Main Ions Research Articles

A state-of-the-art review on the impacts of seawater and sea-sand together with main aggressive ions on the alkali-activated materials

A state-of-the-art review on the impacts of seawater and sea-sand together with main aggressive ions on the alkali-activated materials

Determining the evaporation and evolution of surface water in a large catchment using isotopes and multiple models

The evolution and formation mechanisms of chemical components in surface water can reflect changes in the geological background of a basin and the extent of human interference. The Yangtze River basin is the largest water source area in China, yet its main ion sources and formation mechanisms are not fully understood. This study uses a combination of hydrochemistry, stable isotopes (δ18O, δD), the Craig-Gordon model, and the APCS-MLR model to quantitatively assess the water source replenishment and evaporation intensity of surface water in the Yangtze River. The study reveals the primary ion sources and controlling factors of surface water in the Yangtze River. The results show that the hydrochemical type in the upstream is mainly HCO3−-Ca2+ and Na+-K+, while in the midstream and downstream it is primarily HCO3−-Ca2+ and SO42−-Ca2+. The evolution of hydrochemical types is mainly controlled by rock weathering and human inputs. The surface water sources in the Yangtze River are directly replenished by precipitation, with the evaporation ratio in the upstream (0.66) being higher than in the midstream (0.63) and downstream (0.47). The lc-excess in the upstream (−0.32 ‰) is lower than in the midstream (1.21 ‰) and downstream (−0.27 ‰), indicating more intense evaporation in the upstream. The hydrochemical composition of the Yangtze River surface water mainly comes from geological factors (80.5 %), industrial factors (11.1 %), agricultural factors (6.4 %), and unknown factors (2.0 %). This study enhances the understanding of the chemical composition, water source replenishment, ion sources, and evolution mechanisms of the Yangtze River surface water, providing a basis for maintaining water quality and sustainable development in the Yangtze River basin.

Compositions of the major ions, variations in their sources, and a risk assessment of the Qingshuijiang River Basin in Southwest China: a 10-year comparison of hydrochemical measurements.

Rivers in karst areas face increased risks from persistent growth in human activity that leads to changes in water chemistry and threatens the water environment. In this study, principal component analysis (PCA), ion ratio measurements, and other methods were used to study the water chemistry of the Qingshuijiang River Basin over the past 10 years. The results showed that the main ions in the river were Ca2+ and HCO3 -, with a cation order of Ca2+ (mean: 0.93 mmol/L) > Mg2+ (mean: 0.51 mmol/L) > Na+ (mean: 0.30 mmol/L) > K+ (mean: 0.06 mmol/L) and HCO3 - (mean: 2.00 mmol/L) > SO4 2- (mean: 0.49 mmol/L) > Cl- (mean: 0.15 mmol/L) > NO3 - (mean: 0.096 mmol/L) > F- (mean : 0.012 mmol/L). In the past 10 years, the concentration of major ions in the river water in the basin has increased significantly. The weathering input of rock (mainly upstream carbonate) was the main source of Mg2+, Ca2+, and HCO3 -, though sulfuric acid was also involved in this process. While K+ and Na+ were affected by the combination of human activity and the weathering input of silicate rock in the middle and lower reaches of the river, human activity was the main source of SO4 2-, NO3 -, and F- ions. Irrigation water quality and health risks were evaluated by calculating the sodium adsorption ratio (SAR), soluble sodium percentage (Na%), residual sodium carbonate (RSC), and hazard quotient (HQ). The findings indicated that the river water was generally safe for irrigation and drinking, and the health risks were gradually reduced over time. However, long-term monitoring of the river basin is still essential, especially for the risk of excessive F- in a few tributaries in the basin.

Cross Comparison of GALDIT Method Application in Three Costal Aquifers in Greece

Seawater intrusion into Greece’s coastal aquifers is a prevalent issue. The Greek coastline extends for 15,147 km. Once groundwater sources become contaminated, remediation methods are often challenging, costly, and protracted. This study focuses on three coastal aquifer systems in the Peloponnese region. Initially, the main ions and cations were determined for these aquifers. Hydrochemical analyses revealed elevated concentrations of Na+, Mg2+, Ca2+, SO42−, and Cl−, indicating a significant impact from seawater intrusion. The study evaluates the vulnerability of groundwater to this intrusion. Utilizing Geographical Information Systems (GIS) software (ArcGISPro), maps were created to illustrate each parameter of the GALDIT method. The acronym GALDIT encapsulates the main elements influencing seawater intrusion. Each parameter is analyzed as follows: Groundwater occurrence (including the following aquifer types: unconfined, confined, and leaky confined), Aquifer hydraulic conductivity, depth to groundwater Level above the sea, Distance from the shore (inland distance perpendicular from shoreline), Impact of existing status of sea water intrusion in the area, and Thickness of the aquifer. The final map that emerged from this study shows their vulnerability to seawater intrusion in Peloponnese. Notably, Larissos exhibits lower vulnerability in contrast to the seawater incursion in the other two groundwater systems.

Evaluation of SPARC divertor conditions in H-mode operation using SOLPS-ITER

Abstract The predicted divertor conditions for the SPARC tokamak are calculated using SOLPS-ITER for a range of scrape-off-layer (SOL) heat flux widths $\lamq$, input powers, and particle fuelling locations. Under H-mode scenario conditions with an upstream separatrix density of 1\e20 m$^{-3}$, the most conservative range of $\lamq$ extrapolations ($\approx$ 0.15 mm) results in extremely high unmitigated particle and energy fluxes to the divertor, both under full field (12.2 T) and power ($P_{SOL}$ = 29 MW) conditions, and 2/3 field with $P_{SOL}$ = 10 MW. Increasing the cross-field SOL diffusivities by 2-10x reduces the magnitude of the mitigation challenge, however strategies such as impurity seeding or strike-point-sweeping will likely still be required. 

A combination of steady-state and time-dependent SOLPS-ITER simulations are used to map out phase space diagrams of upstream and divertor conditions. At low upstream density the inner and outer divertor conditions are highly asymmetric, with a large temperature difference and significant heat fluxes driven by parallel currents. The solution has sharp bifurcations with a region of hysteresis, depending on whether the initial state is at a low or high density. This behavior is observed even when the fuelling location, cross-field diffusivity, and impurity level is changed, although the density window with asymmetry is reduced.

The addition of neon impurity seeding reduces the divertor heat fluxes, but also causes a drop in the upstream electron density with fixed particle throughput. This drop can be counteracted by increased main ion throughput, however too much neon results in a back transition into the asymmetric divertor regimes suggesting a need for control of both main ion and impurity seeding levels to achieve a desired divertor state.

Assessing drinking water quality in Eloued, south-East Algeria, using the groundwater pollution index (GPI) and the synthetic pollution index (SPI) model.

Groundwater quality degradation is a significant environmental issue worldwide, with potentially severe economic consequences and harm to ecosystems and biodiversity. This can directly affect human health, particularly in developing countries where rapid and uncontrolled urbanization is on the rise. Groundwater is the primary resource for meeting the water needs of the Eloued region, located in southeastern Algeria. Water is considered unfit for human consumption if its physico-chemical elements exceed national or international standards or guidelines. We used the GPI and SPI indices to evaluate the quality of groundwater suited for drinking. Groundwater samples were obtained from 22 wells at depths of more than 250m. Standard analytical procedures were used to determine the physicochemical characteristics of the collected samples, which included pH, EC, TDS, Na+, Ca+2, Mg+2, K+, Cl-, HCO3-, SO4-2, NO3-, NO2-, NH4+ and PO4-3. Multivariate statistical analysis and GIS techniques were used to process the results. The results of the selected physicochemical parameters were compared with World Health Organization (WHO) guidelines to determine the quality of drinking water. The findings indicate that the waters of the terminal complex aquifer are salty and contain medium to high quantities of main ions that surpass the established drinking water limits. The primary ions' relative abundance is Cl- > SO4-2 > HCO3- > NO3 for anions and Na+ > Ca+2 > Mg+2 > K+ for cations. Groundwater chemical types were dominated by Na+, Ca+2, Cl-, and SO4-2. Principal Component Analysis (PCA) showed that alteration and dissolution of carbonates, evaporates, salts, partly silicates, and evaporation, are the main reasons affecting the chemical composition of water in Eloued. The GPI results show that 18.18%, 54.54%, and 27.27% of the water samples were classed as lightly polluted, moderately polluted, or substantially polluted for drinking purposes, respectively. According to the SPI study, 9.09%, 36.36%, 36.36%, and 18.18% were considered drinkable, mildly contaminated, moderately polluted, and seriously polluted for drinking purposes, respectively. According to the GPI and SPI models' geographical distribution maps, potable water is generally scarce and concentrated in the northeastern section of the research area, near the town of Ourmes.

Thermodynamic Modeling of the Composition of the Main Background Ions and Determination of Gas-Kinetic Temperature in the Normal (“Hot”) Inductively Coupled Plasma

Thermodynamic Modeling of the Composition of the Main Background Ions and Determination of Gas-Kinetic Temperature in the Normal (“Hot”) Inductively Coupled Plasma

Slowing Down a Coherent Superposition of Circular Rydberg States of Strontium.

Rydberg alkaline earth atoms are promising tools for quantum simulation and metrology. When one of the two valence electrons is promoted to long-lived circular states, the second valence electron can be optically manipulated without significant autoionization. We harness this feature to demonstrate laser slowing of a thermal atomic beam of circular strontium atoms. By driving the main ion core 422nm wavelength resonance, we observe a velocity reduction of 50 m/s without significant autoionization. We also show that a superposition of circular states undergoes very weak decoherence during the cooling process, up to the scattering of more than 1000 photons. This robustness opens new perspectives for quantum simulations over long timescales with circular atoms, while simultaneously cooling their motional state. It makes it possible to mitigate the harmful effects of unavoidable heating due to spin-motion coupling during a quantum simulation.

Simulation on the hollow cathode discharge in hydrogen

A rectangular hollow cathode discharge (HCD) in hydrogen with a pressure of 2 Torr is simulated using a 2-D fluid model. The potential, electric field, particle density, and average electron temperature are calculated. The discharge space consists of the cathode sheath region near the cathode electrode and the negative glow (NG) region in the central region of the discharge cell. A high electric field of thousands of V/cm and a low electric field of tens of V/cm appear in the cathode sheath region and NG region, respectively. The average electron temperature in the cathode sheath region is tens of eV, which is significantly higher than that in the NG region. Electrons and H3 + are the main negative particles and positive ions, whose peaks appear in the NG region, and the peak magnitude is on the order of 1010 cm−3. H atom is the highest-density neutral particle other than H2 with a peak density of 1013 cm−3. The reaction kinetics of the generation and consumption of different particles are explored. The results show that each reaction generates certain particles while consuming other particles, ultimately achieving a dynamic equilibrium in the density of various particles. The electrons mainly originate from the ground state ionization between electron and H2 (e+H2 → e+H2 ++e) and are consumed by the dissociative attachment (e+H2 → H−+H). The charge transfer collision reaction (H2 ++H2 → H3 ++H) is the only reaction that produces H3 + ions. Different reactions to the consumption of H3 + ions do not differ significantly. The generation and consumption of H mainly originate from the electron collision dissociation reaction (e+H2 → e+H+H) and the ionization reaction (e+H→H++2e).

Exploiting the triple quadrupole mass analyzer for the open detection and tentative identification of synthetic cannabinoid receptor agonists based on common fragmentation pathways

BackgroundThe use of new psychoactive substances (NPS) has emerged as a significant public health concern globally, due to their unknown and unpredictable effects on both physical and mental health. Among them, synthetic cannabinoids receptor agonists (SCRAs) currently stand as the most widely consumed NPS family in Europe. Since the detection of JWH-018 in 2008, the structures of these compounds have evolved to circumvent legislation and/or enhance their effects, consequently increasing the number of reported SCRAs to be monitored. Therefore, new strategies are needed to identify these compounds, whether in seized products or in biological samples. ResultsThis study presents the development of an open method for detecting SCRAs employing a “pseudo-target” screening approach, a strategy previously developed and used in our laboratory for synthetic cathinones identification. The methodology involves monitoring the main product ions and neutral losses derived from 179 SCRAs of the third and fourth generations, based on their fragmentation pathways. This approach allows for the tentative identification of the SCRAs, supported also by the created database. The versatility of the developed methodology is highlighted, extending its utility beyond seizure products or ‘legal highs’, to biological samples. In this sense, it has been successfully applied not only to the detection of SCRAs in research chemicals but also in authentic urine from an anonymous SCRAs consumer, through the identification of a metabolite. SignificanceThis strategy will be particularly useful for the rapid detection of SCRAs in forensic and toxicological laboratories equipped with low-resolution MS/MS instrumentation. This is a valuable tool for the identification and monitoring of SCRAs across various contexts, significantly contributing to public health and forensic security efforts. It is especially beneficial for healthcare providers, enabling them to make informed treatment decisions.

Neoclassical transport computations in non-isothermal tokamak plasmas

Neoclassical transport in a non-isothermal plasma in which each plasma species has different equilibrium temperature is investigated by solving the drift kinetic equation with a Fokker–Planck (FP) collision operator in a circular tokamak model. Since it is known that a linearized FP operator does not have a self-adjoint property in a non-isothermal plasma, approximate models are developed for comparison to intend to have the self-adjoint property in the non-isothermal case. To achieve this, we set a common temperature that the system should reach after a long time, and the individual temperature of each particle species is expressed by a parameter to measure a shift of the individual temperature from the common one. Then, both the Vlasov part and the collision term of the kinetic equation are expanded around the common temperature, taking the temperature shift parameter up to the first order. It is found that the lowest order collision term of expansion preserves the self-adjointness while the first-order, nonlinear FP term does not. A large difference of the ion heat neoclassical transport is found in comparison between the developed models with and without the self-adjointness and the original FP collision term in the non-isothermal plasma, especially in a strong temperature equilibration regime, showing that a contribution of the collision term without the self-adjointness seems to be significant. Furthermore, when an impurity species is included, the result is complicated where the usual enhancement in the main ion particle transport coefficient, due to the impurity effect, is rather suppressed with the increase in the ion heat transport coefficients by the non-isothermal effects.

Overview of the KSTAR experiments toward fusion reactor

Abstract The KSTAR has been focused on exploring the key physics and engineering issues for future fusion reactors by demonstrating the long pulse operation of high beta steady-state discharge. Advanced scenarios are being developed with the goal for steady-state operation, and significant progress has been made in high ℓi, hybrid and high beta scenarios with βN of 3. In the new operation scenario called FIRE, fast ions play an essential role in confinement enhancement. GK simulations show a significant reduction of the thermal energy flux when the thermal ion fraction decreases and the main ion density gradient is reversed by the fast ions in FIRE mode. Optimization of 3D magnetic field techniques, including adaptive control and real-time machine learning (ML) control algorithm, enabled long-pulse operation and high-performance ELM-suppressed discharge. Symmetric multiple shattered pellet injections and real-time DECAF are being performed to mitigate and avoid the disruptions associated with high-performance, long-pulse ITER-like scenarios. Finally, the near-term research plan will be addressed with the actively cooled tungsten divertor, a major upgrade of the NBI and helicon current drive heating, and transition to a full metallic wall.

Effect of humidity on atmospheric pressure humid air discharge—interpretation from the perspective of detachment reactions

Detachment reactions have an important influence on the decreasing trend of electron density after high-field excitation, yet existing studies on humidity’s impact on discharge have failed to address this issue. To bridge this gap, we utilize a validated global model to explore how species density changes during humid air discharge corona inception. Our results indicate that humidity influences the detachment reaction rate by altering the negative ion composition. In dry conditions, the primary species involved in detachment reactions is O− ions. However, in environments with higher water vapor density, O− ions primarily react with water molecules, depleting O− ions. This change results in H− ions becoming the main detachment negative ions during the pulse. The greater the rate of the Detachment reaction the slower the decrease in electron density, and a rise in humidity causes the Detachment reaction to peak at a higher value and have a shorter duration, thus causing the electron density to decrease more rapidly. This discovery offers fresh insights into humidity’s effect on discharges. Additionally, we introduce the concept of the average negative ion detachment reaction rate constant, denoted as k d, to quantify the impact of detachment reactions within the three-element model.

Unraveling the interplay of common groundwater ions in arsenic removal by sulfide-modified nanoscale zerovalent iron.

Sulphidation of nZVI (S-nZVI) has shown to significantly improve the arsenic removal capacity of nZVI, concurrently modifying the sequestration mechanism. However, to better apply S-nZVI for groundwater arsenic remediation, the impact of groundwater coexisting ions on the efficacy of arsenic uptake by S-nZVI needs to be investigated. This present study evaluates the potential of S-nZVI to remove arsenic in the presence of typical groundwater coexisting ions such as Cl-, HA, HCO3-, PO43- and SO42- through batch adsorption experiments. Individually, PO43- and HA had a dominant inhibition effect, while SO42- promoted As(III) removal by S-nZVI. Conversely, for As(V) removal, HCO3- and SO42- impeded the removal process. X-ray spectroscopic investigation suggests that the coexisting ions can either compete with arsenic for the adsorption sites, influence the S-nZVI corrosion rates and/or generate distinct corrosion products, thereby interfering with arsenic removal by S-nZVI. To investigate the cumulative effects of these ions, a 25-1 Fractional Factorial Design of experiments was employed, wherein the concentration of all the ions were varied simultaneously in an optimized manner, and their impact on arsenic removal by S-nZVI was observed. Our results shows that when these ions are present concurrently, PO43-, SO42- and HA still exerted a dominant influence on As(III) removal, whereas HCO3- was the main ions affecting As(V) removal, although the combined influence of the ions was not merely a summation of their individual effects. Overall, the finding of our study might provide valuable insight for predicting the actual performance of S-nZVI in field-scale applications for the remediation of arsenic-contaminated groundwater.

Hif1α-dependent mitochondrial acute O2 sensing and signaling to myocyte Ca2+ channels mediate arterial hypoxic vasodilation

Vasodilation in response to low oxygen (O2) tension (hypoxic vasodilation) is an essential homeostatic response of systemic arteries that facilitates O2 supply to tissues according to demand. However, how blood vessels react to O2 deficiency is not well understood. A common belief is that arterial myocytes are O2-sensitive. Supporting this concept, it has been shown that the activity of myocyte L-type Ca2+channels, the main ion channels responsible for vascular contractility, is reversibly inhibited by hypoxia, although the underlying molecular mechanisms have remained elusive. Here, we show that genetic or pharmacological disruption of mitochondrial electron transport selectively abolishes O2 modulation of Ca2+ channels and hypoxic vasodilation. Mitochondria function as O2 sensors and effectors that signal myocyte Ca2+ channels due to constitutive Hif1α-mediated expression of specific electron transport subunit isoforms. These findings reveal the acute O2-sensing mechanisms of vascular cells and may guide new developments in vascular pharmacology.

Visible core spectroscopy at Wendelstein 7-X.

This paper presents an overview of recent hardware extensions and data analysis developments to the Wendelstein 7-X visible core spectroscopy systems. These include upgrades to prepare the in-vessel components for long-pulse operation, nine additional spectrometers, a new line of sight array for passive spectroscopy, and a coherence imaging charge exchange spectroscopy diagnostic. Progress in data analysis includes ion temperatures and densities from multiple impurity species, a statistical comparison with x-ray crystal spectrometer measurements, neutral density measurements from thermal passive Balmer-alpha emission, and a Bayesian analysis of active hydrogen emission, which is able to infer electron density and main ion temperature profiles.

Constraining the properties of the heat sources of high-temperature hydrogeothermal systems: Evidence from the lithium concentrations of geothermal waters

The properties of the heat source determine the exploitation potential and scientific research value of a high-temperature hydrothermal geothermal system. Existing hydrogeochemical and geophysical methods for discriminating heat sources have noticeable shortcomings, and an economic and universally applicable discrimination method is needed. In this study, three groups of typical geothermal waters from magmatic and non-magmatic geothermal systems in China were taken as the research objects. The Li concentrations of these geothermal waters were analyzed and the differences in their Li enrichment mechanisms were explored, while taking the cooling process of the geothermal water and the water–rock interactions into consideration. Finally, a more economical and universal new method for determining whether a hydrothermal geothermal system has a magmatic heat source based on the Li concentration was developed. The results show that: (1) the main ions in the magmatic geothermal waters were Na, HCO3, and Cl, but for the main ions in the non-magmatic geothermal waters were Na, Ca, and SO4. (2) Generally, the Li concentrations of the magmatic geothermal water samples were significantly higher than those of the non-magmatic geothermal water samples and most of the geothermal waters with a magmatic heat source were characterized by Li concentration of ≥5 mg/L and reservoir temperatures of ≥150 °C, while the geothermal waters with a non-magmatic heat source did not have this characteristic. (3) The magmatic geothermal waters mainly underwent the conductive and adiabatic cooling processes and also experienced cold-water mixing, whereas the non-magmatic geothermal waters mainly experienced cold-water mixing and conductive cooling. (4) Li-bearing mica was the main source of the Li from the host rocks and the amount of Li that removed by the adsorption of octahedral silicate minerals was greater in the magmatic geothermal systems than in the non-magmatic geothermal systems. (5) The additional amount of Li and heat provided by magmatic fluids were the key factors causing the Li enrichment, and the water–rock interactions between the geothermal waters and the host rocks were not sufficient to make the Li concentration of the geothermal waters reach 5 mg/L. (6) The Li concentration can be used universally to indicate the properties of the heat source of hydrothermal high-temperature geothermal system. In this study, a universal method for discriminating the heat sources of hydrothermal high-temperature geothermal systems based on the Li concentration was developed. Our findings provide a theoretical basis and effective method for evaluating types of geothermal resource and are of great significance for understanding the enrichment of lithium in geothermal water.

Chemical characteristics, formation mechanisms, and geological evolution processes of high-salinity coal reservoir water in the Binchang area of the southern Ordos Basin, China

The chemical characteristics of coal reservoir water are important for studying the formation and enrichment of biogenic coalbed methane (BCM). Based on geological and sampling test data, this paper studied the geochemical characteristics and formation mechanisms of high-salinity coal reservoir water (CRW) in the Jurassic Yan'an Formation of the Binchang area in the southern Ordos Basin. The results show that the TDS contents of the CRW in the Binchang area are between 7577.38 and 15,138.61 mg/L (av. 13,268.95 mg/L), which is high-salinity brackish water. The ion types of CRW are mainly Na+, Cl− and HCO3−, and the correlations between TDS and Na+ and Cl− are close to 1. The Piper trilinear diagram indicates that the evolution direction of the CRW is deep concentrated brine, and the hydrochemical type is the NaCl type. The 127I concentrations of CRW are between 285 and 484 μg/L, which are much higher than the values of 55.88 μg/L for seawater. The results of 129I dating show that the minimum age of the CRW in the study area is between 6.7 Ma and 39.97 Ma, which is much younger than the actual geological age of the Yan'an Formation. The hydrogen and oxygen isotope results show that the CRW in the study area experiences an apparent oxygen drift, indicating that the coal reservoir of the Yan'an Formation has good sealing and a long retention time for the CRW. The hydrodynamic factors show that the hydrodynamic conditions of the coal reservoir are weak, and the primary ions in the CRW originated from the dissolution of salt rocks. The main ion differentiation indices show that high-salinity coal seam water is mainly formed by evaporation, and the ion exchange between CRW and the surrounding rock and the alternating adsorption of cations in water are very weak. Evaporation and diagenesis lead to an increase in the contents of Na+, Cl− and I+ in coalbed water, which in turn leads to an increase in the total dissolved solids contents of CRW and its evolution toward concentrated brine. The genesis and evolution of the CRW in the study area are affected by the combination of the relationships among the paleoclimate, aquifers and aquifuges, and tectonic evolution processes. The CRW in the study area has experienced five evolution stages, i.e., sedimentary water and diagenetic water, high-salinity infiltration water, primary mixed water, paleoatmospheric precipitation recharge water, and secondary mixed water. The above understanding can provide a basis for studying the formation period and accumulation mechanism of BCM and provide a hydrogeological basis for water resource utilisation and pollution prevention and the control of high-salinity water.

Isotope effects and Alfvén eigenmode stability in JET H, D, T, DT, and He plasmas

While much about Alfvén eigenmode (AE) stability has been explored in previous and current tokamaks, open questions remain for future burning plasma experiments, especially regarding exact stability threshold conditions and related isotope effects; the latter, of course, requiring good knowledge of the plasma ion composition. In the JET tokamak, eight in-vessel antennas actively excite stable AEs, from which their frequencies, toroidal mode numbers, and net damping rates are assessed. The effective ion mass can also be inferred using measurements of the plasma density and magnetic geometry. Thousands of AE stability measurements have been collected by the Alfvén Eigenmode Active Diagnostic in hundreds of JET plasmas during the recent Hydrogen, Deuterium, Tritium, DT, and Helium-4 campaigns. In this novel AE stability database, spanning all four main ion species, damping is observed to decrease with increasing Hydrogenic mass, but increase for Helium, a trend consistent with radiative damping as the dominant damping mechanism. These data are important for confident predictions of AE stability in both non-nuclear (H/He) and nuclear (D/T) operations in future devices. In particular, if radiative damping plays a significant role in overall stability, some AEs could be more easily destabilized in D/T plasmas than their H/He reference pulses, even before considering fast ion and alpha particle drive. Active MHD spectroscopy is also employed on select HD, HT, and DT plasmas to infer the effective ion mass, thereby closing the loop on isotope analysis and demonstrating a complementary method to typical diagnosis of the isotope ratio.

Using dopants in the atmospheric pressure chemical ionization ion source to determine the site of protonation by ion mobility spectrometry.

Compounds like caffeine metabolites with more than one proton acceptor site can produce a mixture of isomeric protonated ions (protomers) in electrospray ionization and atmospheric pressure chemical ionization (APCI) ion sources. Discrimination between the protomers is of interest as the charge location influences ion structure and chemical and physical properties. Protonation of caffeine in an APCI ion source was studied using ion mobility spectrometry. The hydronium ions, H3O+(H2O)n, are the main reactant ions in the APCI ion source. Different dopant gases including NO2, NH3, and CH3NH2 were used to produce new reactant ions NO+, NH4 +, and CH3NH3 +, respectively. Density functional theory was employed to explain the experimental results and calculate the energies of the ionization reactions. The ion mobility spectrum of caffeine showed three peaks. In the presence of NO2 dopant and NO+ reactant ion, caffeine was ionized via charge transfer and formation of M+ ion. As NH3 and CH3NH2 are stronger bases than H2O, the reactant ions NH4 + and CH3NH3 + selectively protonated the more basic site of caffeine, that is, the imidazole nitrogen. Using these dopants, we could attribute the first ion mobility peak to M+ ion, the second peak to the protonation of caffeine at the carbonyl oxygen atom, and the third peak to the protonation of the imidazole nitrogen atom. The calculated collisional cross-sections of M+ and the protomers of caffeine confirmed the peaks' assignment. The criterion for the selection of an appropriate dopant is that its proton affinity (PA) should be between those of the proton acceptor sites of the molecule studied.