Martensitic Phase Transformation Research Articles

A three-dimensional phase-field model for studying the orientation-dependent interface evolution in stress-induced martensitic phase transformation

In this study, we address the challenging task of predicting the motion of interfaces in stress-driven martensitic phase transformations within shape memory alloys. The novelty of our approach lies in the introduction of a monolithically solved thermodynamic-based phase-field method, specifically tailored for large strain conditions at the nanoscale for three-dimensional problems. To achieve this, we have developed a custom finite element software seamlessly integrated into the FEniCS open-source framework, providing a sophisticated and efficient tool for the examination of nanostructure evolution. Our investigation delves into five distinct and complex scenarios under diverse loading conditions for two– and three-dimensional problems, each presenting unique challenges: (i) a straightforward uniaxial tension scenario featuring a square domain with a pre-existing martensitic nucleus; (ii) the evolution of interfaces in a square sample incorporating a circular central nanovoid under biaxial tensile stress; (iii) the analysis of a rectangular beam subjected to horizontal and vertical compressive loads; (iv) the assessment of an initially voided rectangular beam experiencing mixed loading conditions; and (v) the three-dimensional simulations of cubic-to-tetragonal phase transformation using various orientation of the habit plane. In contrast to prior studies, our analysis not only explores the standard factors of habit plane reorientation and strain transformation values but also delves into the impact of nanovoids on austenite–martensite interface evolution.

Exceptional fatigue-resistant austenitic stainless steel for cryogenic applications

Most alloys change from ductile to brittle at cryogenic temperatures, whereas high-entropy alloys show better strength, ductility, and toughness. However, they suffer from cost and mass-production challenges. We discerned the fatigue behaviour of a cost-effective austenitic stainless steel, SS316L, at an ultra-low temperature (ULT) of 15 K. For the cryogenic applications, our work demonstrates that compared to room-temperature (RT), ULT exhibits eight times higher fatigue life, despite even higher applied stress [ σmax=1.3×σysRT/ULT (280 MPaRT; 517 MPa15 K)]. At 15 K, the fatigue mechanisms involve stacking faults, a two-step martensitic phase transformation (γ→ϵ→α′) and α′-martensite twinning, utilizing the applied fatigue strain efficiently. The remarkable improvement in the mechanical strength and fatigue life at ULT is the key to revolutionizing sustainable advancements in space exploration and energy storage.

On the fcc to hcp transformation in a Co-Ru alloy: Variant selection and intervariant boundary character

Ru is a common addition to the Co-binder in WCCo hardmetals for advanced cutting tool applications. Internal Co-Co interfaces control many properties such as hot-hardness, toughness, and creep resistance. Hence, phase transformations determining the internal interface character can be harnessed to achieve superior properties. We investigate the γ (face-centred cubic) to α (hexagonally closed packed) martensitic phase transformation of a model Co-Ru binder alloy. We describe the crystallography of γ to α phase transformations and the resulting α/γ and α/α interface character distributions. The stabilisation of the γ-phase results in the formation of low energy (0 0 0 1) α/γ interphase boundary planes. Preferred formation of α/α intervariant and twin-related boundaries with symmetrical tilt configurations are also observed. We discuss how crystallographic constraints of the transformation promote the formation of grain boundary planes other than those of the lowest energy configurations.

Hyper‐Elastic Deformation via Martensitic Phase Transformation in Cadmium Telluride

Cadmium telluride (CdTe) is a highly promising material for photovoltaics (PV) and photodetectors due to its light‐absorbing properties. However, efficient design and use of flexible devices require a deep understanding of its atomic‐level deformation mechanism. Herein, uniaxial compression deformation of CdTe monocrystalline with varying crystal orientations is investigated using molecular dynamics (MD) with a newly developed machine‐learning force field (ML‐FF), alongside in‐situ micropillar compression experiments. The findings reveal that CdTe bulk deformation is dominated by reversible martensitic phase transformation, whereas CdTe pillar deformation is primarily driven by dislocation nucleation and movement. CdTe monocrystals possess exceptional super‐recoverable deformation along the <100> orientation due to hyper‐elastic processes induced by martensitic transformation. This discovery not only sheds light on the peculiarities observed in micropillar experimental measurements, but also provides pivotal insights into the fundamental deformation behaviors of CdTe and similar II–VI compounds under various stress conditions. These insights are crucial for the innovative design and enhanced functionality of future flexible electronic devices.

Experimental and computational study of the NiTi thin wires mechanical behavior

NiTi wires used for biological implants demonstrated ductile fracture. NiTi 40, 60, and 90 µm thick wires were tested in uniaxial tension to fracture and loading-unloading. Uniaxial stress-strain curves demonstrate superelastic behavior. The inelastic martensite transformation strain is completely recovered upon unloading, forming thermo-mechanical hysteresis. A mathematical model was developed to describe superelasticity effects in NiTi wires. Modeling results are qualitatively and quantitatively similar to experimental data, and capture elastic deformation of austenite, forward martensite phase transformation stress plateau before the onset of martensite elastic deformation and the entire unloading range. The elastic limit and strength increase with the wire thickness.

The effect of γ′-martensite on the corrosion resistance of an Fe-Mn-Al-Ni-Cr shape memory alloy in a sodium chloride solution

The martensitic phase transformation in iron-based shape memory alloys has a strong influence on the corrosion properties. To investigate the effect of different amounts of martensite, potentiodynamic polarization measurements were conducted on specimens that were subjected to varying prestrain levels prior to the corrosion experiments. While the passive behavior deteriorates with an increasing martensite amount, the observed corrosion damage changes as well. While an entirely austenitic specimen is characterized by a predominantly surface corrosion with some randomly distributed pitting corrosion, the introduction of the martensitic phase results in micropitting and selective corrosion of the martensite plates.

In-situ synchrotron X-ray diffraction study of the effects of grain orientation on the martensitic phase transformations during tensile loading at different strain rates in metastable austenitic stainless steel

In this work, in-situ high-energy X-ray diffraction was used to analyze the effects of strain rate and austenite (γ) grain orientation on the strain-induced martensitic transformation in metastable austenitic stainless steel 301LN. The diffraction measurements were carried out at strain rates ranging from 10–3 s–1 to 1 s–1 continuously without interrupting the experiment and thus creating nearly adiabatic conditions at the highest studied strain rate. The results indicate that <100>γ fiber-oriented grains preferentially transform at the strain rate of 10–3 s–1 when the true strain is above 0.10, whereas the <111>γ fiber-oriented grains transform only at later stages of plastic deformation. The phase transformation rate of the <111>γ and <100>γ fiber-oriented grains decreases with increase in strain rate. A theoretical model based on stacking fault width as a function of external stress and temperature (stacking fault energy) was used to predict lower-bound estimates for the critical tensile stress needed to start ε-martensite and α’-martensite phase transformations. The model can predict the experimentally observed phase transformation behavior of the <111>γ fiber orientations at all strain rates but is unable to predict the decrease of phase transformation rate of <100> fiber-oriented γ grains with increase in strain rate, which could be related to change in dislocation structure.

Localized plastic strain accumulation in shape memory ceramics under cyclic loading

The premature failure of shape memory ceramics (SMC)s under cyclic loading is a critical issue limiting their applications as actuators and thermal protection layers. Martensitic phase transformation (MPT), essential for superelasticity and shape memory functionalities in SMCs, induces localized plastic deformations due to phase expansion. In polycrystalline materials, the accumulation of localized plastic strain serves as the primary mechanism for fatigue crack initiation under cyclic loading. In this research, a phase-field (PF) phase transformation model coupled with a viscoplasticity model is presented to study the effects of microstructural features, engineered pores, and sample size on plastic strain accumulation (PSA) during cyclic loading of SMCs. Our findings highlight that the grain boundaries (GB)s are critical regions with high PSA, with noticeable reductions observed by decreasing the grain boundary density (GBD). Additionally, we found that engineered pores effectively reduced cyclic PSA, however, we identified a threshold on the volume fraction of pores. Also, textured microstructures with certain characteristics demonstrate significant influence on cyclic PSA. A cross-correlation data analysis approach is employed to study the relationship between the studied microstructural features and PSA to facilitate the identification of the most important factors controlling the irreversible PSA during compressive cyclic loading. By mitigating the rate of PSA, significant enhancements in cyclic life before fatigue crack initiation can be achieved, enabling superior performance in practical applications.

Assessing the tribo-corrosion resistance of surface nanostructured stainless-steel

In this work, surface mechanical rolling treatment (SMRT) was applied as a post-process nanostructuring technique to improve the tribo-corrosion degradation resistance of coarse grain (CG) 316 L stainless steel (SS). The experimental findings reveal that when tribo-corrosion wear took place, the CG specimen experienced severe surface de-passivation, which increased wear-corrosion synergy and the rate of material loss. On the other hand, the SMRT specimen experienced enhanced re-passivation kinetics, which reduced wear-corrosion synergy and the rate of material loss. The wear mechanism for both the CG and SMRT specimens was abrasion-dominant, with the CG specimen having the presence of micro-pits within the wear track. In addition to these findings, the reduced surface roughness, improved hardness, formed compressive stresses, microstructural refinement, and martensite phase transformation induced by the SMRT process contributed to the enhanced tribo-corrosion resistance of the SMRT specimen. In total, SMRT was found to be a feasible technique to improve the tribo-corrosion resistance of CG 316 L SS.

Dynamics of a piezoelectric vibration energy harvester with a pseudoelastic SMA spring

The development of small-scale and low power consumption devices has been motivating the design of intelligent mechanisms, exhibiting a wide power density spectrum across various external sources. Smart materials come up as an attractive alternative due to their intrinsic multi-coupling between different physical domains. In this context, piezoelectric materials allow conversion of mechanical energy of movement into electrical power through the direct piezoelectric effect. This work investigates a piezoelectric energy harvester combined with a shape memory alloy (SMA) spring to explore the combination of both the smart materials for energy harvesting. The pseudoelastic hysteretic effect of SMA is explored in order to passively change the internal system properties such as stiffness and damping during the harvesting process. Numerical analyses are performed considering the normalized power converted by the harvester, focusing on the influence of the SMA martensite phase transformation under different scenarios. The results exhibit an increment in the harvester bandwidth when compared with a traditional linear piezoelectric energy harvester.

Microstructure of stress‐induced martensite in micron‐sized zirconia single crystal spheres

Martensitic phase transformation of zirconia (ZrO2), when realized from the superelastic effect, has immense potential in energy applications, such as micro‐actuation and high‐energy dissipation/damping. In this study, martensitic transformation in ZrO2 is studied using a newly developed microscale phase field model, which is scale‐independent and contains an averaged gradient term. The model is implemented using the FEniCS package in Python. With a thorough explanation of the model construction, the mechanics of phase transformation are detailed, and the material behaviors under different stress conditions are discussed. Mesh sensitivity, multivariant evolution, and the effect of particle size are analyzed to understand the martensite evolution in superelastic ZrO2. This work provides new insight into the martensitic phase transformation behaviors of micron‐sized spherical ZrO2 particles.This article is protected by copyright. All rights reserved.

Thermomechanical response and elastocaloric effect of shape memory alloy wires

Refrigeration technologies based on the elastocaloric effect of shape memory alloys (SMAs) have attracted much interest in recent years. To seek for schemes that can improve the temperature span and efficiency of elastocaloric devices, this work explores more practical loading conditions (between adiabatic and isothermal) of SMAs. To account for the smoothness of the martensite phase transformation of SMAs, a general polynomial form of hardening-like function is adopted in the phenomenological multi-physics coupling framework. The modeling framework is further calibrated by measurements of the thermomechanical responses of pre-trained Ni–Ti wires. Due to the hardening-like function, the martensitic volume fraction cannot be explicitly expressed. Accordingly, a new numerical scheme is also presented in this work. Moreover, an empirical function of the maximum transformation strain is proposed based on the experimental observation, which improves the capability of the model to capture experimental data. This work aims to provide a paradigm from material characterization to theoretical modeling and numerical simulation, and then to elastocaloric cooling performance analysis of SMAs.

Multi-field coupling numerical simulation and experimental research of submerged arc surfacing process on the descaling rolls with different wall thickness

Iron and steel industry descale rolls long-term high-pressure water erosion, high temperature, easy to wear, corrosion failure and other problems, the continuous production of steel rolling impact, descale rolls base wall thickness is the main cause of cracking of the surfacing gradient lap organization. This article combines numerical simulation and experimental testing, the use of CALPHAD method to calculate the surfacing material temperature change physical parameters, based on the double ellipsoid heat source model, the establishment of the descale roller submerged arc surfacing process of multi-field coupling three-dimensional numerical model, calculations and reveal the descale roller submerged arc surfacing process of the temperature field, the stress field, the phase change field and the flow field of the transient evolution of the law, and further analyze the descale roller wall thickness of the surfacing process of the influence of the mechanism. Calculation results show that the depth of melting of the surfacing matrix is positively correlated with the width of the double ellipsoid heat source, and the larger the wall thickness, the faster the cooling rate, the greater the formation of residual stress. The austenite and martensite phase transformation of the overlay welding process is greatly influenced by the wall thickness. At the same time, SEM, EDS, XRD material science microcharacterization experiments were carried out to observe the micro-morphology, phase and elemental composition of the cladding layer. This study lays an important theoretical foundation for optimizing the submerged arc surfacing process of descale roller.

Influence of grain boundary and twin boundary on the stretching deformation behaviors of Cu/Ta interface material

Molecular dynamics simulation is performed to study the stretching characteristics in three Cu/Ta interface models. The crystal structure of Cu layer is changed from single crystal to columnar polycrystal and then to layered twin crystal. The presence of both grain and twin boundaries within Cu layer improves the tensile strength and toughness significantly, demonstrating the fine-grain strengthening. The short-duration plastic deformation in Ta layer starts at the yield point after that the deformation in Cu layer is suppressed, revealing the damage of Cu/Ta interface, and the effect of two kinds of boundaries on the plasticity mainly happens in the early deformation stage. It is interesting that the presence of twin boundary induces the martensitic phase transformation in the early stretching process, while those BCC phases or clusters transform to HCP stacking faults finally. This work will be helpful to understand the role of interface defects in the incipient plasticity of layered metallics, guiding the design of high-performance materials.

Ultrasonic Impact Treatment (UIT) combined with powder bed fusion (PBF) process for precipitation hardened martensitic steels

High-strength martensitic stainless steels such as 17–4 PH (SS 17–4 PH) generally exhibit poor ductility and strain-hardening rates. In this study, an Ultrasonic Impact Treatment (UIT) is combined with a powder bed fusion (PBF) manufacturing process with the objective of enhancing the mechanical properties of SS 17–4 PH. UIT is introduced as a surface peening step at regular intervals during the PBF process after depositing a set of predetermined number of layers. The coupon specimens extracted from the build are then subjected to a post-build heat treatment. Then the microstructural and the mechanical properties of these specimens are characterized. The characterizations reveal that the heavy plastic deformation induced by UIT drives microstructural relaxation and recrystallization under heat treatment, reducing defects extensively. The heavy plastic deformation also drives diffusional reversion of the austenite phase during deposition and an inhibition of the martensitic phase transformation during the post-build heat treatment. As a result, the UIT specimens subjected to post-build heat treatment exhibit remarkable enhancement in ductility along with high strength and strain-hardening rate compared to the non-UIT PBF specimens under as-built condition.

Heat treatment protocol for additively manufactured nitinol shape memory alloys in biomedical applications

Additive manufacturing (AM) is getting significant attention in realizing customizable nitinol (NiTi) devices for biomedical applications. However, due to the change in composition and constituent phases occurring during printing and the microstructural inhomogeneity in the printed parts, obtaining a desired set of phase transformation behaviors and superelastic properties is a major challenge. In this work, laser powder bed fusion (LPBF) was used to fabricate NiTi at a very low laser energy density (35 J/mm3) on a titanium base plate while keeping these behaviors and properties within desirable ranges without any structural defects such as crack and delamination. Our measurements showed that the as-printed NiTi exhibited distinct one-step phase transformation with the austenite finish (Af) temperature of 2.1 °C. To increase the Af temperature to 30.2 °C (within the recommended range of Af temperature for biomedical applications), a heat treatment protocol was developed, which includes a solution cycle (at 900 °C for 1 h) followed by an aging cycle (at 450 °C for 30 min). The heat treatment protocol enabled us to attain the homogenized microstructure while creating ultrafine metastable Ni-rich precipitate, Ni4Ti3, which facilitated the desirable phase transformation behavior with the increased Af temperature. The heat-treated sample showed narrower and sharper two-step martensitic phase transformation with the formation of intermediate R-phase. The presence of both Ni4Ti3 and the R-phase was confirmed by the transmission electron microscopic (TEM) analysis. In the superelasticity test at the body temperature, these samples, starting from the 2nd cycle, demonstrated a recovery ratio of more than 90% and a recoverable strain of more than 6.5%. After 10th cycles, the stable recoverable strain was 6.52% with a recovery ratio of 96%, which is the highest superelasticity reported for the LPBF processed NiTi to the best of our knowledge. After the initial deformation process, we expect these NiTi samples to attain near full superelasticity during service. The micro-hardness study also showed that the hardness of the heat-treated samples is less affected by the cyclic loading. Therefore, this paper presents a viable heat treatment protocol, which provides an important processing roadmap in making NiTi implants by AM while maintaining excellent functional properties of NiTi for biomedical applications.

Characterization on thermal hysteresis of shape memory alloys via macroscopic interface propagation

A specimen of Shape Memory Alloy (SMA) starts martensitic phase transformation normally by the nucleation of a macroscopic austenite-martensite interface at the specimen's boundary (i.e., the nucleation is sensitive to boundary conditions). By contrast, the interface propagation only needs to overcome the energy barrier of the incompatibility between the austenite and martensite phases (i.e., the interface-propagation driving force reflects material's intrinsic properties). In this paper, we observe the thermally induced forward and reverse quasi-static propagation of the macroscopic austenite-martensite interface in a Ni-Mn-Ga single-crystal bar. It is found that the temperature difference between the forward and reverse propagation is only 2.8 °C, which is obviously less than the thermal hysteresis evaluated from Differential Scanning Calorimetry measurement (6.3 °C) on the same material. This result not only gives a better characterization of the thermal hysteresis of the phase transformation, but also helps deeply understand the relation between the phase-transformation kinetics and the microstructures of the macroscopic austenite-martensite interface.

Low-Temperature Elastic Properties of Molybdenum Doped Non-Equiatomic High Entropy Alloys of the Fe-Co-Ni-Cr System

The mechanical properties and microstructural evolution of a medium-entropy alloy Co17.5Cr12.5Fe55Ni10Mo5 (at%) in a low temperature range (including the record low temperatures region down to 0.5 K) were investigated. It has been established that low-temperature plastic deformation initiates martensitic phase transformations in this alloy, and the values of the dynamic modulus of elasticity correlate with the degree of phase transformations.

Effects of laser welding on the martensitic transformation of a shape-memory Ti-Ni alloy

The objective of this study is to investigate the martensitic transformation behavior of a Ti-Ni alloy subjected to a laser welding process. Materials characterization techniques were used to analyze the influences of this welding procedure on the phase transformation behavior. This study can provide valuable insights for the improvement of Ti-Ni alloy welding processes used for technological applications, such as in the aerospace industry. In this study, samples were prepared under three conditions: thermal treatment at 400°C, thermal treatment at 500°C, and as-received. The characterization techniques used were: Optical Microscopy (OM), Differential Scanning Calorimetry (DSC), Electron Dispersion Spectroscopy (EDS), X-Ray Diffraction (XRD), and Vickers Microhardness (HV). The results allow for analysis of thermoelastic martensitic transformation and variations in the compositions of the alloy elements. The research, in general, aims to repurpose welding waste in Ti-Ni alloys for the production of mini sensors. The enthalpy was higher for the alloy treated at 500°C and welded. The research findings led to the observation of martensitic phase transformation in the laser-welded Ti-Ni alloy, which suggests that it can be used as a sensor/actuator.

An atomistic study of effects of temperature and Ni element on the phase transition and wear behavior of NiTi shape memory alloy

Phase transition and tribological behavior of NiTi alloys have drawn great attention. Molecular dynamics simulation was adopted to investigate the effects of temperature on the mechanical behavior and variant formation of NiTi, as well as its wear behavior. Thermally and stress-induced phase transition behavior of NiTi alloys were studied. It is found that residual austenite phase boundaries during martensitic phase transformation could inhibit martensitic phase transition, changing the phase transition temperatures, and the mechanical properties of NiTi. Wear behavior of single-crystal NiTi with a wide temperature domain and content was studied. The optimal wear resistance of NiTi was at 300 K during cooling. Appropriate improvement in Ni content is beneficial to the formation of martensite variants and enhancement of the wear resistance.