Interaction Of Magma Research Articles

Estimation and uncertainty quantification of magma interaction times using statistical emulation

The evolution of volcanic plumbing systems, which controls the style and size of eruptions, is largely determined by processes at depths that are not observable. Scientists use numerical models to simulate these processes and compare the outputs with data on erupted products to understand the plumbing system and eruption processes. However, our ability to explore the parameter space in order to match petrological and geophysical observations is limited by the computational cost required for such simulations. As an alternative, we present a statistical emulator that can reproduce the numerical results as a function of a set of input parameters. This approach can be used to invert the observed distribution of whole rock chemistry to determine the duration of interaction between magmas preceding an eruption and identify the best matching input parameters. This method intrinsically includes error propagation, thus providing reliable confidence intervals for the relevant parameters of the numerical simulations.

The slab failure in Central Java (Indonesia): New insight into its tectonic setting and origin

The geochemical and tectonic characteristics of volcanic formations in Central Java, specifically the Sumbing-Slamet volcanics, were investigated to understand the processes associated with slab failure in the region. Through comprehensive geochemical analysis and comparison with other volcanic formations, insights into the magmatic evolution and tectonic settings of the Sumbing-Slamet volcanics were gained. The findings support the hypothesis of slab tearing beneath Central Java, as evidenced by distinct geochemical signatures and magmatic interactions observed in the Sumbing-Slamet volcanics. Geochemical data reveal medium to high potassium content (K2O = 0.77–2.32%), low Nb/Y (<0.6561), low TiO2 relative to Al2O3 [TiO2 < (−1.1610 + 0.1935 × Al2O3)], Th/La >0.2, as well as a wide range of Nb/La and Nb/Zr (0.14–0.89 and 0.0304–0.0744, respectively), notable depletions in high-field strength elements (HFSE; such as Nb, Ti), low to high Ta-anomaly (δTa = 0.21–1.03), and whole-rock isotopes of 87Sr/86Sr (0.704458–0.705800) and 143Nd/144Nd (0.513059–0.512766) demonstrate that they were formed from active continental margin (ACM) tectonics involving subducted sediment input. These magmatic processes likely resulted from the mixing of lithospheric and asthenospheric mantle sources due to slab failure in the northern part of Central Java. The research contributes to strengthening the geophysical view regarding the existence of slab tearing in Central Java, understanding the dynamic geological processes occurring in subduction zones, and emphasizing the importance of interdisciplinary approaches in studying such phenomena.

Platinum-Group Elements and Nb-Ta geochemistry of the Deccan basalts from Kumbharli and other Ghat sections and the Koyna Seismic Zone, Maharashtra (India): Crustal contamination and implication for sulfide saturation of the magma

The Deccan basalts from Kumbharli, Nadlapur, Bijaynagar, Hazarmacchi, and Surli Ghat sections (surface samples) and the Koyna borehole-7 (KBH-7, sub-surface samples) from Maharashtra (western India) demonstrate a two-stage crystallization process. Olivine and chromite were crystallized earlier in a shallow crustal magma chamber while clinopyroxene and plagioclase phenocrysts were crystallized in the sub-volcanic conduits forming the crystal mush, and carried to the surface by the evolved Fe-Ti-rich ascending basaltic magma. The high modal abundance of plagioclase at the top and clinopyroxene at the bottom part of the Kumbharli Ghat section is responsible for an increase in Sr and a decrease in Sc content towards the upper flows. The surface and sub-surface basalt samples contain Pd = 5–31 ppb, Pt = 4–15 ppb, Ir = 1–4 ppb, Ru = 1–3 ppb, and Rh = 3–5 ppb. Negative relations of Pd/Ir, Pd/Ru, and Pd/Rh with MgO from both sets of samples indicate partitioning of Ir, Ru, and Rh to early fractionated cumulus chromite (or olivine). Magnetite is a late crystallizing phase from the evolved Fe-Ti-rich basaltic magma. With an increasing modal abundance of magnetite, there is an increase of FeO total , TiO 2 , and V with Pd indicating fractionation of Pd by magnetite. Geochemical characters show that the surface basalt samples are less contaminated compared to the sub-surface KBH-7 basalts. High Nb (6.8–13.6 ppm) and low Ta (0.2–0.37 ppm) content and elevated Nb/Ta ratios of the surface samples from the ghat sections indicate the possible interaction of the basaltic magma with the carbonate metasomatized subcontinental lithospheric mantle (SCLM). On the other hand, a high degree of partial melting with limited crustal contamination can also elevate the Nb/Ta ratios of the basalts from the ghat sections. Deccan basalts from the study areas do not bear the signature of sulfide supersaturation and subsequent immiscible sulfide segregation. This is evidenced by their high chalcophile element concentrations (Ni = 79–103 ppm, Cu = 121–259 ppm) and ratios like Cu/Zr (≥ 1), Ni/MgO (13.7–21.8) with low Cu/Pd (2140–29938) compared to other Ni-Cu (PGE) sulfide mineralized continental flood basalts. The lack of crustal sulfur in the various contaminants is perhaps the main reason for this sulfide-undersaturated character of the Deccan basalts of the current study.

Fault–Dike–Magma Interactions Inferred from Transcrustal Conical Structures under Akutan Volcano

Abstract Volcano monitoring and eruption forecasting require accurate characterization of transcrustal magmatic structures to place volcanic unrest in context within the system where it occurs. Structural imaging using local seismicity is limited to seismogenic depths. Here, we exploit arrivals in teleseismic receiver functions that change polarity with backazimuth to image two surfaces beneath Akutan volcano in the Aleutian arc. The two surfaces delineate an upper to midcrustal inverted conical volume that deepens and thickens away from the volcanic center, with thicknesses of 3–13 km. The top of the volume is at depths of 2–3 km below sea level at distances of ∼5–15 km from the caldera center. The bottom is at depths of 7–15 km at the same distances, and the cone’s thickness increases outward from ∼5 to ∼10 km. The signal is best fit by a volume with anisotropy with fast symmetry planes that dip outward from the center and downward increases in shear velocity at both interfaces. The upper boundary coincides with the top of Akutan’s volcanotectonic (VT) seismogenic zone, with the VT seismicity exhibiting outward dipping planar features that match the anisotropic fast plane orientation within the volume. The bottom of the anisotropic volume is below the termination depth of the majority of the VT seismicity and is therefore likely associated with the brittle–ductile transition. Long-period (LP) events associated previously with magma movement are concentrated below the anisotropic VT volume. Because of the strong spatial association with VT seismicity, we interpret the volume as consisting of concentric outward dipping faults and dikes that align the seismogenic response to stress changes from magmatic processes. Our observations map this volume independent of the present-day seismicity distribution and thus provide a spatially more complete image of the magmatic system.

Mafic microgranular enclaves and magmatic fabrics in the Ediacaran granitoids of Saghro, Eastern Anti-Atlas: Insights into magma emplacement and tectonic evolution

The Saghro inlier in the Anti-Atlas belt of Morocco comprises several granitoids dating from 600 to 550 million years ago (Ma), which are overlain by a volcano-sedimentary series. In particular, the granodioritic plutons exhibit widespread enclaves, which is a tool for emplacements mode and magma interaction processus during the Ediacaran evolution of the Anti-Atlas belt. This paper presents a detailed field mapping, petrographic analysis, and deformation quantification of the mafic microgranular enclaves (MMEs) and their host granitoids to characterize the emplacement mode of the plutons and the origin of MMEs.Macroscopically, the MMEs are rounded to ellipsoidal shapes and characterized by sharp, crenulated contacts, fine-grained textures, and some of them include fragments of host rock and feldspar xenocrysts. Petrographically, the MMEs exhibit a range of compositions from gabbroic to quartz diorite, and they are characterized by the presence of acicular apatite, quartz-feldspar ocelli, poikilitic and zoned plagioclases, which are the result of mixing/mingling of mafic and felsic magmas during the genesis of MMEs. The magmatic structures and enclave's organization in Saghro granitoids indicate two styles of emplacement. The c. 600 Ma Iknioun granodiorite exhibits an S-sigmoidal structure, representative of a syntectonic emplacement model within a transpressive dextral movement along E-W shear zones. While, in the 580-560 Ma Oussilkane, Tagmout, Igoudrane, and Bou Teglimt plutons, the organization of magmatic flow and orientations of enclaves suggest that the magma was emplaced as a post-tectonic dome. The variation in emplacement mode and the decrease in deformation intensity from the c. a. 600 Ma in the Iknioun pluton to the 580-560 Ma for the others plutons indicate a progressive shift in deformation regime from transpressive during the middle Ediacaran to a transtensive regime in the late Ediacaran, highlighting the progressive transition from Pan-African/Cadomian orogeny to Cambrian rifting.

980-970 Ma Sette-Daban event of the Siberian craton: new geochronological and geochemical data, relationship to LIP and potential connection with other LIPs

ABSTRACT The paper presents new geological, geochronological, geochemical and Nd-Sr isotopic data on the Meso- Neoproterozoic dolerites of the Siberian Craton. New U-Pb baddeleyite and apatite ages of a E-W-trending dyke and two sills from southeastern Siberia are 982 ± 11, 977 ± 7, 970 ± 31 and 972 ± 60 Ma, respectively, extending the area of distribution of the event by more than 100 km to the north. The Sette-Daban intrusions are subalkalic mostly low-Ti dolerites, although high-Ti dolerites have been locally documented as well. Trace element abundances in dolerites vary from typical to E-MORB to OIB with arc-like signatures represented by high Th/Yb and low TiO2/Yb ratios. All dolerite samples display moderately positive εNd(t) values varying from +3.3 to +7.7 and indicating the magmas were derived from a depleted mantle source. E-MORB and OIB intrusions are attributed to the different degree of interaction of magma between the depleted asthenospheric mantle and regions within the sub-continental lithospheric mantle (SCLM) that were metasomatically enriched during earlier subduction events. Available data on Sette-Daban event distribution, composition and duration satisfy the characteristics of a typical Large Igneous Province (LIP). Similar age 1000–950 Ma mafic magmatism is also recognized in the Baltic and Amazonian cratons and can be potentially correlated with the Sette-Daban event.

Slab failure‐related magmatism in the Pinheiro Machado Complex, southern Dom Feliciano Belt, Brazil

In the Dom Feliciano Belt, Brazil, the Pinheiro Machado Complex (PMC) includes diorites, tonalites, granodiorites, syenogranites and granites, whose evolution is related to several magmatic pulses and complex petrogenetic processes. Two magmatic stages were identified (early and late), resulting in different rock subgroups. The geochemical data showed that the early magmatism was chemically affected by partial melting. Geochemical modelling results suggest that fractional crystallization processes with assimilation of around 40% from the crustal basement and the decoupling of assimilated magma are crucial for the PMC rocks' genesis. Geochemical data also show that during the early magmatism, the subsequent process of early diorite anatexis developed by heating and continuous activity of the underlying magma chamber possibly occurred at a melting rate of 5%–10%. The hybrid rocks have contributions from the mixing process related to early terms, showing geochemical correlations in the major element curves, for the early diorite and syenogranitic melt members, at 60%–50% and 50%–40%, respectively. Slab failure tectonic context is related to the multi‐intrusive events dynamics recorded in the studied rocks. Recharge and melting events of the recently formed crust due to the constant heating of new pulses of deep slab melting would explain the magmatic interactions observed in the Complex. The results demonstrate that the studied rocks crystallized in an open system, including mixing processes to form hybrid rocks, physical disaggregation and assimilation of early intrusions, truncation, dragging and erosion of early mushes by younger pulses.

Magmatic priming of a phreatic eruption sequence: the 2012 Te Maari eruptions at Mt Tongariro (New Zealand) imaged by magnetotellurics and seismicity

SUMMARY Magnetotelluric data from Mount Tongariro have been analysed using an unstructured tetrahedral finite-element inversion code that incorporates topography, which was not included in previous analysis of these data. Incorporating topography adds information, which stabilizes the resistivity inversion modelling, and for the first time allows details of the shallow hydrothermal system and its relationship with the underlying magmatic system to be resolved. Specifically, an electrically conductive zone between 4 and 12.5 km depth marks the underlying magmatic system, which is shown to directly connect via conductive pathways to the area where the most recent phreatic eruptions at Tongariro occurred in 2012. The resultant phreatic eruptions in 2012 August and November showed no new magmatic component to the eruption deposits. Nevertheless, by combining the magnetotelluric resistivity image with relocated seismicity, we can see that seismicity (a proxy for magma ascent) migrated from the top of the magmatic system into the hydrothermal system in the months preceding these eruptions. Magmatic interaction with the extant hydrothermal system likely caused the over pressurization for the phreatic eruption. This work highlights the utility of combining geophysical methods and petrological data to constrain phreatic eruption processes.

Origin of calcite by magma mixing in mingled rocks of the Ghansura Rhyolite Dome, Bathani volcano-sedimentary sequence, eastern India

Abstract The Ghansura Rhyolite Dome (GRD) is an integral part of the Bathani volcano-sedimentary sequence (BVSs), which in turn is a vital component of the Chotanagpur Granite Gneiss Complex (CGGC), eastern India. The rhyolite dome represents a shallow-level felsic magma chamber that underwent intrusion by basaltic magma during its evolution. The rocks present in the felsic dome such as basalts, rhyolites, and intermediate hybrid rocks preserve evidence of magma mixing and mingling. The objective of this contribution is to take into account, for the first time, that magma mixing processes can play an important role in the generation of calcite in magmatic rocks. The present study focuses on the mingled rocks exposed within the rhyolite dome. Previous reports have documented the existence of two distinct zones (mafic and felsic) interfacing each other in the mingled rocks of the rhyolite dome. The mafic zones dominantly consist of mineral phases such as actinolite, hornblende, biotite, plagioclase, ilmenite, calcite, and titanite. The felsic zones comprise quartz, K-feldspar, plagioclase, and biotite. When mafic magma intruded into the felsic magma chamber, interaction between the mafic and felsic magmas caused diffusion of H, Al, and K ions from the felsic to the mafic endmember. Such diffusive activities resulted in the breakdown of augite, already crystallized in the mafic magma, to form newer minerals like actinolite, hornblende, biotite, calcite, and ilmenite. The presence of ilmenite in the mingled rocks indicates the prevalence of reducing conditions during magma interaction and evolution. Breakdown of hornblende to biotite in such a reduced environmental condition led to the formation of calcite in the mingled rocks. From the results presented in this work, we are proposing that magma mixing can be a viable mechanism to form calcite in igneous rocks by magmatic processes.

The relative contribution of mantle and continental crustal sources to primitive arc magmas: Insights from the early Palaeozoic Famatinian - Puna arc

Subduction zone magmatism plays a crucial role in driving the exchange of chemical elements between Earth's interior and surface. This survey focuses on the compositional analysis of primitive mafic rocks within an ancient Early Palaeozoic subduction-related magmatic belt. The primary objective is to assess the petrological processes involved in the cycling of chemical elements from the Earth's surface, through the slab and mantle reservoirs, to the crustal arc magmatic systems. By examining the composition of primitive mafic rocks and utilizing inverse modelling techniques, we estimate the composition of the ambient mantle source, which appears to have undergone depletion due to melt extraction before being metasomatized by slab agents. The inverse approach reveals that fluid-mobile elements (Th, U, La, Ce, and Sr) were primarily derived from the slab contribution and suggests that subduction had influenced the abundances of Nb and Ta in the modified mantle source. Conversely, Zr, Hf, and Ti were sourced from the ambient mantle. However, the available mineral/melt partition coefficients used in inverse modelling may overestimate the contribution of Sr and Nb from the slab. Instead, forward modelling is limited by the incomplete preservation of ancient volcanic arc geology. The forward mixing models that consider the interaction between slab-released sedimentary-derived melts and the ambient depleted mantle can explain the observed variations in Nd and Sr isotopic ratios in primitive mafic rocks. Two-component mixing shows that a small mass fraction (≤1.5 wt%) of average Cambrian continental sediments subducted beneath the Early Ordovician arc into a MORB-depleted mantle source account for the abundance of sedimentary-supplied elements such as Th, La, and Ba, as well as radiogenic isotope ratios of 143Nd/144N and 87Sr/86Sr in the primitive mafic magmas. The chemical and isotopic composition of deep-seated primitive mafic rocks reveals a decoupling between incompatible trace elements, which display minimal variation, and radiogenic isotopic ratios, which exhibit a wide range and reflect contributions from continental crustal reservoirs. To explain the observed variations in trace elements and isotopes, we propose a simple model involving simultaneous bulk assimilation (A) and imperfect fractional crystallization (IFC) in an open igneous system, where crystal accumulation and assimilation occur concurrently. Especially, deep crustal physicochemical interaction of primitive arc magmas with supracrustal host rocks may mask the expected clear signature of subarc mantle petrological processes. Our assessment of the Famatinian-Puna arc, an ancient subduction zone, concurs with estimates from active volcanic arcs, underscoring the general applicability of this study case to subduction zone magmatism.

Chronological and Mineralogical Records of the Langqi Pluton, Fuzhou: Constraints on the Magma Mixing Process

The mafic microgranular enclaves (MMEs) from Mesozoic intermediate-acid magmatic rocks, widely developed along the Fujian coast, are considered to be the results of large-scale crust–mantle interaction by magma mixing. This paper is based on zircon U-Pb chronology, along with zircon Hf isotope and mineral analyses for the host granite and MMEs from Langqi Island, in order to investigate the magma mixing mechanism of the Langqi pluton in Fuzhou, Southeast China. The results indicate that the MMEs were emplaced during the late Early Cretaceous (98.9 ± 2.2 Ma), identical to the age of the granite (100.1 ± 1.1 Ma) within the error range. The zircon εHf(t) values for the granite and MMEs are in the ranges of −2.1~0.0 and −1.7~+1.1. The zircon Hf isotope data indicate that both the granite and MMEs were predominantly derived from the ancient crustal basement of Cathaysia, with a partial mantle-derived contribution. The An values of plagioclase phenocrysts with oscillatory zoning patterns in the MMEs show oscillatory changes from the core to the rim, indicating multiple mixing events between the two magmas with different compositions. Amphiboles in the MMEs show characteristics of crust–mantle contamination, and the Ti migrated from the mafic magma with high concentration to the felsic magma with low concentration during the magma mixing process. Biotites in the host rock and MMEs belong to primary biotite, and they have relatively high MgO contents (ave. 12.78 wt.%) and relatively low FeOT/(MgO + FeOT) ratios (ave. 0.56), showing characteristics of crust–mantle contamination. The crust–mantle magma interaction in a crystal, mushy state played a significant role in controlling the formation and evolution of the Langqi pluton. The magmatism was predominantly sourced from mixing between the mantle-derived mafic magma and the crust-derived felsic magma during the subduction of the Paleo-Pacific Plate, resulting in the formation of the Langqi doleritic veins, granites, and MMEs.

The role of magmatic-to-carbohydrothermal processes in rare earth mineralization in Hogenakkal carbonatites, India

The Paleoproterozoic Hogenakkal complex (India) consists of silicate-rich-, silicate-poor calcite carbonatite (carbonatite-I and II) and clinopyroxenite emplaced in granulite country rocks. Carbonatite-I contains abundant clinopyroxenite and K-feldspar pegmatite xenoliths. Silicate minerals are the primary governing factors in the formation of a distinctive lithology-specific REE mineralization. Carbonatite-I consists of magmatic Mg-Fe-Sr-bearing calcite (Cal-1), and REE-poor apatite (Ap-1) together with minor REE-rich apatite (Ap-2). The interaction of the carbonatite-forming magma with the clinopyroxenite and K-feldspar pegmatite xenoliths releases K, Al, and Si, forming phlogopite and pargasite-edenite. The late-magmatic carbonatite-II consists of Sr-rich calcite (Cal-2), Ap-2 and minor Ap-1. The carbohydrothermal REE-mineralization in both the carbonatites is induced by a magma-derived fluid dominated by REE, OH−, CO32−, and SO42−. The high modal abundance of silicate minerals and the continuous leaching of Si and Al from clinopyroxene, K-feldspar xenocrysts, and phlogopite by REE-enriched fluid facilitated the formation of allanite-(Ce) and actinolite in carbonatite-I. In contrast, in the silicate-poor carbonatite-II, the same fluid with low Si-saturation resulted in monazite-(Ce) + celestine-baryte±strontianite precipitation. The carbohydrothermal fluid is also responsible for the alteration of apatite to monazite-(Ce) by a dissolution-reprecipitation mechanism releasing fluorine. Consequently, localized crystallization of F-rich hydroxylbastnäsite-(Ce) is common in carbonatite-II. Complex intra-grain compositional and textural variations of monazite-(Ce) and hydroxylbastnäsite-(Ce) suggest further interaction of these minerals with evolving fluid. The waning phase of the carbohydrothermal activity is marked by an assemblage consisting of pure calcite (Cal-3) + quartz±magnetite in carbonatite-I. The Ba-Sr-REE mineralization and the overall mineral assemblages of the Hogenakkal carbonatites represent a transition from a magmatic to a carbohydrothermal stage.

Neoarchean to Paleoproterozoic crustal evolution of the central Aravalli-Banded Gneissic Complex (NW India): Evidence from zircon U-Pb-Hf isotope systematics and whole-rock composition of Neoarchean sanukitoids, Paleoproterozoic granitoids and metasedimentary rocks

The central Aravalli-Banded Gneissic Complex in NW India is an Archean nucleus that was extensively reworked during the late Paleo- to Neoproterozoic. New results of combined zircon U-Pb-Hf isotopes and whole-rock geochemical data reveal that the basement was affected by felsic magmatism during the Neoarchean and Paleoproterozoic, followed by a passive margin stage. The results provide evidence for coeval emplacement of sanukitoids and TTGs at ca. 2540 Ma, and for granitoid magmatism at ca. 1875 Ma. Similar REE patterns of the synchronous sanukitoids and TTGs, coupled with high SiO2 contents (59.2–70.9 wt%), subchondritic εHf2.55 Ga values (−5.0 to −2.6) and Hf-model ages (3246–3123 Ma) of the Masuda sanukitoids indicate that the sanukitoid magmas were formed mainly by interaction of TTG magmas (generated by the melting of subducted Paleo- to Mesoarchean oceanic crust) with the overlying enriched peridotite. The calc-alkalic and magnesian compositions, enrichment in LREE and LILE along with pronounced depletion in HFSE (Nb, P and Ti) in ca. 1875 Ma granitoid gneisses imply subduction-related magmatism during Paleoproterozoic. The predominance of subchondritic εHf1.87 Ga values, ranging from −4.4 to +1.7, suggests that the parental magmas mainly resulted from the reworking of heterogeneous Meso- to Neoarchean felsic crust. Age-Hf isotope data of detrital zircon grains provide evidence that clastic sedimentary rocks covering the central Aravalli basement were deposited in a passive margin setting at < 1730 Ma, and the detritus was mainly sourced from adjoining Neoarchean and Paleoproterozoic granitoids. Comparison of our new data with other Indian and worldwide cratons indicate that the Aravalli orogen represents a unique terrane, where the Neoarchean TTGs and sanukitoids with subchondritic Hf isotopic signatures were emplaced nearly coeval in a close spatial relationship. The Aravalli Archean basement was subsequently reconfigured by voluminous felsic magmatism during Paleoproterozoic at 1875–1810 Ma. Furthermore, the compiled zircon U-Pb age and Hf-Nd isotope data for the late Paleoproterozoic subduction-related magmatic rocks provide evidence for substantial crustal reworking during assembly of the Columbia supercontinent.

Neodymium isotope variations in the Flatreef on Macalacaskop, northern limb, Bushveld Complex

The origin of the recently discovered Flatreef remains debated due to the pronounced interaction of the magmatic rocks with sedimentary floor rocks, resulting in a complex intrusive stratigraphy. In this study, we report new Nd isotopic compositions of Flatreef lithologies intersected by borehole UMT-393 on the farm Macalacaskop in order to improve our understanding of the magmatic history of the deposit and to further test the putative correlation between the Flatreef/Platreef and the Upper Critical Zone of the remainder of the Bushveld Complex. The initial epsilon Nd (εNdi) values for the Flatreef range between −5.2 and −7.6, overlapping with εNdi values of the Upper Critical Zone from the eastern (ranging between − 4.8 and − 8.5) and the Upper Critical Zone and Main Zone from the western limb (−6.3 and −7.6, and −6.3 and −7.4 respectively) of the Bushveld Complex. The Flatreef εNdi values also overlap with those of the Platreef; however, due to the varying footwall lithologies of the Platreef along strike, Platreef rocks display a wider variation in isotopic composition. Our findings support the correlation of the Flatreef with the Upper Critical Zone — Main Zone transition interval in the remainder of the Bushveld Complex, which includes the Merensky and Bastard reefs. Due to significant overlap between the εNdi values of the Flatreef and local potential contaminants occurring at the base of the Northern Limb, we propose that the Sr–Nd isotopic composition of the magmas that gave rise to the Flatreef are most likely attributable to the interaction of mantle-derived magma with upper and lower crustal rocks of the Kaapvaal Craton within a sub-Bushveld staging chamber, with possible syn- to post-emplacement modification as a result of interaction with dolomitic footwall rocks.

Ten Thousand Years of Magma Storage Preceding the Last Caldera-Forming Eruption of the Bandelier Magmatic System, New Mexico, USA

Abstract In this study, we present new evidence for changes in magma storage conditions that preceded the 1232 ka caldera-forming eruption of the Bandelier magmatic system in the Jemez Mountains Volcanic Field. Using high precision 40Ar/39Ar sanidine dating we determine that at least eight rhyolites erupted within 8.6 ± 3.4 kyr of the ~400 km3 eruption that formed Valles caldera. Some of those rhyolites contain fayalite with or without biotite, others contain only biotite. An eruption of fayalite-bearing rhyolite at 1240.5 ± 2.1 ka ended an eruption hiatus of at least 100 kyr. Following that first post-hiatus episode of volcanism, at least four more eruptions of fayalite-bearing rhyolite and three eruptions of biotite-bearing rhyolite occurred prior to the caldera-forming eruption. We use phase equilibrium experiments and geothermobarometry to infer the storage conditions and processes that led to these differing crystal cargos and ultimately generated ~400 km3 of predominantly fayalite rhyolite ignimbrite (Tshirege Member of the Bandelier Tuff). We find that biotite-bearing rhyolites were stored at 695–750°C, 75–160 MPa, and at an oxygen fugacity more oxidizing than the quartz-fayalite-magnetite (QFM) buffer reaction. Fayalite-bearing rhyolites were similarly stored at 695–745°C and 70–190 MPa, but at more reducing conditions (${f}_{O_2}$≤ QFM). We suggest that the reduced, fayalite-bearing rhyolite was most likely produced via interaction of crystal-poor rhyolitic magma with a reducing, potentially Cl-bearing, and H2O-rich supercritical fluid phase. This fluid flux event was a key component of the substantial magmatic rejuvenation that enabled the mobilization of ~400 km3 of mostly fayalite-bearing rhyolite prior to not only the Tshirege event, but the older Otowi event as well.

Mantle-crust-interaction and subduction dynamics in Central Cameroon: Evidence from the Pan-African Linté microgranular magmatic enclaves (MMEs) and host syenite

The Central African Fold Belt (CAFB) in Cameroon is characterized by voluminous intrusive rocks hosting microgranular magmatic enclaves (MMEs) whose petrogenesis and tectonic implications remain unclear. Here, we present detailed geochronological and geochemical data of the host rocks and their MMEs from the Linté pluton in central Cameroon. The MMEs are finer-grained than their host syenite and both rocks are composed of alkali feldspar, plagioclase, biotite, amphibole and pyroxenes as main mineral phases. The enclaves show lower Mg#, total alkalis and transition elements contents, and are more HFSEs depleted than the host syenite. Both rocks are characterized by high-K, metaluminous I-type, alkaline to sub-alkaline and magnesian affinities. The Ti-in-zircon thermometer suggests crystallization temperatures of 615–1080 °C and 613–1008 °C for syenites and MMEs, respectively. Their zircon trace element distribution and patterns coupled with whole-rock geochemical features indicate that the Linté intrusive rocks were most likely originated from interaction of mantle-derived magma with crustal material. LA-ICP-MS UPb zircon analyses yield emplacement age of 599 ± 3 Ma and 597 ± 4 Ma for the host syenite and MMEs, respectively, indicating coeval crystallization date. Integrated whole rock geochemistry, UPb dating and Ti-in-zircon thermometry data indicate that the Linté syenite were probably formed from a mantle-derived ultrapotassic alkaline melt with significant crustal contribution, while MMEs are likely derived from a similar but separate melt with more fractionation and crustal contamination. The genesis of the host syenite and MMEs magmas started with break-off of the Congo plate after subduction and collision. This initiated an upwelling thermal pulse and underplating of mafic magma which led to partial melting of the Paleoproterozoic crust of the Central Cameroon.

Ebeko Volcano Activity in 2022: Mechanism and Products of Eruption

The paper provides information about the eruptive activity of the Ebeko volcano in 2022. From January 22 to June 13, phreatic explosions occurred in the crater lake caused by water seeping through the plug formed in the upper part of the magma channel and its boiling. On June 14, Vulcanian explosions began, destroying the lake. The granulometric composition of the ashes has changed in the direction of reducing the particle size. Petrographic and mineralogical-geochemical studies of tephra allow us to define this period as a phreatomagmatic eruption by the presence of fresh juvenile material. It is established that the interaction of magma with the waters of the hydrothermal system of the Ebeko volcano leads to its depletion with alkali metals and enrichment with silica. It is suggested that the formation of amorphous water-containing silica in the form of numerous separations and its subsequent dehydration may contribute to the explosive activity of the volcano.

Genesis and interaction of magmas at Nishinoshima volcano in the Ogasawara arc, western Pacific: new insights from submarine deposits of the 2020 explosive eruptions

Sudden changes of eruption styles and magma compositions at arc volcanoes are enigmatic processes. Nishinoshima volcano, western Pacific, has had historical eruptions in 1973–1974 and from 2013 on and off to the present day. These eruptions were characterized by effusive Strombolian eruptions of andesite magmas until mid-June 2020, when they suddenly transitioned to violent explosive Strombolian eruptions that produced tephra fallout over a wide area. To understand this transition, we conducted marine surveys and sampling of the extensive submarine deposits of the tephra fallout. Our new data demonstrate that the full compositional range of the 2020 eruptions spans from basalt to dacite. We present evidence for magma mixing of newly injected basalt with andesite magmas. Nishinoshima consists of an andesitic main edifice surrounded by basaltic knolls: previous studies have shown that Nishinoshima andesite compositions can be generated by olivine fractionation of primary andesitic magmas that result from partial melting of hydrous mantle at relatively low pressures under the thin crust of the Ogasawara arc; knoll basalt compositions can be generated by partial melting of mantle at greater depths and were interpreted as older events of the volcano. We show that basalt magmas could have been generated throughout the entire history of Nishinoshima. In addition, we show that andesites from Nishinoshima and nearby Nishinoshima-Minami Knoll, which are only ∼8 km apart, have distinct subduction components. Together, these data improve our understanding of the diverse primary magmas responsible for the construction and continuing eruptive activity of an active island arc volcano.

Petrogenesis of the Qiongduojiang Gabbro in Tethys Himalaya and Its Metallogenetic Implication

With the northward subduction and final closure of the Neo-Tethyan oceanic crust, the Indian and Eurasian plates finally collided together and underwent a strong collision orogenic event, resulting in large-scale crust–mantle magmatic interactions. In order to clarify the controversies about tectono-magmatic activities after the Indian–Eurasian continental collision, we report the newly dated Eocene Qiongduojiang gabbro explored in the Tethyan–Himalaya belt, southern Tibet. LA-ICP-MS zircon U-Pb dating shows that the crystallization age of the Qiongduojiang gabbro is 46.1 ± 1.7 Ma. The whole-rock major and trace elements, as well as Rb-Sr, Sm-Nd, and Pb isotopic data results, show that the Qiongduojiang gabbro is apparently depleted in Nd isotopes, is enriched in Pb isotopes, and has maintained a consistent 87Sr/86Sr(t) value. This paper argues that the E-MORB-like Qiongduojiang gabbro originated from asthenosphere upwelling caused by slab breakoff of the Neo-Tethyan oceanic plate. This event caused large-scale magmatic activities, a magmatic mixing process between ancient crust and deep mantle, and wild distribution of Eocene Gangdese plutons along the Yarlung–Tsangpo Suture Zone, and it rendered the subduction-modified Tibetan lithosphere fertile from the Gangdese porphyry Cu deposits.

Complex monogenetic volcano in karst setting: Lechmine N'kettane volcano (Middle Atlas, Morocco)

The Lechmine N'kettane is a Quaternary volcano, located within the Middle Atlas Volcanic Field (MAVF) in central Morocco. It is built on the faulted contact between Liassic limestone and Plio-Quaternary fluvio-lacustrine deposits. In map-view it consists of an elliptical maar crater, surrounded by a tephra ring, within which a scoria cone is nested in its northern crater zone.The Lechmine N'Kettane volcano is monogenetic in the sense of its small eruptive product volume and lack of evidence of significant time breakthrough it grows. The volcano formed from an eruptive locus that migrated laterally and vertically within the short duration of the eruption in a zigzagging pattern, along a complex set of generally NE-SW and NW-SE-trending faults. It represents a perfect example of how a volcano form and evolve under the influence of a combination of specific factors such as the lithological characteristics of the substrate, its hydrogeological parameters, magma flux and the local structural framework of the country rocks.The petrographic, granulometric and morphological (including terrain modelling) analyses of the Lechmine N'kettane pyroclastic deposits show that it was constructed in four eruptive phases with variable eruptive styles. The first, relatively dry, phreatomagmatic phase, that took place on a NE-SW fault in the northeastern part of the crater, was generated by the interaction between the ascending basaltic magma with meteoric water in the karst aquifer hosted by the Liassic limestone. The second phase is represented by a magmatic scoria fallout deposit whose explosion locus moved westward, along the same NE-SW fault. During the third phase, the explosion center migrated southward, along a NNW-SSE fault, and produced the last phreatomagmatic event by interaction of magma and water-saturated Plio-Quaternary sediment. The fourth eruptive phase is a purely scoria event, corresponding to the construction of the nephelinitic scoria cone in the northwestern part of the tephra ring. Between eruptive products formed in respective eruptive phases no evidence was recognized to establish significant time gaps between their formation.