The magnetoacoustic nonlinear periodic (cnoidal) wave and solitons in multi-ion plasmas are studied, and its Korteweg–de Vries (KdV) equation is derived by applying the reductive perturbation (RP) method with appropriate boundary conditions. The dynamics of all species in a multi-ion plasma, which consists of warm (light) ions, cold (heavy) ions, and hot electrons, are taken in the electromagnetic field. Two types of multi-ion plasmas, i.e., H+-O+-e (positive ion plasma) and H+-O2−-e (negative ion plasma), are chosen, which can exist in different layers of the ionosphere. It is found that for the H+-O+-e plasma case, the nonlinear structure forms compressive magnetoacoustic wave pulses (which move with the super-Alfvénic speed of light ions in the lab frame) and depends on plasma parameters such as the external magnetic field intensity and light ion temperature and density. It is also found that the rarefactive magnetoacoustic wave structures (move with the sub-Alfvénic speed of light ions in the lab frame) are also formed in H+-O+-e plasma if heavy and light ions' density ratio is increased beyond a certain limit. In the case of negative ion (i.e., H+-O2−-e) plasma, again, compressive magnetoacoustic cnoidal waves and soliton structures are formed at a comparatively lower value of heavy to light ions' density ratio (χ) with the positive ion plasma case. Again, these compressive magnetoacoustic structures switch to the rarefactive ones in negative ion plasma when density ratio χ is increased beyond a certain limit. The parametric analysis and numerical plots are illustrated, and the obtained theoretical results are found to be consistent with the Freja experimental observations in the upper ionosphere.
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