The article has an empirical nature. The subject of detailed analysis is the variations in spatial distribution of human capital in rural areas of Poland and the analysis of the correlation of this phenomenon with local structures of the socio-economic development process. The diagnosis and assessment of variations in the spatial distribution of human capital were performed based on an author’s indicator—a synthetic measure of human capital level (HCI—human capital index). The characterisation of local socio-economic structures was based on the typology of rural areas according to Rural Development Monitoring (RDM 2014 and 2023). The study was conducted for rural areas in Poland defined by the Main Statistical Office based on the administrative criteria of rural and rural-urban municipalities. A total of 2172 municipalities were covered by the study. The data analysis was conducted spatially at the NUTS 5 level and comparatively at the NUTS 2 level for the years 2013–2018. The assumption was verified that the processes of human capital concentration in rural areas in Poland are related to local socio-economic structures of development processes, and the local structure factor that influences the existing differences is the degree of use of agricultural functions. The results of statistical tests positively verify this relationship as statistically significant. Moreover, the article provides strong arguments for shaping regional and rural policy and its implementation. The assumption about the need to change the approach to the study of rural space was positively verified; it is suggested to move away from analyses conducted at the level of the NUTS 2 region to the level of the NUTS 5 municipality. Research on rural areas makes sense only from a local perspective; it allows for a more accurate illustration of the specificity of local communities, revealing their development potentials and barriers, and, as a result, more effective programming of instruments supporting local development, dedicating specific support programs individually for each municipality, while the regional approach presents the state of differences too generally and may often lead to incorrect interpretation. In the empirical part of the article, taxonomic methods of hierarchy (patternless) and classification of multi-featured objects were used. As a result, each object (municipality) was assigned a synthetic measure—the relative human capital level index (HCI). Based on the HCI index, an ex-post hierarchical classification of municipalities was carried out. The main sources of data (diagnostic variables) for the construction of the HCI index were the Local Data Bank of the Central Statistical Office (BDL GUS), the national census of NSP 2011, the Ministry of Finance, the Ministry of Family and Social Policy, and District Examination Boards. The source of data on local socio-economic structures expressed based on the typology of rural areas according to the Rural Development Monitoring (RDM) methodology was the European Fund for the Development of Polish Villages (EFRWP).