Structure Of Materials Research Articles

Polarization-dependent photoemission electron microscopy for domain imaging of inorganic and molecular materials.

Polarization-dependent photoemission electron microscopy (PD-PEEM) exploits spatial variation in the optical selection rules of materials to image domain formation and material organization on the nanoscale. In this Perspective, we discuss the mechanism of PD-PEEM that results in the observed image contrast in experiments and provide examples of a wide range of material domain structures that PD-PEEM has been able to elucidate, including molecular and polymer domains, local electronic structure and defect symmetry, (anti)ferroelectricity, and ferromagnetism. In the end, we discuss challenges and new directions that are possible with this tool for probing domain structure in materials, including investigating the formation of transient ordered states, multiferroics, and the influence of molecular and polymer order and disorder on excited state dynamics and charge transport.

Revolutionizing Wing-in-Ground Effect: Investigating Structural Rigidity

The Wing-in-ground (WIG) effect aircraft utilize the ground effect to maintain flight above water or another surface while minimizing continuous contact with the ground. The propulsion of this aircraft primarily relies on the aerodynamic lift generated by specially designed wings, hulls, or other components that harness the ground effect phenomenon. The problem statement that occurs once conventional boats fail to successfully carry out the mission of intercepting intruders trespassing on national waterways. Due to inherent constraints in watercraft technical standards, existing watercraft technology lacks the power to pursue intruders to their full extent. To further improve the WIG craft operation, we propose enhancing its performance by using materials with better mechanical qualities and optimizing the construction to lower its overall size. These enhancements aim to bolster the WIG craft's capabilities and enable more efficient and effective interception of intruders in water environments. This research aims to investigate structural material qualities suited for WIG effect application and structural rigidity characteristics, with a particular focus on the joining model. In order to accomplish these objectives, the study utilizes Solidworks simulation to replicate the WIG craft model. The static simulation involves testing four different parameters: Models A, B, C, and D. The key focus during the model simulation is varying the types of connections used. The simulation data is then examined to estimate the strength of the material structure. The material applied to the WIG craft structure is S-glass fiber and 6061 aluminum alloy. Model D produced acceptable values for the least maximum stress, strain, and resultant displacement, among other models. The maximum stress value of Model D is 1,601 MPa, which does not exceed the tensile strength of the material. For the rigidity analysis in operating conditions, the Solidworks flow simulation is conducted. The manipulated variable for flow simulation is the velocity of airflow. The velocities conducted are 60 km/h, 90 km/h, 120 km/h, 15 km/h and 180 km/h. The flow simulation shows the maximum total pressure exerted on the structure, where the highest velocity produced is 103433 Pa. From both static and airflow simulation, it was concluded that the WIG craft model has good rigidity in terms of withstanding the external load and airflow pressure during the cruising conditions proposed.

Harnessing Near-Infrared Light for Highly Efficient Photocatalysis.

Near-infrared (NIR) light, accounting for approximately 50% of solar light, cannot directly excite photocatalytic reactions due to its lower energy, which severely restricts the photocatalytic solar energy conversion efficiency and hinders the application of photocatalysis. To overcome this dilemma, some viable strategies have been proposed to harness NIR light for enhancing photocatalytic performance based on material structure, composition, and function designs, and obvious progresses have been witnessed. In this review, the basic principles and representative advances in photocatalyst heterojunction designs (including p-n junctions, S-scheme, Z-scheme, and type-ІІ heterojunctions), photocatalyst composition and function designs (such as preparing rare earth element doped upconversion photocatalysts, rare earth upconversion photocatalytic hybrids and triplet-triplet annihilation upconversion photocatalytic composites), and photothermal-photocatalytic bifunction designs for NIR light utilization are exclusively scrutinized. Meanwhile, the applications of the above-mentioned NIR responsive photocatalyst composites in energy and environmental fields are summarized. Importantly, the challenges and outlooks in the field of NIR light harnessing for efficient photocatalysis are proposed, which may provide theoretical and experimental guidance to those working in solar energy conversion and utilization and other related fields.

Mechanical properties and micro-mechanism of seawater cementitious materials reinforced by in-situ polymerization

Understanding the potential mechanism of in-situ polymerization of acrylamide (AM) for modifying seawater cementitious materials is crucial for designing high-strength and durable marine concrete. Herein, the acrylamide (AM) in-situ polymerization was investigated for its effects on the hydration behavior, micro-morphology, and pore structure of cementitious materials mixed with seawater and freshwater through a series of elaborately designed microscopic characterization methods. The results reveal that the hydration process of cementitious materials proceeds simultaneously with in-situ polymerization. However, compared with freshwater mixtures, seawater provides a large number of metal ions and SO42- ions, which can cross-link with the generated polyacrylamide (PAM) during in-situ polymerization to form a three-dimensional network structure. The synergistic effect of the hydration, in-situ polymerization, and cross-linking processes of cementitious materials can improve the pore structure of seawater-mixed paste, enhance erosion resistance, and improve the stability and toughness of microstructure. These findings were further confirmed by comparing infrared spectroscopy results, hydration products, pore size, and micro-morphology analysis as well as flexural performance tests. This is of great significance to guide the design of novel materials in marine infrastructure.

Thermal conductivity of 3D-printed block-copolymer-inspired structures

This study primarily focuses on examining the impact that geometric structure has on thermal conductivity of multi-phase constructs in different 3D-printed poly(lactic acid), PLA, samples. The investigated structures are inspired by morphologies formed by diblock copolymers: lamellae, hexagonally packed cylinders, and gyroid. This research also investigates how volume percentage and material combination influence the thermal conductivity of these structures. The samples can be tailored to simulate various thermal management structures observed in practical applications, such as thermal interface materials in electronic devices. Thermal conductivity ratio is controlled using air, the least conductive material at 0.026 W/(m K), PLA at 0.136 W/(m K), and thermal paste at 5.11 W/(m K). Different models were tested against thermal conductivity measurements in order to capture the effect of material type (PLA-Air versus PLA-Thermal Paste), volume percentage, structure, and orientation. Simple, effective medium models were good predictions of thermal conductivity in lamellar structures, but it was necessary to develop models for conduction through cylindrical and gyroid structures. Finally, all results were normalized to find a universal model that is independent of structure and material. This approach provides a simple method to predict how to reduce or enhance transport properties and heat management capabilities of 3D printed objects.

Damping optimization of a fully viscoelastic structure with enforced mass reduction

Current damping methods employed in industry, such as Constrained Layer Damping (CLD), all require the introduction of additional mass and a secondary material to the structure. In transportation industries, this weight addition is often correlated with an increase in operational costs. Additionally, in applications with large temperature changes, such as in space, the secondary material introduces an additional source of stress during thermal expansion and contraction. This work presents a methodology to significantly improve the damping performance of a fully viscoelastic, single material structure while also enforcing a mass reduction. The work expands upon the modal strain energy (MSE) method to calculate the damping performance of a fully viscoelastic structure and develops a novel weighting scheme to make the optimization more robust. The methodology is then implemented on a technology demonstration thermoplastic lunar rover. This implementation demonstrates the ability to optimize a fully viscoelastic structure to significantly improve the damping performance while also achieving a large decrease in mass. The implementation also demonstrates the robustness of the weighting scheme as it allows the natural frequencies to shift between iterations. The skin thickness of the rover’s base panel was optimized. After optimization, the base panel of the rover achieved a 20% damping improvement for Mode 1 with a 9% mass reduction. The skin thickness of the full rover was optimized and achieved a 15% damping improvement for Mode 2 with an 11% mass reduction.

Crystal Structure, Microstructure, and Dielectric and Electrical Properties of Ceramic Material Prepared Using Volcanic Ash

In the present work, the electrical and dielectric properties of ceramic samples prepared from volcanic ash were investigated. For this purpose, ceramic samples were prepared using milled volcanic ash with a binder material at a sintering temperature of 950 °C for 2 h. The chemical content of the milled volcanic ash was investigated using XRF. Differential thermal analysis and thermogravimetry were performed to determine the firing conditions. The crystalline phases and microstructures of the ceramic samples were investigated using XRD and SEM, respectively. Finally, the electrical and dielectric properties of the obtained samples were evaluated at a frequency ranging from 1 × 102 to 4 × 106 Hz and temperatures ranging from room temperature to 800 °C. The XRD results revealed that the ceramic samples contained three main phases: albite, hematite, and augite. Moreover, the microstructures of the samples exhibited a large crystal size with a dense surface. The conductivities and dielectric constants of the samples remained stable up to 500 °C. The real and imaginary parts of the dielectric constant decreased with an increase in frequency and increased with an increase in temperature. The results indicated that ceramics based on volcanic ash are promising for use in technological applications such as high-voltage power insulators.

Experimental Study on Reinforcement Properties of Tension-Resistant Reinforced Soil Retaining Wall

The tensioned reinforced soil retaining wall, a novel retaining structure, utilizes either anchors or geosynthetic materials as reinforcements that contribute to load-bearing and friction within the structure. This study aims to explore the tension distribution and strain patterns in the reinforcements, and their influence on the reinforced soil retaining walls. To this end, tensile, direct shear, and pullout tests were conducted on GeoStrap@5-50 geotextile strips and TGDG130HDPE geogrids to evaluate the tensile strength and interface strength between the reinforcement and the soil. The characteristics of the reinforcement–soil interface and the deformation behavior under stress were examined, with a comparative analysis of the technical merits of the two types of reinforcements. The results indicate that both the geotextile strips and geogrids enhanced the strength of the reinforced soil, primarily by increasing cohesion. The GeoStrap@5-50 geotextile strips exhibited superior tensile strength compared to the TGDG130HDPE geogrids; the reinforcement with the geotextile and geogrids both enhanced the cohesion of the standard sand, albeit with a slight decrease in the internal friction angle, by 4.6% and 3.1%, respectively, offering enhanced mechanical properties and economic value in reinforced soil retaining wall applications.

Synthesis and Characterization of Monolayer Colloidal Sheets.

Sheet-like colloidal assemblies represent model systems to investigate the structure and properties of two-dimensional materials. Here, we report a simple yet versatile method for the preparation of colloidal monolayer sheet-like assemblies that affords control over the size, crystalline order, flexibility, and defect density. The protocol that we report relies on self-assembly of colloids as a sessile drop of dispersion is evaporated on an oil-covered substrate. In this case, the contact line continually moves as the drop shrinks. Polyethyleneimine polymer-covered micrometer-sized colloidal particles are transported to the air-water interface and assemble to form a monolayer sheet as the drop dries. Cross-linking the polymer renders the colloidal assembly permanent. Interestingly, monodisperse colloidal particles form disordered assemblies when dried from low concentration dispersions, while polycrystalline ordered assemblies form at higher concentrations. We demonstrate that increasing the cross-linker to polymer ratio decreases the flexibility of the assembly. Introduction of different-sized colloidal particles in a sheet leads to increased disorder. Removal of sacrificial particles from the sheet allowed the introduction of "holes" in the sheets. Thus, these colloidal sheets are models for probing the effects of disorder, doping, and vacancies in two-dimensional systems.

Challenges and Progress in Rechargeable Magnesium‐Ion Batteries: Materials, Interfaces, and Devices

AbstractRechargeable magnesium‐ion batteries (RMBs) have garnered increasing research interest in the field of post‐lithium‐ion battery technologies owing to their potential for high energy density, enhanced safety, cost‐effectiveness, and material resourcefulness. Despite substantial advancements in RMB research, a number of intrinsic challenges remain unresolved, such as the strong Coulombic interaction between Mg2+ and the host crystal structure of cathode materials, sluggish Mg2+ diffusion kinetic, poor electrolyte compatibility, and the formation of passivation films on the Mg anode interface. These issues hinder the commercial applications of RMBs. This review provides a comprehensive overview of the progress in key areas of RMB research, including representative magnesium‐ion storage cathode/anode materials and magnesium‐ion conducting electrolytes. Additionally, recent developments in electrode‐electrolyte interface regulations and pouch‐cell fabrication are outlined, highlighting current challenges and the implementation of effective solutions. Finally, future research directions are proposed to guide the development of high‐performance RMBs with practical applications.

Механизмы электронного транспорта в низкоразмерных полупроводниковых структурах: обзор

Background: Low-dimensional semiconductor structures such as quantum wells, wires, and dots have sparked widespread attention due to their distinct electron transport properties that differ dramatically from bulk materials. These characteristics are critical for advances in nanoscale electrical and optoelectronic devices. Objective: The article aims to summarize current knowledge of electron transport processes in low-dimensional semiconductor devices, focusing on the impact of reduced dimensionality on electron behaviour. Methods: A thorough literature analysis was carried out, emphasizing experimental and theoretical investigations that shed light on electron transport dynamics in quantum wells, wires, and dots. The analysis looked into scattering mechanisms, quantum confinement effects, and the significance of material composition and structure. Results: The findings show that quantum confinement produces discrete energy states that drastically change electron mobility and conductivity. Furthermore, electron scattering by phonons, contaminants, and surfaces is shown to be heavily impacted by decreased dimensionality, which either enhances or suppresses electron transport depending on the precise configuration and size of the structures. Conclusion: Low-dimensional semiconductor structures have complex electron transport behaviours that differ significantly from their bulk counterparts. Understanding these mechanisms is critical for designing and developing future electronic devices, and this overview serves as a starting point for ongoing articles on this technologically significant topic.

Soft Robotic Honeycomb-Velcro Jamming Gripper Design

In this paper, using a honeycomb-velcro structure to generate a novel jamming gripper is explored. Each finger of the gripper consists of multi-layers with a honeycomb sandwich structure acting as a core wrapped by a fabric sheet and sealed by a latex membrane. This structure can transit between unjammed (flexible) and jammed (rigid) states thanks to the vacuum pressure. Various materials of honeycomb structure, fabric, and reinforcements are investigated to seek optimal combinations for making the jamming fingers. Then, such fingers are deployed in experiments to evaluate the stiffness and the surface friction with different loads in terms of with or without vacuum. Vacuum pressure boosts the stiffness and friction of all the jamming fingers compared with the without-vacuum case. Attached to a gripper, the jamming finger shows good performance in diverse manipulation with food, a metal component, a toy, a can, and a bottle. Furthermore, the variable-stiffness finger under vacuum pressure can be utilized to perform assembly and installation operations such as pushing a bolt into an aligned hole.

Characterization of human trabecular bone across multiple length scales using a correlative approach combining X-ray tomography with LaserFIB and plasma FIB-SEM

Three-dimensional correlative multimodal and multiscale imaging is an emerging method for investigating the complex hierarchical structure of biological materials such as bone. This approach synthesizes images acquired across multiple length scales, for the same region of interest, to provide a comprehensive view of the material structure of a sample. Here, we develop a workflow for the structural analysis of human trabecular bone using a femtosecond laser to produce a precise grid to facilitate correlation between imaging modalities and identification of structures of interest, in this case, a single trabecula within a volume of trabecular bone. Through such image registration, high resolution X-ray microscopy imaging revealed fine architectural details, including the cement sheath and bone cell lacunae of the selected bone trabecula. The selected bone volume was exposed with a combination of manual polishing and site-specific femtosecond laser ablation and then examined with plasma focused ion beam-scanning electron microscopy. This reliable and versatile correlation approach has the potential to be applied to a variety of biological tissues and traditional engineered materials. The proposed workflow has the enhanced capability for generating highly resolved and broadly contextualized structural data for a better understanding of the architectural features of a material spanning its macroscopic to nanoscopic levels.

Hierarchical Structure of Soft Materials Studied at Small-Angle Neutron Scattering Instrument, SANS-U

Hierarchical Structure of Soft Materials Studied at Small-Angle Neutron Scattering Instrument, SANS-U

Improving the electrochemical performance of nickel-cobalt organic framework by hybridizing with carbon quantum dots

To improve the electrochemical properties of nickel-cobalt metal-organic skeleton materials, two carbon quantum dots (CQDs), namely, CQD-CA and N-doped CQD-CAn, were prepared by using citric acid as carbon source and then introduced into NiCo-MOF to prepare CQDs/NiCo-MOF composites. Through the application of physical characterization and electrochemical analysis methods, such as SEM, TEM, XRD, XPS and BET, it was found that NiCo-MOF@CA and NiCo-MOF@CAn exhibited a nano thinner lamellar structure, higher specific surface area, larger pore structure, and excellent electron transport ability. Especially, by introducing CQDs, the charge could transfer from oxygen to Ni and Co, and there was some higher electron cloud density around active metals Ni and Co in NiCo-MOF@CAn than in NiCo-MOF, effectively activating the metal center Ni and Co. As the result, the specific capacitance of NiCo-MOF@CAn reached 1917.7 F·g−1 at the potential scan rate 5 mV·s−1, significantly higher than that of NiCo-MOF (1173.4 F·g−1) and NiCo-MOF@CA (1489.3 F·g−1). The method might provide an alternative strategy for modulating the morphology, porous structure and the partial electron structure of the target materials by introducing various CQDs.

Confinement synthesis of few-layer MXene-cobalt@N-doped carbon and its application for electrochemical sensing

Herein, the few-layer Ti3C2Tx nanosheets loaded zeolitic imidazolate framework-67 nanoplates (Ti3C2Tx-ZIF-67) with a unique structure has been synthesized by surfactant control method, and then is employed as the core of precursor. A thin layer of polydopamine as the shell of precursor covered Ti3C2Tx-ZIF-67 forms a micro-nano reactor, leading to the confinement carbonization process. Consequently, a novel sensing material that few-layer Ti3C2Tx nanosheets loaded Co nanoparticles coated N-doped carbon (Ti3C2Tx-Co@NC) is obtained for the non-enzymatic determination of glucose. Owing to the impressive structure, the established glucose sensor based on Ti3C2Tx-Co@NC/glassy carbon electrode exhibits 0.5–100.0 μM of linear detection range and 66.8 nM of detection limit, which tends to detect low concentration of glucose. The synergistic few-layer Ti3C2Tx nanosheets, Co nanoparticles and NC are considered through a series of control experiments. First, few-layer Ti3C2Tx nanosheets provide a good transport channel for electron transfer, resulting in the lower steric hindrance. Second, Co nanoparticles provide active centers for the electrochemical detection. Third, N-doped carbon with conductivity and hydrophilia plays the role of stabilizing material structure to prevent the fragmentation of Ti3C2Tx and the agglomeration of Co nanoparticles. Such work proposes a confined strategy to develop MXene-ZIF-67-derived nanocomposite with high-performance structure.

Doping telluride for tuning the crystal structure and thermoelectric performance of copper selenide-based materials

Doping telluride for tuning the crystal structure and thermoelectric performance of copper selenide-based materials

Effect of morphology on the optical limiting of BiVO4 films

Precise control over the morphology and crystal structure of semiconductor-based optical materials is essential for optimizing their nonlinear optical properties. Morphological factors significantly affect the material’s interaction with light, influencing nonlinear absorption, harmonic generation, and optical confinement. In this study, the nonlinear optical (NLO) properties and optical limiting (OL) performance of bismuth vanadate (BiVO4) films depending on precursor solution pH condition, powder morphology and weight percentage of the BiVO4 powders in PMMA (10–30 wt.%) were investigated. The BiVO4 powders were synthesized via the hydrothermal method and the effect of precursor solution pH (pH of 1, 7.5 and 12) was investigated on the size and morphology of the BiVO4 powders. BiVO4 films were prepared using the spin coating method utilizing the BiVO4 powders and PMMA. The bandgap values of films were found to change from 3.39 to 3.56 eV depending on the BiVO4 growth solution pH. The nonlinear absorption coefficients (βeff), saturation intensity thresholds (ISAT) and optical limiting (OL) threshold were obtained using the open aperture (OA) Z-scan experiment. It has been observed that the nonlinear absorption and optical limitation performance of the BiVO4 films can be altered by changing the powder morphology and BiVO4 weight concentration. BiVO4 thin films fabricated using a precursor solution pH 12 and weight concentration of 30 wt.% showed the best performance among all fabricated films with the highest nonlinear absorption coefficient (βeff), saturation density threshold (ISAT) and lowest OL threshold value.

Benchmark Study of Core-Ionization Energies with the Generalized Active Space-Driven Similarity Renormalization Group.

X-ray photoelectron spectroscopy (XPS) is a powerful experimental technique for probing the electronic structure of molecules and materials; however, interpreting XPS data requires accurate computational methods to model core-ionized states. This work proposes and benchmarks a new approach based on the generalized active space-driven similarity renormalization group (GAS-DSRG) for calculating core-ionization energies and treating correlation effects at the perturbative and nonperturbative levels. We tested the GAS-DSRG across three data sets. First, the vertical core-ionization energies of small molecules containing first-row elements are evaluated. GAS-DSRG achieves mean absolute errors below 0.3 eV, which is comparable to high-level coupled cluster methods. Next, the accuracy of GAS-DSRG is evaluated for larger organic molecules using the CORE65 data set, with the DSRG-MRPT3 level yielding a mean absolute error of only 0.34 eV for 65 core-ionization transitions. Insights are provided into the treatment of static and dynamic correlation, the importance of high-order perturbation theory, and notable differences from density functional theory in the predicted energy ordering of core-ionized states for specific molecules. Finally, vibrationally resolved XPS spectra of diatomic molecules (CO, N2, and O2) are simulated, showing excellent agreement with experimental data.

A new type of pentagonal structure HgS2 monolayer with abundant active sites and low Gibbs free energy for photocatalytic water splitting

Discovery of new two-dimensional (2D) materials not only has important fundamental research significance but also has promising application prospects. Through systematic structure searching combined with density functional theory calculations and simulations, we predict a new 2D monolayer HgS2 material featuring with a previously unreported type of pentagonal structure with orthorhombic P21212 symmetry. The penta-HgS2 monolayer shows good thermal, thermodynamic, mechanical and dynamic stabilities, exhibiting ferroelastic phase transition with an ultralow switching energy barrier (about 1 meV/atom), high ultimate strength of 12 N/m, moderate indirect band gap of 2.25 eV. In addition, the penta-HgS2 monolayer shows significantly anisotropic carrier mobility with a large anisotropy ratio of 98.5 along the y direction. More importantly, the penta-HgS2 monolayer exhibits abundant catalytic active sites, low Gibbs free energy (ΔGH ranging from 0.656 to 1.687 eV) for hydrogen evolution reactions, excellent solar light absorption capacity (∼105 cm−1) with the solar-to-hydrogen efficiency reaching up to 11.83%. The excellent ultimate tensile ability and the ultralow ferroelastic phase transition energy barrier implies penta-HgS2 monolayer material can be used to manufacture flexible mechanical and nanoelectronic devices. The suitable band edge alignments, ultrahigh carrier mobility anisotropy, high catalytic activity and excellent visible light adsorption performance indicate that penta-HgS2 monolayer is a promising candidate photocatalyst for high-performance photocatalytic water splitting. The present work not only supplements a new member to the 2D pentagonal structure material family, but also points out its promising applications in nanoscale devices and photocatalytic hydrogen productions.