Abstract This study investigates the evolution of temperature and lifetime of evaporating, supercooled cloud droplets considering initial droplet radius (r0) and temperature (), and environmental relative humidity (RH), temperature (T∞), and pressure (P). The time (tss) required by droplets to reach a lower steady-state temperature (Tss) after sudden introduction into a new subsaturated environment, the magnitude of ΔT = T∞ − Tss, and droplet survival time (tst) at Tss are calculated. The temperature difference (ΔT) is found to increase with T∞, and decrease with RH and P. ΔT was typically 1–5 K lower than T∞, with highest values (∼10.3 K) for very low RH, low P, and T∞ closer to 0°C. Results show that tss is <0.5 s over the range of initial droplet and environmental conditions considered. Larger droplets (r0 = 30–50 μm) can survive at Tss for about 5 s to over 10 min, depending on the subsaturation of the environment. For higher RH and larger droplets, droplet lifetimes can increase by more than 100 s compared to those with droplet cooling ignored. Tss of the evaporating droplets can be approximated by the environmental thermodynamic wet-bulb temperature. Radiation was found to play a minor role in influencing droplet temperatures, except for larger droplets in environments close to saturation. The implications for ice nucleation in cloud-top generating cells and near cloud edges are discussed. Using Tss instead of T∞ in widely used parameterization schemes could lead to enhanced number concentrations of activated ice-nucleating particles (INPs), by a typical factor of 2–30, with the greatest increases (≥100) coincident with low RH, low P, and T∞ closer to 0°C. Significance Statement Cloud droplet temperature plays an important role in fundamental cloud processes like droplet growth and decay, activation of ice-nucleating particles, and determination of radiative parameters like refractive indices of water droplets. Near cloud boundaries such as cloud tops, dry air mixes with cloudy air exposing droplets to environments with low relative humidities. This study examines how the temperature of a cloud droplet that is supercooled (i.e., has an initial temperature < 0°C) evolves in these subsaturated environments. Results show that when supercooled cloud droplets evaporate near cloud boundaries, their temperatures can be several degrees Celsius lower than the surrounding drier environment. The implications of this additional cooling of droplets near cloud edges on ice particle formation are discussed.
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