Markovian Dynamics Research Articles

Non-Markovian dynamics control of an open quantum system in a Schwarzschild space–time

By considering two qubits respectively coupled with two independent reservoirs and ignoring the interaction between them, two different cases are studied in two models: only one qubit accelerates and hovers near the event horizon or both two qubits accelerate and hover near the event horizon. The first model is given by referring to the damping Jaynes–Cummings model with a reservoir described by Lorentzian spectral density. And the second model is a pure dephasing model with a reservoir described by Ohmic spectral density. We investigate the impact of acceleration and Hawking temperature on the non-Markovianity and the quantum speed limit time of a two-qubit open quantum system. Through the numerical calculation, it is found that for these two models, by reducing the acceleration of qubits and the Hawking temperature outside the event horizon, the non-Markovianity of the dynamic process of the quantum system in the Schwarzschild space–time can be enhanced until it approaches the non-Markovianity when both qubits are in the inertial frame. However, we find that in the first model, the evolution speed of quantum state can be accelerated with decreasing acceleration and Hawking temperature. While in the second model, the quantum state evolution speed can be accelerated with increasing acceleration and Hawking temperature. For both models, the evolution speed of the quantum state of the system in the Markovian dynamics can still be accelerated.

Quantumness of electron transport in quantum dot devices through Leggett–Garg inequalities: A non-equilibrium Green’s function approach

Although coherent manipulation of electronic states can be achieved in quantum dot (QD) devices by harnessing nanofabrication tools, it is often hard to fathom the extent to which these nanoelectronic devices can behave quantum mechanically. Witnessing their nonclassical nature would thus remain of paramount importance in the emerging world of quantum technologies, since the coherent dynamics of electronic states plays there a crucial role. Against this backdrop, we resort to the general framework of Leggett-Garg inequalities (LGI) as it allows for distinguishing the classical and quantum transport through nanostructures by way of various two-time correlation functions. Using the local charge detection at two different time, we investigate here theoretically whether any quantum violation of the original LGI exists with varying device configurations and parameters under both Markovian and non-Markovian dynamics. Two-time correlators within LGI are derived in terms of the non-equilibrium Green’s functions (NEGFs) by exactly solving the quantum Langevin equations. The present study of non-Markovian dynamics of quantum systems interacting with reservoirs is significant for understanding the relaxation phenomenon in the ultrafast transient regime to especially mimic what happens to high-speed quantum devices. We can potentially capture the effect of finite reservoir correlation time by accounting for level-broadening at the electrodes along with non-Markovian memory effects. Furthermore, the large bias restriction is no longer imposed in our calculations so that we can safely consider a finite bias between the electronic reservoirs. Our approach is likely to open up new possibilities of witnessing the quantumness for other quantum many-body systems as well that are driven out of the equilibrium.

Spectral Map for Slow Collective Variables, Markovian Dynamics, and Transition State Ensembles.

Understanding the behavior of complex molecular systems is a fundamental problem in physical chemistry. To describe the long-time dynamics of such systems, which is responsible for their most informative characteristics, we can identify a few slow collective variables (CVs) while treating the remaining fast variables as thermal noise. This enables us to simplify the dynamics and treat it as diffusion in a free-energy landscape spanned by slow CVs, effectively rendering the dynamics Markovian. Our recent statistical learning technique, spectral map [Rydzewski, J. J. Phys. Chem. Lett. 2023, 14(22), 5216-5220], explores this strategy to learn slow CVs by maximizing a spectral gap of a transition matrix. In this work, we introduce several advancements into our framework, using a high-dimensional reversible folding process of a protein as an example. We implement an algorithm for coarse-graining Markov transition matrices to partition the reduced space of slow CVs kinetically and use it to define a transition state ensemble. We show that slow CVs learned by spectral map closely approach the Markovian limit for an overdamped diffusion. We demonstrate that coordinate-dependent diffusion coefficients only slightly affect the constructed free-energy landscapes. Finally, we present how spectral maps can be used to quantify the importance of features and compare slow CVs with structural descriptors commonly used in protein folding. Overall, we demonstrate that a single slow CV learned by spectral map can be used as a physical reaction coordinate to capture essential characteristics of protein folding.

Markovian to non-Markovian phase transition in the operator dynamics of a mobile impurity

We study a random unitary circuit model of an impurity moving through a chaotic medium. The exchange of information between the medium and impurity is controlled by varying the velocity of the impurity, v_dvd, relative to the speed of information propagation within the medium, v_BvB. Above supersonic velocities, v_d> v_Bvd>vB, information cannot flow back to the impurity after it has moved into the medium, and the resulting dynamics are Markovian. Below supersonic velocities, v_d< v_Bvd<vB, the dynamics of the impurity and medium are non-Markovian, and information is able to flow back onto the impurity. We show the two regimes are separated by a continuous phase transition with exponents directly related to the diffusive spreading of operators in the medium. This is demonstrated by monitoring an out-of-time-order correlator (OTOC) in a scenario where the impurity is substituted at an intermediate time. During the Markovian phase, information from the medium cannot transfer onto the replaced impurity, manifesting in no significant operator development. Conversely, in the non-Markovian phase, we observe that operators acquire support on the newly introduced impurity. We also characterize the dynamics using the coherent information and provide two decoders which can efficiently probe the transition between Markovian and non-Markovian information flow. Our work demonstrates that Markovian and non-Markovian dynamics can be separated by a phase transition, and we propose an efficient protocol for observing this transition.

Induced magnetization in anisotropic environment

The non-Markovian dynamics of a two-dimensional charged harmonic oscillator linearly coupled to a neutral bosonic heat bath is investigated in a linear-polarized electric field. The analytical expressions for the time-dependent and asymptotic magnetic moment are derived for the Markovian and non-Markovian dynamics. It is predicted that the liner-polarized electric field generates strong orbital currents and magnetization in a symmetric harmonic oscillator embedded into anisotropic heat bath. The role of the mixed dissipative kernel in magnetization is analyzed.

Inferring Kinetics and Entropy Production from Observable Transitions in Partially Accessible, Periodically Driven Markov Networks

For a network of discrete states with a periodically driven Markovian dynamics, we develop an inference scheme for an external observer who has access to some transitions. Based on waiting-time distributions between these transitions, the periodic probabilities of states connected by these observed transitions and their time-dependent transition rates can be inferred. Moreover, the smallest number of hidden transitions between accessible ones and some of their transition rates can be extracted. We prove and conjecture lower bounds on the total entropy production for such periodic stationary states. Even though our techniques are based on generalizations of known methods for steady states, we obtain original results for those as well.

Spin-boson model under dephasing: Markovian versus non-Markovian dynamics

Spin-boson model under dephasing: Markovian versus non-Markovian dynamics

Quantum fluctuation dynamics of open quantum systems with collective operator-valued rates, and applications to Hopfield-like networks

We consider a class of open quantum many-body systems that evolves in a Markovian fashion, the dynamical generator being in GKS-Lindblad form. Here, the Hamiltonian contribution is characterized by an all-to-all coupling, and the dissipation features local transitions that depend on collective, operator-valued rates, encoding average properties of the system. These types of generators can be formally obtained by generalizing, to the quantum realm, classical (mean-field) stochastic Markov dynamics, with state-dependent transitions. Focusing on the dynamics emerging in the limit of infinitely large systems, we build on the exactness of the mean-field equations for the dynamics of average operators. In this framework, we derive the dynamics of quantum fluctuation operators, that can be used in turn to understand the fate of quantum correlations in the system. We then apply our results to quantum generalized Hopfield associative memories. Here we show that, asymptotically and at the description level of quantum fluctuations, only a very weak amount of quantum correlations, in the form of quantum discord, emerges beyond classical correlations.

Multiparty Spohn's theorem for a combination of local Markovian and non-Markovian quantum dynamics

Multiparty Spohn's theorem for a combination of local Markovian and non-Markovian quantum dynamics

Markovian dynamics for a quantum/classical system and quantum trajectories

Quantum trajectory techniques have been used in the theory of open systems as a starting point for numerical computations and to describe the monitoring of a quantum system in continuous time. We extend this technique to develop a general approach to the dynamics of quantum/classical hybrid systems. By using two coupled stochastic differential equations, we can describe a classical component and a quantum one which have their own intrinsic dynamics and which interact with each other. A mathematically rigorous construction is given, under the restriction of having a Markovian joint dynamics and of involving only bounded operators on the Hilbert space of the quantum component. An important feature is that, if the interaction allows for a flow of information from the quantum component to the classical one, necessarily the dynamics is dissipative. We show also how this theory is connected to a suitable hybrid dynamical semigroup, which reduces to a quantum dynamical semigroup in the purely quantum case and includes Liouville and Kolmogorov–Fokker–Planck equations in the purely classical case. Moreover, this semigroup allows to compare the proposed stochastic dynamics with various other proposals based on hybrid master equations. Some simple examples are constructed in order to show the variety of physical behaviors which can be described; in particular, a model presenting hidden entanglement is introduced.

Collective photon emission in solid state environments: Concatenating non-Markovian and Markovian dynamics

Collective light emission and multiqubit dynamics of solid-state quantum emitters are affected both by their coupling to the light field and to lattice vibrations. The effect of phonons on quantum emitters is twofold: polaron formation is described by ultrafast non-Markovian dynamics, while slower dephasing is well described by exponential decay. Of the two temperature-dependent processes, the effect of the former on the collective emission and the entanglement decay of emitters is usually not modeled, and also the latter is sometimes neglected. Here we propose and compare two methods that are efficient also for several emitters: the first method concatenates the fast and slow phonon dynamics, and the second is the polaron method. For a single quantum emitter, we show that the dynamical equations are identical in both methods, while predictions for two or more emitters also agree very well. Both of our methods incorporate non-Markovian dynamics due to phonons demonstrating the temperature sensitivity of the collective photon emission. Utilizing a simplified Markovian model instead may not be accurate enough especially for quantum information applications: for example, we show how the Markovian model may considerably overestimate the two-emitter concurrence, except at very low temperatures. Our concatenation and polaron methods can be applied to an arbitrary number and type of quantum emitters, and beyond the bulk GaAs environment that we consider here. Especially the concatenation method can take phonon effects into account at the same computational cost as modeling the emitter-photon interaction alone. Finally, we present approximate analytical expressions for the collective emission spectrum for N emitters on a one-dimensional chain. Published by the American Physical Society 2024

Free-energy estimates from nonequilibrium trajectories under varying-temperature protocols.

The Jarzynski equality allows the calculation of free-energy differences using values of work measured from nonequilibrium trajectories. The number of trajectories required to accurately estimate free-energy differences in this way grows sharply with the size of work fluctuations, motivating the search for protocols that perform desired transformations with minimum work. However, protocols of this nature can involve varying temperature, to which the Jarzynski equality does not apply. We derive a variant of the Jarzynski equality that applies to varying-temperature protocols, and show that it can have better convergence properties than the standard version of the equality. We derive this modified equality and the associated fluctuation relation within the framework of Markovian stochastic dynamics, complementing related derivations done within the framework of Hamiltonian dynamics.

Entropy production from waiting-time distributions for overdamped Langevin dynamics

For a Markovian dynamics on discrete states, the logarithmic ratio of waiting-time distributions between two successive, instantaneous transitions in forward and backward direction is a measure of time-irreversibility. It thus serves as an entropy estimator, which is exact in the case of a uni-cyclic network. We adopt this framework to overdamped Langevin dynamics, where such transitions have finite duration. By introducing milestones based on the observation of a particle at at least two milestones and an additional third event, we identify an entropy estimator that becomes exact for driven motion along a one-dimensional potential.

Hybrid quantum-classical systems: Quasi-free Markovian dynamics

In the case of a quantum-classical hybrid system with a finite number of degrees of freedom, the problem of characterizing the most general dynamical semigroup is solved, under the restriction of being quasi-free. This is a generalization of a Gaussian dynamics, and it is defined by the property of sending (hybrid) Weyl operators into Weyl operators in the Heisenberg description. The result is a quantum generalization of the Lévy–Khintchine formula; Gaussian and jump contributions are included. As a byproduct, the most general quasi-free quantum-dynamical semigroup is obtained; on the classical side the Liouville equation and the Kolmogorov–Fokker–Planck equation are included. As a classical subsystem can be observed, in principle, without perturbing it, information can be extracted from the quantum system, even in continuous time; indeed, the whole construction is related to the theory of quantum measurements in continuous time. While the dynamics is formulated to give the hybrid state at a generic time [Formula: see text], we show how to extract multi-time probabilities and how to connect them to the quantum notions of positive operator-valued measure and instrument. The structure of the generator of the dynamical semigroup is analyzed, in order to understand how to go on to non-quasi-free cases and to understand the possible classical-quantum interactions; in particular, all the interaction terms which allow to extract information from the quantum system necessarily vanish if no dissipation is present in the dynamics of the quantum component. A concrete example is given, showing how a classical component can input noise into a quantum one and how the classical system can extract information on the behavior of the quantum one.

Strong coupling spontaneous emission interference near a graphene nanodisk

Abstract In this work, we analyze the spontaneous emission dynamics of a V-type quantum emitter near a graphene nanodisk based on the combination of electromagnetic and quantum dynamical calculations. The presence of the graphene nanodisk gives strong anisotropy to the Purcell factors of the quantum emitter, leading to interference effects in spontaneous emission appearing as coupling between the emitter’s upper levels. This effect is further enhanced by the strong light–matter interaction of the quantum emitter with the modified electromagnetic mode continuum, which induces non-Markovian spontaneous emission dynamics. We have studied the population dynamics of the quantum emitter at a specific distance from the center of the graphene nanodisk for various free-space decay widths and different quantum emitter’s initial conditions and have shown weak coupling results appearing with Markovian decay dynamics, obtained for quantum emitters with small free-space decay widths, and population dynamics that exhibits distinctly non-Markovian features, such as prominent decaying Rabi oscillations in the population evolution of the quantum emitter’s excited states and energy exchange between them during the overall population decay into the photonic mode continuum for largest free-space decay widths. Also, for the largest value of the free-space decay width, we obtain significant population trapping effects in the excited states of the quantum emitter. Furthermore, we find that the population dynamics for specific light–matter interaction strength conditions between the quantum emitter and the graphene nanodisk depend distinctively on the initial state of the quantum emitter, whether it is a single state or a superposition state.

Memory Corrections to Markovian Langevin Dynamics.

Analysis of non-Markovian systems and memory-induced phenomena poses an everlasting challenge in the realm of physics. As a paradigmatic example, we consider a classical Brownian particle of mass M subjected to an external force and exposed to correlated thermal fluctuations. We show that the recently developed approach to this system, in which its non-Markovian dynamics given by the Generalized Langevin Equation is approximated by its memoryless counterpart but with the effective particle mass M∗<M, can be derived within the Markovian embedding technique. Using this method, we calculate the first- and the second-order memory correction to Markovian dynamics of the Brownian particle for the memory kernel represented as the Prony series. The second one lowers the effective mass of the system further and improves the precision of the approximation. Our work opens the door for the derivation of higher-order memory corrections to Markovian Langevin dynamics.

Asymptotic Analysis for the Generalized Langevin Equation with Singular Potentials

We consider a system of interacting particles governed by the generalized Langevin equation (GLE) in the presence of external confining potentials, singular repulsive forces, as well as memory kernels. Using a Mori–Zwanzig approach, we represent the system by a class of Markovian dynamics. Under a general set of conditions on the nonlinearities, we study the large-time asymptotics of the multi-particle Markovian GLEs. We show that the system is always exponentially attractive toward the unique invariant Gibbs probability measure. The proof relies on a novel construction of Lyapunov functions. We then establish the validity of the small-mass approximation for the solutions by an appropriate equation on any finite-time window. Important examples of singular potentials in our results include the Lennard–Jones and Coulomb functions.

Entanglement Assisted Probe of the Non-Markovian to Markovian Transition in Open Quantum System Dynamics.

We utilize a superconducting qubit processor to experimentally probe non-Markovian dynamics of an entangled qubit pair. We prepare an entangled state between two qubits and monitor the evolution of entanglement over time as one of the qubits interacts with a small quantum environment consisting of an auxiliary transmon qubit coupled to its readout cavity. We observe the collapse and revival of the entanglement as a signature of quantum memory effects in the environment. We then engineer the non-Markovianity of the environment by populating its readout cavity with thermal photons to show a transition from non-Markovian to Markovian dynamics, ultimately reaching a regime where the quantum Zeno effect creates a decoherence-free subspace that effectively stabilizes the entanglement between the qubits.

On the relevance of weak measurements in dissipative quantum systems

We investigate the impact of dissipation, including energy relaxation and decoherence, on weak measurements. While weak measurements have been successful in signal amplification, dissipation can compromise their usefulness. More precisely, we show that in systems with a unique steady state, weak values always converge to an expectation value of the measured observable as dissipation time tends to infinity, in contrast to systems with multiple steady states, where the weak values can remain anomalous, i.e. outside the range of eigenvalues of the observable, even in the limit of an infinite dissipation time. In addition, we propose a method for extracting information about the dissipative dynamics of a system using weak values at short dissipation times. Specifically, we explore the amplification of the dissipation rate in a two-level system and the use of weak values to differentiate between Markovian and non-Markovian dissipative dynamics. We also find that weak measurements operating around a weak atom-cavity coupling can probe the atom dissipation through the weak value of non-Hermitian operators within the rotating-wave approximation of the weak interaction.

Experimental investigation of geometric quantum speed limits in an open quantum system

The quantum speed limit (QSL) is a fundamental lower bound on the evolution time for quantum systems, and its tightness has been observed to be dependent on the properties of the physical process. However, experimental studies exploring the QSL in open quantum systems are still missing. Here, we studied geometric quantum speed limits of a qubit subject to decoherence in an ensemble of chloroform molecules in a Nuclear Magnetic Resonance experiment. We controlled the system-reservoir interaction and the spin relaxation rates by adding a paramagnetic salt, allowing the observation of both Markovian and non-Markovian open system dynamics for the qubit. We used two distinguishability measures of quantum states to assess the speed of the qubit evolution: the quantum Fisher information (QFI) and Wigner-Yanase skew information (WY). For non-Markovianity and low salt concentrations, we found crossovers between QSLs related to those metrics. The WY metric sets the tighter QSL for high concentrations and Markovian dynamics. We also show that QSLs are sensitive even to small fluctuations in spin magnetization.