Magnetic Structure Research Articles

Unity gives strength: combining Bertaut's and Belov's concepts and the formalism of aperiodic crystals to solve magnetic structures of unprecedented complexity.

We draw attention to the exceptional work of Geers et al. [(2024). IUCrJ, 11, https://doi.org/10.1107/S2052252524008583] on the analysis of magnetic phases, in which challenging magnetic structures are determined by a combination of modern computational methods and a connection between nuclear modulation and the ordering of magnetic moments is shown.

Dynamics and structure of network magnetic fields: Supergranular vortex expansion-contraction

Abstract We report on the formation of a large magnetic coherent structure in a vortex expansion-contraction interval, resulting from the merger of two plasmoids driven by a supergranular vortex observed by Hinode in the quiet-Sun. Strong vortical flows at the interior of vortex boundary are detected by the localized regions of high values of the Instantaneous Vorticity Deviation, and intense current sheets in the merging plasmoids are detected by the localized regions of high values of the Local Current Deviation. The spatiotemporal evolution of the line-of-sight magnetic field, the horizontal electric current density, and the horizontal electromagnetic energy flux is investigated by elucidating the relation between velocity and magnetic fields in the photospheric plasma turbulence. A local and continuous amplification of magnetic field from 286 G to 591 G is detected at the centre of one merging plasmoid during the vortex expansion-contraction interval of 60 min. During the period of vortex contraction of 22.5 min, the line-of-sight magnetic field at the centre of plasmoid-1 (2) exhibits a steady decrease (increase), respectively, indicating a steady transfer of magnetic flux from plasmoid-1 to plasmoid-2. At the end of the vortex expansion-contraction interval, the two merging plasmoids reach an equipartition of electromagnetic energy flux leading to the formation of an elongated magnetic coherent structure encircled by a shell of intense current sheets. Evidence of the disruption of a thin current sheet at the turbulent interface boundary layers of two merging plasmoids is presented.

Reentrant multiple-q magnetic order and a “spin meta-cholesteric” phase in Sr3Fe2O7

Topologically nontrivial magnetic structures such as skyrmion lattices are well known in materials lacking lattice inversion symmetry, where antisymmetric exchange interactions are allowed. Only recently, topological multi-q magnetic textures that spontaneously break the chiral symmetry, for example, three-dimensional hedgehog lattices, were discovered in centrosymmetric compounds, where they are instead driven by frustrated interactions. Here we show that the bilayer perovskite Sr3Fe2O7, previously believed to adopt a simple single-q spin-helical order, hosts two distinct types of multi-q spin textures. Its ground state represents a novel multi-q spin texture with unequally intense spin modulations at the two ordering vectors. This is followed in temperature by a new “spin meta-cholesteric” phase, in which the chiral symmetry is spontaneously broken along one of the crystal directions, but the weaker orthogonal modulation melts, giving rise to intense short-range dynamical fluctuations. Shortly before the transition to the paramagnetic state, vortex-crystal order spanned by two equivalent q vectors emerges. This renders Sr3Fe2O7 an ideal material to study transitions among multiple-q spin textures in a centrosymmetric host.

Current-Induced Field-Free Switching of Co/Pt Multilayer via Modulation of Interlayer Exchange Coupling and Magnetic Anisotropy

Current-induced field-free magnetic switching using spin–orbit torque has been an important topic for decades due to both academic and industrial interest. Most research has focused on introducing symmetry breakers, such as geometrical and compositional variation, pinned layers, and symmetry-broken crystal structures, which add complexity to the magnetic structure and fabrication process. We designed a relatively simple magnetic structure, composed of a [Co/Pt] multilayer and a Co layer with perpendicular and in-plane magnetic anisotropy, respectively, with a Cu layer between them. Current-induced deterministic magnetic switching was observed in this magnetic system. The system is advantageous due to its easy control of the parameters to achieve the optimal condition for magnetic switching. The balance between magnetic anisotropic strength and interlayer coupling strength is found to provide the optimal condition. This simple design and easy adjustability open various possibilities for magnetic structures in spin-based electronics applications using spin–orbit torque.

Mitigating the Kinetic Hysteresis of Co-Free Ni-Rich Cathodes via Gradient Penetration of Nonmagnetic Silicon.

Co-free Ni-rich layered oxides are considered a promising cathode material for next-generation Li-ion batteries due to their cost-effectiveness and high capacity. However, they still suffer from the practical challenges of low discharge capacity and poor rate capability due to the hysteresis of Li-ion diffusion kinetics. Herein, based on the regulation of the lattice magnetic frustration, the Li/Ni intermixing defects as the primary origin of kinetic hysteresis are radically addressed via the doping of the nonmagnetic Si element. Meanwhile, by adopting gradient penetration doping, a robust Si-O surface structure with reversible lattice oxygen evolution and low lattice strain is constructed on Co-free Ni-rich cathodes to suppress the formation of surface dense barrier layer. With the remarkably enhanced Li-ion diffusion kinetics in atomic and electrode particle scales, the as-obtained cathodes (LiNixMn1-xSi0.01O2, 0.6≤x≤0.9) achieve superior performance in discharge capacity, rate capability, and durability. This work highlights the coupling effect of magnetic structure and interfacial chemicals on Li-ion transport properties, and the concept will inspire more researchers to conduct an intensive study.

Mitigating the Kinetic Hysteresis of Co‐Free Ni‐Rich Cathodes via Gradient Penetration of Nonmagnetic Silicon

AbstractCo‐free Ni‐rich layered oxides are considered a promising cathode material for next‐generation Li‐ion batteries due to their cost‐effectiveness and high capacity. However, they still suffer from the practical challenges of low discharge capacity and poor rate capability due to the hysteresis of Li‐ion diffusion kinetics. Herein, based on the regulation of the lattice magnetic frustration, the Li/Ni intermixing defects as the primary origin of kinetic hysteresis are radically addressed via the doping of the nonmagnetic Si element. Meanwhile, by adopting gradient penetration doping, a robust Si−O surface structure with reversible lattice oxygen evolution and low lattice strain is constructed on Co‐free Ni‐rich cathodes to suppress the formation of surface dense barrier layer. With the remarkably enhanced Li‐ion diffusion kinetics in atomic and electrode particle scales, the as‐obtained cathodes (LiNixMn1−xSi0.01O2, 0.6≤x≤0.9) achieve superior performance in discharge capacity, rate capability, and durability. This work highlights the coupling effect of magnetic structure and interfacial chemicals on Li‐ion transport properties, and the concept will inspire more researchers to conduct an intensive study.

Accreting Neutron Stars in 3D General-relativistic Magnetohydrodynamic Simulations: Jets, Magnetic Polarity, and the Interchange Slingshot

Abstract Accreting neutron stars differ from black holes by the presence of the star’s own magnetic field, whose interaction with the accretion flow is a central component in understanding these systems’ disk structure, outflows, jets, and spin evolution. It also introduces an additional degree of freedom, as the stellar dipole can have any orientation relative to the inner disk’s magnetic field. We present a suite of 3D general-relativistic magnetohydrodynamic simulations in which we investigate the two extreme polarities, with the dipole field being either parallel or antiparallel to the initial disk field, in both the accreting and propeller states. When the magnetosphere truncates the disk near or beyond the corotation radius, most of the system’s properties, including the relativistic jet power, are independent of the star–disk relative polarity. However, when the disk extends well inside the corotation radius, in the parallel orientation the jet power is suppressed and the inner disk is less dense and more strongly magnetized. We suggest a physical mechanism that may account for this behavior—the interchange slingshot—and discuss its astrophysical implications. When the star is in the rapidly accreting regime, which in most cases will be associated with strong spin-up, we expect large observational differences between the two magnetic orientations. This may be reflected in increased variability as the accretion flow drags in successive magnetic structures of varying polarity.

Modeling the Effects of a Light Bridge on Properties of Magnetohydrodynamic Waves in Solar Pores

Solar pores are ideal magnetic structures for wave propagation and transport of energy radially outwards across the upper layers of the solar atmosphere. We aim to model the excitation and propagation of magnetohydrodynamic waves in a pore with a light bridge modeled as two interacting magnetic flux tubes separated by a thin, weaker-field layer. We solve the three-dimensional magnetohydrodynamic equations numerically and calculate the circulation as a measure of net torsional motion. We find that the interaction between flux tubes results in the natural excitation of propagating torsional Alfvén waves but find no torsional waves in the model with a single flux tube. The torsional Alfvén waves propagate with wave speeds matching the local Alfvén speed where wave amplitude peaks.

Feature extraction and classification of microstructure and magnetic tomography images of an advanced Nd-Fe-B sintered magnet

Abstract Although the microstructure and magnetic tomography images of an advanced Nd-Fe-B sintered magnet were previously reported [Takeuchi, SO., NPG Asia Mater. 14, 70 (2022)], the relationship between these three-dimensional images has not been well analyzed. In this work, a feature extraction method of histogram of oriented gradients and a classification method of uniform manifold approximation and projection are employed for this issue. The microstructural features with superimposing the information of magnetic domain structure are classified into two groups depending on the external magnetic field, resulting in the different microstructural features for the different magnetization states are successfully classified. These differences of the microstructural features are difficult to be found by human recognition. Further detailed analysis of these microstructural features may clarify the key microstructures for the nucleation of reversed domains and their propagations.

Parametric Excitation and Instabilities of Spin Waves Driven by Surface Acoustic Waves

AbstractThe parametric excitation of spin waves by coherent surface acoustic waves in metallic magnetic thin film structures is demonstrated experimentally using Brillouin light scattering spectroscopy. Complementary micromagnetic simulations and analytical modeling reveal that, depending on the experimental conditions, the spin‐wave instabilities originate from different phonon‐magnon and magnon‐magnon scattering processes. This opens novel ways to create micro‐scaled nonlinear magnonic systems for logic and data processing that profit from the efficient excitation of phonons using piezoelectricity.

Unraveling Magnet Structural Defects in Permanent Magnet Synchronous Machines—Harmonic Diagnosis and Performance Signatures

Rare-earth-based permanent magnets (PMs) have a vital role in numerous sustainable energy systems, such as electrical machines (EMs). However, their production can greatly harm the environment and their supply chain monopoly presents economic threats. Alternative materials are emerging, but the use of rare-earth PMs remains dominant due to their exceptional performance. Damage to magnet structure can cause loss of performance and efficiency, and propagation of cracks in PMs can result in breaking. In this context, prolonging the service life of PMs and ensuring that they remain damage-free and suitable for re-use is important both for sustainability reasons and cost management. This paper presents a new harmonic content diagnosis and motor performance analysis caused by various magnet structure defects or faults, such as cracked or broken magnets. The proposed method is used for modeling the successive physical failure of the magnet structure in the form of crack formation, crack growth, and magnet breakage. A surface-mounted permanent magnet synchronous motor (PMSM) is studied using simulation in Ansys Maxwell software (Version 2023), and different cracks and PM faults are modeled using the two-dimensional finite element method (FEM). The frequency domain simulation results demonstrate the influence of magnet cracks and their propagation on EM performance measures, such as stator current, distribution of magnetic flux density, back EMF, flux linkage, losses, and efficiency. The results show strong potential for application in health monitoring systems, which could be used to reduce the occurrence of in-service failures, thus reducing the usage of rare-earth magnet materials as well as cost.

Deconvolution of X-ray natural and magnetic circular dichroism in chiral Dy-ferroborate.

Structural chirality and magnetism, when intertwined, can have profound implications on materials properties. Using X-ray imaging and spectroscopic measurements that leverage the natural and magnetic circular dichroic effects present in magnetized chiral crystal structures, we probe the interplay between chirality and magnetism across the field-induced spin-flop transition of Dy ferroborate, ( ) . Deconvolution of natural and magnetic circular dichroic signals at the Fe K and Dy L absorption edges of the non-centrosymmetric structure was enabled by use of tunable temperature and magnetic field, providing access to element-specific magnetic information across the spin-flop transition. The magnetic response of Fe and Dy sublattices was found to be independent of domain chirality. The chiral domains were robust against both the (chirality preserving) R32 to P3 21/P3 21 structural phase transition at 280 K, and application of magnetic field up to 4 Tesla. A third flavor of X-ray dichroism, magneto-chiral dichroism, was not detected within the accuracy of our measurements. The absence of significant Fe magnetization along the screw, c-axis for the magnetic field strength used in this study, together with non-linear coupling of magnetic field to electric polarization across the spin-flop transition, may hinder observation of magneto-chiral dichroic effects in this system.

Structural order and disorder within novel antiferromagnetic RCrxGa3-yGey and R4Cr1-xGa12-yGey intermetallic compounds (R = Tb, Dy)

Single crystals of intermetallic phases RCrxGa3−yGey (R = Tb, Dy; x = 0.19–0.23, y = 0–0.4) and R4Cr1−xGa12−yGey (R = Tb, Dy; x = 0–0.13, y = 3–4) were grown from Ga flux ensuring the absence of magnetic impurities. The X-ray diffraction experiments revealed that the compounds belong to the family of filled AuCu3-type gallides. The compounds are formed upon the insertion of Cr atoms into E6 octahedral voids (E = Ga/Ge), which can occur in either disordered (RCrxGa3-yGey) or ordered (R4Cr1-xGa12-yGey) fashion. The unique feature of the obtained compounds is the strong correlation between the level of Ge doping and the Cr concentration in the phases, which allows one to control both the structural and magnetic ordering. At low Ge concentration, the cubic RCrxGa3-yGey phases form, which then experience tetragonal distortion upon the increase in the Ge content, and the cubic R4Cr1-xGa12-yGey 2×2×2 superstructures are formed at even higher Ge concentrations. The X-ray diffraction analysis also showed a presence of structural defects in the phases, which are caused by different size of empty E6 and filled CrE6 octahedra. Magnetic measurements of the single crystals of the cubic phases reveal antiferromagnetic ordering of the rare earth sublattice with the Neel temperatures decreasing upon Ge doping from 22 K for RCrxGa3 to 10 K for R4Cr1−xGa12−yGey. The Ge doping causes gradual decrease in the strength of antiferromagnetic R-R interactions ultimately leading to noncollinear magnetic structure in the superstructure R4Cr1−xGa12−yGey phases.

Interplay between magnetisation dynamics and structure in MnCoGe thin films

Interplay between magnetisation dynamics and structure in MnCoGe thin films

Magnetic structure and colossal dielectric properties in Ga3+ substituted Zn2Y hexaferrites by chemical co-precipitation method

Y-type Ba0.5Sr1.5Zn2Fe12-xGaxO22 (x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) hexaferrites are prepared through modified chemical co-precipitation method. X-ray diffraction (XRD) results reveal that these samples are single-phase and the space group is R3‾m. The field-emission scanning electronic microscope (FE-SEM) measurements indicate that the grains are hexagonal-plate with a diameter of 2–5 μm. In the M-T diagrams, various magnetic structures are modulated, including proper-screw, longitudinal conical (LC), mixed conical (MC), and collinear ferrimagnetic (collinear FIM). In this series of samples, the values of dielectric constant (ε′) achieve an order increase from 102 to 104. For the best x = 0.8 sample, the ε′ is as high as 1804.76 at 1 MHz and 300 K. In conclusion, Ba0.5Sr1.5Zn2Fe12-xGaxO22 with controllable magnetic structures and colossal dielectric constant are potential materials for miniaturization of modern electronic devices.

Core/Shell-Like Magnetic Structure and Optical Properties in CuO Nanoparticles Synthesized by Green Route

Core/Shell-Like Magnetic Structure and Optical Properties in CuO Nanoparticles Synthesized by Green Route

Evidence of Spin Reorientation from Γ4 to Γ2 and Sign Reversal Exchange Bias in CeCrO3 Nanoparticles

Herein, the temperature‐dependent magnetic structure and sign reversal exchange bias in CeCrO3 using magnetization data and time‐of‐flight neutron diffraction data which is given less attention among RCrO3 are investigated. While nuclear structural analysis using Rietveld refinement exhibits distorted orthorhombic structure within Pnma space group, temperature dependence of the magnetic structure using neutron diffraction reveals possible spin configurations, namely, Γ4, Γ2, and Γ1, within the temperature range of 6–300 K. Temperature‐dependent magnetization shows compensation temperature, Tcomp, at 58 K, spin reorientation temperature, TSR, at 15 K along with a Neel temperature, TN, at 260 K which is the outcome of the competition between canted antiferromagnetic ordering of Cr3+ ions and Ce3+ ions in CeCrO3. Furthermore, the magnetization versus magnetic field (M vs H) measurements indicate transition of the Γ4 spin structure to Γ2 spin structure around TSR which is further supported by reversible‐to‐irreversible changes observed in temperature‐dependent MFCC and MFCW. Moreover, a temperature‐driven sign reversal of exchange bias in CeCrO3 is observed, resulting from the competition between antiferromagnetic coupling between chromium moment (MCr) and cerium moment (MCe) in these nanoparticles. This intriguing behavior holds significant potential for the development of thermally assisted magnetic random access memory.

Tri-axial magnetic alignment and magnetic anisotropies in misfit-layered calcium-based cobaltites doped with rare-earth ions

In this study, we introduce an original method for quantifying tri-axial magnetic anisotropy in [Ca2CoO3-δ]0.62CoO2, and its rare earth (RE)-doped variants, [(Ca1-xREx)2CoO3-δ]0.62CoO2, utilizing a modulated rotating magnetic field of 10 T. Our findings reveal a significant correlation between the magnetic anisotropy and local structure of RE ions, particularly bond lengths and coordination numbers, which influence the magnetization axes of these magnetically aligned powders. We introduce an analytical methodology employing linear equations to calculate the magnetic susceptibilities along distinct crystallographic axes, enabling the prediction of tri-axial magnetic anisotropies at elevated concentrations of Er ions. This research not only advances our understanding of magnetic anisotropy control but also paves the way for the successful fabrication of triaxially-aligned ceramics using magneto-science techniques.

Magnetic vortex γ-Fe2O3 nanospheres decorated with gold nanoparticles for dual hyperthermia treatment

In this work, multifunctional systems with potential applications for dual control of thermal heat delivery are developed. For this purpose, the nanosystems produced consist of vortex iron oxide nanospheres (VIONS) decorated with different amounts of gold nanoparticles (AuNPs). The VIONS were synthesized using the solvothermal reduction method, resulting in a 204 ± 24 nm diameter and meeting the requirements for biomedical applications. Magnetic measurements revealed that these systems are composed mainly of maghemite (γ-Fe2O3), exhibiting relatively low coercivity and moderate saturation magnetization, both of which serve as indicative attributes of an exceptional magnetic vortex state as validated by electron holography microscopy. The decoration with gold NPs was achieved through deposition-precipitation, involving the deposition of gold hydroxide on the surface of the previously amine-modified iron oxide NPs, followed by the concurrent reduction of Au3+. Furthermore, the gold NP size modulation was investigated by consecutively adding Au3+ to obtain gold NPs that interact with light differently depending on their size. The study provides crucial information that can aid the decoration of magnetic iron oxide nanospheres with AuNPs with tailored magnetic and optical properties; consequently, they may be promising candidates for magnetic and photothermal hyperthermia based on three-dimensional magnetic vortex structures.

Strain-controlled switching of magnetic skyrmioniums in ultrathin nanodisks

Magnetic skyrmions and skyrmioniums have garnered significant attention due to their distinctive topologically nontrivial spin structures. Gaining a deep understanding of the magnetization dynamics of these structures and their interconversion processes is essential for fully leveraging their potential in magnetic storage technology. Here, the dynamics of strain-controlled generation and annihilation of skyrmions and skyrmioniums are investigated using phase field simulation methods. It is discovered that tensile strain can induce the transformation of a single domain into skyrmions and skyrmioniums, which can still exist stably after the strain is released. Notably, skyrmioniums demonstrate robust stability within a specific strain window of −0.2% to 0.5%. Beyond this, escalating the compressive strain magnitude induces a phase transition from skyrmioniums to skyrmions, culminating in a direct collapse to a single-domain state at a critical compressive strain of −0.8%. This study reveals that strain can effectively control a variety of topological magnetic domain structures and achieve their interconversion, providing guidance for the design of low-power, nonvolatile, multi-state spin storage devices.