Conventionally, volcanic margins have been considered devoid of hydrocarbon, but many discoveries and research in recent past have proved the presence of hydrocarbon prospects within them. However, hydrocarbon exploration within volcanic margin is constrained by seismic imaging. Further, identification of continent to oceanic boundary (COB) is critical to hydrocarbon search as hydrocarbon is found mostly over continental crust. Seaward dipping reflectors, associated with volcano-sedimentary sequences, located along rifted continental margins and represented by highly dipping strong amplitude seismic reflectors, play an important role to study volcanic margins. Keeping in view the problems of hydrocarbon exploration within volcanics, seaward dipping reflectors (SDRs) in Indian context have been studied in detail in this paper. It facilitates mapping of continent-oceanic boundary (COB). It has impact on hydrocarbon prospectivity in volcanic margins as it can provide formidable seal and secondary induced maturity. In India, several discoveries have been made in volcanic margins along west coast, from weathered, fractured basalt and sub-basalt sediments. In the present work, long offset regional seismic data (18 dip lines and 1 cross line), along east coast, have been interpreted. SDRs help in hydrocarbon prospectivity assessment for both discrimination of interbedded sediments and preferential accumulation of hydrocarbon. Mapping of linear features not only helped to demarcate COB but also their presence at 6–10 km depth. For the first time, such comprehensive study on SDRs has been done along Indian peninsular region with indications for hydrocarbon prospectivity at deeper levels along Indian peninsular region.