Martian Origin Research Articles

The influence of ALH 84001 on our understanding of the origin and evolution of Mars

AbstractALH 84001 is an orthopyroxenite that is the oldest known Martian meteorite. Given this rock type and age, and the possible source locations, ALH 84001 represents an opportunity to learn more about basic geologic relations in the Martian highlands in the southern hemisphere. Its orthopyroxene‐rich mineralogy is unique and also includes C‐, S‐, P‐bearing minerals. ALH 84001 can provide constraints on chronology, geology and surface features, crust formation, paleomagnetism, weathering, climate, magmatism, and interior structure. When it was recognized to be of Martian origin (~1994), there were ~12 known Martian meteorite samples. That number is now >150, with only one other meteorite (NWA 7034) having clasts that are similar in age to ALH 84001. Thus, it remains a unique sample and continues to provide opportunities to understand this early period of Martian history.

The influence of oxychlorine phases on the flash pyrolysis of polycyclic aromatic hydrocarbons and implications for mars

A variety of chlorine-bearing hydrocarbons have been detected in the chemical analyses of soil and rock samples performed on Mars with the GCMS instruments onboard the Viking landers and the SAM instrument suite onboard the Curiosity rover. These aromatic and aliphatic chlorohydrocarbons are most likely produced by chemical reactions between salts (e.g., perchlorates, chlorates) and organic molecules of martian origin either during the thermal processing of the samples in flight or generated through radiation processes happening in Mars’ near surface. To understand the influence of salts on the organic molecules during pyrolysis and identify the potential precursors of the chlorohydrocarbons detected on Mars, we performed a systematic study and pyrolyzed three polycyclic aromatic hydrocarbons (PAHs)—naphthalene, phenanthrene, and benzanthracene—in the presence of six perchlorate and chlorate salts that have been identified or are most likely present on Mars—calcium perchlorate, iron perchlorate, sodium perchlorate, magnesium perchlorate, sodium chlorate, and potassium chlorate. Iron perchlorate had the strongest (oxy)chlorination power on the PAHs of all the salts tested whereas magnesium perchlorate and potassium chlorate were the most destructive ones. Despite the presence of these caustic salts, PAHs were highly chemically and thermally stable, suggesting they would likely be detectable natively if present in a martian sample. In addition, chlorohydrocarbons that are characteristic of the parent PAH were formed and could be used to help identify the nature of a PAH. This investigation underlines that PAHs could be the precursors of aromatic chlorohydrocarbons detected on Mars, but a definitive identification will require the detection of the parent PAHs and their respective pyrolyzates, molecules that were not yet detected on Mars likely because of the flight operating constraints of the SAM instrument.

Variability of Atomic Hydrogen Brightness in the Martian Exosphere: Insights From the Emirates Ultraviolet Spectrometer on Board Emirates Mars Mission

AbstractThe Emirates Mars Ultraviolet Spectrometer (EMUS), aboard the Emirates Mars Mission (EMM), has been conducting observations of ultraviolet emissions within the Martian exosphere. Taking advantage of the distinctive orbit of the EMM around Mars, EMUS utilizes a dedicated strafe observation strategy to scan the illuminated Martian exosphere at tangential altitudes ranging from 130 to over 20,000 km. To distinguish between emissions of Martian origin and those from the interplanetary background, EMUS conducts specialized background observations by looking away from the planet. This approach has allowed us to investigate the radial and seasonal variations in Martian coronal emission features at H Lyman‐α, β and γ wavelengths. Our analysis supports the previous studies indicating that Martian exospheric hydrogen Lyman emission brightness attains its highest levels around the southern summer solstice and reaches its lowest levels when Mars is near aphelion. Additionally, a secondary peak emission at all altitudes is observed after perihelion during Martian Year (MY) 36, which can be attributed to a Class C dust storm. Our study establishes a strong correlation between solar flux and coronal brightness for these emissions, highlighting the impact of solar activity on the visibility of Martian corona. In addition, we have examined interannual variability and found that emission intensities in MY 37 surpassed those in MY 36, primarily due to increased solar activity. These observations help to understand potential seasonal patterns of exospheric hydrogen, which is driven by underlying mechanisms in the lower atmosphere and solar activity, eventually suggesting an impact on water loss in the Martian atmosphere.

Tiny Martian Moon May Be a Chip Off the Old Block

A close approach to Deimos reveals that its surface does not look like that of an asteroid, hinting at a Martian origin.

Resolving the History of Life on Earth by Seeking Life As We Know It on Mars

An origin of Earth life on Mars would resolve significant inconsistencies between the inferred history of life and Earth's geologic history. Life as we know it utilizes amino acids, nucleic acids, and lipids for the metabolic, informational, and compartment-forming subsystems of a cell. Such building blocks may have formed simultaneously from cyanosulfidic chemical precursors in a planetary surface scenario involving ultraviolet light, wet-dry cycling, and volcanism. On the inferred water world of early Earth, such an origin would have been limited to volcanic island hotspots. A cyanosulfidic origin of life could have taken place on Mars via photoredox chemistry, facilitated by orders-of-magnitude more sub-aerial crust than early Earth, and an earlier transition to oxidative conditions that could have been involved in final fixation of the genetic code. Meteoritic bombardment may have generated transient habitable environments and ejected and transferred life to Earth. Ongoing and future missions to Mars offer an unprecedented opportunity to confirm or refute evidence consistent with a cyanosulfidic origin of life on Mars, search for evidence of ancient life, and constrain the evolution of Mars' oxidation state over time. We should seek to prove or refute a martian origin for life on Earth alongside other possibilities.

Manganese oxides in Martian meteorites Northwest Africa (NWA) 7034 and 7533

We report the discovery of indigenous Mn-oxides in Martian regolith breccias Northwest Africa (NWA) 7034 and 7533. These Mn-oxides occur in Mn-rich regions as nanocrystals mixed with silicates, FeOOH, and possible phosphates. The Mn-rich regions contain up to 34 wt% Mn and typically display large chemical gradients on the scale of 10–20 μm. The Martian origin of Mn-oxides was established by the presence of Mn-rich glass (4.8–5.6 wt% Mn) in the fusion crust that crosscuts a Mn-oxides-bearing monzonite clast and by the absence of Mn-oxides on the environmentally exposed surfaces (exterior and fractures) of the meteorites. Manganese K-edge X-ray absorption spectrum (XAS) of the Mn-rich glass in the fusion crust indicated that this glass included high-valent Mn species. Synchrotron micro-X-ray diffraction of a Mn-rich region in a basalt clast and XAS of Mn-rich regions in three monzonite clasts indicate Mn-oxides in these regions are dominantly hollandite-structured with 67–85 mol% of the total Mn being Mn4+. The fact that Mn-rich regions are present in diverse petrological associations but are absent in the matrix of the breccias indicates that the Mn-oxides formed through surface alteration prior to the final brecciation event that assembled NWA 7034 and 7533. Thus, the age of the Mn-oxides is older than the lithification age (arguably 1.35 Ga) of NWA 7034 and 7533. Together with findings of Mn-rich phases within Noachian and Hesperian sedimentary strata in Endeavour and Gale craters, our results suggest that Mn-oxides are a common weathering product on Mars, suggesting aqueous environment on the Martian surface with high redox potential.

Advances in Cosmochemistry Enabled by Antarctic Meteorites.

At present, meteorites collected in Antarctica dominate the total number of the world's known meteorites. We focus here on the scientific advances in cosmochemistry and planetary science that have been enabled by access to, and investigations of, these Antarctic meteorites. A meteorite recovered during one of the earliest field seasons of systematic searches, Elephant Moraine (EET) A79001, was identified as having originated on Mars based on the composition of gases released from shock melt pockets in this rock. Subsequently, the first lunar meteorite, Allan Hills (ALH) 81005, was also recovered from the Antarctic. Since then, many more meteorites belonging to these two classes of planetary meteorites, as well as other previously rare or unknown classes of meteorites (particularly primitive chondrites and achondrites), have been recovered from Antarctica. Studies of these samples are providing unique insights into the origin and evolution of the Solar System and planetary bodies.

Real time history of 21st century bacteria: giants and martians

We denominate "21st century bacteria" two types of strange and amazing creatures from the kingdom Protista, discovered between the last years of the twentieth and the present days: the giant bacteria and those with a possible Martian origin. Searching for them, bold investigators have travelled to distant and hostile lands, desolate places and deep waters, performing a kind of investigation that we only can describe as "investigation-adventure". This paper presents expeditions to the Red Sea, fishing the Epulopiscium; to Lake Mono, searching a bacteria able to growth with arsenic; to the Antarctic Circle, finding a meteorite with petrified alien microorganisms; and… to the quiet laboratory, a not less dangerous place.

How Will We React to the Discovery of Extraterrestrial Life?

How will humanity react to the discovery of extraterrestrial life? Speculation on this topic abounds, but empirical research is practically non-existent. We report the results of three empirical studies assessing psychological reactions to the discovery of extraterrestrial life using the Linguistic Inquiry and Word Count (LIWC) text analysis software. We examined language use in media coverage of past discovery announcements of this nature, with a focus on extraterrestrial microbial life (Pilot Study). A large online sample (N = 501) was asked to write about their own and humanity’s reaction to a hypothetical announcement of such a discovery (Study 1), and an independent, large online sample (N = 256) was asked to read and respond to a newspaper story about the claim that fossilized extraterrestrial microbial life had been found in a meteorite of Martian origin (Study 2). Across these studies, we found that reactions were significantly more positive than negative, and more reward vs. risk oriented. A mini-meta-analysis revealed large overall effect sizes (positive vs. negative affect language: g = 0.98; reward vs. risk language: g = 0.81). We also found that people’s forecasts of their own reactions showed a greater positivity bias than their forecasts of humanity’s reactions (Study 1), and that responses to reading an actual announcement of the discovery of extraterrestrial microbial life showed a greater positivity bias than responses to reading an actual announcement of the creation of man-made synthetic life (Study 2). Taken together, this work suggests that our reactions to a future confirmed discovery of microbial extraterrestrial life are likely to be fairly positive.

Effects of shock and Martian alteration on Tissint hydrogen isotope ratios and water content

The Tissint meteorite, a picritic shergottite, fell to Earth in Morocco on the 18th of July 2011, and is only the fifth Martian meteorite witnessed to fall. Hydrogen isotope ratios and water contents are variable within different minerals in Tissint. Ringwoodite and shock melt pockets contain elevated D/H ratios relative to terrestrial values (δD=761–4224‰). These high ratios in recrystallized phases indicate significant implantation of hydrogen from the D-rich Martian atmosphere during shock. In contrast, although olivine has detectable water abundances (230–485ppm), it exhibits much lower D/H ratios (δD=+88 to −150‰), suggesting this water was not implanted from the Martian atmosphere. The minimal terrestrial weathering experienced by Tissint gives confidence that the olivine-hosted water has a Martian origin, but its high concentration indicates direct inheritance from the parental melt is improbable, especially given the low pressure of olivine crystallisation. Incorporation of a low δD crustal fluid, or deuteric alteration during crystallisation, could explain the relatively high water contents and low D/H ratios in Tissint olivine.

Rare-earth-element minerals in martian breccia meteorites NWA 7034 and 7533: Implications for fluid–rock interaction in the martian crust

Paired martian breccia meteorites, Northwest Africa (NWA) 7034 and 7533, are the first martian rocks found to contain rare-earth-element (REE) phosphates and silicates. The most common occurrence is as clusters of anhedral monazite-(Ce) inclusions in apatite. Occasionally, zoned, irregular merrillite inclusions are also present in apatite. Monazite-bearing apatite is sometimes associated with alkali-feldspar and Fe-oxide. Apatite near merrillite and monazite generally contains more F and OH (F-rich region) than the main chlorapatite host and forms irregular boundaries with the main host. Locally, the composition of F-rich regions can reach pure fluorapatite. The chlorapatite hosts are similar in composition to isolated apatite without monazite inclusions, and to euhedral apatite in lithic clasts. The U–Th-total Pb ages of monazite in three apatite are 1.0±0.4Ga (2σ), 1.1±0.5Ga (2σ), and 2.8±0.7Ga (2σ), confirming a martian origin. The texture and composition of monazite inclusions are mostly consistent with their formation by the dissolution of apatite and/or merrillite by fluid at elevated temperatures (>100 °C).In NWA 7034, we observed a monazite-chevkinite-perrierite-bearing benmoreite or trachyandesite clast. Anhedral monazite and chevkinite-perrierite grains occur in a matrix of sub-micrometer REE-phases and silicates inside the clast. Monazite-(Ce) and -(Nd) and chevkinite-perrierite-(Ce) and -(Nd) display unusual La and Ce depletion relative to Sm and Nd. In addition, one xenotime-(Y)-bearing pyrite-ilmenite-zircon clast with small amounts of feldspar and augite occurs in NWA 7034. One xenotime crystal was observed at the edge of an altered zircon grain, and a cluster of xenotime crystals resides in a mixture of alteration materials. Pyrite, ilmenite, and zircon in this clast are all highly altered, zircon being the most likely source of Y and HREE now present in xenotime. The association of xenotime with zircon, low U and Th contents, and the low Yb content relative to Gd and Dy in xenotime suggest the possible formation of xenotime as a byproduct of fluid–zircon reactions.On the basis of relatively fresh apatite grains and lithic clasts in the same samples, we propose that the fluid–rock/mineral reactions occurred in the source rocks before their inclusion in NWA 7034 and 7533. Additionally, monazite-bearing apatite and REE-mineral-bearing clasts are possibly derived from different crustal origins. Thus, our results imply the wide-occurrence of hydrothermal fluids in the martian crust at 1 Ga or older, which were probably induced by impacts or large igneous intrusions.

Heinrich Wänke (1928–2015)

Heinrich Wänke (1928–2015)

Origin of John’s Stone: A quartzitic boulder from the site of the 1908 Tunguska (Siberia) explosion

An exotic meter-size quartzitic boulder known as John’s Stone was found by John Anfinogenov in 1972 buried in permafrost close to the epicenter of the 1908 Tunguska blast in a region of Siberia dominated by Permian–Triassic Siberian Trap basalts. The boulder is made almost entirely of well-cemented quartz grains, mostly around 100μm in size; it contains zones with coarser or finer grain sizes. Rare zircon and rutile crystals are scattered within the quartz matrix. Quartz is often dissected by strain lamellae. The rock contains abundant scattered internal vugs rimmed by euhedral quartz crystals. We cannot exclude that John’s Stone is a fragment of a Permian granite-derived sandstone unit. However, based on structure, mineralogy and chemistry the quartzitic boulder may have originated due to silica deposition from hydrothermal solutions that had reacted with basaltic rocks. Anfinogenov et␣al. (Anfinogenov, J. et␣al. [2014]. Icarus 243, 139–147) interpreted features observed in the permafrost at the base of the boulder as indicating it impacted from above, suggesting the boulder may be a meteorite, possibly of martian origin, given the reported presence on Mars of silica-rich deposits. Triple oxygen isotope ratios determined on two samples of the quartzite reveal a terrestrial rather than a martian meteorites composition. Oxygen isotope data suggest also that the precipitation of SiO2 could have occurred in equilibrium with hydrothermal water (δ18Ow≈−19.5‰) at the temperature of about 50°C. The thermal event that generated the quartzite may be related either to the century-old Tunguska Event, or, more probably, to Permian–Triassic Siberian Traps magmatism, although an extraterrestrial origin cannot be completely ruled out.

The Northwest Africa (NWA) 5790 meteorite: A mesostasis‐rich nakhlite with little or no Martian aqueous alteration

AbstractNorthwest Africa (NWA) 5790 is the most recently discovered member of the nakhlite group. Its mineralogy differs from the other nakhlites with a high abundance mesostasis (38.1 ± 3.6 vol%) and scarcity of olivine (4.0 ± 2.2 vol%). Furthermore, zoning of augite phenocrysts, and other petrographic and chemical characteristics suggest that NWA 5790 samples the chilled margin of its parent lava flow/sill. NWA 5790 contains calcite and rare clay minerals that are evidence for its exposure to liquid water. The calcite forms a cement to coatings of dust on the outer surface of the find and extends into the interior of the meteorite within veins. The presence of microbial remains within the coating confirms that the dust and its carbonate cement are terrestrial in origin, consistent with the carbon and oxygen isotope composition of the calcite. The clay minerals are finely crystalline and comprise ~0.003 vol% of the meteorite. δD values of the clay minerals range from −212 ± 109‰ to −96 ± 132‰, and cannot be used to distinguish between a terrestrial or Martian origin. As petrographic results are also not definitive, we conclude that secondary minerals produced by Martian groundwaters are at best very rare within NWA 5790. The meteorite has therefore sampled a region of the lava flow/sill with little or no exposure to the aqueous solutions that altered other nakhlites. This isolation could relate to the scarcity of olivine in NWA 5790 because dissolution of olivine in other nakhlites by Martian groundwaters enhanced their porosity and permeability, and provided solutes for secondary minerals.

NanoSIMS analysis of organic carbon from the Tissint Martian meteorite: Evidence for the past existence of subsurface organic‐bearing fluids on Mars

AbstractTwo petrographic settings of carbonaceous components, mainly filling open fractures and occasionally enclosed in shock‐melt veins, were found in the recently fallen Tissint Martian meteorite. The presence in shock‐melt veins and the deuterium enrichments (δD up to +1183‰) of these components clearly indicate a pristine Martian origin. The carbonaceous components are kerogen‐like, based on micro‐Raman spectra and multielemental ratios, and were probably deposited from fluids in shock‐induced fractures in the parent rock of Tissint. After precipitation of the organic matter, the rock experienced another severe shock event, producing the melt veins that encapsulated a part of the organic matter. The C isotopic compositions of the organic matter (δ13C = −12.8 to −33.1‰) are significantly lighter than Martian atmospheric CO2 and carbonate, providing a tantalizing hint for a possible biotic process. Alternatively, the organic matter could be derived from carbonaceous chondrites, as insoluble organic matter from the latter has similar chemical and isotopic compositions. The presence of organic‐rich fluids that infiltrated rocks near the surface of Mars has significant implications for the study of Martian paleoenvironment and perhaps to search for possible ancient biological activities on Mars.

Modern atmospheric signatures in 4.4 Ga Martian meteorite NWA 7034

The NWA 7034 Martian basaltic breccia, dated at ∼4.4 Ga, represents an entirely new type of Martian meteorite. However, due to the unique make-up of NWA 7034 compared to other Martian meteorite types (including its anomalous oxygen isotope ratios), noble gas analyses – a key tool for Martian meteorite identification – are important to confirm its Martian origin. Here, we report the first noble gas results for NWA 7034, which show the presence of a trapped component that resembles the current Martian atmosphere. This trapped component is also similar in composition to trapped gases found in the much younger shergottites (∼150–600 Ma). Our formation ages for the sample suggest events at ∼1.6 Ga (K–Ar), and ∼170 Ma (U–Th/He), which are considerably younger than those observed by Rb–Sr (2.1 Ga), and Sm–Nd (4.4 Ga; zircons ∼4.4 Ga). However, our K–Ar age is similar to a disturbance in the U–Pb zircon data at ∼1.7 Ga, which could hint that both chronometers have been subjected to disturbance by a common process or event. The U–Th/He age of ∼170 Ma could relate to complete loss of radiogenic 4He at this time, and is a similar age to the crystallisation age of most shergottites. While this may be coincidental, it could indicate that a single event is responsible for both shergottite formation and NWA 7034 thermal metamorphism. As for cosmic ray exposure ages, our favoured age is ∼5 Ma, which is outside the ranges for other Martian meteorite groups, and may suggest a distinct ejection event. NWA 7034 shows evidence for neutron capture on Br, which has caused elevations in Kr isotopes 80Kr and 82Kr. These elevated abundances indicate significant shielding, and could relate to either a large meteoroid size, and/or shielding in relation to a regolithic origin. We have also applied similar neutron capture corrections to Ar and Xe data, which further refine the likelihood of a modern atmospheric component, though such corrections remain speculative. Cosmogenic production rates and noble gas data are consistent with a meteoroid radius of >50 cm. Fission contributions are clear in the Xe data, with evidence to suggest that NWA 7034 contains both 238U and 244Pu derived fission Xe components. If the gas in NWA 7034 was trapped at its ancient igneous formation, this would suggest little evolution of the Martian atmosphere between ∼4.4 Ga and present day. However, as NWA 7034 is a regolith breccia with multiple lithologies and a strong compositional similarity to Gusev soils, the timing and incorporation of trapped atmospheric gases is unclear. With hints of resetting events at ∼1.5–2.1 Ga, the atmospheric component may have been incorporated during breccia formation – possibly in the Amazonian, though it could also have been incorporated on ejection from the surface.

Volatile and Organic Compositions of Sedimentary Rocks in Yellowknife Bay, Gale Crater, Mars

H2O, CO2, SO2, O2, H2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

Evidence of martian perchlorate, chlorate, and nitrate in Mars meteorite EETA79001: Implications for oxidants and organics

The results from the Viking mission in the mid 1970s provided evidence that the martian surface contained oxidants responsible for destroying organic compounds. In 2008 the Phoenix Wet Chemistry Lab (WCL) found perchlorate (ClO4-) in three soil samples at concentrations from 0.5 to 0.7wt%. The detection of chloromethane (CH3Cl) and dichloromethane (CH2Cl2) by the Viking pyrolysis gas chromatograph–mass spectrometer (GC–MS) may have been a result of ClO4- at that site oxidizing either terrestrial organic contaminates or, if present, indigenous organics. Recently, the Sample Analysis at Mars (SAM) instrument on the Mars Science Laboratory (MSL) Curiosity directly measured the presence of CH3Cl, CH2Cl2 and, along with measurements of HCl and oxygen, indirectly indicate the presence of ClO4-. However, except for Phoenix, no other direct measurement of the ClO4- anion in martian soil or rock has been made. We report here ion chromatographic (IC) and isotopic analyses of a unique sawdust portion of the martian meteorite EETA79001 that show the presence by mass of 0.6±0.1ppm ClO4-, 1.4±0.1ppm ClO3-, and 16±0.2ppm NO3- at a quantity and location within the meteorite that is difficult to reconcile with terrestrial contamination. The sawdust sample consists of basaltic material with a minor salt-rich inclusion in a mass ratio of ∼300:1, thus the salts may be 300 times more concentrated within the inclusion than the whole sample. The molar ratios of NO3-:ClO4- and Cl-:ClO4-, are very different for EETA79001 at ∼40:1 and 15:1, respectively, than the Antarctic soils and ice near where the meteorite was recovered at ∼10,000:1 and 5000:1, respectively. In addition, the isotope ratios for EETA79001 with δ15N=−10.48±0.32‰ and δ18O=+51.61±0.74‰ are significantly different from that of the nearby Miller Range blue ice with δ15N=+102.80±0.14‰ and δ18O=+43.11±0.64‰. This difference is notable, because if the meteorite had been contaminated with nitrate from the blue ice, the δ15N values should be the same. More importantly, the δ15N is similar to the uncontaminated Tissint Mars meteorite with δ15N=−4.5‰. These findings suggest a martian origin of the ClO4-, ClO3- and NO3- in EETA79001, and in conjunction with previous discoveries, support the hypothesis that they are present and ubiquitous on Mars. The presence of ClO3- in EETA79001 suggests the accompanying presence of other highly oxidizing oxychlorines such as ClO2- or ClO−, produced both by UV oxidation of Cl− and γ- and X-ray radiolysis of ClO4-. Since such intermediary species may contribute to oxidization of organic compounds, only highly refractory and/or well-protected organics are likely to survive. The global presence of ClO4-, ClO3-, and NO3-, has broad implications for the planet-wide water cycle, formation of brines, human habitability, organics, and life.

Primordial argon isotope fractionation in the atmosphere of Mars measured by the SAM instrument on Curiosity and implications for atmospheric loss.

[1] The quadrupole mass spectrometer of the Sample Analysis at Mars (SAM) instrument on Curiosity rover has made the first high-precision measurement of the nonradiogenic argon isotope ratio in the atmosphere of Mars. The resulting value of 36Ar/38Ar = 4.2 ± 0.1 is highly significant for it provides excellent evidence that “Mars” meteorites are indeed of Martian origin, and it points to a significant loss of argon of at least 50% and perhaps as high as 85–95% from the atmosphere of Mars in the past 4 billion years. Taken together with the isotopic fractionations in N, C, H, and O measured by SAM, these results imply a substantial loss of atmosphere from Mars in the posthydrodynamic escape phase.

Volcanism on Mars controlled by early oxidation of the upper mantle

Detailed information about the chemical composition and evolution of Mars has been derived principally from the SNC (shergottite-nakhlite-chassignite) meteorites, which are genetically related igneous rocks of Martian origin. They are chemically and texturally similar to terrestrial basalts and cumulates, except that they have higher concentrations of iron and volatile elements such as phosphorus and chlorine and lower concentrations of nickel and other chalcophile (sulphur-loving) elements. Most Martian meteorites have relatively young crystallization ages (1.4 billion years to 180 million years ago) and are considered to be derived from young, lightly cratered volcanic regions, such as the Tharsis plateau. Surface rocks from the Gusev crater analysed by the Spirit rover are much older (about 3.7 billion years old) and exhibit marked compositional differences from the meteorites. Although also basaltic in composition, the surface rocks are richer in nickel and sulphur and have lower manganese/iron ratios than the meteorites. This has led to doubts that Mars can be described adequately using the 'SNC model'. Here we show, however, that the differences between the compositions of meteorites and surface rocks can be explained by differences in the oxygen fugacity during melting of the same sulphur-rich mantle. This ties the sources of Martian meteorites to those of the surface rocks through an early (>3.7 billion years ago) oxidation of the uppermost mantle that had less influence on the deeper regions, which produce the more recent volcanic rocks.