Recently, deteriorated masonry structures aged over 30 years have shown serious structural problems. Simple and rapid maintenance plans are urgently needed for aging masonry structures. Polyurea (PU) is an effective retrofitting material for aging structures due to its easy spray application. This process saves time, reduces costs, and allows the structure to remain in use during retrofitting. However, a general PU is not suitable for retrofitting aged masonry and concrete structures due to its low stiffness. In this study, stiff-type polyurea (STPU) was selected as the reinforcement material for masonry structures. It was developed by modifying the chemical mix of general PU to improve stiffness. To evaluate the strengthening effect of STPU on masonry members under static loading, tests were conducted. The flexural load capacity of masonry beams with STPU-sprayed surfaces was assessed. Three different types of STPU applications were used to select the most efficient strengthening method. Reinforcing masonry structures with STPU allows brittle failure modes to achieve ductile behavior. This improves their structural performance under lateral stresses. The experimental data were used to calibrate FEM models for simulation. These models can be used for future parametric studies and masonry structural design.