Quartz Matrix Research Articles

Mechanical properties and microstructure of quartz fiber-reinforced silica matrix composite with a single layer pyrocarbon interphase

Silica matrix composites (SiO2f/SiO2), reinforced with pyrolytic carbon (PyC) interfacial layers, were synthesized using the precursor impregnation and pyrolysis (PIP) method, mechanical properties and microstructure of these composites were thoroughly investigated. The flexural strength of SiO2f/PyC/SiO2 composites exceeded 55 MPa after treatment at 450°C. Notably, at medium and high temperatures, strength of SiO2f/SiO2 composites was significantly enhanced compared to that of uncoated PyC composites. The experimental resulted indicate that PyC temporary interfacial layer effectively mitigated the strong interfacial reaction between quartz fibers and matrix. Furthermore, fiber pull-out phenomenon observed at the fracture of SiO2f/PyC/SiO2 composites suggested that interfacial bonding was weak, which contributed to the high mechanical strength of these composites.

Arsenopyrite from the Low-sulphidation Sedefche Au-Ag deposit, Eastern Rhodopes: Mineral Association and Gold Potential

The Sedefche Au-Ag deposit is located in the eastern Rhodopes, Bulgaria and is part of the Zvezdel-Pcheloyad ore field. The deposit is of low-sulphidation epithermal type, hosted in Oligocene highly silicificated intermediate volcanic tuffs, which lie above shallow marine sediments of organogenic limestones. The orebody has stratiform shape partly outcroping onto the surface. The ore mineralization is represented by small crystals and fine grained aggregates of sulphides (mainly pyrite, arsenopyrite, marcasite, chalcopyrite, galena, sphalerite) and associated sulphosalts (tetrahedrite, pyrargyrite, freibergite, and miargyrite) within matrix of quartz, formed in several stages of deposition. Gold in the deposit is detected in significant amounts in bulk ore samples, while native gold (a single < 1 μm gold nugget) and gold-bearing phases were sporadically discovered. The form of gold presence in the deposit is nevertheless debatable. Using combined SEM-EDS, EPMA and LA-ICP-MS approach, the highest concentrations of gold have been established in the arsenopyrite – the gold content there is up to hundredfold higher than in other ore minerals being potential concentrators of gold such as pyrite, marcasite and chalcopyrite. The presence of gold in arsenopyrite predominantly as nanoparticles, irregularly disseminated in the crystals as clusters of inclusions is suggested.

High-grade metamorphism of banded iron formations: the role of saline fluids in promoting the growth of pyroxene and garnet reaction textures along magnetite-quartz grain boundaries

Metamorphosed banded iron formation (BIF) in granulite-amphibolite facies, tonalitic orthogneisses from a series of locations in the Kolli Massif of southern India are described and analysed with regard to their lithologies, whole rock chemistry, mineral reaction textures, and mineral chemistry. On the basis of their mineral reaction textures along magnetite-quartz grain boundaries these BIFs are grouped according to their predominant silicate mineralogy: 1) amphibole; 2) orthopyroxene; 3) orthopyroxene–clinopyroxene; 4) orthopyroxene-clinopyroxene-garnet; 5) clinopyroxene-garnet-plagioclase; and 6) Fe-Mg silicates are absent. Two-pyroxene and garnet-pyroxene Fe-Mg exchange thermometry, coupled with thermodynamic pseudo-section modelling of whole rock data from one of the magnetite-quartz-orthopyroxene-clinopyroxene-bearing lithologies, indicates that the magnetite-quartz-orthopyroxene-clinopyroxene-garnet assemblages formed at ~900 to 1200 MPa and 750 to 900 °C under relatively low H2O activities. Magnetite-quartz-orthopyroxene reaction textures were experimentally replicated at 800 and 900 °C and 1000 MPa in a synthetic BIF using isolated magnetite grains in a quartz matrix to which was added a hypersaline Mg- and Al-bearing fluid (approximately 1% by mass), which permeated along all the grain boundaries. The fact that Fe-Mg silicate reaction textures did not form in one of the BIF samples, which had experienced the same P-T conditions as the other BIF samples, suggests that, unless a BIF initially incorporated Mg, Al, and Ca during formation with or was infiltrated from the surrounding rocks by Mg-, Al-, and Ca-bearing saline fluids, these silicate minerals could not and would not have formed from the inherent magnetite and quartz during granulite-facies and amphibolite-facies metamorphism.

Lednevite, Cu[PO<SUB>3</SUB> (OH)]·H<SUB>2</SUB>O, a new mineral from Murzinskoe Au deposit, Altai Krai, Russia

Lednevite, ideally Cu[PO3(OH)]·H2O, is a new mineral discovered at the 255 m level of the Murzinskoe Au deposit, Krasnoshchyokovskiy District, Altai Krai, Western Siberia, Russia. It forms spherulites up to 0.1 mm in diameter, composed of very thin fibers and grouped in aggregates up to 1.5 mm across. Lednevite overgrows philipsburgite crystals on a matrix of epidote-andradite skarn and quartz and associates with malachite, chrysocolla, kaolinite, goethite and P-bearing cornubite. The new mineral is transparent, has sky blue color, very pale blue streak and vitreous lustre. Cleavage is not observed. The Mohs’ hardness is ~3. Dmeas = 3.18(2) g cm–3, Dcalc = 3.196 g cm–3. The chemical composition of lednevite is (electron microprobe, wt.%; H2O by stoichiometry): CuO 40.20, ZnO 3.92, P2O5 36.29, As2O5 4.80, H2O 14.98, total 100.15. The empirical formula calculated on the basis of 3 H and 5 O apfu is (Cu0.91Zn0.09)Σ1.00[(P0.92As0.08)Σ1.00O3(OH)]·H2O. The crystal structure was refined by the Rietveld method to Rp = 0.0042, Rwp = 0.0061, Robs = 0.0354. Lednevite is monoclinic, space group P21/a, with a = 8.6459(6), b = 6.3951(4), c = 6.8210(5) A, β = 93.866(2)°, V = 376.28(4) A3 and Z = 4. The strongest lines of the powder X-ray diffraction pattern [d, A (I, %) (hkl)] are: 5.135 (100) (110), 4.648 (33) (011), 3.241 (28) (21-1), 3.095 (49) (211), 2.891 (27) (11-2), 2.775 (53) (112), 2.568 (29) (220). The new mineral is isotypic to the synthetic CuHPO4·H2O. Some optical and spectroscopic data, which could not be obtained on natural sample, were obtained from the synthesized material. The crystal structure of the synthetic analogue of lednevite was solved from single-crystal X-ray diffraction data and refined to R1 = 0.0173 for 1159 independent reflections with I 2σ(I). All positions of H atoms were determined. Lednevite is named for Vladimir Sergeevich Lednev, amateur mineralogist from Barnaul (Altai Krai) who collected the sample with the new mineral.

Analysis of Influence of Sand Matrix on Properties of Moulding Compounds Made with Furan Resin Intended for 3D Printing

Binder jetting (BJ) sand printing is a 3D printing process in which a sand mould or sand core is produced from an STL file. A single layer of a sand matrix consisting of one or more grains in height of sand is applied to a worktable, and then a liquid resin or binder is applied to bond the grains together. This process is repeated until the final result matches the CAD model. The sand matrix is the main component of ceramic cores and moulds. The present study aims to demonstrate the influence of the matrix used on the properties of the resulting moulding sand. Three types of sand matrices were selected for the study. The first was a quartz matrix for 3D printing with binder jetting; this is characterised by a sharp geometry that allows for proper layering during printing. Ordinary quartz sand was also used for the study; this type of sand is usually used for the production of sand cores in the hotbox process, among other things. The shape of this sand is irregular. The last matrix to be tested was Cerabeads sand; this was selected because its spherical geometry clearly distinguishes it from the other two matrices. The matrices were analysed for their grain sizes. Scanning electron microscope images were also taken to compare the geometries and chemical compositions of the respective matrices. In presented research utilises a sand matrix for the production of self-curing compounds with furan resin dedicated for binder jetting 3D printing. The moulding masses were produced in a laboratory circulation mixer. The laboratory moulds were produced with wooden core boxes and pre-compacted by vibration. The samples from the matrix for the 3D printing were produced using the binder jetting method. The samples were produced to determine the flexural strength, tensile strength, gas permeability, hot distortion, and apparent density. It was not possible to carry out tests for the Cerabeads sand, as the obtained moulds were too brittle to perform adequate tests. Tests with the other matrices have shown that the shape and size of the matrix affect the apparent density and gas permeability.

The effect of weathering on cohesion in granitic fault rocks: A case study from the Yeongdeok Fault, South Korea

Weathering can alter fault-rock cohesion, which is an important criterion in the classification of fault rocks, and can also alter fault-rock mechanical and hydraulic properties. To investigate the effects of weathering on fault rocks, we studied relatively fresh and weathered fault rocks collected from a drill core and outcrop, respectively, of a granitic fault zone (the Yeongdeok Fault, a northern branch of the Yangsan Fault) on the southeastern Korean Peninsula. At the studied outcrop, the Yeongdeok Fault has juxtaposed Triassic granite against Cretaceous sedimentary rocks. Granitic fault rocks in the outcrop are incohesive, whereas the drill core includes both cohesive and incohesive granitic fault rocks. A detailed correlation of the fault rocks from the drill core with those from the outcrop reveals that some incohesive fault rocks from the outcrop are weathered cataclasite. Cataclasites from the drill core are composed of feldspar, plagioclase, and quartz fragments embedded in a matrix of quartz, plagioclase, muscovite, and chlorite. Locally, foliation defined by the preferred orientation of muscovite is developed. The weathered cataclasite comprises quartz, plagioclase, and feldspar fragments, with a fine-grained matrix composed mostly of clay minerals. The measured Chemical Index of Alteration (CIA) values for cataclasite and weathered cataclasite are 47–49 and 60–67, respectively. Measurements of hydraulic properties show that weathered cataclasite has higher porosity and permeability compared with unweathered cataclasite. Physical and chemical weathering are interpreted to have increased the fracture density of the weathered cataclasite and enhanced the dissolution of vein minerals, respectively. These processes have not only contributed to the higher permeability and porosity of the weathered (cf. unweathered) cataclasite but have also resulted in a loss of cohesion. When cohesion is lost due to weathering, distinguishing between cataclasite and fault breccia becomes challenging. Our study demonstrates that the cohesion-based classification of fault rocks becomes limited for fault rocks with CIA value more than 60.

Galactosamine and mannosamine are integral parts of bacterial and fungal extracellular polymeric substances.

Extracellular polymeric substances (EPS) are produced by microorganisms and interact to form a complex matrix called biofilm. In soils, EPS are important contributors to the microbial necromass and, thus, to soil organic carbon (SOC). Amino sugars (AS) are used as indicators for microbial necromass in soil, although the origin of galactosamine and mannosamine is largely unknown. However, indications exist that they are part of EPS. In this study, two bacteria and two fungi were grown in starch medium either with or without a quartz matrix to induce EPS production. Each culture was separated in two fractions: one that directly underwent AS extraction (containing AS from both biomass and EPS), and another that first had EPS extracted, followed then by AS determination (exclusively containing AS from EPS). We did not observe a general effect of the quartz matrix neither of microbial type on AS production. The quantified amounts of galactosamine and mannosamine in the EPS fraction represented on average 100% of the total amounts of these two AS quantified in cell cultures, revealing they are integral parts of the biofilm. In contrast, muramic acid and glucosamine were also quantified in the EPS, but with much lower contribution rates to total AS production, of 18% and 33%, respectively, indicating they are not necessarily part of EPS. Our results allow a meaningful ecological interpretation of mannosamine and galactosamine data in the future as indicators of microbial EPS, and also attract interest of future studies to investigate the role of EPS to SOC and its dynamics.

Self-attenuation correction by transmission method in different geological samples using MCNP

Gamma ray spectrometry of volume sample involves sample matrix that acts as source as well as absorber. In this paper, Monte Carlo simulation using MCNP4C code is used to determine self-attenuation correction, Cutshall factor and Cutshall revision factor for geological volume samples using transmission method. Dependence of Cutshall factor on composition, quantity, packing density and U3O8 concentration of sample is studied by simulating 152Eu point source over various samples in a plastic container. It is observed that Cutshall factor satisfactorily estimates the self-attenuation for quartz, Gulcheru quartzite, granite and Gogi limestone. For samples of varying quantity having same density, relation between Cutshall revision factor and Cutshall factor is obtained. No variation in Cutshall factor is observed with packing density. Thus, a relation between self-attenuation correction and height of sample is obtained. Variation of Cutshall factor with concentration of U3O8 is also studied by varying the concentration of U3O8 in quartz matrix from 0.26% to 15%.

Provenance of Volcanogenic Deposits from the Shanxi Formation of the Daniudi Gas Field, Ordos Basin, and Its Tectonic Implications

Through detailed drill-core description, petrography, cathodoluminescence imaging, and geochemistry analysis, sedimentary deposits with a high content of volcanogenic components (27.6%) were discovered in the Shanxi Formation of the Daniudi Gas Field, Ordos Basin. The volcanogenic components include volcanogenic quartz, lava fragments (dominated by rhyolite fragments), tuff fragments, and tuffaceous matrix. In addition, at least two volcanic ash layers were discovered. Although the metamorphic rocks of the Precambrian succession in the ancient land of Yin Mountain are usually considered the primary source of the Shanxi formation, it is most likely that the volcanogenic components were derived from intermediate-acid volcanic materials that accumulated in the Daqingshan area during the Late Carboniferous to Early Permian. Those volcanogenic components are mainly transported by flowing water rather than by air from origin to basin. In addition, the accumulation of volcanic materials in the Daqingshan area was controlled by volcanic eruptions occurring solely in this area, rather than by the Inner Mongolia Orogenic Belt. Those volcanic eruptions were related to the southward subduction of the Paleo-Asian Ocean Plate beneath the northern margin of the North China Plate in the Late Carboniferous to Early Permian. The active continental margin related to the subduction of the Paleo-Asian Ocean Plate lasted at least until the Early Permian, and the closure of the Paleo-Asian Ocean must have occurred later than the Early Permian.

Porphyry and Epithermal Au-Cu Systems of the Southern Caucasus and Northern Iran

This article presents tangible geological evidence for coexistence of porphyry copper and epithermal gold systems within single polygenic deposits and provides a paleothermophysical model for their origins. Brief metallogenic analysis of the Southern Caucasus and Northern Iran has shown that such deposits are confined to long-living calc-alkaline island arcs and were formed during their orogenesis. Examples of complex Sonajil (Iran), Gharta, and Merisi (Georgia) deposits are considered. Investigation has shown that for combined porphyry and epithermal ore formation some preconditions are suggested to exist: (i) Source of anomalous energy, which exceeds thermodynamics of the enclosing environment; (ii) Existence of temperature gradient, which determines conventional flows of fluids composed of endogenous and meteoric constituents (proven by rhythmical zoning of ore lodes); (iii) Stability of such conditions for a period of sulfide ore formation. However, such a process of sulfide ore formation cannot explain formation of high sulfidation gold deposits. Mass precipitation of free gold requires phreatic collapse in the ore conduit channel already after formation of hydrothermally altered rocks, and this event results in creation of either hydrothermal breccias, often with jigsaw-fit texture or brecciated vuggy silica where host rocks and hydrothermally altered rocks are cemented by a gold-bearing quartz matrix.

Genesis of Devonian volcanic-associated Lahn-Dill-type iron ores — part I: iron mobilisation and mineralisation style

Fe-oxide deposits of the Lahn-Dill-type in the eastern Rhenish Massif comprise haematite and quartz with minor siderite, magnetite, and calcite. The deposits are located in the hanging wall of thick volcaniclastic rock sequences and mark the Middle to Late Devonian boundary. Varying ore types with accompanying footwall rocks were sampled from two formerly important ore deposits, the Fortuna mine (Lahn syncline) and the Briloner Eisenberg mine (East Sauerland anticline), in order to elucidate the interplay of processes leading to ore formation. Deposit geology, petrography, and whole-rock geochemistry suggest that the ores formed by iron mobilisation from deeply altered footwall volcaniclastic rocks, subsequent venting of a modified H2O-CO2-Fe-rich and H2S-poor fluid, and precipitation on the seafloor (sedimentary-type), or locally by metasomatic replacement of wall rocks (replacement-type). Petrographic analysis to the sub-micron scale revealed that the sedimentary-type ores most likely formed from a Fe-Si-rich gel and accompanying maturation. Early gel textures include the presence of spherules, aggregates, tubes, and filamentous stalks consisting of nanocrystalline haematite dispersed in a matrix of microcrystalline quartz. Local diagenetic Fe3+ reduction within the gel is indicated by siderite replacement of haematite. Replacement-type ores formed due to a two-step process including coprecipitation of (precursor) haematite and carbonates and subsequent metasomatic replacement by haematite. These ore-forming processes took place during a time when several restricted shallow marine basins in the north-eastern Rheic Ocean were influenced by extensive volcanism and associated hydrothermal fluid flux. Examples of similar volcanic-associated Fe-oxide occurrences of Silurian to Carboniferous age can be categorised as being of Lahn-Dill-type ores as well.

Different Cooling Histories of Ultrahigh-Temperature Granulites Revealed by Ti-in-Quartz: An Electron Microprobe Approach

The cooling history of granulite is crucial to understanding tectonic scenarios of the continental crust. Ti-in-quartz, a useful indicator of temperature, can decipher the thermal evolution of crustal rocks. Here we apply the Ti-in-quartz (TitaniQ) thermometer to ancient ultrahigh-temperature (UHT) granulites from the Khondalite Belt (KB) in the North China Craton (NCC) and young UHT granulites from the Mogok Metamorphic Belt (MMB), Myanmar. Ti content in quartz was analyzed using a highly precise method constructed in a CAMECA SXFive electron probe microanalyzer (EPMA). The granulites from the two localities show different quartz Ti contents with a constant deforced beam of 10 μm. Matrix quartz and quartz inclusions from the NCC granulites have 57–241 ppm and 65–229 ppm, respectively, corresponding to the TitaniQ temperatures of 653–810 °C and 666–807 °C. The calculated temperatures are significantly lower than the peak temperatures (850–1096 °C) obtained by other methods, due to the formation of abundant rutile exsolution rods in quartz during cooling. Thus, the low calculated temperatures for the NCC granulites reflect a cooling state near or after the exsolution of rutile from quartz, most likely caused by a slow cooling process. However, the matrix quartz from the MMB granulites is exsolution-free and records higher Ti contents of 207–260 ppm and higher metamorphic temperatures of 894–926 °C, close to the peak UHT conditions. This feature indicates that the MMB granulites underwent rapid cooling to overcome Ti loss from quartz. Therefore, determining the amount of Ti loss from quartz by diffusion can provide new insight into the cooling behavior of UHT granulites. When a large deforced beam of 50 μm was used to cover the rutile rods, the matrix quartz in the KB granulites could also yield the TitaniQ temperatures above 900 °C. Thus, our new data suggest that the TitaniQ thermometer could be useful for revealing UHT conditions.

Two-Dimensional Correlation IR Spectroscopy of Humic Substances of Chernozem Size Fractions of Different Land Use

Diffuse reflectance FTIR measurements with two-dimensional correlation spectroscopy (2D-COS) are used for accurate band identification of chernozem comprising soil organic matter (SOM), including humic substances and mineral silicate matrix. Samples of different land use (native steppe, shelterbelt, bare fallow, and arable land) of a long-term field experiment were compared. Homospectral 2D-COS maps for size fractions obtained by wet fractionation were built, and the fraction size was used as a correlation-building variable (external perturbation) of 2D-COS. Synchronous 2D-COS maps are characterized by main correlation regions at 4000–3600 (hydrogen bonds), 1800–1150 (SOM), and 1100–200 cm−1 (quartz matrix). SOM range can be used as a signature of the samples distinguishing two pairs, native steppe–bare fallow and arable land–shelterbelt, by correlations at 1340–1320 cm−1 (CH2) and 1670 cm−1 (aromatic –C=C–). Asynchronous 2D-COS maps show bands at 3690–3620, 2930–2830, in the range of 1640–1250 (8 bands), 1160, 1070, 797, 697, 505, and 400 cm−1, the latter 5 indicate the increasing proportion of silicate to quartz in small fractions. The manifestation of asynchronous correlation bands at 1650, 1580–1560, 1444, 1340, and 1250 cm−1, which have no major contribution from inorganic soil components, are due to carbonyl, carboxylate, and aromatic C–C; their appearance order (accumulation of corresponding substances in larger factions) is different for each land use. The proposed approach provides the identifying SOM components with enough reliability for SOM IR bands that are weaker compared to mineral matrix bands in original IR spectra.

The Possible Role of Anoxic Alkaline High Subcritical Water in the Formation of Ferric Minerals, Methane and Disordered Graphitic Carbon in a BARB3 Drilled Sample of the 3.4Ga Buck Reef Chert.

The present article reports Raman spectroscopic observations of siderite, hematite, disordered graphitic carbon and possibly greenalite inside the quartz matrix of a banded iron sample from the BARB3 core drilled inside the 3.4Ga Buck Reef Chert of the Barberton Greenstone Belt in South Africa. The article also reports Raman spectroscopic observations of quartz cavities, concluding in the presence of water, methane and sodium hydroxide at high concentration leading to pH ~ 15 inside the inclusion, suggesting an Archean water which was strongly basic. FeIII-greenalite may also be present inside the inclusion. The possible role of anoxic alkaline high subcritical water in the formation of ferric minerals and the CO required for the synthesis of molecules of biological interest has been demonstrated theoretically since 2013 and summarized in the concept of Geobiotropy. The present article experimentally confirms the importance of considering water in its anoxic strongly alkaline high subcritical domain for the formation of quartz, hematite, FeIII-greenalite, methane and disordered graphitic carbon. Methane is proposed to form locally when the carbon dioxide that is dissolved in the Archean anoxic alkaline high subcritical water, interacts with the molecular hydrogen that is emitted during the anoxic alkaline oxidation of ferrous silicates. The carbon matter is proposed to form as deposition from the anoxic methane-rich fluid. A detailed study of carbon matter from diverse origins is presented in a supplementary file. The study shows that the BARB3_23B sample has been submitted to ~ 335°C, a temperature of the high subcritical domain, and that the graphitic structure contains very low amounts of oxygen and no hydroxyl functional groups. The importance of considering the structure of water is applied to the constructions of the Neoproterozoic and Archean banded iron formations. It is proposed that their minerals are produced inside chemical reaction chambers containing ferrous silicates, and ejected from the Earth's oceanic crust or upper mantle, during processes involving subduction events or not.

XCT analysis of drill cores of Opalinus clay and determination of sample size for effective properties evaluation

In Switzerland, the Opalinus Clay unit was chosen as host rock for a repository for nuclear waste and has recently been investigated in a deep drilling campaign at possible repository construction sites. X-ray images of drill cores were compiled into virtual rock columns and were statistically analyzed with respect to layered compositional variations. This provides insight into scale-dependent homogenization and improves sampling strategy. To predict the repository behavior, using continuum-based models of Opalinus Clay, requires the knowledge of effective properties related to a minimum volume at which Opalinus Clay behaves homogeneously. It turned out that with respect to rock composition, such a volume does not exist in the sense that a single sample of manageable size provides a reliable mean composition. This is because the variation of the cm to dm thick layers, which differ in composition, does not sufficiently homogenize even at the 10-m scale. Thus, effective properties must be obtained by averaging several handleable samples. Regarding the composition of Opalinus Clay at a particular location, about 30 samples, distributed over the whole thickness, with a length of about 30 cm should be measured so that the relative error of the mean value is not higher than 5%–10%. For the statistical analyses computed tomography (CT) values of X-ray data were calibrated with respect to rock composition based on laboratory measurements. The CT values are largely controlled by the respective volume fraction of calcite, quartz, and porous clay matrix. These three components form >80 vol% of the sedimentary rocks studied (also above and below Opalinus Clay). The relationship between CT value and component contents depends on the rock type. The use of data from different rock types to calibrate CT values with respect to composition can lead to erroneous results.

Revisiting the permanganate oxidizable carbon (POXC) assay assumptions: POXC is lignin sensitive

AbstractPermanganate oxidizable carbon (POXC) is a popular soil health test developed to measure “labile” C via the reduction of permanganate, dependent on several stoichiometric reduction oxidation assumptions. As a proof‐of‐concept experiment to evaluate the interpretation of POXC as “labile” C, we tested 17 compounds ranging in biological lability under standard POXC assay conditions at a fixed C mass (25 mg) in a quartz (2–0.053 mm diameter) matrix. POXC was high for lignin, whereas carbohydrates did not differ from the quartz control. Functional group‐based reactivity partly explained permanganate reduction. These findings indicate that (i) POXC is not a labile C fraction and (ii) corroborate previous concerns that the stoichiometric oxidation–reduction assumptions in the calculation of C oxidation from permanganate reduced are not sound. POXC interpretation should regard POXC as a chemically defined fraction, report in units of moles permanganate reduced per kg soil, and avoid terms such as “labile” and “active.”

Murphyite, Pb(TeO4), the Te-Analogue of Raspite, a New Mineral from Tombstone, Arizona, USA

Abstract A new mineral species, murphyite (IMA 2021-107), ideally Pb(TeO4), has been found from the Grand Central mine, Tombstone, Arizona, USA. It occurs as bladed or prismatic crystals on top of a quartz matrix. Associated minerals include chlorargyrite, emmonsite, ottoite, stolzite, scheelite, schieffelinite, quartz, and jarosite. Individual crystals of murphyite are up to 0.20 × 0.05 × 0.05 mm in size. Twinning is common on {100}. Murphyite is colorless to very pale yellow in transmitted light, transparent with white streak and adamantine luster. It is brittle and has a Mohs hardness of ∼3½, with perfect cleavage on {100}. The calculated density is 7.579 g/cm3. Murphyite is insoluble in water or hydrochloric acid. An electron microprobe analysis yielded the empirical formula (based on 4 O apfu): (Pb0.96Fe0.03Mn0.02)Σ1.01[(Te0.61W0.38)Σ0.99O4], which can be simplified to Pb[(Te,W)O4]. Murphyite is the Te-analogue of raspite, Pb(WO4), and represents the first mineral with Te6+ substituting for W6+ over 50%. It is monoclinic with space group P21/a and unit-cell parameters a = 13.6089(3), b = 5.01750(10), c = 5.5767(2) Å, β = 107.9280(10)°, V = 362.302(17) Å3, and Z = 4. Its crystal structure consists of distorted MO6 (M = Te + W) octahedra sharing edges to form zigzag chains running parallel to [010]. These chains are linked together by PbO7 polyhedra. Compared to raspite, the substitution of W6+ by Te6+, which has a smaller ionic radius, results in a noticeable structural change: a significant decrease in MO6 octahedral angle distortion, with a concomitant increase in both MO6 octahedral volume and average Pb–O bond length. The unit-cell volume increases from 358.72(4) Å3 for raspite to 362.302(17) Å3 for murphyite. Raman spectroscopic data show that the major peak ascribable to M–O symmetrical stretching vibrations within the MO6 octahedron is centered at 870 cm−1 for raspite but at 881 cm−1 for murphyite.

Geochemical and mineralogical characterization of streams and wetlands downstream a former uranium mine (Rophin, France)

The geochemical distribution of U and associated major and trace elements (As, Li, Pb, Sr, Zn) was studied at the former Rophin U mine (Puy-de-Dôme, France). Three zones of contrasting radiological settings were identified and sampled: a background area (<200 nSv·h−1), a streambed flowing downstream of the former mine (radiation level between 200 and 800 nSv·h−1) and a wetland soil (>1000 nSv·h−1). Sediment and water samples were collected both in a streambed located in the background area and in the streambed downslope the former mining area, and a soil sample was collected in the wetland downslope. Using both sequential and selective chemical extractions, and quantifying also the chemical reservoirs of As, Li, Pb, Sr, and Zn, it could be concluded that, in the streams, U was mainly bounded to primary ore minerals (phosphates) that were transported through particulate transport. It was also bound, to a lower extent, to clays, Mn oxyhydroxides and organic matter, certainly due to the sorption of aqueous U originating from partial dissolution or leaching of primary ore materials. Ore minerals remaining stable in the stream sediments were certainly included in a quartz matrix and hence were not in accessible for dissolution. In the wetland soil, selective extractions evidenced that U was about evenly distributed between humid/fulvic acids and organic matter unaffected by NH4OH 1M.

A study on the shear strength characteristics and microscopic mechanism of coal-bearing soil under dry-wet cycles

The slope of coal-bearing strata distributed along the high-speed highway (railway) is affected by the atmospheric dry-wet cycles (DWC), and the collapse occurs many times during the construction of such highways, in Pingxiang city, in the province of Jiangxi. The DWC affect the strength characteristics of the unsaturated coal-bearing soil (CBS). In order to study the shear-strength characteristics of the unsaturated CBS under the DWC, the relationship between the shear strength and matric suction was analyzed by using direct shear test of the unsaturated CBS, the filter paper method of the matrix suction measurement, and the scanning electron microscope test. The internal reasons of shear strength attenuation of unsaturated CBS under DWC are revealed from microscopic perspective. The results show that the DWC at 0 to 4 times, with an increase in the water content, the clay domains expanded unevenly. Further, the clay minerals that served as the cementing junctions and soluble salts were softened and dissolved, and the bonding strength between the basic units and the cohesion of the samples decreased, so that the shear strength of unsaturated CBS samples decreased with an increase in the water content, and increased with the increase of matric suction. Under the influence of the DWC, the CBS samples slaked, the quartz matrix between the fissures slaked, and produce fragments and debris which reduced the size of large particles, and the bonding strength between the basic units was low. Therefore, the matric suction and the shear strength of the unsaturated CBS samples with the same moisture content, under the same normal pressure, decreased gradually with an increase in the number of the DWC. It is feasible to study the strength characteristics of unsaturated CBS by combining the test methods of macroscopic strength, matric suction and microstructure of soil.

Post-magmatic hydrothermal activities in the Bursa ophiolite (NW Turkey): Implications for unusual minerals recovered from ophiolites

Low-temperature hydrothermal activities in ophiolites and their modification of chromite have been less studied compared to the magmatic processes. Here we present evidence of hydrothermal modification of chromitites from the mantle sequence of the Bursa ophiolite (NW Turkey). The chromitites are composed mainly of chromite with variable amounts of magnesite and quartz in the matrix. Many chromite grains contain various inclusions such as monophase magnesite or quartz, as well as multi-phase inclusions of quartz + chlorite ± magnesite associated with or without ferrian chromite, which are unusual in ophiolitic chromitites worldwide. Ferrian chromite intergrown with chlorite and quartz inclusions, has higher Cr# values (88.3–94.1) but lower MgO (6.11–9.74 wt%), and Fe3+/(Fe3++Fe2+) ratios (0.13–0.25) than primary chromite (Cr#: 78.3–79.1); MgO: 15.4–15.6 wt%; Fe3+/(Fe3++Fe2+): 0.36–0.40), indicating the infiltration of reducing and SiO2-rich serpentinizing fluids. The pyroxene and olivine were likely broken down by the pre-existing fluids and contributed to the SiO2-rich characteristic of serpentinizing fluid. Fluxing by CO2-rich fluids produced carbonation of the previous serpentine matrix and formed interstitial magnesite and quartz. Lower MgO contents and overall higher Cr# values of small chromite grains hosted in magnesite matrix compared to those hosted in quartz matrix (MgO: 13.2–15.0 wt% vs. 14.8–15.4 wt%; Cr#: 78.7–79.8 vs. 78.2–78.8) suggest that the carbonated fluids redistributed Mg2+ into magnesite and subtly increased Cr solubility in the fluids. Recrystallization may have prompted fracture healing in chromite grains and preservation of quartz when not associated with ferrian chromite. The carbon and oxygen isotope compositions of magnesite (δ13C: −3.35‰; δ18O: 17.29‰) indicate that the CO2-rich fluids were likely derived by decarbonation of marble and metaclastic rocks from the Tavşanlı zone metamorphic rocks in the Bursa ophiolite.