles the Migdal effect of inelastic dark matter scattering. In this process, atoms may be ionized upon absorption of a scalar particle through the scalar-nucleon Yukawa-type interaction. The crucial difference from the inelastic dark matter scattering on atoms is that the total energy of the particle, including its rest mass mc2 term, is transferred to the electron. As a result, the emitted electron kinetic energy is about 6 orders in magnitude bigger than that in the dark matter scattering process. This absorption process allows one to probe dark matter particles with a relatively small mass, in the range from 1 to 100 keV, that cannot be detected in the scattering process. It is also possible to detect hypothetical scalar particles emitted from the Sun. We calculate absorption cross sections of this process in Na, Si, Ar, Ge, I, Xe, and Tl target atoms and extract limits on the scalar-nucleon interaction constant from null results of the XENONnT experiment. Published by the American Physical Society 2024

Research on COD parameter in water based on the combination of UV absorption photometry and laser spectroscopy

Chemical Oxygen Demand (COD) is widely utilized as a representative and required measurement indicator of water pollution as well as water quality monitoring. The spectral technology is an important development direction in water quality detection. In this paper, a novel COD monitoring instrument is designed based on ultraviolet (UV) absorption photometry and laser spectroscopy. The instrument consists of CODcr and CODmn detection modules. The CODcr module is based on the Lambert-Beer law to measure UV absorption of organic matter in water, which can be used to measure the COD parameter in high concentration organic pollution in water. The CODmn module is based on the ratio method of fluorescence and Raman to analyze the spectral signals generated by the laser-excited water body, which can determine the COD parameter in low contaminated water. By analyzing the CODcr and CODmn parameters together, the comprehensive evaluation of organic pollutants in water can be realized. In the experiment, the CODcr and CODmn modules are respectively calibrated with the potassium hydrogen phthalate (KHP) solution as well as the mixed solution of humic acid sodium and glucose. Then the stabilities of the two detection modules are tested, and the detected result drifts are stable within six days. In addition, to verify the reliability of measuring results in complex environments, we test the instruments at 10 monitoring sites of the Sow River in Weihai city. The results of on-site monitoring are highly consistent with those of national standard method. The study result shows that the instrument developed in this paper can measure both CODcr and CODmn simultaneously, which can expand the COD detection range, and provide a new method for the comprehensive detection of organic pollutants in water.

Compositional differences of near-critical petroleum from closed pores to wellhead in Gulong shale oil play, Songliao Basin, NE China

The Gulong shale oil play located in northern Songliao Basin is a promising exploration target in China. Member 1 of Qingshankou Formation (Well H) with high thermal maturity was preferred to obtain pressure-retained cores, long-time exposed cores, and produced petroleum (crude oil and gas). The selected samples were subjected to sequential extraction, GC, GC-MS, thermal desorption–gas chromatography (TD-GC) and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) analysis. The compositional differences of in-situ fluids, residual bitumen trapped in open, confined, and closed pores, as well as wellstream, were systematically investigated. (1) In-situ fluid compositions, with a 30.8% proportion of nC1−5 in n-alkanes, were studied by TD-GC analysis on pressure-retained cores. Interestingly, limited amounts of C8- compounds were detected in long-time exposed bulk cores but were almost absent in exposed powder. Primally poor pore connectivity and partially adsorption or absorption of organic matter contribute to the retention of gaseous hydrocarbons. (2) Sequential extraction is a best method for obtaining compositions of fluid in pores with variable sizes. Aliphatic compounds of residual bitumen trapped in open pores are similar to those in confined pores, while polar compounds are more enriched in confined and closed pores. Originally connected pores in early oil window, has turned into confined or closed pores by compaction and cementation with increasing depth. (3) Wellstream compositions are significantly different from in-situ fluid compositions, especially in shale oil extraction. The proportion of gaseous hydrocarbons in the wellstream (76.2%) is considerably higher than that of in-situ fluids (34.1%). Comparison of aromatic hydrocarbons indicated that the wellstream is sourced from free fluids and partially adsorbed hydrocarbons in open pores. (4) Nitrogen and oxide compounds with a higher degree of condensation (higher DBE value) have poor movability, leading to extremely low content or even absence in crude oil. The compositional differences from in-situ fluids to the wellbore through the stimulated fractures are caused by selective adsorption of pore walls, confinement effect of nanopores and fluid phase changing. This study provides a window to the compositional differences of fluids released from different occurrence spaces and confirms compounds heterogeneity.

Trace Conservation Laws in T2/Zm Orbifold Gauge Theories

Abstract Gauge theory compactified on an orbifold is defined by gauge symmetry, matter contents, and boundary conditions (BCs). There are equivalence classes (ECs), each of which consists of physically equivalent BCs. We propose the powerful necessary conditions, trace conservation laws (TCLs), which achieve a sufficient classification of ECs in U(N) and SU(N) gauge theories on T2/Zm orbifolds (m = 2, 3, 4, 6). The TCLs yield the equivalent relations between the diagonal BCs without relying on an explicit form of gauge transformations. The TCLs also show the existence of off-diagonal ECs, which consist only of off-diagonal matrices, on T2/Z4 and T2/Z6. After the sufficient classification, the exact numbers of ECs are obtained.

Axion domain walls, small instantons, and non-invertible symmetry breaking

Non-invertible global symmetry often predicts degeneracy in axion potentials and carries important information about the global form of the gauge group. When these symmetries are spontaneously broken they can lead to the formation of stable axion domain wall networks which support topological degrees of freedom on their worldvolume. Such non-invertible symmetries can be broken by embedding into appropriate larger UV gauge groups where small instanton contributions lift the vacuum degeneracy, and provide a possible solution to the domain wall problem. We explain these ideas in simple illustrative examples and then apply them to the Standard Model, whose gauge algebra and matter content are consistent with several possible global structures. Each possible global structure leads to different selection rules on the axion couplings, and various UV completions of the Standard Model lead to more specific relations. As a proof of principle, we also present an example of a UV embedding of the Standard Model which can solve the axion domain wall problem. The formation and annihilation of the long-lived axion domain walls can lead to observables, such as gravitational wave signals. Observing such signals, in combination with the axion coupling measurements, can provide valuable insight into the global structure of the Standard Model, as well as its UV completion.

General perturbations in D+1 standard and brane cosmology revisited

In this work, we generalize the theory of perturbations in a ([Formula: see text])-dimensional space–time with cosmological constant, studying scalar, vector and tensor perturbations, as well as its structure in Newtonian and Synchronous gauge. We also show the theory of perturbations in the context of brane cosmology, where branes are embedded in a set of D-spatial dimensions, a temporal dimension, and an additional spatial dimension. In both standard and brane cosmology, an unperturbed space–time is provided with a Friedmann–Lemaitre–Robertson–Walker metric and arbitrary sectional curvature, the matter content has the shape of a perfect fluid. In addition, we consider the arbitrary sectional curvature, obtaining the respective equations in the Newtonian and Synchronous gauge. We highlight that the results presented in this paper can be used to treat brane cosmology with two concentric branes or tackle the [Formula: see text] tension with a braneworld approach. Finally, as an example of the utility of all the technology presented in this paper, we show an application to the energy flux and the repercussions in the framework of the braneworlds.