Main R-process Research Articles

R-process Abundance Patterns in the Globular Cluster M92

Whereas light-element abundance variations are a hallmark of globular clusters, there is little evidence for variations in neutron-capture elements. A significant exception is M15, which shows a star-to-star dispersion in neutron-capture abundances of at least one order of magnitude. The literature contains evidence both for and against a neutron-capture dispersion in M92. We conducted an analysis of archival Keck/HIRES spectra of 35 stars in M92, 29 of which are giants, which we use exclusively for our conclusions. M92 conforms to the abundance variations typical of massive clusters. Like other globular clusters, its neutron-capture abundances were generated by the r-process. We confirm a star-to-star dispersion in r-process abundances. Unlike M15, the dispersion is limited to “first-generation” (low-Na, high-Mg) stars, and the dispersion is smaller for Sr, Y, and Zr than for Ba and the lanthanides. This is the first detection of a relation between light-element and neutron-capture abundances in a globular cluster. We propose that a source of the main r-process polluted the cluster shortly before or concurrently with the first generation of star formation. The heavier r-process abundances were inhomogeneously distributed while the first-generation stars were forming. The second-generation stars formed after several crossing times (∼0.8 Myr); hence, the second generation shows no r-process dispersion. This scenario imposes a minimum temporal separation of 0.8 Myr between the first and second generations.

A Study of Elemental Abundance Pattern of the r-II Star HD 222925

HD 222925 is a rare r-process enhanced star in the Milky Way because of its metal abundance ([Fe/H] =−1.46 ± 0.10) and Eu abundance ([Eu/Fe] = 1.32 ± 0.08). Based on the very complete set of elemental abundances of HD 222925, we use the abundance decomposition method to fit the observed abundances of 58 elements in the sample star, which is also the largest number of elemental abundances fitted at the same time for a fixed star. We analyze the astrophysical origins of elements in HD 222925 by its abundance ratios and component ratios. It is found that the light elements and the iron group elements in HD 222925 mainly originate from the primary process of the Type II supernovae (SNe II) with the progenitor mass M > 10 M ⊙ and have no contribution from SNe Ia and the first generation of very massive stars. The contribution of the weak r-process to Ga, Ge, and As is superior to that of the other processes, and its contribution decreases linearly with increasing atomic number. The main r-process that is likely derived from a neutron star merger plays a key role in the formation of neutron-capture elements (Z ≥ 38) in HD 222925.

R-Process Sites, their Ejecta Composition, and their Imprint in Galactic Chemical Evolution

From low metallicity stars and the presence of radioactive isotopes in deep-sea sediments we know that the main r-process, producing the heaviest elements, is a rare event. The question remains whether neutron star mergers, via GW170817 the only observed r-process site, are the only contributors or also (a rare class of) supernovae, hypernovae/collapsars, as well as neutron star - black hole mergers qualify as candidates. Early galactic evolution as well as variations in nucleosynthesis signatures, e.g. actinide boost stars, might indicate the need for such other sites. We discuss and present the possible options (a) with respect to possible differences in ejecta amount and composition, and (b) in terms of their timing (onset and frequency) during galactic evolution.

Neutron rich matter in the laboratory and in the heavens after GW170817

The historic observations of the neutron star merger GW170817 advanced our understanding of r-process nucleosynthesis and the equation of state (EOS) of neutron rich matter. Simple neutrino physics suggests that supernovae are not the site of the main r-process. Instead, the very red color of the kilonova associated with GW170817 shows that neutron star (NS) mergers are an important r-process site. We now need to measure the masses and beta decay half-lives of very neutron rich heavy nuclei so that we can more accurately predict the abundances of heavy elements that are produced. This can be done with new radioactive beam accelerators such as the Facility for Rare Isotope Beams (FRIB). GW170817 provided information on the deformability of NS and the equation of state of dense matter. The PREX II experiment will measure the neutron skin of 208Pb and help constrain the low density EOS. As the sensitivity of gravitational wave detectors improve, we expect to observe many more events. We look forward to exciting advances and surprises!

Nucleosynthetic, radiogenic and stable strontium isotopic variations in fine- and coarse-grained refractory inclusions from Allende

We present new nucleosynthetic, radiogenic and stable Sr isotopic data from fifteen previously studied CAIs from the Allende CV3 meteorite, including the highly altered Curious Marie inclusion. We use double-spike TIMS techniques to determine the degrees of isotopic mass fractionation, and also present internally normalised data for the same sample digestions to permit comparisons with previous studies and couple these isotopic data with Rb, Sr, Eu and Th abundance data to consider the origins and relationships of the isotopic variations documented here. Analysed CAIs display elevated μ84Sr anomalies of +58 ppm to +287 ppm, with variability far outside of analytical uncertainties (13 ppm 2 s.d.). We cannot tell at present whether these variations arise from heterogeneities in p-process 84Sr or in the other non-radiogenic isotopes of Sr (86Sr, 88Sr) that are produced by the main s-process, weak s-process, and r-process. All inclusions fall on an offset mass-dependent fractionation line in three-isotope space (δ88/86Sr vs δ84/86Sr) identical within error to that previously defined by bulk undifferentiated meteorites, and have a total range of δ88/86Sr of ∼5.3 ‰ (+1.67 ‰ to −3.67 ‰), reflecting kinetic isotope effects during partial condensation/evaporation and/or low-temperature alteration processes. CI-normalized Sr/Th ratios in our CAIs correlate with normalized Eu/Th ratios with a ∼ 1:1 relationship, regardless of texture or Sr-isotopic values. This indicates that Sr and Eu had similar condensation behaviors with Eu condensing as Eu2+ and having the same chemical behavior in minerals as Sr2+ under conditions relevant to CAI formation in the solar nebula. Rb/Th ratios are highly variable: fine-grained CAIs display elevated Rb/Th ratios, consistent with the introduction of Rb into the CAIs by alkali-rich secondary alteration fluids. The μ84Sr anomalies measured in our CAIs are similar (in magnitude) to those found in carbonaceous chondrites that formed in the outer part of the solar system. A way to reconcile this observation with the formation of CAIs near the Sun would be if the inventories of Sr and other refractory elements in carbonaceous chondrites are dominated by a cryptic refractory dust component (CRD) that was formed early and near the Sun, and was subsequently transported outwards to the carbonaceous chondrite-forming region.

Binary neutron stars and production of heavy elements

We show how merging neutron stars can be responsible for the production of heavy elements in the solar vicinity, in particular we study the evolution of the abundance of europium (Eu) relative to iron (Fe), as derived by stellar abundances measured in the Milky Way halo and disk stars. To do that, we adopt a detailed galactic chemical evolution model able to follow the evolution of the abundances of several chemical elements in the gas in our Galaxy. Merging of neutron stars after emission of gravitational waves has been observed for the first time in the event GW170817, which has represented the very first kilonova ever observed in the local universe. The production of heavy elements such as Eu (a typical r-process element) is discussed critically, pointing out that supernovae core collapse can produce some r-process elements but not enough to explain the solar abundance of Eu. On the other hand, the merging of compact objects can provide an amount of Eu much higher per single event than a single supernova. We discuss the various parameters involved, such as the merging timescales, the fraction of neutron star binaries and the present time rate of kilonova explosions. We compare model results with stellar data and conclude that merging of compact objects can be responsible for the bulk of Eu production in the Galaxy under some assumptions: (i) the merging binaries should have progenitors in the mass range 9–50$$M_{\odot }$$, (ii) the merging timescales should be as short as 1 Myr and iii) each event should produce $$\sim 2 \times 10^{-6}M_{\odot }$$. We also conclude that the Ligo/Virgo merging neutron star rate is consistent with our chemical evolution model and that if GW170817 is a representative event, then the merging neutron stars can be considered as the main r-process production sites.

The R-Process Alliance: First Release from the Northern Search for r-process-enhanced Metal-poor Stars in the Galactic Halo

Abstract This paper presents the detailed abundances and r-process classifications of 126 newly identified metal-poor stars as part of an ongoing collaboration, the R-Process Alliance. The stars were identified as metal-poor candidates from the RAdial Velocity Experiment (RAVE) and were followed up at high spectral resolution (R ∼ 31,500) with the 3.5 m telescope at Apache Point Observatory. The atmospheric parameters were determined spectroscopically from Fe i lines, taking into account non-LTE corrections and using differential abundances with respect to a set of standards. Of the 126 new stars, 124 have [Fe/H] < −1.5, 105 have [Fe/H] < −2.0, and 4 have [Fe/H] < −3.0. Nine new carbon-enhanced metal-poor stars have been discovered, three of which are enhanced in r-process elements. Abundances of neutron-capture elements reveal 60 new r-I stars (with +0.3 ≤ [Eu/Fe] ≤ +1.0 and [Ba/Eu] < 0) and 4 new r-II stars (with [Eu/Fe] > +1.0). Nineteen stars are found to exhibit a “limited-r” signature ([Sr/Ba] > +0.5, [Ba/Eu] < 0). For the r-II stars, the second- and third-peak main r-process patterns are consistent with the r-process signature in other metal-poor stars and the Sun. The abundances of the light, α, and Fe-peak elements match those of typical Milky Way (MW) halo stars, except for one r-I star that has high Na and low Mg, characteristic of globular cluster stars. Parallaxes and proper motions from the second Gaia data release yield UVW space velocities for these stars that are consistent with membership in the MW halo. Intriguingly, all r-II and the majority of r-I stars have retrograde orbits, which may indicate an accretion origin.

MOLYBDENUM AND RUTHENIUM IN THE GALAXY

We present a brief overview of the molybdenum and ruthenium present-day nucleosynthesis calculations and abundance determinations in stars belonging to different substructures (populations) in the Galaxy. The following sources of Mo, Ru production were considered: the Asymptotic Giant Branch (AGB) stars of different masses (main s-process), massive stars (weak s-process), neutrino-induced winds from the core-collapse supernova CCSNe (weak r-process), merging of neutron stars (main r-process). Many production sites of the p-nuclei have been proposed: the Type II and Ia supernovae (at the pre-supernova phase, during and after the supernova explosion), the rp-process in neutrino-driven winds, the high-entropy wind (HEW), the νp-process; inside in a supercritical accretion disk (SSAD), in the He-accreting CO white dwarfs of sub-Chandrasekhar mass, and in the carbon deflagration model for Type Ia. We also emphasize on some additional processes such as the i- process in rapidly accreting white dwarfs (RAWDs), the lighter element primary process LEPP as well as another formation channel, namely the charged-particle process (r- process). The contribution to the solar abundance of neutron capture elements and the Galactic Chemical Evolution (GCE) models for n-capture elements were considered. The Mo and Ru observations in metal-poor stars, Ba stars, globular clusters, meteoritic matter (presolar grains) as well as our new Mo and Ru determinations in Galactic disc are presented. Having analysed our date in the near solar metallicities we found out that there are different sources contributing to the Mo and Ru abundances, and that the main s-process contribution to the Mo and Ru abundances is lower than to the predominant s-element (Y, Zr and Ba) solar abundances. By comparing the behavior of Mo and Ru in the wide range of [Fe/H] with GCE models one can see that the theoretical description of the galactic behavior of Mo not depicts sufficient and we are faced with the underproduction of molybdenum in the sources and in processes that used at the GCE creation. Additional sources may be the p-process (SN Ia and/or SN II), νp-process (massive stars) or several more exotic processes.

Study of the Abundance Features of the Metal-poor Star HD 94028

Abstract Recent work has found that the metal-poor star HD 94028 shows interesting abundance features. The s-process material (e.g., Ba, La, Ce, and Pb) and r-process material (e.g., Eu, Os, Pt) are mildly overabundant while the element C is not enhanced. However, the observed supersolar ratio [As/Ge] (=0.99 ± 0.23) and subsolar ratio [Se/As] (=−0.16 ± 0.22) could not be fitted by the combination of s- and r-process abundances. In this work, adopting the abundance decomposition method, we investigate the astrophysical origins of the elements in this star. We find that the primary process of massive stars dominates the production of the light elements and iron-group elements. The lighter neutron-capture elements from Ge to Te mainly come from the weak r-process. The elements from Ba to Pb are synthesized dominantly by the main s- and main r-process. The observed abundance features of Ge, As, and Se in HD 94028 are mainly produced by the weak r-process, which possesses the features of the supersolar ratio [As/Ge] and subsolar ratio [Se/As]. Because Ge is not synthesized solely by the neutron-capture process, As should be the lightest neutron-capture element. Although the i-process has been suggested in several astrophysical environments, it should be superfluous to explaining the abundances of the lighter neutron-capture elements in HD 94028.

The Origin of r-process Elements in the Milky Way

Abstract Some of the heavy elements, such as gold and europium (Eu), are almost exclusively formed by the rapid neutron capture process (r-process). However, it is still unclear which astrophysical site between core-collapse supernovae and neutron star–neutron star (NS–NS) mergers produced most of the r-process elements in the universe. Galactic chemical evolution (GCE) models can test these scenarios by quantifying the frequency and yields required to reproduce the amount of europium (Eu) observed in galaxies. Although NS–NS mergers have become popular candidates, their required frequency (or rate) needs to be consistent with that obtained from gravitational wave measurements. Here, we address the first NS–NS merger detected by LIGO/Virgo (GW170817) and its associated gamma-ray burst and analyze their implication for the origin of r-process elements. The range of NS–NS merger rate densities of 320–4740 Gpc−3 yr−1 provided by LIGO/Virgo is remarkably consistent with the range required by GCE to explain the Eu abundances in the Milky Way with NS–NS mergers, assuming the solar r-process abundance pattern for the ejecta. Under the same assumption, this event has produced about 1–5 Earth masses of Eu, and 3–13 Earth masses of gold. When using theoretical calculations to derive Eu yields, constraining the role of NS–NS mergers becomes more challenging because of nuclear astrophysics uncertainties. This is the first study that directly combines nuclear physics uncertainties with GCE calculations. If GW170817 is a representative event, NS–NS mergers can produce Eu in sufficient amounts and are likely to be the main r-process site.

Abundance patterns of the light neutron-capture elements in very and extremely metal-poor stars

Aims. The abundance patterns of the neutron-capture elements in metal-poor stars provide a unique record of the nucleosynthesis products of the earlier massive primitive objects. Methods. We measured new abundances of so-called light neutron-capture of first peak elements using local thermodynamic equilibrium (LTE) 1D analysis; this analysis resulted in a sample of 11 very metal-poor stars, from [Fe/H] = –2.5 to [Fe/H] = –3.4, and one carbon-rich star, CS 22949-037 with [Fe/H] = –4.0. The abundances were compared to those observed in two classical metal-poor stars: the typical r-rich star CS 31082-001 ([Eu/Fe] > +1.0) and the r-poor star HD 122563 ([Eu/Fe] < 0.0), which are known to present a strong enrichment of the first peak neutron-capture elements relative to the second peak. Results. Within the first peak, the abundances are well correlated in analogy to the well-known correlation inside the abundances of the second-peak elements. In contrast, there is no correlation between any first peak element with any second peak element. We show that the scatter of the ratio of the first peak abundance over second peak abundance increases when the mean abundance of the second peak elements decreases from r-rich to r-poor stars. We found two new r-poor stars that are very similar to HD 122563. A third r-poor star, CS 22897-008, is even more extreme; this star shows the most extreme example of first peak elements enrichment to date. On the contrary, another r-poor star (BD–18 5550) has a pattern of first peak elements that is similar to the typical r-rich stars CS 31082-001, however this star has some Mo enrichment. Conclusions. The distribution of the neutron-capture elements in our very metal-poor stars can be understood as the combination of at least two mechanisms: one that enriches the forming stars cloud homogeneously through the main r-process and leads to an element pattern similar to the r-rich stars, such as CS 31082-001; and another that forms mainly lighter, first peak elements.

The Odd Isotope Fractions of Barium in the Strongly r-process-enhanced (r-II) Stars*

Abstract We determined the f odd,Ba values, 0.46 ± 0.08, 0.51 ± 0.09, 0.50 ± 0.13, and 0.48 ± 0.12, that correspond to the r-contribution 100% for four r-II stars, CS 29491-069, HE 1219-0312, HE 2327-5642, and HE 2252-4225, respectively. Our results suggest that almost all of the heavy elements (in the range from Ba to Pb) in r-II stars have a common origin, that is, from a single r-process (the main r-process). We found that the f odd,Ba has an intrinsic nature, and should keep a constant value of about 0.46 in the main r-process yields, which is responsible for the heavy element enhancement of r-II stars and of our Galaxy chemical enhancement. In addition, except for the abundance ratio [Ba/Eu] the f odd,Ba is also an important indicator, which can be used to study the relative contributions of the r- and s-processes during the chemical evolution history of the Milky Way and the enhancement mechanism in stars with peculiar abundances of heavy elements.

Using stellar observations to trace the formation processes of Mo, Ru, Pd, and Ag

The exact formation mechanism of many heavy elements remains unknown. Models of the formation site and environment have greatly improved over the past decades, and experiments have provided new data for many of the heavy isotopes. However, much information is still missing to fully describe the neutron-capture formation processes and their sites. Stellar observations combined with mass spectroscopy of meteorites can help to place some of the needed constraints. This, in turn, will help to improve the models and our knowledge on the formation channels creating these heavy elements. Recent studies of Mo, Ru, Pd, and Ag showed that different processes or environments other than the main r-process (forming, e.g., Eu) are needed to explain the production (and observations) of elements with 40 < Z < 50. An observational study of Mo–Ag is presented, where stellar abundances are compared to meteoritic isotopic abundances (at metallicities [Fe/H] > −1.5) to extract information on differences or similarities in their production. Finally, the number of formation processes needed to describe the chemical composition in low metallicity stars ([Fe/H] < −2.5) is discussed.

The Universality of the Rapid Neutron-capture Process Revealed by a Possible Disrupted Dwarf Galaxy Star*

Abstract The rapid neutron-capture or r-process is thought to produce the majority of the heavy elements ( ) in extremely metal-poor stars. The same process is also responsible for a significant fraction of the heavy elements in the Sun. This universality of the r-process is one of its characteristic features, as well as one of the most important clues to its astrophysical origin. We report the discovery of an extremely metal-poor field giant with and , the lowest abundances of strontium and barium relative to iron ever observed. Despite its low abundances, the star 2MASS J151113.24–213003.0 has , therefore its neutron-capture abundances are consistent with the main solar r-process pattern that has . It has been suggested that extremely low neutron-capture abundances are a characteristic of dwarf galaxies, and we find that this star is on a highly eccentric orbit with an apocenter ≳100 kpc that lies in the disk of satellites in the halo of the Milky Way. We show that other extremely metal-poor stars with low [Sr, Ba/H] and [Sr, Ba/Fe] plus solar [Sr/Ba] tend to have orbits with large apocenters, consistent with a dwarf galaxy origin for this class of object. The nucleosynthesis event that produced the neutron-capture elements in 2MASS J151113.24–213003.0 must produce both strontium and barium together in the solar ratio. We exclude contributions from the s-process in intermediate-mass asymptotic giant branch or fast-rotating massive metal-poor stars, pair-instability supernovae, the weak r-process, and neutron-star mergers. We argue that the event was a Pop III or extreme Pop II core-collapse supernova explosion.

Diversity of Abundance Patterns of Light Neutron-capture Elements in Very-metal-poor Stars∗

Abstract We determine the abundances of neutron-capture elements from Sr to Eu for five very-metal-poor stars ( ) in the Milky Way halo to reveal the origin of light neutron-capture elements. Previous spectroscopic studies have shown evidence of at least two components in the r-process; one referred to as the “main r-process” and the other as the “weak r-process,” which is mainly responsible for producing heavy and light neutron-capture elements, respectively. Observational studies of metal-poor stars suggest that there is a universal pattern in the main r-process, similar to the abundance pattern of the r-process component of solar-system material. Still, it is uncertain whether the abundance pattern of the weak r-process shows universality or diversity, due to the sparseness of measured light neutron-capture elements. We have detected the key elements, Mo, Ru, and Pd, in five target stars to give an answer to this question. The abundance patterns of light neutron-capture elements from Sr to Pd suggest a diversity in the weak r-process. In particular, scatter in the abundance ratio between Ru and Pd is significant when the abundance patterns are normalized at Zr. Our results are compared with the elemental abundances predicted by nucleosynthesis models of supernovae with parameters such as electron fraction or proto-neutron-star mass, to investigate sources of such diversity in the abundance patterns of light neutron-capture elements. This paper presents that the variation in the abundances of observed stars can be explained with a small range of parameters, which can serve as constraints on future modeling of supernova models.

Footprints of the weak s-process in the carbon-enhanced metal-poor star ET0097

Historically, the weak s-process contribution to metal-poor stars is thought to be extremely small, due to the effect of the secondary-like nature of the neutron source 22Ne(a;n)25Mg in massive stars, which means that metal-poor weak s-process stars could not be found. ET0097 is the first observed carbon-enhanced metal-poor (CEMP) star in the Sculptor dwarf spheroidal galaxy. Because C is enriched and the elements heavier than Ba are not overabundant, ET0097 can be classified as a CEMP-no star. However, this star shows overabundances of lighter n-capture elements (i.e., Sr, Y and Zr). In this work, having adopted the abundance decomposition approach, we investigate the astrophysical origins of the elements in ET0097. We find that the light elements and iron-peak elements (from O to Zn) of the star mainly originate from the primary process of massive stars and the heavier n-capture elements (heavier than Ba) mainly come from the main r-process. However, the lighter n-capture elements such as Sr, Y and Zr should mainly come from the primary weak s-process. The contributed fractions of the primary weak s-process to the Sr, Y and Zr abundances of ET0097 are about 82%, 84% and 58% respectively, suggesting that the CEMP star ET0097 should have the footprints of the weak s-process. The derived result should be a significant evidence that the weak s-process elements can be produced in metal-poor massive stars.

RELATIVE CONTRIBUTIONS OF THE WEAK, MAIN, AND FISSION-RECYCLING r-PROCESS

ABSTRACT There has been a persistent conundrum in attempts to model the nucleosynthesis of heavy elements by rapid neutron capture (the r-process). Although the locations of the abundance peaks near nuclear mass numbers 130 and 195 identify an environment of rapid neutron capture near closed nuclear shells, the abundances of elements just above and below those peaks are often underproduced by more than an order of magnitude in model calculations. At the same time, there is a debate in the literature as to what degree the r-process elements are produced in supernovae or the mergers of binary neutron stars. In this paper we propose a novel solution to both problems. We demonstrate that the underproduction of nuclides above and below the r-process peaks in main or weak r-process models (like magnetohydrodynamic jets or neutrino-driven winds in core-collapse supernovae) can be supplemented via fission fragment distributions from the recycling of material in a neutron-rich environment such as that encountered in neutron star mergers (NSMs). In this paradigm, the abundance peaks themselves are well reproduced by a moderately neutron-rich, main r-process environment such as that encountered in the magnetohydrodynamical jets in supernovae supplemented with a high-entropy, weakly neutron-rich environment such as that encountered in the neutrino-driven-wind model to produce the lighter r-process isotopes. Moreover, we show that the relative contributions to the r-process abundances in both the solar system and metal-poor stars from the weak, main, and fission-recycling environments required by this proposal are consistent with estimates of the relative Galactic event rates of core-collapse supernovae for the weak and main r-process and NSMs for the fission-recycling r-process.

STUDY OF THE ELEMENT ABUNDANCES IN HD 140283: THE ABUNDANCE ROBUSTNESS OF THE WEAK r- AND MAIN r-PROCESS STARS

Many works have attempted to investigate the astrophysical origin of the neutron-capture elements in the metalpoor star HD 140283. However, no definite conclusions have been drawn. In this work, using the abundancedecomposed approach, we find that the metal-poor star HD 140283 is a weak r-process star. Although this star is a weak r-process star, its Ba abundance mainly originates from the main r-process. This is the reason that the ratio [Ba/Eu]= -0.58+- 0.15 for HD 140283 is close to the ratio of the main r-process. Based on the comparison of the abundances in the six-weak r-process stars, we find that their element abundances possess a robust nature. On the other hand, we find that the robust nature of the abundance of the extreme main r-process stars ([r/Fe]>= 1.5) can be extended to the lighter neutron-capture elements. Furthermore, the abundance characteristics of the weak r-process and main r-process are investigated. The abundance robustness of the two category r-process stars could be used as the constraint of the r-process theory and could be used to investigate the astrophysical origins of the elements in the metal-poor stars and population I stars.

SPECTROSCOPIC ANALYSIS OF METAL-POOR STARS FROM LAMOST: EARLY RESULTS

We report on early results from a pilot program searching for metal-poor stars with LAMOST and follow-up high-resolution observation acquired with the MIKE spectrograph attached to the Magellan~II telescope. We performed detailed abundance analysis for eight objects with iron abundances [Fe/H] < -2.0, including five extremely metal-poor (EMP; [Fe/H] < -3.0) stars with two having [Fe/H] < -3.5. Among these objects, three are newly discovered EMP stars, one of which is confirmed for the first time with high-resolution spectral observations. Three program stars are regarded as carbon-enhanced metal-poor (CEMP) stars, including two stars with no enhancement in their neutron-capture elements, which thus possibly belong to the class of CEMP-no stars; one of these objects also exhibits significant enhancement in nitrogen, and is thus a potential carbon and nitrogen-enhanced metal-poor star. The [X/Fe] ratios of the sample stars generally agree with those reported in the literature for other metal-poor stars in the same [Fe/H] range. We also compared the abundance patterns of individual program stars with the average abundance pattern of metal-poor stars, and find only one chemically peculiar object with abundances of at least two elements (other than C and N) showing deviations larger than 0.5dex. The distribution of [Sr/Ba] versus [Ba/H] agrees that an additional nucleosynthesis mechanism is needed aside from a single r-process. Two program stars with extremely low abundances of Sr and Ba support the prospect that both main and weak r-process may have operated during the early phase of Galactic chemical evolution. The distribution of [C/N] shows that there are two groups of carbon-normal giants with different degrees of mixing. However, it is difficult to explain the observed behavior of the [C/N] of the nitrogen-enhanced unevolved stars based on current data.

Is germanium (Ge, Z = 32) a neutron-capture element?

Historically,Ge has been considered to be a neutron-capture element. In this case, the r-process abundance of Ge is derived by subtracting the s-process abundance from the total abundance in the Solar system. However, the Ge abundance of the metal-poor star HD 108317 is lower than that of the scaled residual r-process abundance in the Solar system, about 1.2 dex. In this paper, based on a comparison of the Ge abundances of metal-poor stars and stellar yields, we find that the Ge abundances are not the result of the primary-like yields in massive stars and come mainly from the r-process. Based on the observed abundances of metal-poor stars, we derived the Ge abundances of the weak r-process and main r-process. The contributed percentage of the neutron-capture process to Ge in the Solar system is about 59 per cent, which means that the contributed percentage of the Ge residual abundance in the Solar system is about 41 per cent. We find that the Ge residual abundance is produced as secondary-like yields in massive stars. This implies that the element Ge in the Solar system is not produced solely by the neutron-capture process.