Mars Exploration Rover Spirit Research Articles

Spectrophotometric properties of materials observed by Pancam on the Mars Exploration Rovers: 4. Final mission observations

The last sets of Panoramic Camera (Pancam) visible/near-infrared (432–1009 nm) multispectral observations made under varying viewing and illumination geometries by the Mars Exploration Rovers Spirit and Opportunity were examined using radiative transfer models to study the surface scattering and microphysical nature of rock and soil units at both sites. Nearly 12,000 individual measurements were collected for this study of soil, dust, and rock units over phase angles of ~0° to ~150°. Images were acquired on sols 1944–1946 (June 2009) at Troy, the final resting place of Spirit on the western side of Home Plate in Gusev crater, and by Opportunity at three locations on the western rim of Endeavour crater in Meridiani Planum between sols 2785 (November 2011) and 3867 (December 2014). Sky models were developed from observations of atmospheric opacity, which enabled corrections for diffuse skylight when combined with surface facet orientations determined from stereo images. Model results were improved by removing data affected by scattered light evident in some high phase angle images (resulting from minor dust contamination on the camera windows). At Troy, relatively dust-free “gray” rock units exhibited narrow, forward scattering behaviors akin to previous analyses of similar gray rock units at Gusev crater. Soils and “red” rocks coated with greater amounts of dust were more backscattering. Red rocks exhibited higher single scattering albedo (w), macroscopic roughness (θ), and opposition effect width (h) parameters, indicative of rough, low-porosity surfaces perhaps with more uniform grain size distributions. At Meridiani Planum, rubbly soils near São Gabriel crater and Cape Tribulation exhibited w values typical of previous soil analyses. However, the large drift “dust” deposits found in depressions on the northern tip of Cape York near Turkey Haven demonstrated elevated w values with a downturn toward 1009 nm, consistent with minor hydration of these materials. The dust deposits were modeled with the lowest θ values and highest h values of all soil units analyzed during the Opportunity mission, indicative of a smooth surface with homogeneous grain size distribution and/or lower porosity than other units. The dust unit scattering function was dissimilar to those for atmospheric and airfall-deposited dusts, however, suggesting that the originally deposited materials had been modified, perhaps by hydration and ongoing aeolian effects. Analyses of phase curve ratios among the units studied here and from laboratory data of analog soils suggested that surface scattering is a major control on the peak phase angle position of the “arch” in phase curve ratios, alongside the effects of particle-scale roughness.

Assessment of InSight Landing Site Predictions.

Comprehensive analysis of remote sensing data used to select the Interior Exploration using Seismic Investigations, Geodesy and Heat Transport (InSight) landing site correctly predicted the atmospheric temperature and pressure profile during entry and descent, the safe landing surface, and the geologic setting of the site. The smooth plains upon which the InSight landing site is located were accurately predicted to be generally similar to the Mars Exploration Rover Spirit landing site with relatively low rock abundance, low slopes, and a moderately dusty surface with a 3–10 m impact fragmented regolith over Hesperian to Early Amazonian basaltic lava flows. The deceleration profile and surface pressure encountered by the spacecraft during entry, descent, and landing compared well (within 1σ) of the envelope of modeled temperature profiles and the expected surface pressure. Orbital estimates of thermal inertia are similar to surface radiometer measurements, and materials at the surface are dominated by poorly consolidated sand as expected. Thin coatings of bright atmospheric dust on the surface were as indicated by orbital albedo and dust cover index measurements. Orbital estimates of rock abundance from shadow measurements in high‐resolution images and thermal differencing indicated very low rock abundance and surface counts show 1–4% area covered by rocks. Slopes at 100 to 5 m length scale measured from orbital topographic and radar data correctly indicated a surface comparably smooth and flat as the two smoothest landing sites (Opportunity and Phoenix). Thermal inertia and radar data indicated the surface would be load bearing as found.

The Italian Solfatara as an analog for Mars fumarolic alteration

AbstractThe first definitive evidence for continental vents on Mars is the in situ detection of amorphous silica-rich outcrops by the Mars Exploration Rover Spirit. These outcrops have been tentatively interpreted as the result of either acid sulfate leaching in fumarolic environments or direct precipitation from hot springs. Such environments represent prime targets for upcoming astrobiology missions but remain difficult to identify with certainty, especially from orbit. To contribute to the identification of fumaroles and hot spring deposits on Mars, we surveyed their characteristics at the analog site of the Solfatara volcanic crater in central Italy. Several techniques of mineral identification (VNIR spectroscopy, Raman spectroscopy, XRD) were used both in the field and in the laboratory on selected samples. The faulted crater walls showed evidence of acid leaching and alteration into the advanced argillic-alunitic facies, with colorful deposits containing alunite, jarosite, and/or hematite. Sublimates containing various Al and Fe hydroxyl-sulfates were observed around the active fumarole vents at 90 °C. One vent at 160 °C was characterized by different sublimates enriched in As and Hb sulfide species. Amorphous silica and alunite assemblages that are diagnostic of silicic alteration were also observed at the Fangaia mud pots inside the crater. A wide range of minerals was identified at the 665 m diameter Solfatara crater that is diagnostic of acid-steam heated alteration of a trachytic, porous bedrock. Importantly, this mineral diversity was captured at each site investigated with at least one of the techniques used, which lends confidence for the recognition of similar environments with the next-generation Mars rovers.

Overview of Spirit Microscopic Imager Results

AbstractThis paper provides an overview of Mars Exploration Rover Spirit Microscopic Imager (MI) operations and the calibration, processing, and analysis of MI data. The focus of this overview is on the last five Earth years (2005–2010) of Spirit's mission in Gusev crater, supplementing the previous overview of the first 450 sols of the Spirit MI investigation. Updates to radiometric calibration using in‐flight data and improvements in high‐level processing are summarized. Released data products are described, and a table of MI observations, including target/feature names and associated data sets, is appended. The MI observed natural and disturbed exposures of rocks and soils as well as magnets and other rover hardware. These hand‐lens‐scale observations have provided key constraints on interpretations of the formation and geologic history of features, rocks, and soils examined by Spirit. MI images complement observations by other Spirit instruments, and together show that impact and volcanic processes have dominated the origin and evolution of the rocks in Gusev crater, with aqueous activity indicated by the presence of silica‐rich rocks and sulfate‐rich soils. The textures of some of the silica‐rich rocks are similar to terrestrial hot spring deposits, and observations of subsurface cemented layers indicate recent aqueous mobilization of sulfates in places. Wind action has recently modified soils and abraded many of the rocks imaged by the MI, as observed at other Mars landing sites.

The albedo of Mars: Six Mars years of observations from Pancam on the Mars Exploration Rovers and comparisons to MOC, CTX and HiRISE

The Mars Exploration Rovers (MER) Spirit and Opportunity have systematically used their Panoramic Camera (Pancam) instruments to estimate the Lambert albedo of the surface across their traverses in Gusev crater and Meridiani Planum. The 360˚ “albedo pan” observations acquired with Pancam's broadband (739 ± 338 nm) L1 filter allow for quantitative estimates of the overall surface albedo and measurements of individual surface features. As of November 2016, over nearly six Mars years of the MER mission, Spirit acquired 20 albedo pans (over 7,730 m of traverse distance) and Opportunity acquired 117 albedo pans (over 42,368 m of traverse distance). For Spirit, this comprises the rover's complete dataset. The ranges of Pancam-derived albedos at Gusev crater (0.14–0.24) and at Meridiani Planum (0.11–0.22, with one anomalously high measurement of 0.27 during the July 2007 global dust storm) are consistent with large-scale albedos of the sites as previously determined by the Viking Orbiter Infrared Thermal Mapper (IRTM), Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES), MGS Mars Orbiter Camera (MOC), Mars Odyssey Thermal Emission Imaging System (THEMIS), Mars Reconnaissance Orbiter (MRO) Context Camera (CTX) and MRO Mars Color Imager (MARCI) instruments. Through comparisons with atmospheric opacity measurements, temporal changes in Pancam albedo values provide insights into interactions between the Martian surface and atmosphere. Pancam observations are also used to “ground truth” measurements from orbit and validate radiometric calibrations, and we present comparisons across the full rover traverses to MOC, CTX, and MRO High Resolution Imaging Science Experiment (HiRISE) data. Albedo averages from the same regions observed by Pancam and all three orbital instruments generally agree to within ± 15%. The few instances found where cross-instrument comparisons exceed the estimated instrument calibration uncertainties can be attributed to atmospheric effects and/or differences in viewing geometries.

Secondary minerals associated with Lassen fumaroles and hot springs: Implications for martian hydrothermal deposits

The active hot springs, fumaroles, and mud pots of the southwestern Lassen hydrothermal system include various alteration environments, which produce a range of hydrothermal mineral assemblages. Analysis of water, mineral precipitates, altered sediment, and rock samples collected at and near these features at Sulphur Works, Bumpass Hell, Little Hot Springs Valley, and Growler and Morgan Hot Springs reveals conditions ranging from ~100 °C acid-sulfate fumaroles (e.g., Sulphur Works and Bumpass Hell) to near-neutral hot springs (e.g., Growler and Morgan), and includes both oxidizing and reducing conditions. Resulting hydrothermal minerals include a wide variety of sulfates (dominated by Al-sulfates, but also including Fe 2+ , Fe 3+ , Ca, Mg, and mixed-cation sulfates), sulfides (pyrite and marcasite), elemental sulfur, and smectite and kaolinite clays. Most altered samples contain at least one silica phase, most commonly quartz, but also including cristobalite, tridymite, and/or amorphous silica. Quartz and other silica phases are not as abundant in the less altered rock samples, thus their abundance in some hydrothermally altered sediment samples suggests a detrital origin, or formation by hydrothermal alteration (either modern or Pleistocene); this requires a high degree of diagenetic (or epigenetic) maturation. These results support a previously identified model that the Lassen hydrothermal system involves the de-coupling of a vapor phase (which becomes acidic as it oxidizes near the surface, producing acid-sulfate fumaroles at higher elevations at Sulphur Works and Bumpass Hell) from the residual near neutral thermal waters that emerge as hot springs at lower elevations (Growler and Morgan). Because both acid-sulfate fumarole and near-neutral sinter-producing hot springs have been invoked to explain the silica-rich deposits observed by the Mars Exploration Rover Spirit near Home Plate in the Columbia Hills on Mars, Lassen can serve as a useful terrestrial analog for comparison.

Abiotic versus biotic iron mineral transformation studied by a miniaturized backscattering Mössbauer spectrometer (MIMOS II), X-ray diffraction and Raman spectroscopy

Searching for biomarkers or signatures of microbial transformations of minerals is a critical aspect for determining how life evolved on Earth, and whether or not life may have existed in other planets, including Mars. In order to solve such questions, several missions to Mars have sought to determine the geochemistry and mineralogy on the Martian surface. This research includes the two miniaturized Mössbauer spectrometers (MIMOS II) on board the Mars Exploration Rovers Spirit and Opportunity, which have detected a variety of iron minerals on Mars, including magnetite (Fe2+Fe3+2O4) and goethite (α-FeO(OH)). On Earth, both minerals can derive from microbiological activity (e.g. through dissimilatory iron reduction of ferrihydrite by Fe(III)-reducing bacteria). Here we used a lab based MIMOS II to characterize the mineral products of biogenic transformations of ferrihydrite to magnetite by the Fe(III)-reducing bacteria Geobacter sulfurreducens. In combination with Raman spectroscopy and X-ray diffraction (XRD), we observed the formation of magnetite, goethite and siderite. We compared the material produced by biogenic transformations to abiotic samples in order to distinguish abiotic and biotic iron minerals by techniques that are or will be available onboard Martian based laboratories. The results showed the possibility to distinguish the abiotic and biotic origin of the minerals. Mossbauer was able to distinguish the biotic/abiotic magnetite with the interpretation of the geological context (Fe content mineral assemblages and accompanying minerals) and the estimation of the particle size in a non-destructive way. The Raman was able to confirm the biotic/abiotic principal peaks of the magnetite, as well as the organic principal vibration bands attributed to the bacteria. Finally, the XRD confirmed the particle size and mineralogy.

Amazonian chemical weathering rate derived from stony meteorite finds at Meridiani Planum on Mars.

Spacecraft exploring Mars such as the Mars Exploration Rovers Spirit and Opportunity, as well as the Mars Science Laboratory or Curiosity rover, have accumulated evidence for wet and habitable conditions on early Mars more than 3 billion years ago. Current conditions, by contrast, are cold, extremely arid and seemingly inhospitable. To evaluate exactly how dry today's environment is, it is important to understand the ongoing current weathering processes. Here we present chemical weathering rates determined for Mars. We use the oxidation of iron in stony meteorites investigated by the Mars Exploration Rover Opportunity at Meridiani Planum. Their maximum exposure age is constrained by the formation of Victoria crater and their minimum age by erosion of the meteorites. The chemical weathering rates thus derived are ∼1 to 4 orders of magnitude slower than that of similar meteorites found in Antarctica where the slowest rates are observed on Earth.

Sensitivity of simulated Martian atmospheric temperature to prescribed dust opacity distribution: Comparison of model results with reconstructed data from Mars Exploration Rover missions

We use the Mars Weather Research and Forecasting (MarsWRF) General Circulation Model to simulate the atmospheric structure corresponding to the landing location and time of the Mars Exploration Rovers (MER) Spirit (A) and Opportunity (B) in 2004. The multi-scale capability of MarsWRF facilitates high-resolution nested model runs centered near the landing site of each of the rovers. Dust opacity distributions based on measurements by Thermal Emission Spectrometer (TES) aboard the Mars Global Surveyor (MGS) spacecraft, and those from an old version of the Mars Climate Database (MCD v3.1 released in 2001) are used to study the sensitivity of the model temperature profile to variations in the dust prescription. The reconstructed Entry, Descent, and Landing (EDL) data from the rover missions are used for comparisons. We show that the model using dust opacity from TES limb and nadir data for the year of MER EDL, Mars Year 26 (MY26), yields temperature profiles in closer agreement with the reconstructed data than the pre-launch EDL simulations and models using other dust opacity specifications. The temperature at 100 Pa from the model (MY26) and the reconstruction are within 5° K. These results highlight the role of vertical dust opacity distribution in determining the atmospheric thermal structure. Similar studies involving data from past missions and models will be useful in understanding the extent to which atmospheric variability is captured by the models and in developing realistic pre-flight characterization required for future lander missions to Mars.

Microbialites at Gusev Crater, Mars.

The Mars Exploration Rover Spirit investigated plains at Gusev crater, where sedimentary rocks are present. The Spirit rover’s Athena morphological investigation shows microstructures organized in intertwined filaments of microspherules: a texture we have also found on samples of terrestrial stromatolites and other microbialites. We performed a quantitative image analysis to compare 45 microbialites samplings with 50 rover’s ones (approximately 25,000/20,000 microstructures). Contours were extracted and morphometric indexes obtained: geometric and algorithmic complexities, entropy, tortuosity, minimum and maximum diameters. Terrestrial and Martian textures resulted multifractals, while terrestrial abiogenic minerals showed a simple fractal structure. Mean values and confidence intervals from the Martian images overlapped perfectly with those from terrestrial samples. The probability of this occurring by chance was less than 1/28, p<0.004. Our work show the presumptive evidence of microbialites in the Martian outcroppings explored by “Spirit”, confirming our previous results concerning the Martian outcroppings explored by Opportunity at Meridiani Planum: unicellular life was widespread on the ancient Mars.

Spectrophotometric properties of materials observed by Pancam on the Mars Exploration Rovers: 3. Sols 500–1525

The Panoramic Camera (Pancam) on the Mars Exploration Rovers Spirit and Opportunity acquired visible/near-infrared (432–1009nm) multispectral observations of soils and rocks under varying viewing and illumination geometries. Data retrieved from these images were modeled using radiative transfer theory to study the microphysical and surface scattering nature of materials at both sites. Nearly 57,000 individual measurements from 1900 images were collected of rock and soil units identified by their color and morphologic properties over a wide range of phase angles (0–150°). Images were acquired between Sols 500 and 1525 in the Columbia Hills and regions around Home Plate in Gusev Crater and in the plains and craters between Erebus and Victoria Craters in Meridiani Planum. Corrections for diffuse skylight incorporated sky models based on observations of atmospheric opacity throughout the mission. Disparity maps created from Pancam stereo images allowed estimates of local facet orientations. For Spirit, soils at lower elevations near Home Plate were modeled with lower single scattering albedo (w) values than those on the summit of Husband Hill, but otherwise soils exhibited similar scattering properties to previous Gusev soils. Dark ripple sands at the El Dorado dunes were among the most forward-scattering materials modeled. Silica-rich soils and nodules near Home Plate were analyzed for the first time, and exhibited increased forward scattering behavior with increasing wavelength, consistent with microporosity inferred from previous high resolution images and thermal infrared spectroscopy. For Opportunity, the opposition effect width parameter for sandstone outcrop rocks was modeled for the first time, and demonstrated average values consistent with surfaces of intermediate porosity and/or grain size distribution between those modeled for spherule-rich soils and darker, clast-poor soils. Soils outside a wind streak emanating from the northern rim of Victoria Crater exhibited w values ∼16% higher than soils inside the streak. Overall, w values and scattering properties for outcrop rocks, spherule-rich soils, and rover tracks were similar to previous Meridiani Planum analyses, emphasizing the homogeneity of these materials across nearly 12km of rover odometry.

SHARAD soundings and surface roughness at past, present, and proposed landing sites on Mars: Reflections at Phoenix may be attributable to deep ground ice

We use the Shallow Radar (SHARAD) on the Mars Reconnaissance Orbiter to search for subsurface interfaces and characterize surface roughness at the landing sites of Viking Landers 1 and 2, Mars Pathfinder, the Mars Exploration Rovers Spirit and Opportunity, the Phoenix Mars lander, the Mars Science Laboratory Curiosity rover, and three other sites proposed for Curiosity. Only at the Phoenix site do we find clear evidence of subsurface radar returns, mapping out an interface that may be the base of ground ice at depths of ~15–66 m across 2900 km2 in the depression where the lander resides. At the Opportunity, Spirit, and candidate Curiosity sites, images and altimetry show layered materials tens to hundreds of meters thick extending tens to hundreds of kilometers laterally. These scales are well within SHARAD's resolution limits, so the lack of detections is attributable either to low density contrasts in layers of similar composition and internal structure or to signal attenuation within the shallowest layers. At each site, we use the radar return power to estimate surface roughness at scales of 10–100 m, a measure that is important for assessing physical properties, landing safety, and site trafficability. The strongest returns are found at the Opportunity site, indicating that Meridiani Planum is exceptionally smooth. Returns of moderate strength at the Spirit site reflect roughness more typical of Mars. Gale crater, Curiosity's ultimate destination, is the smoothest of the four proposed sites we examined, with Holden crater, Eberswalde crater, and Mawrth Vallis exhibiting progressively greater roughness.

The effects of weathering on the strength and chemistry of Columbia River Basalts and their implications for Mars Exploration Rover Rock Abrasion Tool (RAT) results

Basalt physical properties such as compressive strength and density are directly linked to their chemistry and constitution; as weathering progresses, basalts gradually become weaker and transition from intact rock to saprolite and ultimately, to soil. Here we quantify the degree of weathering experienced by the Adirondack-class basalts at the Mars Exploration Rover Spirit site by performing comparative analyses on the strength and chemistry of a series of progressively weathered Columbia River Basalt (CRB) from western Idaho and eastern Washington. CRB samples were subjected to compressive strength tests, Rock Abrasion Tool grinds, neutron activation analysis, and inductively coupled plasma optical emission spectroscopy. Analyses of terrestrial basalts indicate linked strength-chemical changes, as expected. Weathering sufficient to induce the loss of more than 50% of some cations (including >50% of MgO and MnO as well as ∼38% of Fe2O3 and 34% of CaO) was observed to weaken these samples by as much as 50% of their original strength. In comparison with the terrestrial samples, Adirondack-class basalts are most similar to the weakest basalt samples measured in terms of compressive strength, yet they do not exhibit a commensurate amount of chemical alteration. Since fluvial and lacustrine activity in Gusev crater appears to have been limited after the emplacement of flood basalt lavas, the observed weakness is likely attributable to thin-film weathering on exposed, displaced rocks in the Gusev plains (in addition to some likely shock effects). The results indicate that Adirondack-class basalts may possess a several mm-thick weak outer rind encasing an interior that is more pristine than otherwise indicated, and also suggest that long rock residence times may be the norm.

Evidence for a Noachian-aged ephemeral lake in Gusev crater, Mars

Gusev crater has long been considered the site of a lake early in Martian history, but the Mars Exploration Rover Spirit found no apparent evidence of lake deposits along its 7 km traverse from 2004 to 2010. Although outcrops rich in Mg-Fe carbonate, dubbed Comanche, were discovered in the Noachian-aged Columbia Hills, they were inferred to result from volcanic hydrothermal activity. We now find evidence that the alteration of the Comanche outcrops is consistent with evaporative precipitation of low-temperature, near-surface solutions derived from limited water-rock interaction with rocks equivalent to nearby outcrops called Algonquin. Additional observations show that the Algonquin outcrops are remnants of volcanic tephra that covered the Columbia Hills and adjacent plains well before emplacement of basalt flows onto the floor of Gusev crater. Water-limited leaching of formerly widespread Algonquin-like tephra deposits by ephemeral waters, followed by transport and evaporative precipitation of the fluids into the Comanche outcrops, can explain their chemical, mineralogical, and textural characteristics.

MAHLI at the Rocknest sand shadow: Science and science‐enabling activities

AbstractDuring Martian solar days 57–100, the Mars Science Laboratory Curiosity rover acquired and processed a solid (sediment) sample and analyzed its mineralogy and geochemistry with the Chemistry and Mineralogy and Sample Analysis at Mars instruments. An aeolian deposit—herein referred to as the Rocknest sand shadow—was inferred to represent a global average soil composition and selected for study to facilitate integration of analytical results with observations from earlier missions. During first‐time activities, the Mars Hand Lens Imager (MAHLI) was used to support both science and engineering activities related to sample assessment, collection, and delivery. Here we report on MAHLI activities that directly supported sample analysis and provide MAHLI observations regarding the grain‐scale characteristics of the Rocknest sand shadow. MAHLI imaging confirms that the Rocknest sand shadow is one of a family of bimodal aeolian accumulations on Mars—similar to the coarse‐grained ripples interrogated by the Mars Exploration Rovers Spirit and Opportunity—in which a surface veneer of coarse‐grained sediment stabilizes predominantly fine‐grained sediment of the deposit interior. The similarity in grain size distribution of these geographically disparate deposits support the widespread occurrence of bimodal aeolian transport on Mars. We suggest that preservation of bimodal aeolian deposits may be characteristic of regions of active deflation, where winnowing of the fine‐sediment fraction results in a relatively low sediment load and a preferential increase in the coarse‐grained fraction of the sediment load. The compositional similarity of Martian aeolian deposits supports the potential for global redistribution of fine‐grained components, combined with potential local contributions.

Alteration mineralogy of Home Plate and Columbia Hills—Formation conditions in context to impact, volcanism, and fluvial activity

AbstractThe Mars Exploration Rover Spirit investigated the igneous and alteration mineralogy and chemistry of Home Plate and its surrounding deposits. Here, we focus on using thermochemical modeling to understand the secondary alteration mineralogy at the Home Plate outcrop and surrounding Columbia Hills region in Gusev crater. At high temperatures (300 °C), magnetite occurs at very high W/R ratios, but the alteration assemblage is dominated by chlorite and serpentine over most of the W/R range. Quartz, epidote, and typical high‐T phases such as feldspar, pyroxene, and garnet occur at low W/R. At epithermal temperatures (150 °C), hematite occurs at very high W/R. A range of phyllosilicates, including kaolinite, nontronite, chlorite, and serpentine are precipitated at specific W/R. Amphibole, with garnet, feldspar, and pyroxene occur at low W/R. If the CO2 content of the system is high, the assemblage is dominated by carbonate with increasing amounts of an SiO2‐phase, kaolinite, carpholite, and chlorite with lower W/R. At temperatures of hydrous weathering (13 °C), the oxide phase is goethite, silicates are chlorite, nontronite, and talc, plus an SiO2‐phase. In the presence of CO2, the mineral assemblage at high W/R remains the same, and only at low W/R, i.e., with increasing salinity, carbonate precipitates. The geochemical gradients observed at Home Plate are attributed to short‐lived, initially high (300 °C) temperature, but fast cooling events, which are in agreement with our models and our interpretation of a multistage alteration scenario of Home Plate and Gusev in general. Alteration at various temperatures and during different geological processes within Gusev crater has two effects, both of which increase the habitability of the local environment: precipitation of hydrous sheet silicates, and formation of a brine, which might contain elements essential for life in diluted, easily accessible form.

Curiosity at Gale Crater, Mars: Characterization and Analysis of the Rocknest Sand Shadow

The Rocknest aeolian deposit is similar to aeolian features analyzed by the Mars Exploration Rovers (MERs) Spirit and Opportunity. The fraction of sand <150 micrometers in size contains ~55% crystalline material consistent with a basaltic heritage and ~45% x-ray amorphous material. The amorphous component of Rocknest is iron-rich and silicon-poor and is the host of the volatiles (water, oxygen, sulfur dioxide, carbon dioxide, and chlorine) detected by the Sample Analysis at Mars instrument and of the fine-grained nanophase oxide component first described from basaltic soils analyzed by MERs. The similarity between soils and aeolian materials analyzed at Gusev Crater, Meridiani Planum, and Gale Crater implies locally sourced, globally similar basaltic materials or globally and regionally sourced basaltic components deposited locally at all three locations.

Surface reflectance of Mars observed by CRISM/MRO: 2. Estimation of surface photometric properties in Gusev Crater and Meridiani Planum

AbstractThe present article proposes an approach to analyze the photometric properties of the surface materials from multi‐angle observations acquired by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) on‐board the Mars Reconnaissance Orbiter. We estimate photometric parameters using Hapke's model in a Bayesian inversion framework. This work also represents a validation of the atmospheric correction provided by the Multi‐angle Approach for Retrieval of Surface Reflectance from CRISM Observations (MARS‐ReCO) proposed in the companion article. The latter algorithm retrieves photometric curves of surface materials in reflectance units after removing the aerosol contribution. This validation is done by comparing the estimated photometric parameters to those obtained from in situ measurements by Panoramic Camera instrument at the Mars Exploration Rover (MER) Spirit and MER Opportunity landing sites. Consistent photometric parameters with those from in situ measurements are found, demonstrating that MARS‐ReCO gives access to accurate surface reflectance. Moreover, the assumption of a non‐Lambertian surface as included in MARS‐ReCO is shown to be significantly more precise to estimate surface photometric properties from space in comparison to methods based on a Lambertian surface assumption. In the future, the presented method will allow us to map from orbit the surface bidirectional reflectance and the related photometric parameters in order to characterize the Martian surface.

Acid sulfate alteration of fluorapatite, basaltic glass and olivine by hydrothermal vapors and fluids: Implications for fumarolic activity and secondary phosphate phases in sulfate‐rich Paso Robles soil at Gusev Crater, Mars

Phosphate‐rich rocks and a nearby phosphate‐rich soil, Paso Robles, were analyzed in Gusev Crater, Mars, by the Mars Exploration Rover Spirit and interpreted to be highly altered, possibly by hydrothermal or fumarolic alteration of primary, phosphate‐rich material. To test mineral phases resulting from such alteration, we performed hydrothermal acid‐vapor and acid‐fluid experiments on olivine (Ol), fluorapatite (Ap), and basaltic glass (Gl) as single phases and a mixture of phases. Minerals formed include Ca‐, Al‐, Fe‐ and Mg‐sulfates with different hydration states (anhydrite, bassanite, gypsum; alunogen; hexahydrite, and pentahydrite). Phosphate‐bearing minerals formed included monocalcium phosphate monohydrate (MCP) (acid‐vapor and acid‐fluid alteration of fluorapatite only) and ferrian giniite (acid‐fluid alteration of the Ol + Gl + Ap mixture). MCP is likely present in Paso Robles if primary Ca‐phosphate minerals reacted with sulfuric acid with little transport of phosphate. Under fluid:rock ratios allowing transport of phosphate, a ferric phosphate phase such as ferrian giniite might form instead. Mössbauer measurements of ferrian giniite‐bearing alteration products and synthetic ferrian giniite are consistent with Spirit's Mössbauer measurements of the ferric‐bearing phase in Paso Robes soil, but are also consistent with ferric sulfate phases in the low‐P soil Arad_Samra. Therefore, Mössbauer data alone do not constrain the fluid:rock ratio. However, the excess iron (hematite) in Paso Robles soil, which implies aqueous transport, combined with our laboratory experiments, suggest acid‐sulfate alteration in a hydrothermal (fumarolic) environment at fluid:rock ratios sufficient to allow dissolution, transport, and precipitation of secondary chemical components including a ferric phosphate such as ferrian giniite.

Spectrogoniometry and modeling of martian and lunar analog samples and Apollo soils

We present new visible/near-infrared multispectral reflectance measurements of seven lunar soil simulants, two Apollo soils, and eight martian analog samples as functions of illumination and emission angles using the Bloomsburg University Goniometer. By modeling these data with Hapke theory, we provide constraints on photometric parameters (single scattering albedo, phase function parameters, macroscopic roughness, and opposition effect parameters) to provide additional “ground truth” photometric properties to assist analyses of spacecraft data. A wide range of modeled photometric properties were variably related to albedo, color, grain size, and surface texture. Finer-grained samples here have high single-scattering albedo values compared to their coarser-grained counterparts, as well as lower macroscopic roughness values. The Mars analog samples and Apollo soils exhibit slightly lower opposition effect width parameter values than the lunar analogs, whereas the opposition effect magnitude is not well constrained by the models. The Mars analog soils are typically relatively backscattering and consistent with fairly rough particles with a moderate density of internal scatterers, similar to the in situ observations of some soils by the Mars Exploration Rover (MER) Spirit. Some lunar analog soil models result in moderately-forward scattering behaviors, as do the two Apollo soils. Other fine-grained and/or glass-rich lunar analog samples populate a narrowly forward-scattering regime similar to model results from observations of some rover tracks observed by the MER Opportunity rover and some dust-poor “gray” rocks by the Spirit rover. An experiment to mimic the spherule-rich soils observed by Opportunity demonstrated a large decrease in single-scattering albedo compared to spherule-free soil surfaces, as well as increased surface roughness, narrow opposition effects, and a significant increase in backscattering, similar to some of the Opportunity soils. Phase reddening effects are documented in many soils as an increase in near-infrared/visible ratios with phase angle. Some samples exhibit falloffs in these ratio phase curves at phase angles beyond 50–80° that are likely related to an increased importance of surface scattering at high phase angles. None of the lunar analog soils perfectly match the modeled photometric parameters of the two Apollo soils. The phase reddening nature of the mare soil included an upturn in ratio values at phase angles <10° that was not observed for the highland sample. It remains to be verified whether this is a consistent observation between mare and highland samples.