Distribution Of Magnetic Domains Research Articles

Multi-physics coupling simulation and design of magnetic field-driven soft microrobots in liquid environments

Magnetic field-driven soft microrobots have widespread applications in biomedical science, microfluidic chips, nanoengineering, and various other domains. However, the existing methods for designing such magnetic-driven flexible robots largely rely on experimental trial and error or steady-state numerical simulated results, which fall short of meeting the intricate requirements for magnetic field editing and magnetic domain distribution. Addressing this issue, a multi-physics coupling numerical analysis method encompassing Magnetic-Fluid-Solid mechanics was developed. A complete process for transient numerical simulation resolution has been achieved. Utilizing this analysis method, the motion patterns of two typical prototypes of magnetic-driven miniature soft bionic robots, a bionic midge larvae robot, and a bionic jellyfish robot, have been analyzed. The central role of the magnetic field in driving these robotic designs—causing deformation in microrobots by designing magnetic domains and spinning the microrobots by controlling the magnetic field—has been revealed. We developed a theoretical model of a bionic fish tail fin robot driven solely by a rotating magnetic field and conducted comparative studies on the swimming efficiency, flexibility, stability, and relative advantages of the three types of robots. The impact of different magnetic domain distribution rules and different magnetic field driving methods on a robot's performance is analyzed, validating that higher swimming efficiency can be achieved by designing a robot's magnetic domains so that they undergo magnetic displacement under magnetic torque resulting in deformation. This innovative analysis method holds potential to provide valuable references for designing motion patterns of magnetically driven microrobots within liquid environments, thereby deepening our understanding toward various complex gait mechanisms involved in biological swimming.

Probing the magnetic domain interaction and magnetocapacitance in PVDF – (nickel–cobalt–manganese ferrite)@barium titanate core–shell flexible nanocomposites

In this paper, we report a facile method to synthesize Ni0.93Co0.02Mn0.05Fe1.95O4−δ (NCMF)@BaTiO3 (BT) core–shell nanoparticles, analysed the impact of the BT shell phase on the magnetic domain distribution and its interaction on the final properties of the composites.

Spectromicroscopic study of the transformation with low energy ions of a hematite thin film into a magnetite/hematite epitaxial bilayer

The search of new properties in novel oxide heterostructures requires the exploration of new fabrication methods and the study, at the microscopic level, of the processes involved during the synthesis. We present a synchrotron-based spectromicroscopic investigation of a magnetite/hematite bilayer on Pt(111) grown in a two-step process by thermal evaporation and Low Energy Ion Bombardment (LEIB). The characterization includes the study of structural, electronic, chemical, and magnetic properties using X-ray Absorption Spectroscopy (XAS), Low Energy Electron Microscopy (LEEM), Photoemission Electron Microscopy (PEEM), or X-ray Magnetic Circular Dichroism (XMCD). The aim is to obtain microscopic information of the thin film before, during, and after the ion bombardment. Ion bombardment gradually transforms the topmost layers of the hematite thin film into a defective sub-oxide, where magnetite nuclei grow and coalesce with increasing ion doses. Two rotational domains of magnetite coexist, which are typically a few tens of nanometres large and do not grow significantly with temperature annealings. The incoherent growth of the magnetite nuclei favours the formation of stable twin boundaries (TBs) and antiphase boundaries (APBs). Dichroic spectra show the characteristics of the ferrimagnetic (FiM) order of magnetite, and the spatial distribution of magnetic domains shows no apparent correlation with the structural image, displaying smooth domains separated by diffuse frontiers. These findings illustrate the importance of a spectromicroscopic characterization of novel oxide heterostructures for potential future applications.

Thickness, Annealing, and Surface Roughness Effect on Magnetic and Significant Properties of Co40Fe40B10Dy10 Thin Films.

In this study, Co40Fe40B10Dy10 thin films were deposited using a direct current (DC) magnetron sputtering technique. The films were deposited on glass substrates with thicknesses of 10, 20, 30, 40, and 50 nm, and heat-treated in a vacuum annealing furnace at 100, 200, and 300 °C. Various instruments were used to examine and analyze the effects of roughness on the magnetic, adhesive, and mechanical properties. From the low frequency alternating current magnetic susceptibility (χac) results, the optimum resonance frequency is 50 Hz, and the maximum χac value tends to increase with the increase in the thicknesses and annealing temperatures. The maximum χac value is 0.18 at a film thickness of 50 nm and an annealing temperature of 300 °C. From the four-point probe, it is found that the resistivity and sheet resistance values decrease with the increase in film deposition thicknesses and higher annealing temperatures. From the magnetic force microscopy (MFM), the stripe-like magnetic domain distribution is more obvious with the increase in annealing temperature. According to the contact angle data, at the same annealing temperature, the contact angle decreases as the thickness increases due to changes in surface morphology. The maximal surface energy value at 300 °C is 34.71 mJ/mm2. The transmittance decreases with increasing film thickness, while the absorption intensity is inversely proportional to the transmittance, implying that the thickness effect suppresses the photon signal. Smoother roughness has less domain pinning, more carrier conductivity, and less light scattering, resulting in superior magnetic, electrical, adhesive, and optical performance.

Research on Deterioration Mechanism and High-Precision Modelling of the Core Loss for Amorphous Alloys after Wire-Cut Electric Discharge Machining

Amorphous alloys (AAs) have the advantage of low core loss. Thus, they can be used in high-speed motor applications. However, compared with the nominal performances, the performance of the wire-cut electric discharge machine (W-EDM)-processed AA iron core changes significantly, which limits its popularization. This paper focuses on the performance degradation mechanism of the AA ribbon caused by W-EDM and establishes a modified core loss model after machining. First, a 308 × 15 mm ribbon-shaped AA sample machined by W-EDM was prepared. The characterization and analysis of the magnetic properties, phase, magnetic domain, nano-indentation, micro-morphology, and composition were carried out. In this paper, by analysing the variation in the magnetic domain distribution based on domain width and nano-mechanical properties, it is proposed that the performance degradation range of AA ribbons processed by W-EDM is within 1 mm from the edge. By comparing the microscopic morphology and chemical composition changes in the affected and the unaffected area, this paper presents a mechanism for the property deterioration of W-EDM-processed AA ribbons based on electrochemical corrosion. Finally, a modified loss model for W-EDM-processed AAs is established based on the division of the affected area. This model can significantly improve the accuracy of core loss estimation in the medium- and high-frequency bands commonly used in high-speed motors.

Poly(vinyl alcohol)/sodium alginate/magnetite composites: magnetic force microscopy for tracking magnetic domains.

Hydrogels of poly(vinyl alcohol) (PVA)/sodium alginate (SA), and magnetic nanoparticles (MNPs) were prepared by solvent casting in the absence and in the presence of magnets, in order to obtain MNPs distributed randomly (PVA/SA-rMNP) and magnetically oriented MNPs (PVA/SA-gMNP) in the polymer matrix. Atomic force microscopy (AFM) and magnetic force microscopy (MFM) techniques were used to evaluate the topography and to map the distribution of magnetic domains in the polymer matrix, respectively. The tip-surface distance (lift distance) of 50 nm during the MFM analyses facilitated the mapping of magnetic domains because the van der Waals forces were minimized. The magnetic signal stemming from clusters of MNPs were more easily identified than that from isolated MNPs. PVA and SA, PVA/SA, PVA/SA-rMNP, and PVA/SA-gMNP coatings with surface roughness (Ra) values of 3.8 nm, 28.7 nm, and 49.8 nm, respectively, were tested for the proliferation of mouse hippocampal HT-22 cells. While PVA/SA, PVA/SA-rMNP, and PVA/SA-gMNP coatings preserved cell viability >70% in comparison to the control (plastic plate) over 48 h, cell proliferation tended to decrease on surfaces with higher Ra values (PVA/SA-gMNP). These findings showed that the orientation of magnetic domains led to an increase of surface roughness, which decreased the viability of HT-22 cells. Thus, these results might be interesting for situations, where the control of cell proliferation is necessary.

Tunable Perpendicular Magnetoresistive Sensor Driven by Shape and Substrate Induced Magnetic Anisotropy

AbstractControl of magnetization reversal processes is a key issue for the implementation of magnetic materials in technological applications. The modulation of shape magnetic anisotropy in nanowire structures with a high aspect ratio is an efficient way to tune sharp in‐plane magnetic switching. However, control of fast magnetization reversal processes induced by perpendicular magnetic fields is much more challenging. Here, tunable sharp magnetoresistance changes, triggered by out‐of‐plane magnetic fields, are demonstrated in thin permalloy strips grown on LaAlO3 single crystal substrates. Micromagnetic simulations are used to evaluate the resistance changes of the strips at different applied field values and directions and correlate them with the magnetic domain distribution. The experimentally observed sharp magnetic switching, tailored by the shape anisotropy of the strips, is properly accounted for by numerical simulations when considering a substrate‐induced uniaxial magnetic anisotropy. These results are promising for the design of magnetic sensors and other advanced magnetoresistive devices working with perpendicular magnetic fields by using simple structures.

An anisotropic vector hysteresis model of ferromagnetic behavior under alternating and rotational magnetic field

Vector quantities and tensorial properties rule the magnetization mechanisms in ferromagnetic materials. Every ferromagnetic material is anisotropic to some degree in its magnetic response, so this anisotropy has to be considered for a general model. In this study, a multiscale approach based on a statistical description of the magnetic domain distribution and the knowledge of the crystallographic texture is used to predict the anhysteretic behavior along an arbitrary space direction. Combined with the vector Bergqvist dry-friction hysteresis model, qualitatively reliable simulation results are obtained under alternating and rotational magnetization. FeSi 3% grain-oriented (FeSi GO) electrical steel is chosen as study material: FeSi GO are widespread so that extensive data are available and strongly anisotropic, forcing the model toward the “worst-case” scenario from the viewpoint of anisotropy.Moreover, under high excitation of rotational magnetization, losses drop due to the disappearance of the magnetic domains. This behavior is represented correctly by the proposed simulation method. In such conditions, the magnetization behavior is led mainly by the anhysteretic behavior, strengthening the predictive ability of the proposed model. In this manuscript, comparisons between simulations and measurements under many amplitudes of alternating and rotational magnetization for different levels of imposed excitation or magnetization are provided and used to validate the simulation method.

Forming mechanism and tribological properties of a Ni-based coating prepared from transverse static magnetic field-assisted supersonic plasma spraying

Magnetic field-assisted forming represents an environmentally friendly, contactless and high-efficiency technology for the development of advanced in situ manufacturing. The application of this technology provides a new concept for improving the properties of ferromagnetic wear-resistant coatings. In this study, we combine magnetic field-assisted forming with supersonic plasma spraying to prepare a Ni-based coating assisted by a transverse static magnetic field. The porosity of the magnetic field-assisted coating is below 2%, the hardness of the coating increases from 638.46 to 785.45 MPa and the tribological coefficient decreases from 0.466 to 0.422. The presence of the static magnetic field directly affects the bubble movement during the forming process of the coating, which makes the bubbles escape outward and reduces the porosity of the coating. The presence of the static magnetic field also further improves the phase structure of the coating, so that the magnetic domain distribution is uniform and the hard phase inside the coating increases. Finally, the residual stress and tribological properties of the coating are also improved.

Vector analysis of electric-field-induced antiparallel magnetic domain evolution in ferromagnetic/ferroelectric heterostructures

Electric field (E-field) control of magnetism based on magnetoelectric coupling is one of the promising approaches for manipulating the magnetization with low power consumption. The evolution of magnetic domains under in-situ E-fields is significant for the practical applications in integrated micro/nano devices. Here, we report the vector analysis of the E-field-driven antiparallel magnetic domain evolution in FeCoSiB/PMN-PT(011) multiferroic heterostructures via in-situ quantitative magneto-optical Kerr microscope. It is demonstrated that the magnetic domains can be switched to both the 0° and 180° easy directions at the same time by E-fields, resulting in antiparallel magnetization distribution in ferromagnetic/ferroelectric heterostructures. This antiparallel magnetic domain evolution is attributed to energy minimization with the uniaxial strains by E-fields which can induce the rotation of domains no more than 90°. Moreover, domains can be driven along only one or both easy axis directions by reasonably selecting the initial magnetic domain distribution. The vector analysis of magnetic domain evolution can provide visual insights into the strain-mediated magnetoelectric effect, and promote the fundamental understanding of electrical regulation of magnetism.

Ferroelectric and magnetic domain mapping of magneto-dielectric Ce doped BiFeO3 thin films

Co-existent ferroelectric and magnetic ordering at room temperature in multiferroics has generated significant interest for potential applications in low-power sensors, transducers, and memory devices. Despite tremendous efforts centered on site-substitution in BiFeO3 to attain enhanced functionality, local probing of multiferroic domain dynamics with dopant concentration remains overlooked. Here we report a detailed investigation on ferroelectric and magnetic domain mapping of Bi1−XCeXFeO3; 0 ≤ X ≤ 0.2 (BCFOX) thin films and discussed concentration-dependent behavior of piezo-response switching, piezo-actuation butterfly-loop and phase-hysteresis, and magneto-dielectric coupling. Large piezo-response amplitude change of 30 mV and near to complete phase reversal of ~150° together with homogeneous magnetic domain distribution and an enhanced magneto-dielectric coupling coefficient of 2.15% at 0.3 T unveils improved ferroelectric ordering in polycrystalline BCFO0.12 thin film. We believe, our findings will develop a comprehensive understanding of sensitive force microscopy technique for the custom-made advancement of BiFeO3 based multiferroic family.

A local view of the laser induced magnetic domain dynamics in CoPd stripe domains at the picosecond time scale

The dynamics of the magnetic structure in a well ordered ferromagnetic CoPd stripe domain pattern has been investigated upon excitation by femtosecond infrared laser pulses. Time-resolved x-ray magnetic circular dichroism in photoemission electron microscopy (TR-XMCD-PEEM) is used to perform real space magnetic imaging with 100 ps time resolution in order to show local transformations of the domains structures. Using the time resolution of the synchrotron radiation facility of the Helmholtz-Zentrum Berlin, we are able to image the transient magnetic domains in a repetitive pump and probe experiment. In this work, we study the reversible and irreversible transformations of the excited magnetic stripe domains as function of the laser fluence. Our results can be explained by thermal contributions, reducing the XMCD amplitude in each stripe domain below a threshold fluence of 12 mJ cm−2. Above this threshold fluence, irreversible transformations of the magnetic domains are observed. Static XMCD-PEEM images reveal the new partially ordered stripe domain structures characterized by a new local magnetic domain distribution showing an organized pattern at the micrometer scale. This new arrangement is attributed to the recovery of the magnetic anisotropy during heat dissipation under an Oersted field.

Influence of thermal treatment on the magnetic properties and morphology of electrodeposited Fe-Co films

Fe-Co films were prepared by electrodeposition from an electrolyte containing citric acid and annealed afterwards at different temperatures up to 700 °C. The grain sizes of the deposits increased from 11 nm to 30 nm with increasing annealing temperature, which lead to changes in magnetic properties of deposits. SQUID measurements indicate that there is a difference between the coercive force, Hc, of the as deposited samples (17 Oe) and the heat-treated samples (25–40 Oe) with a measurement error of 1–2 Oe. The remnant magnetization, Mr, decreased from 190 ± 12 emu/cm3 for the as deposited to 75 ± 5 emu/cm3 for the annealed samples, respectively. The saturation magnetization, Ms, seems not to be influenced strongly by the thermal treatment, with the only exception for the samples annealed at 500 °C. Thus, Ms has a slightly decreasing tendency from 1880 ± 90 emu/cm3 for the as-deposited samples to 1780 ± 85 emu/cm3 for samples annealed at 700 °C. The biggest value for Ms (2100 ± 105 emu/cm3) was obtained if the samples were annealed at 500 °C. The thermal treatment generated cracks in the deposits. Interestingly, these cracks had a regular rectangular shape only if the deposits were annealed at 600 °C. The coercivity of the layers annealed at 600 °C was lower compared to layers annealed at the other temperatures. Magnetic force microscopy measurements indicated the magnetic domain distribution and the topography of the annealed deposits. The deposits showed the best soft magnetic properties if annealed between 500 and 600 °C.

In-Plane Magnetic Domains and Néel-like Domain Walls in Thin Flakes of the Room Temperature CrTe2 Van der Waals Ferromagnet.

The recent discovery of magnetic van der Waals (vdW) materials triggered a wealth of investigations in materials science and now offers genuinely new prospects for both fundamental and applied research. Although the catalog of vdW ferromagnets is rapidly expanding, most of them have a Curie temperature below 300 K, a notable disadvantage for potential applications. Combining element-selective X-ray magnetic imaging and magnetic force microscopy, we resolve at room temperature the magnetic domains and domain walls in micron-sized flakes of the CrTe2 vdW ferromagnet. Flux-closure magnetic patterns suggesting an in-plane six-fold symmetry are observed. Upon annealing the material above its Curie point (315 K), the magnetic domains disappear. By cooling back the sample, a different magnetic domain distribution is obtained, indicating material stability and lack of magnetic memory upon thermal cycling. The domain walls presumably have Néel texture, are preferentially oriented along directions separated by 120°, and have a width of several tens of nanometers. Besides microscopic mapping of magnetic domains and domain walls, the coercivity of the material is found to be of a few millitesla only, showing that the CrTe2 compound is magnetically soft. The coercivity is found to increase as the volume of the material decreases.

Athermal Shape Memory Effect in Magnetoactive Elastomers.

Shape memory materials (SMMs) are usually referred to as materials with the ability to recover the original shape via certain thermal stimulations, such as temperature increase. Such shape memory behaviors achieved thermally usually exhibit slow response due to the constraint of thermal conductivity, leaving a big challenge for situations with temperature and speed requirements. In this work, different from previous shape memory mechanisms, an athermal fast-response shape memory effect (SME) based on the manipulation of magnetization profiles is introduced both experimentally and theoretically. Through the new mechanism, the shape information of a hard magnetic-particle-embedded magnetoactive elastomer (H-MAE) can be accurately converted into the distribution of magnetic domains and recorded/memorized in the material. Then, upon the application of an external magnetic field, due to the interactions between magnetic domains and the magnetic field, the recorded shape information can be immediately displayed. To exploit this mechanism, the magnetic actuating properties are analyzed and a new way for information writing and repeatable reading is also realized.

Visualization of magnetic domain structure in FeSi based high permeability steel plates by neutron imaging

In the present work, a combined study with polarized neutron imaging (PNI) and neutron-grating interferometry based dark field imaging (DFI) experiments on grain oriented high permeability steel sample with 3% Si and 0.35 mm thickness is reported. With the combination of these two experimental techniques it was possible to obtain the complex picture of magnetic domain distribution and domain walls in the electric steel samples. With the PNI technique, the observed fringe pattern contrast may be correlated with basic magnetic domains. These magnetic domains are oriented anti-parallel with respect to each other and the different magnetic field in each domain may lead to fringe pattern contrast. The magnetic domains are disrupted at the grain boundaries, observed as discontinuities in the fringe pattern contrast. In comparison, with DFI measurements, we visualized scattering contrast from magnetic domain walls. A clear correlation between basic domains (from PNI) and domain walls (using DFI) is observed. In the current study we also demonstrate the potential of combining two differential experimental techniques to visualize and obtain collective information about magnetic domains and domain walls.

The generation of the tribo-magnetization in a ferromagnetic material during the friction process

In this paper, a friction apparatus was developed to explore the magnetization phenomenon of pure iron during the friction process. A series of sliding-friction tests were carried out to study the tribo-magnetization effect under lubrication and non-lubrication condition. Furthermore, the correlation between the distribution and variation of magnetic domains and the metallographic structure of the materials were analyzed. And a model of tribo-magnetization was built. The results showed that the tribo-magnetization phenomenon under non-lubricated conditions was more significant than that under lubricated conditions because of the interaction between two interfaces which affected the range and deformation degree of the area of influence beneath the sliding surface. It was found that the generation of plastic deformation beneath a sliding surface is the principal source of magnetization.

Oil-medium current annealing enhanced giant magneto-impedance properties of Co-based metallic microfibers for magnetic sensor applications

Herein, the effect of oil-medium current annealing on GMI characteristics of rotated-dipping Co-based metallic microfibers was investigated systematically. Based on thermophysical parameters of the metallic microfibers (containing glass transition temperature Tg and initial crystallization temperature Tx1), we constructed a steady-state heat conduction model by ANSYS to simulate the temperature field distribution during its oil-medium current annealing process, and further to determine the annealing current intensity range: 50 mA˜300 mA, according to the crystallization degree of cores of microfibers. The experimental results indicated that, in comparison to as-cast Co-based microfibers, the maximum GMI ratio [ΔZ/Zmax]max and the maximum magnetic field response sensitivity ξmax of oil-medium current annealed microfibers were both significantly improved. Among which, [ΔZ/Zmax]max and ξmax of the microfibers annealed at 225 mA can reach 303.1% and 50.6%/Oe, respectively, at the excitation current frequency f =5 MHz, and the maximum response field Hp increased from 1 Oe to 3 Oe. Meanwhile, the magnetic domain arrangement of oil-medium current annealed microfibers became denser, the width of which got smaller, and the transition regions of domain changed into clearer. This improvement of GMI characteristics is closely related to magnetic domain distribution regulated by high-intensity toroidal magnetic field, which was generated during the medium current annealing process. That is, the atomic magnetic moment tends to be closely and orderly adjusted by the combined action of both the magnetic field energy and thermal activation energy.

Quantum size effect in exchange asymmetry of ultrathin ferromagnetic films studied with Spin Polarized Low Energy Electron Microscopy

The magnetic properties of ultrathin ferromagnetic films are studied by means of Spin Polarized Low Energy Electron Microscopy. Measurements of the onset of ferromagnetic order, distribution and shape of magnetic domains, magnetization direction and their change are now well established standards for this technique. Here, the asymmetry parameter has been determined as a function of film coverage and energy of the incident electron beam. It reveals oscillatory behavior which is usually described as due to the quantum size effect (QSE). We explore the origin of the characteristic features observed in the asymmetry curves and distinguish between the QSE oscillations and other phenomena influencing the shape of the asymmetry curves. As an example we discuss the asymmetry of ultrathin iron films grown on the W(110) surface.

Visualisation of deformation gradients in structural steel by macroscopic magnetic domain distribution imaging (Bitter technique)

AbstractWhile classically used to visualise the magnetic microstructure of functional materials (e.g., for magnetic applications), in this study, the Bitter technique was applied for the first time to visualise macroscopic deformation gradients in a polycrystalline low‐carbon steel. Spherical indentation was chosen to produce a multiaxial elastic–plastic deformation state. After removing the residual imprint, the Bitter technique was applied, and macroscopic contrast differences were captured in optical microscopy. To verify this novel characterisation technique, characteristic “hemispherical” deformation zones evolving during indentation were identified using an analytical model from the field of contact mechanics. In addition, near‐surface residual stresses were determined experimentally using synchrotron radiation diffraction. It is established that the magnetic domain distribution contrast provides deformation‐related information: regions of different domain wall densities correspond to different “hemispherical” deformation zones (i.e., to hydrostatic core, plastic zone and elastic zone, respectively). Moreover, the transitions between these three zones correlate with characteristic features of the residual stress profiles (sign changes in the radial and local extrema in the hoop stress). These results indicate the potential of magnetic domain distribution imaging: visualising macroscopic deformation gradients in fine‐grained ferromagnetic material with a significantly improved spatial resolution as compared to integral, mean value‐based measurement methods.