Marine Inputs Research Articles

Seawater spray as a significant nitrogen source across coastal dune vegetation gradients

BackgroundNitrogen significantly influences plant performance and vegetation development in nutrient-poor ecosystems like coastal dunes. While various sources contribute nitrogen, including N2 fixation and marine inputs, the significance of seawater spray remains understudied. In this study, we aimed to assess the relevance of seawater spray as a source of nitrogen input and its potential role in plant community composition in dune ecosystems. MethodsThe δ15N, δ13C, N, and C content of leaves from the most abundant 21 species were measured in 6 positions across a beach inland gradient in a Mediterranean dune system in SW Spain. Soil samples at different depths were collected in each position and N, C, P, K, NH4+, NO3=, and organic matter were measured. Salt spray accumulation was determined on Achillea maritima leaves across the gradient. ResultsLeaf nitrogen content did not exhibit a beach-inland gradient, but δ15N decreased with distance from the sea. Species displayed three distinct N uptake strategies along the gradient: species from Upper Beach and Foredune communities showed high δ15N values, suggesting a marine origin; species distributed across the gradient exhibited decreasing δ15N patterns from the Upper Beach to the Inland, indicative of seawater spray influence; species farthest from the sea relied on non-marine nitrogen sources. ConclusionsThese results indicate the importance of seawater nitrogen income for the dune system vegetation and evidence that dune plant species exhibit varied N uptake strategies influenced by their position across the beach-inland gradient.

Oil families in the eastern cordillera and llanos basin, Colombia: A comprehensive characterization using advanced geochemical technologies

Three major age-related oil families, clustered into seven groups, were identified in the Llanos basin based on advanced geochemical technologies that unveiled complex mixtures throughout the basin. The analyses included the conventional whole oil and biomarker analysis and the more refined and advanced GC-MS/MS analysis. The latter provided for terrestrial diterpane-based age-specific arrays that discriminated between Cretaceous and Cenozoic floral types. The analysis of asphaltene hydrous pyrolysates revealed the initial charges to the reservoirs, often of early maturity, but also strongly biodegraded and overprinted by fresh oil charges. Extensive analysis on diamondoids allowed the characterization of the late maturity charges, differentiation between mixed and singly-sourced oils and the ability to tie together earlier with later generated oil components of oil mixtures. Oils from Family A are the most widespread in the basin, found in the southern Llanos and in the Foothills and are derived from Lower Cretaceous to Cenomanian marine shale with a terrigenous input. Within Family B, of Upper Cretaceous age, two main source facies were identified, one with a siliciclastic marine input, corresponding to Groups 4 and 5. They have the highest concentrations of the C25 highly branched isoprenoid (HBI) and occur in the Northern and Eastern Llanos and in the Axial Zone of the Eastern Cordillera. The other facies has a more calcareous aspect, identified mainly in the Southern Llanos designated as Groups 2 and 3. Family C, of Cenozoic age, is restricted to the Foothills and two oil Groups were distinguished: Group 6 as the only endmember of a terrigenous Cenozoic facies, identified in Oil 7, and Group 7 shows a Cenozoic terrigenous facies and varying degrees of mixing with a marine Cretaceous input. These families are mixed in a variety of ways, having mixtures from different facies, while others show multiple charges from the same facies.

Evaluating the use of marine subsidies by Arctic foxes without direct coastal access; insights from stable isotopes

The trophic structures of tundra ecosystems are often viewed as a result of local terrestrial primary productivity. However, other resources can be brought in through long-distant migrants or be directly accessible in coastal areas. Hence, trophic structures may deviate from predictions based on local terrestrial resources. The Arctic fox (Vulpes lagopus) is a small canid that may use marine resources when available. We used stable isotope values in Arctic fox fur and literature data on potential prey to evaluate Arctic fox summer resource use in a mountain tundra without coastal access. The dietary contribution of local prey, presumably mostly rodents, declined with declining rodent abundance, with a subsequent increased contribution of migratory prey relying on marine resources. Stable isotope values did not differ between this terrestrial area and an area with direct coastal access during years of high rodent abundance, but isotope values during low rodent abundances suggested less marine input than in a coastal population feeding primarily on marine prey. Our study shows that marine resources may be used by animals in areas without any coastal access, and we highlight that such partial coupling of ecosystems must be included in the modeling and assessments of tundra environments.

Significant influence of urban human activities and marine input on rainwater chemistry in a coastal large city, China

The coastal urban region is generally considered an atmospheric receptor for terrestrial and marine input materials, and rainfall chemistry can trace the wet scavenging process of these materials. Fast urbanization in China's east coastal areas has greatly altered the rainwater chemistry. However, the chemical variations, determinants, and sources of rainfall are unclear. Therefore, the typical coastal city of Fuzhou was selected for 1-year rainwater sampling and inorganic ions were detected to explore above problems. The findings depicted that rainwater ions in Fuzhou were slightly different from those in other coastal cities. Although NO3−, SO42−, Ca2+ and NH4+ dominated the rainwater ions, the marine input Cl− (22 %) and Na+ (11 %) also contributed a considerable percentage to the rainwater ions. Large differences in ion concentrations (2∼28 times) were found in monthly scale due to the rainfall amount. Both natural and anthropogenic determinants influenced the rainwater ions in coastal cities, such as SO2 emission, air SO2 and PM10 content on rainwater SO42−, NO3−, and Ca2+, and soot & dust emission on rainwater SO42−, NO3−, indicating the vital contribution of human activities. Stoichiometry and positive matrix factorization-based sources identification indicated that atmospheric dust/particles were the primary contributor of Ca2+ (83.3 %) and F− (83.7 %), and considerable contributor of SO42− (39.5 %), NO3− (38.3 %) and K+ (41.5 %). Anthropogenic origins, such as urban waste volatilization and fuel combustion emission, contributed 95 % of NH4+, 54.5 % of NO3− and 41.9 % of SO42−, and the traffic sources contribution was relatively higher than fixed emission sources. The marine input represented the vital source of Cl− (77.7 %), Na+ (84.9 %), and Mg2+ (55.3 %). This work highlights the significant influence of urban human activities and marine input on rainwater chemicals and provides new insight into the material cycle between the atmosphere and earth-surface in coastal city.

Organic geochemical evaluation of crude oils from some producing fields in the Niger Delta basin, Nigeria

Geochemical and biomarker characteristics of representative crude oil samples from selected fields in southern Nigeria were evaluated to determine the organic matter input, origin of biological material, depositional environment, thermal maturity, and genetic relationship between the oils. Four crude oil samples were obtained from various oil producing fields from Delta, Bayelsa and Abia state in southern Nigeria and labeled Kwale (KW), Kolo creek (KLC), Owaza (OWA1 and OWA2). The crude oil samples were fractionated into saturates, aromatic hydrocarbons and polar compounds using column chromatography on silica gel thereafter, analyzed using Gas chromatography-mass spectrometry (GC–MS). The calculated ratios of normal alkanes, acyclic isoprenoids, carbon preference index (CPI), hopanes, and steranes showed the following results: Pr/Ph (0.34 to 0.89); C29/C27 (0.78 to 1.25); 20S/(20S + 20R)C29sterane (0.28 to 0.66); 22S/(22S + 22R)C32 homohopane (0.17 to 0.23); CPI (0.96 to 0.98); Ts/Ts + Tm (0.46 to 0.50); and sterane/hopane (0.16 to 0.87). The results obtained were used to correlate the crude oils with respect to depositional environment, thermal maturity, and organic matter source. The Pr/Ph ratios of KW and KLC were less than one, and the cross-plot of Pr/nC17 versus Ph/nC18 of KW and KLC suggested that the oils were deposited under anoxic environments, whereas OWA1 and OWA2 indicated oxic conditions with no biodegradation. From the calculated ratios of 22S (22S + 22R)C32 homohopane and CPI, the oils were mature and had entered the generating window. Sample OWA1 is the most mature, while KLC is the least mature. The calculated ratios also showed that the four oil samples were from a shale source rock with both terrestrial and marine inputs.

Deciphering the sedimentary imprint of tsunamis and storms in the Lesser Antilles (Saint Martin): A 3500-year record in a coastal lagoon

Our study aims at identifying and characterizing tsunami and storm deposits by combining sedimentological, geochemical, and radiocarbon dating analyses. X-ray computed microtomography (micro-CT) is used to characterize the sedimentary fabric of the deposits. The study was conducted on a transect of oriented short sediment cores from a small lagoon at Saint Martin (Lesser Antilles), where both event types could be observed. Using micro-CT data of different event deposits, we were able to derive paleo-flow orientations and directions and compare the dynamics of the events to their environmental setting. The results showed that seven extreme-wave event (EWE) deposits, originating from hurricanes or tsunamis, had the highest Ca/Fe ratios, distinctive for marine input to the lagoon, and were characterized by coarser grains. Some also presented above the sandy part of the event deposit a siliciclastic geochemical signal rich in fine siliciclastic sediment with organic matter, which might correspond to backwash deposits. The thickness and frequency of these sandy EWE deposits in our cores decreased from the proximal to the distal zone in the center of the lagoon, with high lateral and vertical variability in sediment thickness. The youngest EWE deposit relates to the unprecedentedly powerful Category 5 Hurricane Irma, which barely left a fine layer of sand in the lagoon, demonstrating the lagoon's resilience to tropical storms. Five of the six other EWEs, characterized by micro-CT-derived sedimentary fabric, likely originated from tsunamis and occurred over the last 3500 years BP with a recurrence interval of 300–400 years, based on radiocarbon dating. A well-studied tsunami deposit from Pre-Columbian times (∼400 years BP) showed oriented sedimentary fabric, which could be used for paleo-flow reconstruction and EWE-type distinction in the Lesser Antilles, suggesting the use of an additional method for identifying EWE-type deposits in the geological record rather than other methods alone. To develop effective strategies for mitigating the natural hazards faced by communities in the coastal areas of the Lesser Antilles, it will be crucial to examine EWEs in the Caribbean region beyond historic times successfully.

Multiproxy palaeoenvironmental reconstruction of the Bathonian Castelbouc sauropod tracksite (Causses Basin, southern France): Insight into a Middle Jurassic insular ecosystem

We report lignitic fossil rich-beds from the Bathonian Castelbouc sauropod tracksite (Castelbouc Cave N°4, Causses Basin, southern France). Showing the co-occurrence of amber with plant, vertebrate and invertebrate remains, they are a precious tool to reconstruct Middle Jurassic dinosaur ecosystems. A multiproxy approach combining sedimentology, petrology, mineralogy and palaeontology led to determine that these fossil rich-beds were deposited in a range of insular coastal palaeoenvironments. They include protected backshore areas such as freshwater/brackish ponds and brackish bay/lagoon showing co-occurrence of terrestrial and marine inputs. The backshore environments were particularly rich in ostracods (Darwinula sp., Fabanella bathonica) and gyrogonites of charophytes (Porochara douzensis). The abundance of conifer remains including leafy axes (Brachyphyllum), cones (cf. Classostrobus), wood (Brachyoxylon) and pollen grains (Classopollis) shows that ponds and bay/lagoon were bordered by conifer-dominated forests in which Cheirolepidiaceae were the main component. Such a rich and relatively diverse flora was probably an attractive source of food for megaherbivorous dinosaurs. Vertebrate microremains mostly consist of fish scales (Ginglymodi indet.) and crocodylomorph teeth (Atoposauridae indet.), two groups that are common components of Middle Jurassic paralic faunas. The palaeobotanical assemblage suggests a warm subtropical climate probably tropophilous with marked alternation between a wet and a dry season.

Holocene Sea-level impacts on Venice Lagoon's coastal wetlands

Venice Lagoon (Italy), the largest wetland in the Mediterranean basin, is extremely vulnerable to variations in relative sea level (RSL) which is locally defined by an average rising rate of about 2.5mm per year, resulting from both sea-level change and vertical land movements. The environmental pressures stemming from projected higher RSL rising rates will have a profound impact on Venetian coastal ecosystems with a significant loss of wetlands partly due to a drastic reduction of salt marsh habitats. To understand how changes in marine influence could create such ecological upheaval in the near future, and fully remodel these coastal salt marshes, we reconstructed 5650 years of RSL rise history and land subsidence impacts on ecosystem dynamics during the Holocene transgression of Venice Lagoon. We show that the evolution of ecosystems mainly mirrors the gradual intrusion of salt water that progressively reshaped the coastal vegetation by turning the area into salt lagoon habitats. Before marine influence became dominant, the area was mainly fed by substantial freshwater supplies allowing the development of a diversified alluvial vegetation. Environmental pressures increased markedly about 6800–6600 years ago when seawater began to significantly influence the area, affecting marsh-swamp ecosystems. These marine inputs promoted the spread of halophytic and salt-tolerant vegetation types which laid the foundations for what would become the current salt marsh habitats. Venice Lagoon serves as a stark reminder of how rising sea levels, accompanied by increased saltwater intrusion into freshwater habitats and adjacent lands, can drastically alter and reshape pre-existing ecosystems. The lagoon's long-term ecological record indicates that contemporary fluctuations in RSL pose a substantial ecological threat, potentially culminating in a major upheaval of aquatic habitats in the near future.

Evolution and determinants of precipitation chemistry in a plateau city, China: Insight from the pollutants source identification and environmental effect

Rainfall-related chemical ions deposition processes have important environment effects on earth-surface, which is also a vital sink of urban air pollutants. Therefore, identifying the rainwater chemical evolution and determinants, and source is essential. The daily-based rainwater samples during 2022– 2023 and the historical rainwater data in a typical plateau city (Kunming) were investigated. The Ca2+ and NH4+, SO42− and NO3− dominated the rainwater cations and anions, with the cationic and anionic percentages of 78% and 10%, 50% and 33%. The historical variations in ions percentages revealed the achievement of environmental protection. The precipitation amount and the seasonal changes of source emission were critical determinants for the variations of rainwater chemistry. Using the stoichiometry and receptor model, the contributions of potential origins to rainwater chemicals were assessed. 86% of NO3− and 40% SO42− were from combustion-related anthropogenic source, volatilization-related source contributed 85% of NH4+ (e.g., agricultural/municipal wastes emissions), whereas marine input was the main contributor of Cl− (59%) and Na+ (52%). Mg2+ (58%) and Ca2+ (41%) were primary from terrestrial input source. The risk of wet deposition-caused acidification was limited due to the high rainwater neutralization level, whereas the impact of nitrogen-related deposition on gross primary productivity (GPP) was non-negligible and further attention was need. Overall, the present study clarified the rainfall chemical features of plateau city region and further provided decision support for more effective urban air environmental management programs.

Oil-source correlation and Paleozoic source rock analysis in the Siwa Basin, Western Desert: Insights from well-logs, Rock-Eval pyrolysis, and biomarker data

Understanding the origins of potential source rocks and unraveling the intricate connections between reservoir oils and their source formations in the Siwa Basin (Western Desert, Egypt) necessitate a thorough oil-source correlation investigation. This objective is achieved through a meticulous analysis of well-log responses, Rock-Eval pyrolysis, and biomarker data. The analysis of Total Organic Carbon across 31 samples representing Paleozoic formations in the Siwa A-1X well reveals a spectrum of organic richness ranging from 0.17 wt% to 2.04 wt%, thereby highlighting diverse levels of organic content and the presence of both Type II and Type III kerogen. Examination of the fingerprint characteristics of eight samples from the well suggests that the Dhiffah Formation comprises a blend of terrestrial and marine organic matter. Notably, a significant contribution from more oxidized residual organic matter and gas-prone Type III kerogen is observed. Contrarily, the Desouky and Zeitoun formations exhibit mixed organic matter indicative of a transitional environment, and thus featuring a pronounced marine influence within a more reducing setting, which is associated with Type II kerogen. Through analysis of five oil samples from different wells—SIWA L-1X, SIWA R-3X, SIWA D-1X, PTAH 5X, and PTAH 6X, it is evident that terrestrial organic matter, augmented by considerable marine input, was deposited in an oxidizing environment, and contains Type III kerogen. Geochemical scrutiny confirms the coexistence of mixed terrestrial organic matter within varying redox environments. Noteworthy is the uniformity of identified kerogen Types II and III across all samples, known to have potential for hydrocarbon generation. The discovery presented in this paper unveils captivating prospects concerning the genesis of oil in the Jurassic Safa reservoir, suggesting potential links to Paleozoic sources or even originating from the Safa Member itself. These revelations mark a substantial advancement in understanding source rock dynamics and their intricate relationship with reservoir oils within the Siwa Basin. By illuminating the processes of hydrocarbon genesis in the region, this study significantly enriches our knowledge base.

Research status and prospect of microplastics in ship grey water

This paper deeply discusses the microplastic pollution of ship gray water which is getting more and more attention at present. This paper begins with an overview of the potential sources of microplastics and the current management measures. Then, the research progress on the qualitative and quantitative analysis techniques of Marine gray water microplastics, Marine input estimation and type distribution of microplastics in domestic and foreign literature is reviewed in detail. On this basis, the paper puts forward suggestions for future research directions, including establishing the analysis method of gray water composition based on actual ships, strengthening the research on the basic data of microplastics, formulating the inventory of gray water microplastics discharge from ships, and promoting the improvement and development of the control policy of gray water discharge from ships. These suggestions aim to provide scientific basis and strategic guidance for the treatment of ships' grey water microplastics pollution.

Facies distribution and depositional cycles in lacustrine and palustrine carbonates: The Lutetian–Aquitanian record in the Paris Basin

AbstractThe difficulty of correlating continental deposits hinders predicting lacustrine and palustrine carbonate facies variations in time and space. This study aims to understand better the factors governing these facies heterogeneities by measuring carbonate isotopes and conducting facies, petrographic and sequence stratigraphic analyses of the Lutetian–Aquitanian deposits of the Paris Basin, that record the transition from marine to lacustrine environments. Large‐scale correlations enabled the definition of two lacustrine–palustrine carbonate facies models. (1) The coastal lacustrine system (Bartonian to Rupelian), consists of fine‐grained brackish carbonate exhibiting episodic marine inputs during short‐term relative sea‐level maxima and evaporite sedimentation during relative sea‐level minima. Lacustrine sediments differ notably from marine ones with more negative δ13C and δ18O compositions that co‐vary and a biota adapted to low salinity conditions. In the associated palustrine environment, depositional sequences evolve upwards from micritic lacustrine deposits to nodular and then laminar calcretes. Microbial‐coated grains and rhizoliths indicate biological processes during repeated subaerial exposure phases in sub‐tropical to arid climates. (2) The inland lacustrine system (Rupelian and Aquitanian) was disconnected from the marine domain and showed evidence of microbial activity with microbial crusts and oncoidal rudstones. Facies rich in micritic intraclasts composed of palustrine and lacustrine facies indicate the reworking of already lithified sediments along the margins. In the palustrine domain, the calcrete facies are less abundant than breccias formed in‐situ by desiccation, limestones with root traces, or organic‐rich wackestones and marls. This system reflects a more temperate climate with more developed microbial structures and less exposed carbonates than the coastal lacustrine system. The southward migration of the depocentre and the transition from marine environments to (1) coastal and then (2) inland systems are controlled by uplift phases induced by Pyrenean and Alpine orogenesis. Third‐order relative sea‐level variations appear to control only short‐term cycles in coastal systems.

High aerosol loading over the Bohai Sea: Long-term trend, potential sources, and impacts on surrounding cities

Air pollution over the oceans has received less attention compared to densely populated urban areas of continents. The Bohai Sea, a semi-enclosed sea in northern China, is surrounded by thirteen industrial cities that have experienced significant improvements in air quality over the past decade. However, the changes in air pollution over the Bohai Sea and its impacts on surrounding cities remain poorly understood. To address this, this study investigated the evolution of air pollution and its chemical composition in the Bohai Sea over four decades, utilizing satellite remote sensing data, reanalysis datasets, emissions inventories, and statistical modeling. Historically, the region has suffered from severe air pollution, resulting from a combination of continental emissions and marine inputs (e.g., sea salt, ports and maritime vessel activities). The aerosol optical depth (AOD) over the sea was higher than the mean levels observed in its surrounding coastal cities. Statistically, 45% of the air masses reaching the Bohai Sea are associated with natural sources (dust- and marine-rich), while the remainder carry anthropogenic pollutants from continental regions. With the exception of Cangzhou city, these coastal cities suffer from air pollutants originating from the Bohai Sea. Cities in the northern region of the sea, spanning from Tianjin to Yingkou, are particularly impacted. The majority of the surrounding cities are affected by a large proportion of anthropogenic aerosol types transported through air masses from the Bohai Sea, including those from biomass burning and industrial activities. These findings emphasize the considerable influence of human-induced sources in the Bohai Sea on neighboring urban areas. Furthermore, being a maritime region, natural sources like sea salt and dust from the sea may also exert a discernible impact on the neighboring environment.

Equivalent roles of marine subsidies and island characteristics in shaping island bird communities

AbstractAimSpecies distributions across islands are shaped by dispersal limitations, environmental filters and biotic interactions but the relative influence of each of these processes has rarely been assessed. Here, we examine the relative contributions of island characteristics, marine subsidies, species traits, and species interactions on avian community composition.LocationCentral Coast region of British Columbia, Canada.TaxonTerrestrial breeding birds.MethodsWe observed 3610 individuals of 32 bird species on 89 islands that spanned multiple orders of magnitude in area (0.0002–3 km2). We fit a spatially explicit joint species distribution model to estimate the relative contributions of island physical characteristics, island‐specific inputs of marine subsidies, species' traits, and biotic interactions on species distributions. Biogeographic characteristics included island area, isolation, and habitat heterogeneity, while marine influence was represented by forest‐edge soil δ15N, wrack biomass, shoreline substrate, and distance to shore. This approach also allowed us to estimate how much variation in distributions resulted from species' biological traits (i.e. body mass, feeding guild, feeding height, and nesting height).ResultsBird species distributions were determined almost equivalently by island biogeographic characteristics (23.5% of variation explained) and marine influence (24.8%). We detected variation in species‐specific responses to both island biogeographic characteristics and marine influence, but no significant effect of any biological trait examined. Additionally, we found evidence that habitat preferences were a more important driver than competitive interactions.Main ConclusionsAlthough most island biogeographic studies focus only on islands' physical characteristics, we found evidence for an equivalent role of marine subsidy in structuring island bird communities. Our study suggests that for small islands, disentangling the effects of island biogeographic characteristics, marine inputs, and biotic interactions is a useful next step in understanding species distributions.

A multi-isotopic study reveals the palaeoecology of a sebecid from the Paleocene of Bolivia

Sebecids constitute a family of notosuchian crocodylomorphs of probable terrestrial habits. They are notable for having survived the Cretaceous-Paleogene mass extinction and are known until the Miocene in South America. However, ecological traits that favoured their resilience in continental ecosystems remain unknown. Here, using a multi-isotopic approach, we infer several palaeoecological traits of a sebecid from the locality of Tiupampa (Bolivia), which contains a diverse vertebrate fauna of the Early Paleocene. After having constrained the effects of diagenesis, the study of the oxygen isotope compositions of apatite phosphate allows the identification of water resources for the various studied taxa and to infer an ectothermic thermoregulation strategy for the sebecids. A terrestrial lifestyle is also supported by different oxygen isotope compositions observed between sebecids and aquatic dyrosaurid crocodylomorphs. The radiogenic strontium isotope compositions confirm the continental affinities of this fauna, with no marine input in the palaeoenvironment frequented by the different faunal elements. The calcium and carbon isotope compositions show that the sebecids from Tiupampa were at the top of a C3-based food web. Finally, a local dry environment with tropical temperatures for those specimens is inferred both from oxygen and carbon isotope compositions of their hard tissues.

Geochemical approach for decoding the paleoenvironmental and depositional evolution of a coastal lacustrine Konservat-Lagerstätte (Early Cretaceous, south-Central Pyrenees)

The lithographic limestone of La Pedrera de Meià (LPM) in south-Central Pyrenees (NE Spain) is considered one of the best preserved lacustrine-coastal successions of the Early Cretaceous in Europe, hosting a taxonomically diverse record of Barremian biota. While this Konservat-Lagerstätte has been extensively surveyed for paleontological purposes, little is known about the paleoenvironmental and depositional conditions prevailing during the formation of this fossil lagerstätte deposit. LPM limestone is made up of a homogeneous, dark gray to pale brown, faintly laminated 50 m-thick succession of micrite-rich intervals. To shed light on the environmental conditions of deposition, 303 rock samples were studied using a multiproxy approach based on different techniques including petrography, SEM-EDX, XRD, ICP-MS, XRF, Rare Earth Element distributions and C and O stable isotope geochemistry. The combination of sedimentological and geochemical data reveals a vertical shift of facies from littoral to profundal environments and then returning to littoral conditions. Profundal facies are made up of filament-rich mudstones originated from in situ precipitation of micrite either through biotically mediated or physico-chemical processes in undisturbed low energy settings, under anoxic conditions, characterized by the presence of transported terrestrial and lacustrine organisms that are exquisitely well-preserved. Littoral areas are characterized by the presence of in situ charophytes, smooth ostracods, and miliolid foraminifera that accumulated in mud-rich facies indicating low/moderate-energy, shallow-water, and relatively oxygenated conditions. Stable isotopic data and elemental geochemistry suggest a hydrologically closed to semi-closed lacustrine system with a restricted water circulation encouraging dysoxic to anoxic conditions in profundal sediments. Paleoproductivity proxies suggest a good correlation between catchment-derived siliciclastic discharge to the lake and primary productivity peaks. Furthermore, a decline in terrigenous input coupled with a reduction of meteoric water entrance to the lake is interpreted based on elemental proxies derived from paleosalinity and paleoredox analysis. Collectively, the strontium/barium (Sr/Ba) ratios, the sparse presence of miliolid foraminifera, and the isotopic signatures indicate an increase in salinity toward the younger intervals of the lake infilling, although their ultimate causes are unclear (i.e., increased evaporation, or a combination of reduced meteoric input and sporadic marine inputs might explain our data). The present work shows the importance of performing detailed multiproxy geochemical-sedimentological studies to better constrain the unique paleoenvironmental and paleohydrological conditions associated with the exceptional preservation of fossil biotas in Konservat-Lagerstätte deposits in analogous depositional settings.

Aluminium-normalised trace-element paleoredox proxies and their application to the study of the conditions of Burgess Shale-type preservation

The paleo-ecological settings of Burgess Shale-type (BST) fossils have been the subject of extensive investigations, particularly with regard to the role of anoxia in their exceptional preservation. Our understanding of the complexity of both paleontological and geochemical environmental proxies has evolved with increased knowledge of niche communities and marine geochemical and biogeochemical processes. Accordingly, dated approaches should be reevaluated. The commonly applied paleoredox proxies V/Cr, Ni/Co, and V/(V + Ni), as well as the redox proxy V/Al2O3 and productivity proxy Ba/Al2O3, were all tested on the Wheeler Formation (Utah, USA) for which a fluctuating oxycline environment has been well established based on paleontological features. Subsequently, these proxies were applied to three additional BST fossil-bearing deposits: the Emigsville Member of the Kinzers Formation (Pennsylvania, USA), the Burgess Shale (British Columbia, CA) and the Emu Bay Shale (South Australia, AU). Their host shales lack perceptible V of marine origin, indicative of oxic conditions, in contrast to the Wheeler and brine-related strata from the Burgess Shale which include additional marine input of V in some beds, consistent with varying redox conditions. The black shales of the Longs Park Member (Kinzers) have elevated V/Al2O3 indicative of anoxic conditions. Molybdenum concentrations are relatively low in most samples, but minor variations tend to correlate with V/Al2O3 patterns. Ba/Al2O3 indicates high productivity with deposition of BST fossils in the Wheeler Formation, and diagenetic remobilisation of Ba owing to sediment anoxia in the Burgess Shale. Our findings show that redox proxy V/Al2O3 can be effectively applied to BST samples, whereas Ba/Al is a reliable proxy for low to moderate paleoproductivity levels and may be useful as a secondary or tangential proxy for redox conditions. Taphonomic processes leading to BST preservation occur in a variety of environments characterised by oxyclines, matgrounds, variable sedimentation rates, hypersalinity and/or anoxia. KEY POINTS V/Al2O3 and Ba/Al2O3 are effective proxies for anoxia and productivity in BST deposits. BST preservation can occur in a variety of depositional environments. Marine anoxia is not required for BST preservation.

Trace Metals Behaviors in the Superficial Sediments from a Tropical Lagoon

The aim of this study is to assessment the effects of the seasonal water inputs on the seasonal dynamic of trace metals in the superficial sediments from the lagoon area II of Ébrié system. This study was implemented during one year (from June 2020 to May 2021) and all the physical and chemical parameters of these sediments, used in this study, were all obtained according to AFNOR standards. In hot season, the trace metal contents of these sediments, dominated by coarse sands in all seasons, were on the whole favored by the marine inputs; which would induce their very slightly basicity and reduce characters, low salinity and conductivity. However, the majority of their trace metals content decreases in rainy season with the meteorite inputs; would induce their slightly acidic and oxidizing characters and, the increase in their salinity and conductivity. These were again for the slightly basic and reduce characters of the open waters at the interface water-sediment, as their relative important salinity, conductivity and organic matter content in this season. The same effects were observed in flood season but a less marked by the important presence of Comoé river in this ecosystem.

Geochemistry of Permian carbonaceous shales from Raniganj sub-basin, Damodar Valley, India: Implications for provenance, weathering, tectonics and source of organic matter

Raniganj sub-basin, the easternmost depository of Damodar Valley encompasses the entire succession of Gondwana Supergroup, the lower and upper Gondwana sequences. The present investigation of Permian carbonaceous shales belonging to Barakar, Barren Measure and Raniganj formations of lower Gondwana sequence from this basin is an integrated study of inorganic and organic geochemical characteristics viz. major/trace elements, stable isotopic composition and kerogen type to ascertain source rock attributes such as provenance, tectonic setting, prevailing weathering/climatic conditions as well as source and type of organic matters. Trace element indices, such as La/Sc, Th/Co, Th/Sc, (Gd/Yb)CN, Eu/Eu*, Cr/V, Y/Ni, reveal that the shales are originated from felsic/granitic source rock. Prominent Eu-anomaly, enrichment of chondrite normalised light rare earth element (LREE) values and a flat heavy rare earth elements (HREE) pattern reflect post-Archean felsic source for the shales. The major element composition, especially relative enrichment of Al over readily soluble elements, Ca, Na and K yielding high CIA (74.9–84.6%) and CIW (87.1–97.5%) as well as low ICV (0.64–1.32) values, establishes significantly weathered and matured nature of the shales. The distribution of redox-sensitive elements (U/Th, V/Cr, Ni/Co, Ce/Ce*) as well as low ICV, depleted K2O/Al2O3 ratios and high CIA values point towards an oxic environment and warm-humid climatic condition during deposition of these shales. The conventional method for determining tectonic setting using major and trace element composition fails to clearly delineate the tectonic setting for the current shales. The samples show wide scattering across active and passive continental margin in the K2O/Na2O–SiO2 diagram, whereas the samples are concentrated near the active in the continental margin in the Th–Sc–Zr/10 diagram contradicting the geological framework of Raniganj sub-basin. Discriminant functions-based approach which categorises the tectonic setting into continental/oceanic arc, continental rift and continental collision settings has been proved to be suitable in the present case and reveals continental-rift setting for the shales from Raniganj sub-basin. The carbon isotopic signature (δ13Corg) of the shales reveals a range (−24.5 − −22.9‰) intermediate between that of marine and terrestrial (C3 plants) organic matters indicating possible mixed type of organic matters. The fluvio-marginal marine depositional condition obtained from K2O/Al2O3 and MgO/Al2O3 ratios further implies the possibility of mixed nature of organic matter. The geochemical parameters of the organic matter (Rock-Eval pyrolysis parameters S1, S2, TOC, HI, OI etc.) indicate that the studied shales contain thermally matured mixed Type III/II gas-prone kerogen and are derived predominantly from terrestrial sources with significant marine input.

Scale-dependent effects of marine subsidies on the island biogeographic patterns of plants.

Although species richness can be determined by different mechanisms at different spatial scales, the role of scale in the effects of marine inputs on island biogeography has not been studied explicitly. Here, we evaluated the potential influence of island characteristics and marine inputs (seaweed wrack biomass and marine‐derived nitrogen in the soil) on plant species richness at both a local (plot) and regional (island) scale on 92 islands in British Columbia, Canada. We found that the effects of subsidies on species richness depend strongly on spatial scale. Despite detecting no effects of marine subsidies at the island scale, we found that as plot level subsidies increased, species richness decreased; plots with more marine‐derived nitrogen in the soil hosted fewer plant species. We found no effect of seaweed wrack at either scale. To identify potential mechanisms underlying the decrease in diversity, we fit a spatially explicit joint species distribution model to evaluate species level responses to marine subsidies and effects of biotic interactions among species. We found mixed evidence for competition for both light and nutrients, and cannot rule out an alternative mechanism; the observed decrease in species richness may be due to disturbances associated with animal‐mediated nutrient deposits, particularly those from North American river otters (Lontra canadensis). By evaluating the scale‐dependent effects of marine subsidies on island biogeographic patterns of plants and revealing likely mechanisms that act on community composition, we provide novel insights on the scale dependence of a fundamental ecological theory, and on the rarely examined links between marine and terrestrial ecosystems often bridged by animal vectors.