Dc Magnetization Research Articles

Spin glass behavior of single-crystalline ErFe2O4−δ

Abstract We investigated magnetic properties of ErFe2O4-δ single crystal containing oxygen vacancies with value of δ being estimated to be 0.066. The temperature dependence of dc magnetization in zero field cooling (ZFC) process reveals that ErFe2O4-δ undergoes a ferrimagnetic transition at 234 K followed by a broad peak at 224.3 K. The latter is attributable to the spin glass transition as indicated by the strong frequency dependence of temperature-dependent ac susceptibility. The frequency variation of transition temperature is described well by the dynamic scaling law and the critical exponent is similar to those reported for typical spin glasses. Additionally, the spin glass transition at 224.3 K is confirmed by the fact that the magnetic field dependence of irreversible transition temperature is coincident with the de Almeida-Thouless line and that the aging memory and rejuvenation effect is observed. Noticeably, ErFe2O4-δ single crystal exhibits the field-cooled hysteresis loop shift and training effect below 200 K, suggesting the occurrence of exchange bias effect originating from the spin glass phase.

Unveiling the impact of Ni doping on the structural, electronic, and magnetic properties of nanocrystalline FeCo2O4spinel oxide: A combined experimental andab initioinvestigations.

In the present work, nanocrystalline samples of compositions 〖Ni〗_x 〖Fe〗_(1-x) 〖Co〗_2 O_4 (x = 0.0, 0.25, 0.50, and 0.75) have been synthesized via co-precipitation method by annealing at 900 oC. The nanocrystalline samples of compositions Ni0.25Fe0.75Co2O4 (D0.25) and Ni0.5Fe0.5Co2O4 (D0.5) crystallize in a pure spinel phase, whereas Ni0.75Fe0.25Co2O4 (D0.75) show the existence of secondary phase of NiO, as confirmed by the X-ray diffraction analysis. The particle size and lattice strain in the samples both decrease as Ni substitution is increased. The field-dependent dc magnetization M(H) virgin curve measured at 5 K for sample D0.75 shows the existence of field-induced metamagnetic transition, while this behavior is absent in samples D0.5 and D0.25. Dynamic magnetic properties have been investigated by ac susceptibility measurement, which shows a strong frequency dependence behavior resulting from the blocking/spin-glass freezing states depending upon the amount of Ni substitution and the range of measurement temperature. High-resolution X-ray photoelectron spectroscopy (HR-XPS) analysis reveals the presence of mixed valence states of Fe2+/Fe3+, Co2+/Co+3, and Ni2+/Ni+3 in all samples. Using first principles-based Density Functional Theory (DFT) calculations with HSE06 exchange-correlation functional predicts the correct description of ground state which is ferrimagnetic and insulating in their inverse spinel case for D0.25, D0.5, and D0.75 samples that agreed well with our experimental observations. A closer look at the electronic structure near the Fermi level (EF) of Ni-doped samples suggests a typical Mott-Hubbard insulating state while it is found to be a mixture of charge-transfer and Mott-Hubbard insulating state for parent compound FeCo2O4. The obtained spin-dependent gap hierarchy can have possible application in spintronics. We have studied a detailed correlation between experiment and theory.

Design of Quench Detection System for Background DC Magnet in the Conductor Performance Research Platform of CRAFT

Design of Quench Detection System for Background DC Magnet in the Conductor Performance Research Platform of CRAFT

Effect of carbon ion implantation on the superconducting properties of MgB2 bulks prepared by powder-in-sealed-tube method

We studied the effect of carbon (C) ion implantation on the microstructure and superconducting properties of bulk MgB2 prepared by the powder-in-sealed-tube (PIST) method. FESEM and TEM analysis indicate microstructural changes due to carbon ion implantation. DC magnetization measurements reveal a slight improvement of TC and small ΔTC values due to ion implantation. The JC(B) characteristics of implanted samples show a significant enhancement of JC compared with pristine MgB2 at 10 and 20 K. MgB2 samples implanted with 80 keV carbon ions with a dose of 2 × 1016 ions cm−2 show maximum enhancement in JC i.e., 2.07 × 105 A/cm2 at 5 T and 10 K. The flux pinning force density curves are theoretically analyzed using the Dew-Hughes model. The results reveal that significant enhancements in the flux pinning properties are contributed by the normal point defects caused by carbon ion implantation, which acts as a strong pinning center.

Ocean current turbine power take-off design using fluid dynamics and towing tank experiments

This study investigates the performance and power generation capabilities of a small-scale hydrokinetic turbine by comparing numerical simulations with experimental measurements. The key difference between the two models comes from the initial numerical analysis which focused only on the permanent magnet DC motor (PMDC) motor’s parameters and did not account for the gear-head reduction that leads to discrepancies in current and torque predictions, especially at lower input voltages. In practice, friction losses within the gear-head increased the required current and torque, highlighting inefficiencies in the motor gear-head system. A modified experimental setup incorporated a magnetic coupling to address leakage issues and enhance system reliability. While the magnetic coupling resulted in a slight reduction in speed, current, and torque, it improved the overall integrity of the system which is essential for marine applications. The comparison between experimental results and Blade Element Momentum (BEM) simulations showed good agreement at lower speeds, but the simulations under-predicted power at higher speeds, likely due to the model’s limitations in capturing complex hydrodynamic phenomena. This shows the need for comprehensive analysis, integrating both numerical and experimental approaches to optimize turbine performance. Future research will focus on refining experimental methodologies and further improving turbine design and efficiency for hydrokinetic energy systems.

Ocean current turbine power take-off design using fluid dynamics and towing tank experiments

This study investigates the performance and power generation capabilities of a small-scale hydrokinetic turbine by comparing numerical simulations with experimental measurements. The key difference between the two models comes from the initial numerical analysis which focused only on the permanent magnet DC motor (PMDC) motor’s parameters and did not account for the gear-head reduction that leads to discrepancies in current and torque predictions, especially at lower input voltages. In practice, friction losses within the gear-head increased the required current and torque, highlighting inefficiencies in the motor gear-head system. A modified experimental setup incorporated a magnetic coupling to address leakage issues and enhance system reliability. While the magnetic coupling resulted in a slight reduction in speed, current, and torque, it improved the overall integrity of the system which is essential for marine applications. The comparison between experimental results and Blade Element Momentum (BEM) simulations showed good agreement at lower speeds, but the simulations under-predicted power at higher speeds, likely due to the model’s limitations in capturing complex hydrodynamic phenomena. This shows the need for comprehensive analysis, integrating both numerical and experimental approaches to optimize turbine performance. Future research will focus on refining experimental methodologies and further improving turbine design and efficiency for hydrokinetic energy systems.

Coexistence of Superconductivity and Magnetic Ordering in the In-Ag Alloy Under Nanoconfinement.

The impact of the interface phenomena on the properties of nanostructured materials is the focus of modern physics. We studied the magnetic properties of the nanostructured In-Ag alloy confined within a porous glass. The alloy composition was close to the eutectic point in the indium-rich range of the phase diagram. Temperature dependences of DC magnetization evidenced two superconducting transitions at 4.05 and 3.38 K. The magnetization isotherms demonstrated the superposition of two hysteresis loops with low and high critical fields below the second transition, a single hysteresis between the transitions and ferromagnetism with weak remanence in the normal state of the alloy. The shape of the loop seen below the second transition, which closes at a low magnetic field, corresponded to the intermediate state of the type-I superconductor. It was ascribed to strongly linked indium segregates. The loop observed below the first transition is referred to as type-II superconductivity. The secondary and tertiary magnetization branches measured at decreasing and increasing fields were shifted relative to each other, revealing the proximity of superconducting and ferromagnetic phases at the nanometer scale. This phenomenon was observed for the first time in the alloy, whose components were not magnetic in bulk. The sign of the shift shows the dominant role of the stray fields of ferromagnetic regions. Ferromagnetism was suggested to emerge at the interface between the In and AgIn2 segregates.

Effect of Substituents in Equatorial Hexaazamacrocyclic Schiff Base Ligands on the Construction and Magnetism of Pseudo D6h Single-Ion Magnets.

Three mononuclear DyIII compounds [DyL1(Ph3SiO)2][BPh4]·MeCN·2H2O (1), [DyL2(Ph3SiO)2][BPh4]·C2H5OH·H2O (2), and [DyL3(Ph3SiO)(OAc)][BPh4]·CH3OH·3H2O (3) and their corresponding YIII diluted analogues [Dy0.0967Y0.9033L1(Ph3SiO)2][BPh4]·MeCN·2H2O (1@Y), [Dy0.2668Y0.7332L2(Ph3SiO)2][BPh4]·C2H5OH·H2O (2@Y), and [Dy0.1260Y0.8740L3(Ph3SiO)(OAc)][BPh4]·CH3OH·3H2O (3@Y) were synthesized with hexaazamacrocyclic Schiff base ligands as an equatorial ligand. The substituents in the equatorial hexaazamacrocyclic Schiff base ligand show a significant effect on the replacement of the axial ligands. Compounds 1, 2, and 3 are typical zero dc field single-molecule magnets with effective energy barriers (Ueff) of 1092(6), 946.1(7), and 150.1(9) K, respectively. Although the effective energy barriers of 1 and 2 are close, the magnetic hysteresis remains open up to 20 K for 1, twice as large as that of 2 (10 K), which is different from the previously reported compounds, probably due to nonplanarity N6 in the equator. Ab initio calculations indicate that the ground states of compounds 1 and 2 exhibit high anisotropy and pure second and third excited states, while compound 3 exhibits pure ground-state anisotropy and highly mixed excited states, leading to the easy occurrence of quantum tunneling of magnetization between the ground and excited states in compound 3. This work indicates that the substituents in equatorial hexaazamacrocyclic Schiff base ligands have a significant effect on the construction and magnetic properties of DyIII SIMs with D6h symmetry.

Superparamagnetic Relaxation in Ensembles of Ultrasmall Ferrihydrite Nanoparticles

The paper examines the impact of interparticle interactions on the superparamagnetic relaxation of ultrasmall nanoparticle ensembles, using Fe2O3∙nH2O iron oxyhydroxide (ferrihydrite) nanoparticles as an example. Two samples were analyzed: ferrihydrite of biogenic origin (with an average particle size of d ≈ 2.7 nm) with a natural organic shell, and a sample (with d ≈ 3.5 nm) that underwent low-temperature annealing, during which the organic shell was partially removed. The DC and AC magnetic susceptibilities (χ′(T), χ′′(T)) in a small magnetic field in the superparamagnetic (SPM) blocking region of the nanoparticles were measured. The results show that an increase in interparticle interactions leads to an increase in the SPM blocking temperature from 28 to 52 K according to DC magnetization data. It is shown that below the SPM blocking temperature, magnetic interactions of nanoparticles lead to the formation of a collective state similar to spin glass in bulk materials. The scaling approach reveals that the dynamics of correlated magnetic moments on the particle surface slow down with increasing interparticle interactions. Simulation of χ′′(T) dependence has shown that the dissipation of magnetic energy occurs in two stages. The first stage is directly related to the blocking of the magnetic moment of nanoparticles, while the second stage reflects the spin-glass behavior of surface spins and strongly depends on the strength of interparticle interactions.

Investigating the multifunctionality of Cu2+ doped LaSrMnO3: understanding structural, optical, and magnetic responses

Abstract This study examines the impact of copper ions (Cu2+) on the structural, optical, and magnetic, characteristics of La0.6Sr0.4Mn1-xCuxO3 (LSMCO) manganites. Various techniques, including X-ray diffraction, field emission scanning electron microscopy, Raman spectroscopy, DC magnetization, and photoluminescence measurements were employed for a comprehensive analysis. Structural examinations revealed that all compositions exhibit a single-phase orthorhombic structure. Raman spectroscopy reveals the structural distortion due to the inclusion of Cu at Mn site. The photoluminescence properties of the manganite were found to be influenced by the excitation wavelength, demonstrating energy transfer from Mn ions. Magnetic investigations indicated that the introduction of Cu leads to a reduction in the saturation magnetization of the manganite.

Manganese diluted TlInS2 layered semiconductor: Optical, electronic and magnetic properties

Manganese–doped TlInS2 (TlInS2+Mn) layered semiconductors with different doping concentrations of about 0.1 and 0.3 at. percent were investigated. Photo–induced current transient spectroscopy (PICTS) measurements in the temperature range of 80 and 300 K have been made for identifying energy levels related to Mn dopant within the electronic bandgap of TlInS2+Mn crystal. Optical absorption spectra in the photon energy range of ∼1.8–3.1 eV have been extracted by fitting the transmittance spectra of TlInS2+Mn recorded at the temperatures varied from ∼40–300 K. A redshift trend of the absorption edge with increasing of temperature was observed. On the other hand, a blue shift in the absorption edge with Mn doping was observed in the absorption spectra. The Mn dopant induced photoluminescence (PL) was also investigated in the visible region ranging from 320 to 960 nm. Seven peaks were observed in the PL spectra of Mn doped TlInS2 crystal in the regions both ∼960–620 nm (∼1.3–2 eV) and ∼620–320 nm (∼2–3.8 eV) due to the electronic states of Mn ions. Laser–induced breakdown spectroscopy (LIBS) technique was applied to establish of the elemental chemical composition and to confirm presence of each constituent element in TlInS2:Mn. The dc magnetization measurements of TlInS2+Mn performed in a wide temperature range of ∼5 and ∼300 K revealed different (diamagnetic and paramagnetic states) magnetic phases inside the studied temperature range. The X–band electron paramagnetic resonance (ESR) experiments were carried out in the low–temperature phase of TlInS2+Mn to probe the structure of Mn centers in TlInS2. The measurements revealed that the ESR spectrum changes drastically in the low–temperature phase of TlInS2+Mn bulk sample. Finally, a detailed density functional theory (DFT) based computational investigation of electronic band structures, density of states and optical properties of TlInS2+Mn compound has been performed. The results of ab–initio calculations are discussed for three possible states when the manganese atom was doped by replacing either the Tl, In or S atoms in the unit cell of TlInS2. Additionally, the effect of interstitial Mn dopant on the electronic structure and optical properties of TlInS2 material has been simulated.

Effect of charge-discharge with higher capacitance performance of Ni-substituted CoFe2O4 magnetic nanoparticles for energy storage

In this work, we synthesized NixCo1-xFe2O4 (0 ≤ x ≤ 0.8) magnetic nanoparticles (MNPs) by using ultrasonication-assisted reverse chemical co-precipitation method. The X-ray diffraction (XRD) patterns confirm the single-phase with mixed spinel structure of the NixCo1-xFe2O4 (0 ≤ x ≤ 0.8) MNPs with the crystallite size range between 12 nm - 17 nm. The molecular dynamics and oleic acid coated Ni-substituted CoFe2O4 magnetic nanoparticles were confirmed by FTIR measurements. The surface composition of NixCo1-xFe2O4 (0 ≤ x ≤ 0.8) MNPs (Ni, Co, Fe and O) and their oxidation states were estimated using X-ray photoelectron spectroscopy. The NixCo1-xFe2O4 (0 ≤ x ≤ 0.8) MNPs are spherical in shape and polycrystalline in nature, confirmed by FESEM and HRTEM measurements. The Ni-substituted CoFe2O4 MNPs with higher zeta potential (ζ) from −24 mV to -41 mV with an increase in Ni concentration, signifies the stable colloidal stability due to the electrostatic repulsion between MNPs. The DC magnetization (M-vs-H) measurements reveal the ferrimagnetic behavior of NixCo1-xFe2O4 (0 ≤ x ≤ 0.8) MNPs, which suppress the saturation magnetization (MS) from 48.6 emu/g to 5.3 emu/g with the enhanced coercivity (HC) from 335 Oe to 1700 Oe with the substitution of Ni2+ ions is in corroboration with electron paramagnetic resonance (EPR) measurements. The enhanced EPR resonance field (Hres = 2335 Oe - 3261 Oe) with the substitution of Ni2+ ions is attributed to the generation of oxygen vacancies and defects, which are predominant in Ni0.8Co0.2Fe2O4, resulting in significantly enhanced electrochemical performance. Therefore, the three-electrode system was utilized to investigate the electrochemical properties of NixCo1-xFe2O4 (0 ≤ x ≤ 0.8) MNPs. The Ni-substituted CoFe2O4 MNPs have demonstrated significantly enhanced capacity retention of 77 % even after 5000 cycles in 1 M H2SO4 electrolyte solution. NixCo1-xFe2O4 (0 ≤ x ≤ 0.8) MNPs exhibit an excellent specific capacity (Cs) of 794.5 F/g at a current density of 1 A/g, signifies the rate of redox reaction at surface electrolyte interface (SEI) is greatly influenced by the surface to volume ratio. Thus, with the enhancement of Ni2+ ions, redox reaction kinetics might become more efficient resulting in the enhanced charge storage capacity.

Magnetic properties and linear negative magnetocapacitance in rutile like LiFe2SbO6

Abstract We report the high-temperature magnetic ordering and the observation of linear negative magnetocapacitance mediated by a low-temperature magnetic phase crossover in the compound LiFe2SbO6. The combined observations of the absence of a second harmonic generation (SHG) signal, and Rietveld refinements of X-ray and neutron powder diffraction (NPD) patterns of the sample confirm that LiFe2SbO6 crystalizes in a centrosymmetric Pnnm structure. The DC magnetization measurements reveal that an antiferromagnetic ordering sets in at high temperature (TN= 850). The magnetic anomaly in the DC magnetization at a lower temperature T = 13 K, is corroborated by AC susceptibility and the specific heat measurements. We observe a linear negative magnetocapacitance below T = 13 K, demonstrating an indirect magneto-dielectric coupling. Further, the neutron powder diffraction study reveals a collinear antiferromagnetic ordering with a wavevector k = (0, 0, 0).

Superconducting Magnetic Energy Storage-Based DC Circuit Breaker for HVDC Applications

Superconducting Magnetic Energy Storage-Based DC Circuit Breaker for HVDC Applications

Freezing of short-range ordered antiferromagnetic clusters in the CrFeTi2O7system.

We report on the CrFeTi2O7(CFTO) system using a combination of x-ray diffraction, dc magnetization, ac susceptibility, specific heat and neutron diffraction measurements. CFTO is seen to crystallize in a monoclinic P21/a symmetry. It shows a glassy freezing at Tf ~ 22 K, characterized by the observation of bifurcation between ZFC and FC χ (T) curves, frequency dispersion across Tf in ac susceptibility, and follows Vogel-Fulcher and power law type critical dynamics, very slow relaxation of iso-thermal remanent magnetization with time and the absence of an anomaly in the temperature dependence of specific heat measurements. The microscopic neutron diffraction analysis of CFTO not only confirms the absence of long-range antiferromagnetic ordering but also exhibits diffuse scattering due to the presence of short-range ordered antiferromagnetically correlated spin clusters.&#xD.

Anisotropic spin-glass-like behavior in single crystal GdCo2B2

A high-quality single crystal of GdCo2B2 was successfully synthesized and subjected to a comprehensive investigation into its spin-glass characteristics. We conducted a systematic analysis of magnetization, aging effects, and alternating current (AC) susceptibility. Interestingly, a clear separation was observed between the zero-field-cooled (ZFC) and field-cooled (FC) magnetization curves under low magnetic field of 0.01 T. Furthermore, the crystal exhibited a long-time relaxation behavior at 4 K. The freezing temperature increases with frequency increasing. Additionally, we explored the response of the crystal to DC magnetization and AC susceptibility under different pressure conditions, up to 1.58 GPa. The crystal exhibits three anomalies TC = 22.0 K, T1 = 20.5 K and TN = 11.0 K under ambient pressure. An analysis of the anisotropy of the spin-glass-like behavior in the crystal was conducted, with a specific focus on the a-axis as the preferred direction of magnetization. All of the results provide evidence for the coexistence of mixed ordering states in the crystal.

Performance enhancement of permanent magnet DC motor with sepic converter through higher order sliding surface

Performance enhancement of permanent magnet DC motor with sepic converter through higher order sliding surface

Observation of competing interactions and field-induced ferromagnetism in noncentrosymmetric cubic Nd3Te4 lattice

Unconventional magnetism is key to advancement in a variety of spintronic applications and thus needs to be explored in new materials. Here, we report the in-depth magnetic studies of noncentrosymmetric Nd3Te4 and findings support the existence of Dzyaloshinskii-Moriya interaction in addition to symmetric exchange interaction among the moments. The large magnetic irreversibility with negative magnetization in M(T) data and associated first-order magnetic transition in isothermal magnetization data suggest the competing interactions resulting in multiple magnetic phases. The gradual evolution of magnetic texture has been probed by changes in the magnetization entropy having interesting characteristics like the inverse magnetocaloric effect. Most importantly, we have probed the existing nontrivial magnetic phase under a low applied magnetic field by ac-χ(T, H) and dc magnetization (M − H) data, having the same critical field in both measurements. The existence of multiple magnetic phases which are interconnected through first-order field-induced magnetic phase transitions have been probed at low field. The transition from paramagnetic to field-induced state for larger applied fields follows a second-order.

Zernike radial basis neural network control of DC–DC power converter driven permanent magnet DC motor: design and experimental validation

Zernike radial basis neural network control of DC–DC power converter driven permanent magnet DC motor: design and experimental validation

Research on Pretension Bending of Layer Coil for 15 T DC Magnet

Research on Pretension Bending of Layer Coil for 15 T DC Magnet