Maleic Anhydride Grafted Polypropylene Compatibilizer Research Articles

Examination Of Perlite-Polymer Interface Interactions in Polypropylene-Based Composites via Several Compatibilizers

The surface interaction between the polymer and the mineral additive is one of the most significant aspects influencing the efficiency of mineral-filled polymeric composites. In this work, three distinct compatibilizers were introduced to composites based on polypropylene (PP) and perlite to improve interactions between the constituents. On composites comprising 10% expanded perlite content, three different ratios of ethylene vinyl acetate copolymer (EVA), thermoplastic polyurethane elastomer (TPU), and maleic anhydride grafted polypropylene (MA-PP) compatibilizers were employed. Composites were produced using an approach designated melt blending followed by injection molding. The composites containing MA-PP compatibilizer possessed the most outstanding performance, according to the results of mechanical, physical, and dynamic mechanical evaluations and morphological characterizations. The investigated aspects indicated a rise in the composites containing 10 percent compatibilizer with the lowest adding amount, whereas performances declined at high compatibilizer contents. Along with these results, it was determined that the compatibilizers included in the PP/perlite composite system assisted in the fabrication of the composites by promoting the force values and melt flow rates identified during melt mixing. Following the test outcomes, MA-PP performed better than TPU and EVA in terms of compatibilizer efficiency. In general, it has been revealed that the selection of MA-PP compatibilizer in the manufacturing stages would offer benefits in terms of both simplicity of processing and mechanical strength where expanded perlite will be adopted as a natural filler for PP-based composites.

Effect of Compatibilizer on the Persistent Luminescence of Polypropylene/Strontium Aluminate Composites.

There is a demand for long afterglow composites due to their potential applications in nighttime signal boards, sensors, and biomedical areas. In this study, Polypropylene (PP)/strontium aluminate-based composites [SrAl2O4:Eu2+/Dy3+ (SAO1) and Sr4Al14O25: Eu+2, Dy+3 (SAO2)] with maleic anhydride grafted PP compatibilizer (PRIEX) were prepared, and their auto-glowing properties were examined. After UV excitation at 320 nm, the PP/5PRIEX/SAO1 composites showed green emission at 520 nm, and blue emission was observed for PP/5PRIEX/SAO2 around 495 nm. The intensity of phosphorescence emission and phosphorescence decay was found to be proportional to the filler content (SAO1 and SAO2). The FTIR analysis excluded the copolymerization reaction between the SAO1 and SAO2 fillers and the PP matrix during the high-temperature melt mixing process. The SAO1 and SAO2 fillers decreased the overall crystallinity of the composites without affecting the Tm and Tc (melting and crystallization temperature) values. The thermal stability of the composites was slightly improved with the SAO1 and SAO2 fillers, as seen from the TGA curve. Due to the plasticizing effect of the compatibilizer and the agglomeration of the SAO1 and SAO2 fillers, the tensile modulus, tensile strength, and storage modulus of the composites was found to be decreased with an increase in the SAO1 and SAO2 content. The decreasing effect was more pronounced, especially with the bulk-sized SAO2 filler.

Injection molded discontinuous and continuous rattan fiber reinforced polypropylene composite: Development, experimental and analytical investigations

Because of the superabundant accessibility and availability of natural fiber, the research field of natural fiber-reinforced composites is becoming an emerging interest in sustainable technology. In this present study, injection molded rattan fiber inreinforced polypropylene composites were prepared, where maleic anhydride grafted polypropylene (MAPP) was used as compatibilizer. The extreme amount of lignin percentage in rattan fiber was the primary motive for fabricating the rattan-based polypropylene composite with MAPP compatibilizer. Three different fiber volume percentages (10, 20 and 30%) were considered for preparing the composites. The mechanical characterizations, such as tensile behavior, flexural behavior, impact strength, hardness, and thermal characterization, such as thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were investigated. Several thermal properties, such as onset temperature, endset temperature, melting temperature, heat capacity, melting enthalpy, decomposition behavior of these composites were observed from these TGA and DSC curves. As well, the wet absorption characteristics of the composites were examined to investigate hydrophilic behavior. Furthermore, continuous rattan fiber reinforced polypropylene composites with indistinguishable fiber volume percentages and compatibilizer were prepared by partial injection molding technique for comparing the mechanical and wet absorption behaviors and validating elastic modulus by the analytical findings. The tensile strength, flexural strength and impact toughness of discontinuous fiber composites were enhanced up to 23, 25, 153% respectively within the fiber content. The improvement of mechanical properties was higher when polypropylene was reinforced by continuous rattan fiber. Nevertheless, the continuous fiber composites were more hydrophilic than discontinuous fiber composites.

Effects on MAPP Compatibilizer on Mechanical Properties of Kenaf Core Fibre/Graphene Nanoplatelets reinforced Polypropylene Hybrid Composites

Natural fibre has high potential to be used as reinforcement due to more save, greener and environmentally friendly compared to synthetic fibre. In this research, kenaf core fibre (KCF)-graphene nanoplatelets (GNP) reinforced polypropylene (PP) composites were melt blending using Brabender internal mixer and fabricated by compression moulding. This research aims to fabricate and study the effect of different amounts of MAPP on the mechanical properties of the PP/KCF/GNP composites. The difference amount of maleic anhydride grafted polypropylene (MAPP) as a compatibilizer in hybrid composite was added to enhance the mechanical properties by improving the interfacial adhesion of matrix and KCF. The pure polypropylene (PP) matrix was used as a control. The mechanical properties (tensile and flexural test) were determined using Universal Testing Machine (UTM). Overall, the results show that the presence of MAPP compatibilizer successfully enhanced the mechanical properties as a result of improvement of the fibre-matrix adhesion between the KCF and PP matrix.

Properties of PP Wood-Plastic Composites with Biocompatibility Additives

Maleic anhydride grafted polypropylene compatibilizer (MAPP) and chitosan (CS) were mixed and used as a compound coupling agent to modify the PP matrix. 5 wt% NaOH and 10 wt% NaOH aqueous solution were used to treat corn stalk fiber (CSF), respectively. The effect of the complex coupling agent and the alkali treatment on the mechanical properties of CSF/PP composite was investigated. Morphological observation of the fracture surfaces was accepted to confirm CSF dispersion and wetting with the help of SEM. The results of the water absorption further demonstrated the binding of the interface between the CSF and the PP matrix. The wetting of the CSF in the PP was improved with the addition of the complex compatibilizer (5% MAPP + 5% CS). The formation of chemical bonding between the fiber and the matrix resulted in enhancing the interfacial compatibility between them. Compared with the pure PP, the flexural strength of 15-UT-5MAPPCS (63.14 MPa) and 15-UT-5MAPPCS (69.35 MPa) increased by 22.5% and 34.5%, respectively. The complex compatibilizer can replace alkaline treatment process to improve the mechanical properties of the composite.

Isothermal Crystallization Kinetics of Highly Filled Wood Plastic Composites: Effect of Wood Particles Content and Compatibilizer

The isothermal crystallization behavior and crystal structure of the polypropylene (PP) component in wood plastic composites (WPC) with respect to wood particle content and maleic anhydride-grafted polypropylene (MAHPP) compatibilizer were studied by means of polarized optical microscopy, scanning electron microscopy, x-ray diffraction, and differential scanning calorimetry. It was found that under the experimental conditions of this research, the speed of crystallization of PP was faster in WPC with MAHPP than in composites without MAHPP. This is ascribed to the difference in undercooling due to the change in the equilibrium melting temperatures (T 0 m ) of the PP component in WPC due to the addition of wood flour and MAHPP compatibilizer. T 0 m decreased with the increase of wood particle content, and it decreased more severely with the addition of wood flour than the addition of compatibilizer. The half-crystallization time was the smallest in PP/wood composites, intermediate in PP/wood/compatibilizer system, and the largest in pure PP under the same undercooling. The fast crystallization in PP/wood composites is ascribed to the heterogeneous nucleation effects of wood particles, which could be hindered by the MAHPP compatibilizers; this was verified by the higher fold surface free energy in WPC with compatibilizer than in WPC without compatibilizer.