Massive Sulfide Orebodies Research Articles

Neoproterozoic-Early Cambrian Northern Chah-Farsakh Cu-Zn VMS-type deposit, Iran: Constraints from geology, geochemistry, fluid inclusions and geodynamic

Northern Chah-Farsakh is the first seafloor VMS described in the Torud-Chahshirin metallogenic belt of Iran. The deposit is hosted by Neoproterozoic-Early Cambrian mafic (basaltic andesitic)-siliciclastic rocks in volcano-sedimentary basin. The evolution of the ore-bearing basin is governed by the Proto-Tethys Oceanic crust subduction beneath the Central Iranian microcontinent. Three ore facies can be distinguished based on the ore textures studies: stringer zone ore facies, massive-replacement ore facies, bedded ore and distal facies. Pyrite, chalcopyrite, magnetite and sphalerite are the main minerals, together with minor amounts of pyrrhotite, bornite, tetrahedrite and tennantite. Textures include laminated, banded, replacement, massive, and vein-veinlet texture. There is a distinct metal zonation in the massive sulfide orebody; Gold, Ag, and Zn contents increase vertically from the stringer to the bedded ore facies; Cu and Co increase in the massive ore facies, and Pb is highest in the stringer zone. Ore mineralization in the Northern Chah-Farsakh deposit has emplaced in two stages. The fine-grained ore bands (stage 1) which are intricately interlayered with host rock beds, exhibit sedimentary structure such as laminae and bedding are consistent with a syn-sedimentary origin. Coarser-grained stage 2 ores have massive and vein-veinlet textures that are considered to form by replacement during sub-seafloor fluid flow. Based on SEM-EDS analysis, significant compositional variations were observed in the Py-1b grains. Py-1b is enriched in Pb compared to Py-1a. The elemental distribution map shows that the chalcopyrite (Cpy-2) minerals in Northern Chah-Farsakh deposit do not have variable composition and are homogeneous. Fluid inclusions in quartz minerals rom the footwall stringer zone have trapping temperatures between 203 and 500 °C with salinities (3.39–16 wt% NaCl equiv.) higher than modern seawater. Fluid inclusion studies suggest that the ore-forming fluids were derived from seawater. High level of Se in the massive ore facies of the Northern Chah-Farsakh supports the formation of mineralization from a high-temperature hydrothermal fluid. The Northern Chah-Farsakh Cu-Zn VMS deposit typify the mafic-siliciclastic type (Besshi-type), where the majority of the host stratigraphy is composed of a mafic flow-volcaniclastics and sedimentary rocks.

The improvement of sparsity gravity inversion using an adaptive lanczos bidiagonalization method

Inversion of gravity data is one the important steps in the interpretation of practical data. The detection of sharp boundaries between anomalous bodies and host rocks is an interesting point in the geological frameworks. The gravity inversion with sparsity constraint is a useful method to recover block subsurface density distribution, which is efficiently used for the quantitative interpretation of gravity data. The reweighted regularized method is a useful method to solve the inverse problem. However, in this type, we must face the updating gravity forward matrix and large matrix operation. The application of Lanczos bidiagonalization method can reduce the size of data and matrix in the inversion to resolve the large scale inversion problem. However, a very important problem is not resolved, which is update of reweighted forward matrix and new Lanczos bidiagonalization matrix. Here, an adaptive Lanczos bidiagonalization method is studied to select the Lanczos bidiagonalization factor. And a new projected method with adaptive Lanczos bidiagonalization method is study to avoid the updating sparsity reweighted function. We calculate the reweighted forward matrix and Lanczos bidiagonalization matrix only one time, which can essentially reduce the computational complexity. The inversion results of synthetic data show that the new improved method is faster and better than common reweight regularized Lanczos bidiagonalization method to produce an acceptable solution for focusing inverse problem. The improvement of adaptive Lanczos bidiagonalization in sparsity gravity inversion is also tested on gravity data collected over the Mobrun massive sulfide ore body in Noranda, Quebec, Canada. The inversion results indicate a remarkable correlation with true structure of the ore body that is achieved from drilling data.

Bi-Ag-Sulfosalts and Sulfoarsenides in the Ruwai Zn-Pb-Ag Skarn Deposit, Central Borneo, Indonesia

The Ruwai skarn deposit is located in the Schwaner Mountain complex within the central Borneo gold belt and is currently considered the largest Zn skarn deposit in Indonesia. The deposit has been known to host Zn-Pb-Ag mineralization in the form of massive sulfide ore bodies; however, the occurrence of Ag-bearing minerals has not been identified yet. This study documents the mineralogical characteristics of several Bi-Ag sulfosalts and sulfoarsenides, as well as their chemical compositions. Ten Bi-Ag sulfosalts were identified, including native bismuth, tetrahedrite, cossalite, tsumoite, bismuthinite, joseite-B, Bi6Te2S, Bi-Pb-Te-S, Bi-Ag-S, and Bi-Te-Ag. Three sulfoarsenides were identified, including arsenopyrite, glaucodot, and alloclasite. The occurrence of Bi-Ag sulfosalts is typically associated with massive sulfide mineralization, although tsumoite can also be found associated with massive magnetite. In terms of sulfoarsenides, both arsenopyrite and glaucodot are associated with massive sulfide mineralization, whereas alloclasite is associated with massive magnetite mineralization. The Bi-bearing minerals are characterized by irregular, bleb-like texture or patch morphology, and occur either as free grains or inclusions within sulfides, such as galena or pyrite. Tetrahedrite typically has an anhedral shape with a rim or atoll texture surrounding sphalerite or galena. In contrast, sulfoarsenides are typically found as euhedral–subhedral grains where glaucodot typically is rimmed by arsenopyrite. Both Bi-Ag sulfosalt and sulfoarsenides were formed during the retrograde stage under high oxidation and a low sulfidation state condition. The ore-forming temperature based on arsenopyrite geothermometry ranges from 428 °C to 493 °C.

The synergistic use of multi-scale remote sensing data for the identification of hydrothermal alteration patterns in Los Frailes, Spain

• FieldSpec4, SisuROCK, AisaFenix and WorldView-3 results are used synergistically. • Spectral data characterise hydrothermal alterations typical for massive sulphides. • Chlorite and white mica mapping results coincide mostly between the data scales. • Mapping discrepancies are explained by different data types and analysis methods. • Multi-scale spectral data can help to identify potential exploration targets. Remote sensing data can be successfully applied in mineral resource prospecting and exploration. With the increasing number of remote sensing sensors and methods, the application of multi-scale remote sensing data has met a broad audience in the geological remote sensing community over the last few years. Multi-scale remote sensing data close the scale gap between distal (satellite) and proximal (laboratory) remote sensing data, offering both a general and detailed overview of the target and allowing a synergistic use. In this study, the volcano-sedimentary hosted massive sulphide ore deposit Los Frailes in the east of the Iberian Pyrite Belt (IPB) in Spain is investigated for the first time with multi-scale remote sensing techniques. A typical hydrothermal alteration zonation is associated to the massive sulphide ore body in Los Frailes, which is characterised by an inner chlorite-rich zonation showing a strong Fe-enrichment and a peripheral muscovite-rich zonation, which is moderately enriched in Fe. The characterisation of these zones support traditional mineral exploration techniques especially in the prospecting phase by detecting regions of interest, thereby reducing time and cost consumption. By evaluating the synergistic use of multi-scale remote sensing data for massive sulphide exploration, an enhanced application for the economic prospecting and exploration of mineral resources in Los Frailes is introduced. Optical data are used for the detection, identification and characterisation of chlorite and white mica occurrences and compositions. A drill core is analysed with the FieldSpec4 Hi-res hyperspectral point spectrometer. Rock samples are investigated in the laboratory using the SisuROCK hyperspectral core imaging station. AisaFENIX hyperspectral field-based and WorldView-3 multispectral satellite data of the open pit are analysed. The mineral(-group) identification and characterisation are performed with either spectral feature fitting methods (hyperspectral) or mineral indices (multispectral). Hyperspectral analyses show Mg-/Al-substitutions due to Fe-enrichment owing to wavelength shifts of the absorption maximum in chlorite and white mica, respectively. The identification and characterisation of the Fe-OH absorption feature of chlorite at around 2250 nm is more challenging compared to the Al-OH absorption feature of muscovite at around 2200 nm because the spectral signature is more subtle regarding the depth and width. However, the chloritic hydrothermal alteration zonation in the footwall is successfully detected in all scales. The hydrothermal muscovite-rich zonation in the footwall is barely outcropping in the pit and is not captured in the drill core. However, the muscovite-rich alteration zonation in the hanging wall is indicated in all scales. Discrepancies in the results arise mainly from different spectral and spatial resolutions of the sensors and differing data acquirement conditions, such as different surface exposures, viewing angles and illumination conditions. The results show that the multi-scale method offers great opportunities to localise potential prospecting and exploration targets in the Iberian Pyrite Belt. The synergistic use of the different remote sensing scales offers a complete picture of the target by gaining macroscopic to regional spectral information collectively, which is superior to using only one scale. The method is relatively fast and cost-effective, which makes the identification of potential exploration targets more efficient.

A 3D forward-modeling approach for airborne electromagnetic data using a modified spectral-element method

The spectral-element (SE) method, which is based on the Galerkin technique, has been gradually implemented in geophysical electromagnetic (EM) 3D simulation. The accuracy and efficiency of this approach, implemented for deformed hexahedral and regular meshes, has been verified for airborne EM forward modeling. One advantage of the SE method over the conventional finite-element method is that it provides accurate results for earth models that can be adequately parameterized using a coarse mesh. However, realistic models can contain important small-scale conductivity variations or larger features with complicated boundaries. To overcome the limitations imposed by using the same mesh to parameterize the model and for implementing the forward-modeling approach, we have developed an adaptation of the conventional SE method. This is inspired by the ideas behind the element-free Galerkin (EFG) method, in which the conductivity is no longer assumed to be constant within a cell; instead, it is handled via the same kind of numerical integration as in the EFG method. This allows a coarse, regular hexahedral mesh to be used for the forward modeling for complex earth models. After presenting the theory for this new SE approach, we test it for airborne EM modeling of 1D and 3D models to verify its flexibility and accuracy. Finally, we model the Ovoid Zone massive sulfide ore body located at Voisey’s Bay, Labrador, Canada, to illustrate the flexibility and practicality of our approach.

Evolution of the Garmab-e-Paein native copper-rich volcanogenic massive sulfide deposit from northeast Iran: Insights from sulfur isotope and chlorite chemistry

The Garmab-e-Paein Cu-Ag volcanogenic massive sulfide (VMS) deposit occurs as stratiform and stratabound orebody within a specific stratigraphic horizon in a Late Cretaceous volcano-sedimentary sequence of the Sabzevar zone, northeast Iran. The host rocks to mineralization are andesitic-trachyandesitic volcanic and volcaniclastic rocks. Based on textural and mineralogical studies, the VMS mineralization is comprised of four ore facies: 1) vein-veinlets (stringer) containing chalcopyrite, pyrite and minor magnetite, 2) massive ore, dominated by pyrite and minor chalcopyrite, 3) bedded ore containing laminated pyrite, and 4) exhalite containing Fe-Mn oxide-hydroxides such as hematite, psilomelane and pyrolusite. Wall rock alteration styles are chloritic, minor silicic and secondary argillic. There is a distinct metal zonation in the massive sulfide orebody; Au, Pb, As, and Ag contents and the Cu/Zn ratio increase vertically from the stringer to the massive facies, but decrease laterally from the stringer to the bedded facies. Zinc and Mn increase from the stringer to the bedded ore facies. Sulfur isotope values for pyrite range from −1.7 to +5.1‰, with average +1.4‰. The δ34S values of massive ore facies (−1.7 and +2.7‰) increase downward toward the stockwork (+2.2 to +4.3‰) and laterally outward toward the bedded (+5.1‰) zones. The near-zero sulfur isotope values indicate that most of the sulfur was derived from leaching of underlying host volcanic rocks by hydrothermal fluids circulating in the high temperature reaction zone.Extensive disseminations and vein-veinlets of native copper mineralization formed within the hanging wall Late Cretaceous volcanic rocks and younger Paleocene conglomerates. The native copper mineralization is accompanied by chlorite and zeolite alteration, and both formed after formation of the Garmab-e-Paein VMS deposit during diagenesis, burial metamorphism and uplift. The deposit is now potentially economic due to the native copper mineralization.Two generations of chlorite are observed in the deposit: Chl-I is accompanied pyrite and chalcopyrite, in the VMS mineralization system, and the second Chl-II occurs along with zeolite and native copper mineralization. The EPMA results show that Chl-I is more Fe-rich than Chl-II.

Metallogeny of a Pan-African oceanic arc: VHMS and gold deposits in the Ariab-Arbaat belt, Haya terrane, Red Sea Hills (Sudan)

Gold in the Ariab district (Red Sea Hills, Sudan) is mined in gossans developed over volcanogenic massive sulphide (VHMS) deposits formed in the context of a Tonian ensimatic arc of the Haiya terrane, in the Neoproterozoic Arabo-Nubian Shield. All the primary gold occurrences of the Ariab belt, whatever their style (VHMS-, quartz lode- or shear-zone-hosted), appear, however, to have been syn-to late-kinematic, i.e., formed in the context of the final Pan-African collision leading to the Arabian-Nubian Shield (D3 event), and therefore are post-VHMS. Gold is thus found associated with either galena or bismuth telluride in late syn- to post-metamorphic sets of (micro)cracks, mostly within earlier pyrite or arsenopyrite. Gold deposition as native gold or electrum occurred when an intense fluid circulation of metamorphic CO2-H2O rich fluids underwent significant decompression from lithostatic to hydrostatic pressures at temperatures decreasing from 400 to 430 °C at around 8 km depth down to 300 °C. Although no clear evidence of volatile unmixing was observed, the decompression, together with a temperature decrease due to dilution by aqueous rich fluids, favoured gold deposition.The late-D3 gold event in the Ariab belt has all the makings of an orogenic gold system, notably similar to the Late Carboniferous gold event in the West European Variscan belt. Thus, it is possible to propose that, at the end of the collision events, fluids released from the newly formed terrane root were channelled towards the upper crust through the major D3 shear zones such as the Oko shear zone. The fluids outpouring from these major drains were then conveyed through fault plays and damaged zones, up to specific chemical traps within massive sulphide ore bodies or quartz veins systems. Thus, the Ariab gold district could be classified as a representative of the class of orogenic gold deposits.

Structural controls on the localization of the mineralized Copper Cliff embayment and the Copper Cliff Offset dyke, Sudbury Igneous Complex, Canada

The Main Mass of the Sudbury Igneous Complex (SIC) is a 1.5–5 km thick, layered sheet of impact melt rocks, intensely studied because of the magmatic Ni-Cu-PGE sulfide deposits associated with the base of the Main Mass and connected dykes, known as the Sublayer and Offset dykes, respectively. The mode of emplacement of the mineralized Offset dykes that connect to the Main Mass through morphologic crater-floor irregularities (embayments) and the style of post-cratering deformation that affected the Offset dykes is not fully understood. This field-based study of the Copper Cliff Embayment (CCE) and Offset (CCO) dyke contributes to unraveling the mode of melt emplacement and the role of pre-impact faults in the deformation of the southern SIC. Field relationships indicate that the CCO dyke formed before the CCE and Sublayer were chemically fully evolved. Respective melts were injected into footwall rocks weakened by pre-impact deformation and cratering as a protracted event, with barren quartz diorite (QD) emplaced prior to mineralized, inclusion-bearing quartz diorite (IQD). Massive sulfide ore bodies appear to have formed late in the evolution of the dyke and physical separation (decoupling) of silicate magma and sulfide melt is required. NW-SE-shortening folded and faulted the strata hosting the CCO dyke and deformation was facilitated through re-activated E-W-striking, pre-impact faults. Restoring the initial geometry of the dyke and embayment, using 3D modelling and field constraints, helped to refine total slip estimates along major faults and confirmed that melts migrated gravitationally downward into the CCO dyke.

Chemical composition of magnetite and chlorite from the stringer zone of the Nudeh volcanogenic massive sulfide (VMS) deposit, Iran: geological implications

The southwest Sabzevar basin situated in the Sabzevar zone is considered to be an attractive metallogenic province in Iran that hosts both volcanogenic massive sulfide (VMS) and stratiform manganese deposits. The Nudeh Besshi-type VMS deposit is located in the Lower Late Cretaceous volcano-sedimentary sequence. The ore mineralization in this deposit is hosted in the alkali olivine basalt flow and tuffaceous silty sandstone rocks. The Nudeh VMS deposit consists of 2 million metric tons of Cu-Zn massive sulfide overlying a Cu-Fe-rich stringer. The massive sulfide orebody consists dominantly of pyrite, chalcopyrite, friedrichite, magnetite, and sphalerite, together with minor quartz, chlorite, and sericite. Chloritization, silicification, and sericitization are the main wall-rock alteration types; alteration intensity increases towards the stringer zone. Chloritized footwall rocks extend up to 20 m below the stringer zone. The quartz-bearing stringer veins also contain pyrite, chalcopyrite, magnetite, and bornite. Magnetite crystals from the stringer ores show variable contents of many elements, such as MgO (0.05 wt%), Al2O3 (0.63 wt%), TiO2 (0.07 wt%), V2O3 (0.045 wt%), SiO2 (0.65 wt%), CoO (0.10 wt%), NiO (0.009 wt%), ZnO (0.023 wt%), and CaO (0.03 wt%). The moderate to high V contents are interpreted to result from relatively reduced, seafloor hydrothermal activiy. Compositional variations of magnetite are possibly related to variations in oxygen fugacity, temperature, and water/rock interaction. Within the stringer zone, chlorite 2 (Chl-2) in the vein-veinlets and chlorite 1 (Chl-1) in the chloritized alkali olivine basalt rock are chemically indistinguishable, with 26.92–34.67 wt% FeO and 5.99–14.01 wt% MgO. Chlorite geothermometer studies indicate crystallization formation temperatures of 414 °C (Chl-1) and 303 °C (Chl-2), respectively.

Silicate-replacive high sulfidation massive sulfide orebodies in a porphyry Cu-Au system: Bor, Serbia

The Cu-Au deposit of Bor (Serbia) represents a continuum of mineralization styles, from porphyry-style ore occurring in quartz-magnetite-chalcopyrite veins and chalcopyrite disseminations to high-sulfidation epithermal Cu-Au ores in pyrite-chalcopyrite and anhydrite-sulfide veins. Decisive for the great economic importance of Bor is the presence of exceptionally rich high-sulfidation massive sulfide orebodies, composed of pyrite + covellite + chalcocite/digenite and minor anhydrite and enargite. They form irregular bodies measuring 0.5–10 million tons of ore grading up to 7% Cu, hosted by andesites and surrounded by intense argillic alteration. This study focuses on a small but rich underground orebody mined out recently, where limited drillcore is preserved for quantitative geochemical study. This paper documents the vein relationships within the deep porphyry-style orebody of Borska Reka, the transitional porphyry-epithermal veins, and the overlying and laterally surrounding epithermal massive sulfides of the Bor deposit. Geological observations indicate that the formation of massive sulfide orebodies concludes the ore formation. Mass balance calculations, recast into geologically realistic bulk fluid-rock reactions, confirm textural evidence that near-isovolumetric replacement of andesite host rocks is the dominant formation mechanism of massive sulfide orebodies at Bor, whereby all lithophile elements including Si are dissolved and only Ti stays relatively immobile. While net volume changes for individual mineralization styles within the massive sulfide orebody vary from − 16% volume loss to + 127% volume gain, overall volume change for the whole massive sulfide orebody was probably slightly negative. Brecciation is important only as means of creating channelways for reactive fluid that turns the andesite protolith into massive sulfide, whereas net breccia infill occurred only locally.

Lithostratigraphy of the Copperton Formation, Areachap Group

Abstract The type area of the Copperton Formation is on the farms Vogelstruisbult 104, Somuspan 105 and Dooniespan 108 in Prieska District. Outcrop is poor and the type material is preserved in exploration borehole cores from the Prieska Copper Mines and the Annex Cu-Zn deposits. It is highly deformed and variably metamorphosed. Thus it is a lithodemic unit, but interpreted as a supracrustal sequence and described as a formation including lithologically distinct members. The Copperton Formation comprises a wide range of rock types including metabasic and intermediate gneisses with minor amounts of metapelitic and calc-silicate rocks. Metamorphic parageneses generally reflect amphibolite facies metamorphism, but granulite and retrograde greenschist facies zones also occur. The protoliths are interpreted as an arc-related volcano-sedimentary package and the Smouspan Member metadacite is dated at 1284 ± 9 Ma. Members are distinguished as follows: The Magazine Member is dominated by calc-silicate rocks which are dominant in outcrop but rarely found in borehole cores. The Smouspan Gneiss is a fairly homogeneous hornblende-biotite intermediate gneiss which is up to 400 meters thick in an isoclinal fold structure. It comprises the footwall to the Prieska Copper Mines Member, in which the massive sulphide orebody occurs, enclosed in an alteration assemblage comprising dark gedrite fels and strongly foliated, leucocratic quartz-perthite-sillimanite gneiss. The ore is interpreted as a volcanogenic massive sulphide deposit formed in a Mesoproterozoic island arc system. The Vogelstruisbult Member is the hanging wall unit, comprising mainly laminated amphibolites and metapelites, but also containing a variety of rock types including hornblende gneiss, biotite gneiss, chlorite schist, and calc-silicate gneiss. Away from the Prieska Mines orebody, a similar variety of rock types is found, and not subdivided but classified as Copperton Formation, a mappable unit. The same assemblage of rock types, including massive sulphide mineralization, was intersected in drill holes on the farms Kielder (portion of Doonies Pan 108), Eierdop Pan and Kantienpan to the north. The Copperton Formation is the southernmost unit of the Areachap Group which is exposed between Prieska Copper Mines and Areachap Mine north of Upington, where the Jannelsepan and Bethesda formations occur. The Copperton Formation is partly obscured in many places by Dwyka Group tillite cover which thickens southwards. A sequence of structural and metamorphic events affected the Copperton Formation and Areachap Group during the 1.2 to 1.0 Ga Namaqua-Natal orogeny. These involved collision of the Areachap Terrane with the Kaapvaal-Rehoboth Craton at about 1220 Ma, a thermal and deformational event coeval with the continental-scale Umkondo mantle event at about 1100 Ma, followed by uplift, erosion and the development of right-lateral shear zones of the Doornberg Lineament, with cooling below 300°C by 920 Ma. A Cambrian peneplain developed in the region which was first covered by Nama Group sandstones, then glaciated and covered by Permian Dwyka Group tillites which are presently being eroded to expose the Copperton Formation.

Origin of Au-Rich Carbonate-Hosted Replacement Deposits of the Kassandra Mining District, Northern Greece: Evidence for Late Oligocene, Structurally Controlled, and Zoned Hydrothermal Systems

Abstract The Au-rich polymetallic massive sulfide orebodies of the Kassandra mining district belong to the intrusion-related carbonate-hosted replacement deposit class. Marble lenses contained within the Stratoni fault zone host the Madem Lakkos and Mavres Petres deposits at the eastern end of the fault system, where paragenetically early skarn and massive sulfide are spatially associated with late Oligocene aplitic and porphyritic dikes. Skarn transitions into predominant massive and banded replacement sulfide bodies, which are overprinted by a younger assemblage of boulangerite-bearing, quartz-rich sulfide and late quartz-rhodochrosite vein breccias. The latter style of mineralization is most abundant at the Piavitsa prospect at the western end of the exposed fault system. The sulfide orebodies at the Olympias deposit are hosted by marble in association with the Kassandra fault, where textural and mineralogical similarities to the sulfide bodies within the Stratoni fault zone suggest a genetic relationship. Estimated trapping temperatures and pressures based on fluid inclusion data indicate that carbonate replacement mineralization took place at depths less than about 5.9 km. Carbon and oxygen isotope patterns in carbonate from the Stratoni fault zone support isotopic exchange principally through fluid–wall-rock interaction, whereas decarbonation and fluid-rock exchange reactions were important at the Olympias deposit. Carbonate minerals associated with skarn and replacement sulfide throughout the district have isotopic compositions that are consistent with formation from a hydrothermal fluid of magmatic origin. Lower homogenization temperatures and salinities in the younger quartz-rich sulfide assemblage and quartz-rhodochrosite vein breccias, together with low δ18O values of gangue carbonate, suggest dilution of a primary magmatic fluid with meteoric water late in the evolution of the hydrothermal system in both the Olympias area and the Stratoni fault zone. The replacement sulfide orebodies in the district likely inherited their uniform Pb isotope composition from a late Oligocene igneous source and the isotopically heterogeneous metamorphic basement units. Metal distribution patterns at the scale of the Stratoni fault zone show diminishing Cu concentration with decreasing Pb/Zn and Ag/Au ratios from Madem Lakkos to Mavres Petres and the Piavitsa prospect in the west. The sulfide orebodies at the Olympias deposit exhibit elevated Cu values in the east with increasing Pb/Zn and Ag/Au ratios down-plunge to the south-southwest. Metal concentration and ratios support zoning related to temperature and solubility changes with increasing distance from a probable magmatic source. Structural and igneous relationships, together with fluid inclusion microthermometric and carbon-oxygen isotope data and metal distribution patterns, are supportive of a zoned hydrothermal system that exceeded 12 km along the Stratoni fault zone, sourced by an igneous intrusion to the southeast of the Madem Lakkos deposit. The Olympias replacement sulfide orebodies, associated with the Kassandra fault, resulted from a local hydrothermal system that was likely derived from a concealed igneous intrusion to the east of the deposit.

Tectonic setting and metallogenic chronology of the Ashele Cu–Zn deposit in Xinjiang, NW China: Constraints from Re-Os dating of pyrite, U-Pb dating of zircon and Hf isotopes

The Ashele Cu-Zn deposit, an important volcanogenic massive sulfide (VMS) deposit, is located in the centre of the Ashele volcano-sedimentary basin of the Altay metallogenic belt, North Xinjiang, NW China. The No. 1 orebody is located between the roof basalt and the base tuff. The roof basalt yielded a zircon U-Pb age of 342 ± 4.6 Ma (MSWD = 1.5). Four pyrite samples from massive ores sulfides yielded a Re-Os isochron age of 342 ± 11 Ma (MSWD = 9.2), while the vein sulfide has a model age of 315 Ma. This shows that massive sulfide orebodies developed contemporaneously with the emplacement of the roof basalt. The basalts have geochemical characteristics of tholeiitic basalts with relatively high Mg# values (62.7–63.9), Cr and Ni, a slightly negative Eu anomaly (δEu = 0.75–0.87), and relatively low concentrations of Sr, Nb/Ta and (La/Yb)N. The dacite has characteristics similar to those of sanukite, in terms of high concentrations of Mg# values (52.7–53.0), a weakly negative Eu anomaly (δEu = 0.90–1.04), and low concentrations of Cr, Ni, Sr and (La/Yb)N. Hf isotope analysis in the basalt exhibits the εHf(t) value of (+9.68 to + 17.03). The two-stage Hf model age (TDM2) shows 259–727 Ma with an average of 500 Ma. These geochemical characteristics indicate that the deposit formed in the magmatic arc setting, whereas the basalt originated from young (regenerated) mantle material. Re/Os and common Os imply that crust-derived and S-rich sediments also contributed to the ore formation. Accordingly, based on the results of this study and review of the regional magmatic framework, we can conclude that the Ashele deposit is diplogenetic, with VMS epigenetic and hydrothermal mineralization expressed.

Geochemistry and architecture of the host sequence of the massive sulfides in the northern Iberian Pyrite Belt

The northernmost Iberian Pyrite Belt hosts several small felsic volcanogenic massive sulfide orebodies (<15 Mt), except the Aguas Teñidas and Magdalena each with ca. 45 Mt, which are economically important because of their high base and precious metal grades if compared with the bulk of the IPB. They occur aligned in a E-W belt located just south of the major suture that limits the South Portuguese Zone with the Pulo do Lobo Unit. The mineralization is related to a specific felsic volcanic unit that occurs in different tectonically dismembered units, but has a specific geochemical signature and a characteristic hydrothermal alteration. Six principal tectonostratigraphic units can be differentiated: (1) The Lower Felsic Unit is composed of feldspar-quartz-phyric rhyodacite (crypto)-dome complexes, intruded by sills and dykes of similar composition. Pumice and glass-rich breccia beds occur at the top and on the lateral margins of the dome complexes. A major shear zone separates the Lower Felsic Unit from the overlying Volcano-Sedimentary Unit; (2) The Volcano-Sedimentary Unit consists of vesicular basaltic lava and associated mafic epiclastic sandstone and siltstone, intercalated with thin beds of shale. A major tectonic contact marks the upper boundary; (3) The Middle Felsic Unit represents a series of intercalated coherent rhyolite domes with associated volcaniclastic rocks, and polymictic epiclastic sedimentary rocks. They are cut by numerous volcanic dykes and geochemically equivalent sub-volcanic intrusions; (4) The Sedimentary Unit is a highly deformed package of grey siltstone with interlayered shale and fine-grained epiclastic sedimentary rocks; (5) The Upper Felsic Unit is a package of dacitic to rhyolitic dome complexes with similar characteristics to the Lower Felsic Unit. Both the basal and upper contacts of this unit are narrow and high-strain tectonized zones. (6) The uppermost unit, the Andesite Unit, is comprised of andesitic dome complexes rich in hyaloclastite breccias and andesitic volcaniclastic rocks. Massive sulfides are hosted dominantly by the Lower Felsic Unit with only some orebodies related spatially to the Upper Felsic Unit (Lomero Poyatos, San Telmo and El Carpio).Geochemically, the Volcanic Sedimentary Complex is dominated by andesitic to rhyolitic calc-alkaline magmatic rocks with a significant proportion of dacite and andesite. The Lower Felsic and Upper Felsic Units are geochemically identical and probably represent dismembered parts of a single volcanic felsic complex. If that holds true, massive sulfide deposits of the northern IPB are hosted by volcaniclastic rocks located in the hanging wall of a single unit dominated by dacite-rhyolite dome complexes. This volcanic unit is characterized by Zr contents <200 µg/g (ppm) which are significantly lower than those of the more evolved Middle Felsic Unit (200–750 µg/g).Structural analysis and the geochemistry suggest that the volcanic sequence is tectonically imbricated, with the youngest units located at the lowest structural position. The proposed reconstructed stratigraphic sequence comprises an andesitic footwall, overlain by the felsic complexes of the Middle Felsic and Lower-Upper Felsic Units. Thus, the massive sulfide deposits formed toward the top of the whole sequence, and associated with the youngest felsic rocks having a specific geochemistry.

He-Ar Isotopes and Trace Gas Compositions of Fluid Inclusions in Massive Sulphides from the Yushui Copper-Polymetallic Deposit, South China: Metallogenic Implications

The Yushui ore deposit, located in the middle section of the Yong’an-Meixian Hercynian depression, is a medium-sized Cu-polymetallic massive sulphide deposit in Eastern Guangdong Province, South China. This deposit is characterized by unusually high copper grade (up to 50–60 wt. % Cu). Other metallic elements, such as lead, zinc and silver, are also economically important in the Yushui ore bodies. The aim of this study was to apply N2–Ar–He systematics, together with organic gases (light-hydrocarbon tracers), to constrain the origin and evolution of ore-forming fluids. The helium-argon isotopes and trace gas compositions of fluid inclusions trapped within metal sulphide minerals were measured for a number of bonanza ores from the Yushui deposit. The noble gas concentrations in the studied samples vary over one to two orders of magnitude (4He: 2.27–160.00 × 10−5 cm3 STP g−1; 3He: 0.53–34.88 × 10−12 cm3 STP g−1; 40Ar: 6.28–37.82 × 10−7 cm3 STP g−1; 36Ar: 1.25–10.40 × 10−9 cm3 STP g−1). Our data show a narrow range of 3He/4He ratios from 0.006 to 0.056 Ra (~0.026 Ra on average, n = 8), which are considerably lower than the modern atmospheric end-member value; whereas the 40Ar/36Ar ratios (ranging from 333.76 to 501.68, with an average of 397.53) are significantly greater than that of air-saturated water. Most of the bornite samples have somewhat higher 3He/4He ratios of trapped fluids when compared to chalcopyrite. Overall, these He-Ar results are well within the range of crustal reservoir, thus implying a predominantly crustal source (originated from Caledonian basement) for ore-forming solutions, with little contribution from mantle-derived fluids. Analysis of the N2–Ar–He composition in Cu-rich sulphides indicates that the Yushui ore-forming fluids were probably derived from formation water (or basinal hot brines). Moreover, organic gas species identified in sulphide-hosted fluid inclusions are mainly composed of C1–C4 alkanes, while the concentrations of unsaturated olefins and aromatic hydrocarbons are very low. In particular, most chalcopyrite samples with relatively low 3He/4He ratios (0.006–0.016 Ra) and 40Ar*/4He values (0.0002–0.0012) are generally characterized by very high CO2/CH4 ratios (~60–102). All these suggest that main-stage Cu-Ag metallogenic processes might have not been affected by high-temperature magmatic activities or superimposed by strong metamorphic overprinting, although some chalcopyrite-rich ores appear to be influenced by later stage hydrothermal processes. In summary, neither magmatic input nor convecting seawater has played an important role in the formation of Yushui copper-polymetallic deposit. The massive sulphide ore bodies were products of water–rock interaction between metal-bearing basinal brines and the host sedimentary strata.

Jurassic ore-forming systems during the Tethyan orogeny: constraints from the Shamlugh deposit, Alaverdi district, Armenia, Lesser Caucasus

The Shamlugh polymetallic deposit located in the Alaverdi mining district, Armenia, is hosted by Middle Jurassic magmatic rocks of the Somkheto–Karabakh island arc, Lesser Caucasus. Lithogeochemistry and radiogenic isotope geochemistry indicate a subduction setting with an evolution from tholeitiic to transitional Middle Jurassic magmatism to calc-alkaline to high-K calc-alkaline Late Jurassic magmatism. A progressively more juvenile mantellic input in the magmatic source is noted. Ore consists of stratabound massive sulfide ore bodies, ore-bearing breccia, stockwork-style mineralization, and disseminated ore hosted by a pyroclastic host rock unit below a subvolcanic rhyolitic sill. Towards depth, the stratabound ore is connected to subvertical high-grade sulfide veins hosted by basaltic andesitic, andesitic, and dacitic tuff and lava breccia. Ore minerals include principally pyrite and chalcopyrite with minor sphalerite and hematite. Hydrothermal alteration consists of quartz, chlorite, carbonate, and sericite in the footwall pyroclastic rock, tuff, and lava breccia, which are also crosscut by late-stage carbonate and barite veins. The rhyolitic sill has been altered by silica and sericite and contains rare sulfides. Sulfur isotope values for sulfides range from + 0.7 to + 4.6‰ and suggest an essentially magmatic source for sulfur. Strontium isotopic compositions of hydrothermal carbonates and sulfates (0.70507–0.70660), sulfur isotopes of sulfates (+ 16.8 to + 17.3), and carbon and oxygen isotopic compositions of late-stage carbonates (δ18O VSMOW + 15.9 to + 17.6‰; δ13C VPDB − 1.8 to − 0.8‰) not only are permissive with seawater incursion in the ore-forming hydrothermal system but can also be attributed to fluid–rock interaction with hidden metamorphic basement rocks and Jurassic magmatic rocks. The lead isotopic composition of sulfides (206Pb/204Pb 18.505 to 18.586, 207Pb/204Pb 15.611 to 15.636, 208Pb/204Pb 38.516 to 38.640) implies leaching of the Middle Jurassic host rocks as the main source of Pb. LA-ICP-MS U–Pb zircon dating of the hanging wall rhyolitic sill affected by hydrothermal alteration yielded an age of 155.0 ± 1.0 Ma and provides a maximum age for mineralization. Ore formation at Shamlugh is younger than the immediate Middle Jurassic host rocks and is related to the Late Jurassic calc-alkaline and high-K calc-alkaline magmatic evolution. Late Jurassic magmatism includes a tonalite dated by LA-ICP-MS U–Pb zircon geochronology at 152.9 ± 0.7 Ma that hosts the 146-Ma-old Teghout porphyry deposit. In the absence of other age constraints, the genetic relationship of the polymetallic Shamlugh deposit with the Teghout porphyry deposit remains open to question. Nevertheless, hydrothermal minerals and alteration paragenesis and the lithologically and structurally controlled ore body geometry at Shamlugh are consistent with a low to intermediate sulfidation epithermal model.

Numerical heat and fluid flow modeling of the Hercynian Draa Sfar polymetallic (Zn–Pb–Cu) massive sulfide deposit, Central Jbilets, Morocco

Draa Sfar is a polymetallic (Zn–Pb–Cu) volcanogenic massive sulfide deposit with an actual resource of 13 Mt at 4.0% Zn and 1.3% Pb. It is part of the central Jbilets area known for its several Cu–Zn ore deposits. The ore is hosted in the upper Visean-Namurien sedimentary formation. Owing to the complexity of the geology of the ore deposits, numerical simulation approach was attempted to shed light into the temperature distribution, the circulation of the hydrothermal fluid and the genesis of massive sulfide ore bodies by evaluating the permeability, porosity, and thermal conductivity. On the basis of this simulation approach, the ore is predicted to be deposited at a temperature ranging between 230 and 290 °C. This temperature range is dependent on the pre-existing temperature of the discharge area where a metal-rich fluid precipitated the ore. The duration of the Draa Sfar ore body formation is predicted to be 15, 000 to 50, 000 years. Based on geological studies of Draa Sfar deposit together with the aforementioned results of the simulation approach, an ore genetic model for the massive sulfide ore bodies is proposed. In this model, the supply of ore-forming fluids is ensured by the combination of seawater and magmatic waters. Magma that generated rhyodacite dome acted as the heat source that remobilized the circulation of these ore-bearing fluids. The NW-SE trending faults acted as potential pathways for both the downward and upward migration of the ore-forming fluids. Due to their high permeability, the ignimbritic facies, host rocks of Draa Sfar ore bodies, have favored the circulation of the fluids. The mixing between the ore-forming fluids of magmatic origin and the descending seawaters and/or in situ pore waters led to the formation the ore bodies in 35,000 years. The position and size of the ore body, determined by the simulation approach, is consistent with the actual field geological data.

Critical elements in non-sulfide Zn deposits: a reanalysis of the Kabwe Zn-Pb ores (central Zambia)

ABSTRACTThe Kabwe Zn-Pb deposit (central Zambia) consists of a cluster of mixed sulfide and non-sulfide orebodies. The sulfide ores comprise sphalerite, galena, pyrite, chalcopyrite and accessory Ge-sulfides (±Ga and In). The non-sulfide ores comprise: (1) willemite-dominated zones encasing massive sulfide orebodies and (2) oxide-dominated alteration bands, overlying both the sulfide and Zn-silicate orebodies. This study focuses on the Ge, In and Ga distribution in the non-sulfide mineralization, and was carried out on a suite of Kabwe specimens, housed in the Natural History Museum Ore Collection (London). Petrography confirmed that the original sulfides were overprinted by at least two contrasting oxidation stages dominated by the formation of willemite (W1 and W2), and a further event characterized by weathering-related processes. Oxygen isotopic analyses have shown that W1 and W2 are unrelated genetically and furthermore not related to supergene Zn-Pb-carbonates in the oxide-dominated assemblage. The δ18O composition of 13.9–15.7‰ V-SMOW strongly supports a hydrothermal origin for W1. The δ18O composition of W2 (−3.5‰ to 0‰ V-SMOW) indicates that it precipitated from groundwaters of meteoric origin in either a supergene or a low-T hydrothermal environment. Gallium and Ge show a diversity of distribution among the range of Zn-bearing minerals. Gallium has been detected at the ppm level in W1, sphalerite, goethite and hematite. Germanium occurs at ppm levels in W1 and W2, and in scarcely detectable amounts in hemimorphite, goethite and hematite. Indium has low concentrations in goethite and hematite. These different deportments among the various phases are probably due to the different initial Ga, In and Ge abundances in the mineralization, to the different solubilities of the three elements at different temperatures and pH values, and finally to their variable affinities with the various minerals formed.

Variation of acceleration due to gravity (g) in Sokoto metropolis of Sokoto state, Nigeria

Gravity method was reportedly the first geophysical technique to be used in oil and gas exploration. Despite being eclipsed by seismology, it has continued to be important in a number of exploration areas. Gravity method is being used in mining applications to map subsurface geology and to directly calculate ore reserves for some massive sulphide ore-bodies. There is also a modest increase in the use of gravity techniques in specialized investigations for shallow targets. Acceleration due to gravity, g, of 7 different locations within Sokoto metropolis of Sokoto state Nigeria was determined using a Kater reversible pendulum. The measured acceleration due to gravity ranges from 9.791 to 9.813 m/s2.

Geochemical behavior during mineralization and alteration events in the Baiyinchang volcanic-hosted massive sulfide deposits, Gansu Province, China

The Zheyaoshan deposit is the largest within the Baiyinchang (BYC) volcanic-hosted massive sulfide (VHMS) district, located in the northern Qilian orogenic belt of North China. The deposit is hosted by quartz keratophyre tuffs, with wall-rock alteration mainly comprising chlorite, sericite, quartz, pyrite and epidote. Mineral assemblages within the altered host rocks can be divided into a sericite-quartz-dominant assemblage (sericite-silicified zone), a chlorite-dominant assemblage (chlorite-dominant zone) and a pyrite-dominant assemblage (mineralized zone) based on geochemical analysis and alteration characteristics. We have conducted detailed processing and critical analysis of the geochemical data of both the altered and least-altered host rocks in order to investigate the problem of closure in the geochemical dataset to eliminate the influence that each component has on the other in terms of mass change, and have applied the standardized method of the mass change calculation to analyze this data. The results show that: (1) the sericite-silicified zone formed along fissures due to the ingress of hydrothermal fluids, with MnO2, Na2O and CaO being mobilized into the hydrothermal fluids leached and MgO, Fe2O3, SiO2, K2O, BaO deposited. Additionally, Ag, Cu and chalcophile elements (Ag, As and Bi) were enriched while Pb, Zn and large ion lithophile elements (LILEs) (Cs, Sr, Eu, Be) were mobilized into hydrothermal fluids; (2) the physiochemical conditions and pH levels of the hydrothermal fluids changed during sericitization, with MgO, Fe2O3, BaO being further enriched and MnO, Na2O, CaO further depleted, leading to formation of chlorite and the initial precipitation of metallogenic the (Cu, Zn, Pb) and chalcophile elements (Ag, As, Bi); (3) the negative Eu anomaly was mainly due to its strong activity when Eu is mobilized into the hydrothermal fluids during since plagioclase break-down during the sericite-silicification process; (4) AI and CCPI values gradually increase towards the orebody. The chlorite-dominant assemblage and sericite-quartz-dominant assemblage on the periphery of the chlorite-dominant zone can all be used as vectors towards the volcanic massive sulfide orebody and for regional-scale mineral exploration. Either leached elements or enriched elements can be considered as significant indicator elements and as prospective indicators for geochemical exploration within the BYC district. The Eu anomaly may be especially useful as an indicator for distinguishing the least-altered rocks which has great significance for exploration on the regional scale.