Industrial Materials Research Articles

Chemical and Thermal Changes in Mg3Si2O5 (OH)4 Polymorph Minerals and Importance as an Industrial Material

Serpentine (Mg3Si2O5(OH)4), like quartz, dolomite and magnesite minerals, is a versatile mineral group characterized by silica and magnesium silicate contents with multiple polymorphic phases. Among the phases composed of antigorite, lizardite, and chrysotile, lizardite and chrysotile are the most prevalent phases in the serpentinites studied here. The formation process of serpentinites, which arise from the hydrothermal alteration of peridotites, influences the ratio of light rare earth elements (LREE) to heavy rare earth elements (HREE). In serpentinites, the ratio of light rare earth elements (LREE)/heavy rare earth elements (HREE) provides insights into formation conditions, geochemical evolution, and magmatic processes. The depletion of REE compositions in serpentinites indicates high melting extraction for fore-arc/mantle wedge serpentinites. The studied serpentinites show a depletion in REE concentrations compared to chondrite values, with HREE exhibiting a lesser degree of depletion compared to LREE. The high ΣLREE/ΣHREE ratios of the samples are between 0.16 and 4 ppm. While Ce shows a strong negative anomaly (0.1–12), Eu shows a weak positive anomaly (0.1–0.3). This indicates that fluid interacts significantly with rock during serpentinization, and highly incompatible elements (HIEs) gradually become involved in the serpentinization process. While high REE concentrations indicate mantle wedge serpentinites, REE levels are lower in mid-ocean ridge serpentinites. The enrichment of LREE in the analyzed samples reflects melt/rock interaction with depleted mantle and is consistent with rock–water interaction during serpentinization. The gradual increase in highly incompatible elements (HIEs) suggests that they result from fluid integration into the system and a subduction process. The large differential thermal analysis (DTA) peak at 810–830 °C is an important sign of dehydration, transformation reactions and thermal decomposition, and is compatible with H2O phyllosilicates in the mineral structure losing water at this temperature. In SEM images, chrysotile, which has a fibrous structure, and lizardite, which has a flat appearance, transform into talc as a result of dehydration with increasing temperature. Therefore, the sudden temperature drop observed in DTA graphs is an indicator of crystal form transformation and CO2 loss. In this study, the mineralogical and structural properties and the formation of serpentinites were examined for the first time using thermo-gravimetric analysis methods. In addition, the mineralogical and physical properties of serpentinites can be recommended for industrial use as additives in polymers or in the adsorption of organic pollutants. As a result, the high refractory nature of examined serpentine suggests that it is well-suited for applications involving high temperatures. This includes industries such as metallurgy and steel production, glass manufacturing, ceramic production, and the chemical industry.

Development of a Diamond Composite in the NI-CO-FE3P-SN-WC System Via Free Sintering for Use in Multi-Find Diamond Pearls

Objective: The main objective of this study is to manufacture a diamond composite with a metallic matrix based on Ni-Co-Fe3P-Sn-WC, using the Free Sintering process through cold uniaxial compaction, intended for the production of pearls for diamond wire saws, used in cutting ornamental stones. Theoretical Framework: The multi-wire technology represents an advancement in cutting ornamental stone blocks, allowing the simultaneous production of multiple slabs. Powder metallurgy is the predominant technique used in the manufacturing of pearls for diamond wire saws. Through testing, including scanning electron microscopy (SEM) and shear tests, it is possible to evaluate the alloy's strength, diamond crystal adhesion, and failure behavior of the alloy. Methodology: The adopted methodology involves the processing and characterization of pearls for diamond wire saws, following the techniques of powder metallurgy. Initially, parametric calculations were performed using Excel, providing a basis for subsequent analyses. Diamond-coated pearls were produced with different proportions of constituent elements, and uniaxial compressive strength tests and microstructural characterization were conducted to evaluate the results. Results and Discussion: In the adhesion tests to the metal tube, the pearls produced with the NICOFE alloy showed similar performance to the commercial pearls "A" and "B," with satisfactory direct shear strength values. However, some point defects were observed, such as porosity in the transition zone, creating a weaker bond, negatively impacting the final strength of the composite. Analysis of the commercial samples indicated that diamond abrasion was not related to the composition of the sintered alloy. Research Implications: This research suggests significant economic and technological implications, such as the development and nationalization of technology for the ornamental stone industry. The use of the NICOFE alloy could strengthen the local industry by providing a viable and more accessible alternative for the production of diamond pearls. Originality/Value: The NICOFE blend presents technical advantages for manufacturing diamond wire pearls, highlighting the environmental benefits from reduced cobalt use and economic advantages by offering more accessible materials for the ornamental stone industry.

Bamboo (Dendrocalamus Asper) as an Eco-Friendly Sustainable Material: Optimising Mechanical Properties and Enhancing Load-Bearing Capacity for Environmental Architectural Design

This study will assess the utilisation of Bamboo (a Thai vernacular material) in the construction industry. Bamboo is a sustainable and environmentally friendly material which provides a suitable alternative to traditional construction materials. This research will examine its mechanical strength properties as determined by a review of the existing literature and an examination of the bearing area variations of bamboo nodes. The research data and ensuing experiments facilitated the simulation of the load-bearing capacities of bamboo columnar and beam structures via optimisation. Additionally, this study examined the limitations of bamboo-based structures. The assimilation of mechanical property data and bamboo strength was imperative for the production of load-bearing simulations for bamboo columns and beams within ANSYS software. In many countries, bamboo is a commonly employed construction material because of the many benefits it provides such as its rapid growth speed. The compressive strength tests conducted in this study revealed that the middle nodes could withstand up to 64.9 kN, which was the highest value amongs the three samples tested. These findings will contribute to ongoing optimisation and research regarding the damage mechanisms affecting column and beam structures under load. Notably, this damage was prevalent at the junctures of column and beam interfaces. The intention is to conduct additional research that will enhance the current understanding and ensure the sustainability of bamboo as an architectural building material.

Fabrication of Long‐Lasting Superhydrophilic Anti‐Fogging Film Via Rapid and Simple UV Process

AbstractSurface fogging is a common phenomenon that can result in restricted visibility, reduced light absorption, and image distortion. Although both hydrophobic and hydrophilic surfaces are effective in preventing this phenomenon, typical coatings in both have limitations, including low durability and the need for frequent reapplication. To address these issues, a highly durable anti‐fogging film that lasts over five weeks, even under high moisture conditions, while maintaining a promising degree of transparency (> 60%) is developed. A novel statistical random copolymer containing superhydrophilic and photo‐crosslinkable segments that can be simultaneously crosslinked and chemically bonded to various substrates via a simple ultraviolet (UV) irradiation process is synthesized. Notably, the chemical bonding between the anti‐fogging coating and substrate improves not only the durability but also the resistance to external forces and environmental changes. Furthermore, this film is versatile and applicable to diverse substrates, such as car windshields, polymer films, and aluminum foil. The innovative strategy offers a simple, rapid process and durable anti‐fogging performance with broad applications in the automotive industry, optical devices, and building materials.

Real-Time Modeling for Design and Control of Material Additive Manufacturing Processes

The use of digital twin and shadow concepts for industrial material processes has introduced new approaches to bridge the gap between physical and cyber manufacturing processes. Consequently, many multidisciplinary areas, such as advanced sensor technologies, material science, data analytics, and machine learning algorithms, are employed to create these hybrid systems. Meanwhile, new additive manufacturing (AM) processes for metals and polymers, based on emerging technologies, have shown promise for the manufacturing of sophisticated parts with complex geometries. These processes are undergoing a major transformation with the advent of digital technology, hybrid physical-data-driven modeling, and fast-reduced models. This study presents a fresh perspective on hybrid physical-data-driven and reduced order modeling (ROM) techniques for the digitalization of AM processes within a digital twin concept. The main contribution of this study is to demonstrate the benefits of ROM and machine learning (ML) technologies for process data handling, optimization/control, and their integration into the real-time assessment of AM processes. Therefore, a novel combination of efficient data-solver technology and an architecturally designed neural network (NN) module is developed for transient manufacturing processes with high heating/cooling rates. Furthermore, a real-world case study is presented, showcasing the use of hybrid modeling with ROM and ML schemes for an industrial wire arc AM (WAAM) process.

Compare the Properties of Composite Material by Date Leaves with Different Additives

Almost no product is made today without the use of composite materials, which have demonstrated their value over time in a variety of applications. Examples include household products, automobiles, oil and gas stations and spacecraft. Instead of using timber, leaves will be used to create a solid material. The goal of this study is to identify the distinguishing features of composite materials made from dates palm waste, as well as the overall effects on the properties when changing the mixture's proportions and the amount to which those materials are vulnerable to outside influences. It also aims to identify the best material that can be produced and used in home furnishings, manufacturing, architectural design, practical applications, and other science-related fields. This project will address the use of natural fibers from dates palm waste and some other materials to convert them into a strong, lightweight, low-cost composite material to replace wood, aluminum, synthetic fibers, and other materials in industries and uses. It will also explore the manufacturing processes, testing methods, and the outcomes of comparing it with other materials. The UHU (adhesive) matrix has the lowest hardness value compared to others. Structure tests show composites' internal composition; it plays an important role in understanding the properties of composites. The water absorption test demonstrates the duration required for composites to become saturated with water, with optimal results falling within the range of 13 to 24 hours for saturation.

Exploration of Bituminous Materials Using 2D Electrical Resistivity Imaging, Kurdistan Region, NE Iraq

Solid bituminous materials are widely spread in the Iraqi Kurdistan Region, they are filled so many locations, such as fracture zones, fault planes, and bedding planes. These materials can be used in several industries like pavement road, roofing, bituminous paint and waterproof, etc. The study aims to find an economical quantity of these materials by using 2D resistivity imaging in three locations that are different in geology and tectonic settings. These locations are Alla Syaw, Mera De, and Nasalih villages. The data are collected using Syscal R1 plus resistivity meter, for the sake of following up horizontal and vertical extension of these materials Wenner-Schlumberger array is used with 72 electrodes and a spacing interval of 5 m. Three profiles were conducted for each location, which have lengths equal to 360 m. The data processing was carried out by using the RES2DINV, and the smoothness was performed using finite difference forward modeling. The results show that all the bituminous materials are detected in shallow depths and only in the sandstone layers of the Tanjero, Gercus, and Injana formations filling the fracture zones and fault planes. This is also attributed to the more brittle behavior of the sandstone layer than other layers of these formations which deforms easily by applying external stresses. In the Tanjero Formation bituminous body is detected at a depth of about 10 m, which has an extension of more than 50 m from profile-1 to profile-2 (this is a lateral extension). The average width and height of the body are about 8m and 20 m, so it forms an approximate total volume equal to 8000 m3. The study concludes that the preliminary estimation of the total volume of the detected bituminous bodies is about 20000 m3, which has great importance as raw material for different industries. The bituminous material has a high resistivity value in most of the profiles reaching more than 200 ohm.m.

Phenolic Compound Profiles, Antioxidant, and Cytoprotective Activity of Elaeagnus conferta Roxb. Fruit.

In this paper, three varieties of Elaeagnus conferta Roxb fruits prepared by ultrasonic-assisted extraction from a subtropical region southwest of China were utilized as raw materials to investigate their phenolic profiles, antioxidant activities, and protective effects on injured human umbilical vein endothelial cells (HUVECs). The ultra performance liquid chromatography-electrospray ionization tandem mass spectrometry (UPLC-ESI-MS/MS) findings revealed that fifteen substances, including seven phenolic acids, seven flavonoids, and one gallic acid derivative, were discovered. The dihydromyricetin, ellagic acid, gallic acid were the predominant phenolic compounds in all E.conferta fruits. These E.conferta fruits extracts shown excellent antioxidant activity varied from 2.258±0.03~7.844±0.39 μM Trolox/g and protective effect on HUVECs injured by H2O2 through decrease the level of ROS, MDA, LDH and enhance the SOD level. These finding indicate that E.conferta is a valuable source of high-capacity antioxidants that might be used as an alternative material for food industries.

CHARACTERIZATION OF CLAYS FROM “MINES MARITSA IZTOK” AS RAW MATERIALS FOR CERAMIC INDUSTRY

The chemical and phase compositions of the clays from coal mining were evaluated by XRF and powder XRD method, respectively. Hot Stage Microscope was used to estimate the thermal behaviour. In addition, the thermal losses of the clays after 1 h thermal treatment at different temperatures were measured. This preliminary analysis elucidates potential prospects for using some of clays as raw materials for ceramic industry. It seems that samples which are montmorillonite type are more plastic, while the others, where higher sand content is observed, and the drying shrinkage is negligible could be characterized as less plastic. The initial results for the thermal behaviour and the structure of a brick sample (obtained by mixing two types of clays) and a foamed geopolymer are also reported. The first sample shows a beginning of the firing shrinkage at about 1000°C, while the second demonstrates intensive bloating after 950°C, leading to specimen with about 56 % closed porosity. Finally, X - ray Computed Tomography and SEM was used to highlight the structure of some test samples.

Plasma Tailoring of NH2-MIL-53 with Enhanced Fluorescence Emission for Simultaneous Detection of Multiple Heavy Metals in Water.

Indium, copper, and mercury are important raw materials in the electronics industry and often coexist in factory wastewater. Therefore, the development of a highly sensitive and selective method for the simultaneous detection of these heavy metal ions is of great significance for water quality monitoring and environmental protection. Herein, we report a NH2-MIL-53 fluorescent probe for the simultaneous detection of trace In3+, Cu2+, and Hg2+ in water. After a low-temperature NH3 plasma tailoring treatment for grafting electron-donor amine groups, the obtained NH2-MIL-53-M exhibited enhanced fluorescence emission intensity (∼6 times) coupled with selective adsorption of In3+, Cu2+, and Hg2+. This quenched the NH2-MIL-53-M fluorescence and allowed to significantly increase the selectivity and sensitivity for detection of In3+, Cu2+, and Hg2+. The fluorescence quenching constant (Ksv) values were 2.23 × 105, 1.00 × 105, and 2.74 × 104 M-1, while the limit of detection (LODs) values were 0.06, 0.14, and 0.53 μM, for In3+, Cu2+, and Hg2+, respectively. The concentrations of In3+, Cu2+, and Hg2+ in real environmental samples could be determined by addition of appropriate masking agents, and the recoveries were within the range of 94-110%. This study not only supplied a strategy for constructing a highly sensitive and selective fluorescent probe but also established a platform for simultaneous detection of multiple heavy metal ions in water.

Assessment of Radiological Impact for Individuals Associated with Natural Occurring Radioactive Material in Ceramic Industry

Assessment of Radiological Impact for Individuals Associated with Natural Occurring Radioactive Material in Ceramic Industry

Financing the capital-constrained farmer under random yield and investment information asymmetry: bank credit versus trade credit

PurposeFinancing the capital-constrained farmers to facilitate the production of agri-products is one of the greatest challenges facing the farming supply chain in the developing countries. In this study, we investigate the optimal financing scheme for the farming supply chain under random yield and investment information asymmetry environment to support rural economic development.Design/methodology/approachWe analyze a stylized model of farming supply chain where the capital-constrained farmer produces and sells agri-products through the agribusiness firm, and investigate the optimal financing scheme incorporating the investment information asymmetry and the challenge of yield uncertainty.FindingsThe results show that there is no one financing scheme equilibrium dominates for all situations, the financing scheme equilibrium is affected by the bank’s supervision cost to monitor the farmer’s moral hazard behavior, the variance of random yield and the farmer’s initial capital. The preference of the financing scheme for the agribusiness firm may be different from that for the farmer. The agribusiness firm might suffer from overfinancing problem under trade credit financing when the bank’s supervision cost is larger and the farmer’s own initial capital is lower; the higher variance of random yield will flare up the effect.Practical implicationsThis study sheds light on the choice of financing scheme under random yield and investment information asymmetry environment. This problem is particularly important for developing economies. Financing the capital-constrained farmers not only increases supplies of food and industrial raw materials, but also reduces poverty. The findings provide managerial implications for practitioners for how to leverage different financing scheme to support rural economic development.Originality/valueThis study develops new theoretical model for farming supply chain financing incorporating the challenge of yield uncertainty and investment information asymmetry, the two prominent factors that would impact the financial risk significantly. We analyze the equilibrium under both bank financing and trade credit financing schemes, and the results suggest that the financing scheme equilibrium is affected by the bank’s supervision cost to monitor the farmer’s moral hazard behavior, the variance of random yield and the farmer’s initial capital. The agribusiness firm might suffer from overfinancing problem under trade credit financing.

Methodological approach to assessing the digital infrastructure of the northern regions of the Russian Federation

The northern territories of Russia need high-quality strategic digital changes in the structure of the regional economy. Digitalization and the introduction of digital technologies in the medium term will be able to transform economic relations in the old industrial and raw materials regions of the North, improve the quality of life of local communities. The growth of digital inequality among the regions under study leads to disproportions in their socio-economic development. The purpose of this study is to develop and test a methodology for assessing the level of development of the digital infrastructure of the Russian northern regions, including classification of an indicators system for each level of digital infrastructure, calculation of an integral index and typology of the territories under study. The objects of the study were 13 northern regions of the Russian Federation, the entire territory of which is classified as regions of the Extreme North and equivalent areas. The methodology made it possible to determine the level of technical, technological and personnel readiness of the northern regions for digitalization, to identify regions with the best solutions at each level of digital infrastructure development. The analysis of the results in dynamics helped to assess the effectiveness of regional policy for managing digitalization processes. As a result, the authors came to the conclusion that increasing the competitiveness of northern regions in the era of rapid digitalization is possible through investments in human capital and the creation of a network of scientific and technological clusters. The presented approach to assessing the development of individual levels and elements of digital infrastructure will allow for the diagnosis of priority needs of territories under study in the field of digitalization. The results of the study can form the basis for regional policy in the field of sustainable digital development of Russia.

Utilization of coalmine overburden-furnace slag and fly ash mixed cement-treated subbase/base course material for sustainable flexible pavements: mechanical performance and environmental impact.

The scarcity of conventional aggregates with tremendous growth in highway construction and the indiscriminate dumping of industrial waste materials in precious landfills has become a huge global concern. This study is aimed at utilizing wastes from various industries, including coalmine overburden (OB) dump, basic oxygen furnace (BOF) slag, and fly ash to produce suitable and sustainable cement-treated subbase/base course layers (CBSB/CTB) for flexible pavement construction. Response surface methodology was used to optimize the composition of the blended material considering unconfined compressive strength (UCS) and Poisson's ratio. Results demonstrated that 50% OB dump, 40% slag, 5% fly ash, and 5% cement achieved a 7-day UCS of 4.84MPa and Poisson's ratio of 0.25, in line with IRC:37-2018 guidelines. X-ray diffraction (XRD) and field emission scanning electron microscope (FESEM) analysis confirmed the presence of ettringite crystals, calcium-silicate-hydrate (C-S-H), and calcium-aluminosilicate-hydrate (C-A-S-H) gels which are the source of strength development in the blend. Further, a soaked California bearing ratio (CBR) of 136.08% and flexural strength of 2.06MPa after 7days and 28days of curing, respectively, demonstrates the overall strength of the stabilized waste. Approximately 4% weight loss was observed after wet-dry durability tests, indicating exceptional performance of the optimal blend in inclement weather conditions. Furthermore, the environmental impact of the blended material was studied through a leaching study. Fly ash had a high zinc (Zn) level, while BOF slag showed a rich concentrationof chromium (Cr), manganese (Mn), and iron (Fe) in the acid digestion test. In spite of this, the toxicity characteristics leaching procedure (TCLP) test indicated that the levels of heavy metals that leached from the stabilized material stayed considerably below the permissible limits set forth in Indian Standard, IS:10500 (2012). Finally, cost analysis showed a 51.6% reduction in construction cost with cement-treated industrial wastes instead of granular base/subbase made with conventional aggregates. The study recommends the suitability of the stabilized waste material as an alternate construction material for large-scale field applications, which could encourage the construction of flexible pavements that are environmentally benign, economical, and sustainable.

Adsorption Removal of Organophosphates from Water by Steel Slag: Modification, Performance, and Energy Site Analysis

Organophosphates are a type of emerging environmental contaminant, which can be removed effectively by adsorption. Here, modified steel slag was examined for its adsorptive performance in the removal of hydroxyethylidene diphosphonic acid (HEDP) from water. Compared to acid (55.3%, maximum removal rate) and base (85.5%) modification, high-temperature modification (90.6%) significantly enhanced steel slag’s adsorption capacity for HEDP, surpassing that of unmodified slag (71.2%). Kinetic analyses elucidated a two-phase adsorption process—initial rapid adsorption followed by a slower equilibrium phase. The results of adsorption energy analysis showed that modified steel slag preferentially occupied the sites with higher energy, which promoted the adsorption. After five regeneration cycles, the adsorption properties of the material were not significantly reduced, which indicates that the material has good application potential. Microscopic and spectroscopic techniques, including SEM-EDS, FTIR, and XPS, were employed to uncover the surface chemistry and structural changes responsible for the enhanced adsorption efficiency. The adsorption mechanism of HEDP on steel slag is a complete process guided by hydrogen bonding interactions, strengthened surface complexation, and optimized ligand exchange. This study advances the sustainable utilization of industrial waste materials and contributes significantly to the development of innovative water treatment technologies.

Synthesis and Characterization of Carbonaceous Materials for Medical Applications: A Comprehensive Review

Carbonaceous materials have gained significant attention in recent years for their various applications in the field of medicine and biotechnology. This comprehensive review explores the synthesis and characterization of carbon-based materials and their potentials in various medical applications. The paper delves into the methods of fabrication of carbon-based nanoparticles, such as carbon nanotubes, biochar, and graphene, while highlighting their unique properties. Characterization techniques, such as microscopy, spectroscopy, and surface analysis, are discussed to provide insights into the chemical and structural properties of these materials. Furthermore, the review examined their wide-ranging medical applications, encompassing tissue engineering, drug delivery, biosensing, and imaging, showcasing the versatility and promising contributions of carbonaceous materials in the healthcare industry. The review outlines the current challenges and prospects in the field, emphasizing the growing significance of carbon-based materials as valuable tools in advancing medical science and technology, as well as public health.

An analysis of the textural properties of activated carbons obtained from biomass via the LBET, NLDFT and QSDFT methods

This article presents the unique research results of the comprehensive analysis of the porous structure of activated carbons obtained from biomass waste materials from the wood industry during activation in an air atmosphere. The porous structure was analysed on the basis of nitrogen and argon adsorption isotherms via complementary multi-method analysis, i.e. the new numerical clustering-based adsorption analysis, the non-local density functional theory and the quenched solid density functional theory methods. The analytical results for the prepared activated carbons were compared with analogous results obtained for commercial activated carbon. On the basis of the conducted studies it has been determined that the new numerical clustering-based adsorption analysis method gives credible and valuable information on the textural properties of activated carbons which are in strict correlation and mutually complement with the results of the analysis with the use of the quenched solid density functional theory method. The research results obtained in this paper, it has also been shown that from waste materials of the wood industry, in a relatively cheap and cleaner production process, it is possible not only to obtain carbonaceous materials almost comparable to commercial activated carbon, but also to manage the waste in accordance with the principles of a closed-loop economy and sustainable development. The paper pays also attention to the often overlooked economic and ecological aspects, which should nevertheless be taken into account when comparing different adsorbents, rather than their textural properties alone.

Examining the challenges impeding the utilization of construction materials with lower embodied carbon in the construction sector

ABSTRACT This paper aimed at determining the barriers preventing the extensive utilization of innovative materials in the construction sector. As a way of providing clear understanding of the complex interrelationship between the barriers, the literature review was supplemented by an expert-based survey to determine the barriers, whereas the hierarchical structure between the barriers was analyzed using the interpretive structural modelling (ISM) approach. Based on the outcome of the level partitioning of the ISM approach, it was found out that “reluctance to take responsibility for embodied carbon reduction (B14) was partitioned at the 8th level indicating that it is the most highly prioritized barrier considered to be the most crucial in preventing the use of low-carbon building materials in the construction industry. The paper produces vital knowledge and evidence that could be applied to encourage more sustainable construction practices by the wide adoption of alternative construction materials with lower embodied carbon in the construction sector. The implications inferred based on the findings of this paper seek to suggest remedies, strategies, and actions that could help to overcome the undesirable impact of the barriers that affect the utilization of low-carbon building materials, particularly amongst prominent stakeholders of construction projects.

Highly protective and functional strengthening strategies for 3D printed continuous carbon fiber reinforced polymer composites: manufacturing and properties

Carbon fiber-reinforced polymer (CFRP) composites have gradually emerged as a crucial material in the aerospace industry. However, inadequate impact resistance and thermal stability limit survival in extreme environments. Inspired by the specific functions of multiple layers of tissue, from bird feathers to the musculoskeletal system. We propose low-cost composite strengthening strategies and efficient novel three-dimensional graphene aerogel manufacturing methods. A novel graphene aerogel/carbon fiber reinforced polymer (GAC) composite prepared by in-situ laser-induced graphene (LIG) layers on the surface of 3D-printed CFRP. GAC composites enhance CFRP's impact protection, thermal insulation, and electromagnetic shielding capabilities. For protection, GAC composites reduce low-velocity impact damage by 26.2%. The graphene layer can increase the thermal buffering capacity of the material four times, and the long-term service temperature can be increased by 40% compared to traditional CFRP. For functionality, the composites enable electromagnetic interference (EMI) shielding effectiveness of up to 50.2 dB. Furthermore, it can achieve surface heating above 400 °C and rapid de-icing through electrothermal effects. The simple and efficient processing method of GAC composites and tunable functionalities holds promise for the development of highly protective and intelligent aircraft skins.

Enhancing the viscoelastic properties of bacterial cellulose hydrogels through ultrasonic and enzymatic modification of xyloglucan

Bacterial cellulose (BC) hydrogels exhibit nanofibril porous network with good viscoelasticity for use as food ingredients and medical materials. Xyloglucan (XG), a hemicellulose with branching residues, can hybridize with BC to improve the hydrogel's extensibility. Thus, modifying the molecular structure of XG can fine-tune the viscoelastic properties of BC hydrogels. In this study, tamarind seed XG subjected to ultrasonic and enzymatic treatment was hybridized with BC to form composite materials. The results indicated that incorporating modified XG reduced the modulus and enhanced the viscous behaviour of BC to varying degrees. XG modified via ultrasonic treatment demonstrated a higher binding efficiency (19–22 %) with cellulose compared to enzymatically treated XG (11–13 %). The enzymatically treated XG improved the maximum elongation ratio to 57 %, but reduced the storage modulus to 30 kPa. Although ultrasonic-treated XG had a similar effect on the shear modulus, it had less impact on the extensibility of BC, with an elongation ratio of 38 %. Additionally, the incorporation of modified XG also regulated the nonlinear viscoelasticity of BC. These findings advance our understanding of the application of XG as a regulator of mechanical and rheological properties, broadening its utility in BC hydrogel formulations for the food industry and medical material development.