Macroscopic Length Scales Research Articles

An extended two-parameter mixed-dimensional model of fractured porous media incorporating entrance flow and boundary-layer transition effects

We develop an enhanced reduced model for single-phase flow in fractured porous media capable of incorporating more realistic interface conditions at the fracture terminations. In addition to the traditional dimensional model reduction, where the elements of the discrete fracture network are treated as lower dimensional manifolds embedded in the porous matrix, we explore the microscale behavior of the boundary layer flow at the entrances of a fracture bounded by two parallel plates to construct a new set of interface conditions of Robin-type, giving rise to localized pressure jumps at the fracture edges. Within this enriched description, sharper reduced flow and tracer transport mixed-dimensional models are constructed in the asymptotic limit ruled by two small parameters related to the ratio between fracture aperture and entrance developing length and a macroscopic length scale. The discrete flow/transport mixed-dimensional model is discretized by a new discontinuous Galerkin(dG)-based formulation. An adequate version of the Galerkin-Newton method is developed for the numerical treatment of the non-linear Robin interface condition. Considering several fracture arrangements, numerical results illustrate the sharper description of the model proposed herein in predicting flow and tracer transport patterns in fractured media.

Thin-film evaporation in microchannels: A combined analytical and computational fluid dynamics approach to assessing meniscus curvature impact

Computational fluid dynamics (CFD) is employed to investigate the effects of variation in bulk meniscus curvature on evaporative heat and mass transfer in microchannels. Evaporation in microchannels presents a classic multiscale problem, encompassing both microscopic and macroscopic length scales in the thin-film and bulk meniscus regions, respectively. Therefore, the liquid-vapor interface or meniscus shape is first determined through thin-film evaporation analysis using numerical approaches found in the literature. However, a new approach for establishing boundary conditions is also proposed, allowing for the representation of varying curvatures within the bulk meniscus region. Then, the obtained meniscus thickness profiles are exported to a two-dimensional CFD framework. The primary advantage of this developed CFD framework lies in its capability to simultaneously analyze evaporative heat and mass transfer from both microscopic and macroscopic regions, a feature that enhances research endeavors concerning micro and miniature heat pipes. The developed model is applied to various rectangular microchannel sizes, ranging from 10 to 100 μm in width, with wall superheats varying from 0.1 to 3.0 K. The aim is to quantify the effects of variations in bulk meniscus curvature on the evaporative characteristics of the extended meniscus (comprising both thin-film and bulk meniscus regions), using the concept of thermal resistance. Consequently, based on the CFD simulation results, multiple regression analysis is employed to formulate the total thermal resistance in terms of independent parameters, namely the microchannel width, wall superheat, and the radius of curvature (Rc). It is observed that the radius of curvature has a marginal impact on the total thermal resistance, allowing its influence to be expressed by a power-law function of (Rc/Rm)0.102, where Rm represents the minimum radius of curvature.

New μ forces from νμ sources

Accelerator-based experiments reliant on charged pion and kaon decays to produce muon-neutrino beams also deliver an associated powerful flux of muons. Therefore, these experiments can additionally be sensitive to light new particles that preferentially couple to muons and decay to visible final states on macroscopic length scales. Such particles are produced through rare 3-body meson decays in the decay pipe or via muon scattering in the beam dump, and decay in a downstream detector. To demonstrate the potential of this search strategy, we recast existing MiniBooNE and MicroBooNE studies of neutral pion production in neutrino-induced neutral-current scattering (νμN→νμNπ0,π0→γγ) to place limits on light (<2mμ) muon-philic scalar particles that decay to diphotons through loops of virtual muons. While much of this parameter space has already been excluded by E137, we also project that SBND can be sensitive to unexplored parameter space for these models, and provide a road map for future neutrino experiments to perform dedicated searches for muon-philic forces. Published by the American Physical Society 2024

Magnetic skin effect in Pb(Fe _{1/2}$ Nb _{1/2}$ )O3

Relaxor-ferroelectrics display exceptional dielectric properties resulting from the underlying random dipolar fields induced by strong chemical inhomogeneity. An unusual structural aspect of relaxors is a skin-effect where the near-surface region in single crystals exhibit structures and critical phenomena that differ from the bulk. Relaxors are unique in that this skin effect extends over a macroscopic lengthscale of ∼100 μm whereas usual surface layers only extend over a few unit cells (or ∼nm). We present a muon spectroscopy study of Pb(Fe _{1/2} Nb _{1/2} )O3 (PFN) which displays ferroelectric order, including many relaxor-like dielectric properties such as a frequency broadened dielectric response, and antiferromagnetism with spatially short-range polar correlations and hence can be termed a multiferroic. In terms of the magnetic behavior determined by the Fe3+ ( S=5/2 , L ≈ 0) ions, PFN has been characterized as a unique example of a ‘cluster spin-glass’. We use variable momentum muon spectroscopy to study the depth dependence of the slow magnetic relaxations in a large 1 cm3 crystal of PFN. Zero-field positive muon spin relaxation is parameterized using a stretched exponential, indicative of a distribution of relaxation rates of the Fe3+ spins. This bandwidth of frequencies changes as a function of muon momentum, indicative of a change in the Fe3+ relaxation rates as a function of muon implantation depth in our single crystal. Using negative muon elemental analysis, we find small-to-no measurable change in the Fe3+/Nb5+ concentration with depth implying that chemical concentration alone cannot account for the change in the relaxational dynamics. PFN displays an analogous magnetic skin effect reported to exist in the structural properties of relaxor-ferroelectrics.

Hyperbolic high-fidelity simulations of cratering on a particle bed induced by a turbulent supersonic plume

A recently proposed hyperbolic granular model (Balakrishnan and Bellan, 2024) has been used to investigate the problem of supersonic-jet induced cratering on a solid-particle bed. This model relies upon the concept of added mass and a fluid-mediated particle pressure to render the system of equations hyperbolic. The jet is modeled using Large Eddy Simulation (LES) and the solid phase is modeled in an Eulerian framework using a Kinetic-Theory-based model modified for dense particle collections. The formulation also incorporates pseudo-turbulent kinetic energy (PTKE) which has been shown to modify a flow field laden with particles. The results explore the influence of the jet-to-ambient fluid density ratio, of the ambient fluid density, and of PTKE. A detailed analysis of the local and time-wise evolution of the added mass is presented through quantification of convection, added mass source and velocity-difference contributions. A quantitative assessment of the PTKE equation shows that while production is mostly effective at the crater base and walls, the dissipation and source term, both of which are also effective in the ejecta, nearly balance each other. The influence of the PTKE is mostly observed in the dilute particle regions (soil/gas interface and ejecta), with no effect on the macroscopic length scales of the flow. Both the jet-to-ambient fluid density ratio and the ambient fluid density affect the macroscopic crater features through entertainment into the jet that is determined by the former, and through the density of the fluid entrained, determined by the latter. This complex interaction governs the evolution of the crater diameter, visible top-view depth, and lower depth of the compacted region.

Microstructural Evolution of Tantalum During Deformation and Subsequent Annealing

Microstructure-aware models are necessary to predict the behavior of material based on process knowledge or to extrapolate mechanical properties of materials to environmental conditions which are not easily reproduced in the laboratory, e.g., nuclear reactor environments. Elemental Ta provides a relatively simple BCC system in which to develop a microstructural understanding of deformation processes which can then be applied to more complicated BCC alloys. In situ neutron diffraction during compressive deformation and subsequent heat treatment have been used to monitor the evolution of microstructural features in Ta throughout simulated processing steps. Crystallographic texture and dislocation density are determined as a function of first plastic strain, then temperature. Lattice strains are determined and attributed to stresses at macroscopic, grain and dislocation length scales. The increase of the dislocation density through deformation and subsequent recovery during heat treatment is monitored through the changing diffraction line profile. Also, randomization of the texture is used as a signature of recrystallization. The recovery of dislocations through annihilation is not observed to depend on the initial dislocation density in the range studied here. In contrast, recrystallization is observed to depend strongly on the initially dislocation density.

Correlated high throughput nanoindentation mapping and microstructural characterization of wire and arc additively manufactured 2205 duplex stainless steel

Duplex stainless steels (DSS) in wire and arc additive manufacturing (WAAM) have attracted significant research attention due to their mechanical properties and corrosion resistance. This study uses conventional and nanomechanical testing methods to compare the mechanical and microstructural behaviors at macroscopic and microscopic length scales. Macro hardness (HV10) testing yielded 259 and 249 in low and high heat input (HI) samples, respectively, while ferrite content averaged 52.7 and 48.5%. However, these results fail to provide conclusive insight into the potential influence of microstructural variations at the macroscopic level, likely due to the composite response of the material. To overcome this limitation, the mechanical response of the DSS samples is assessed at the grain level via high throughput nanoindentation mapping with image processing to track the location of each indent. This approach enabled differentiating the indents landing on ferrite and austenite phases as well as those landing on the interfaces. The results showed that the austenite phase had higher hardness (4.30 and 4.35 GPa) than the ferrite phase (3.89 GPa and 4.03 GPa) for high and low HI samples, respectively. The observed differences in hardness between the phases can be attributed to higher nitrogen content in the austenitic phase.

Aqueous Supramolecular Transformations of Motor Bola-Amphiphiles at Multiple Length-Scale.

Molecular motor amphiphiles have already been widely attempted for dynamic nanosystems across multiple length-scale for developments of small functional materials, including controlling macroscopic foam properties, amplifying motion as artificial molecular muscles, and serving as extracellular matrix mimicking cell scaffolds. However, limiting examples of bola-type molecular motor amphiphiles are considered for constructing macroscopic biomaterials. Herein, this work presents the designed two second generation molecular motor amphiphiles, motor bola-amphiphiles (MBAs). Aside from the photoinduced motor rotation of MBAs achieved in both organic and aqueous media, the rate of recovering thermal helix inversion step can be controlled by the rotor part with different steric hindrances. Dynamic assembled structures of MBAs are observed under (cryo)-transmission electron microscopy (TEM). This dynamicity assists MBAs in further assembling as macroscopic soft scaffolds by applying a shear-flow method. Upon photoirradiation, the phototropic bending function of MBA scaffolds is observed, demonstrating the amplification of molecular motion into macroscopic phototropic bending functions at the macroscopic length-scale. Since MBAs are confirmed with low cytotoxicity, human bone marrow-derived mesenchymal stem cells (hBM-MSCs) can grow on the surface of MBA scaffolds. These results clearly demonstrate the concept of designing MBAs for developing photoresponsive dynamic functional materials to create new-generation soft robotic systems and cell-material interfaces.

Improved Formulae for Low-Frequency Ultrasonic Attenuation in Metals

A range of ultrasonic techniques associated with the nondestructive evaluation of metals involves the propagation of low-frequency elastic waves. Metals that are isotropic and homogeneous in the macroscopic length scale contain elastic heterogeneities, such as grain boundaries within the microstructures. Ultrasonic waves propagating through such microstructures get scattered from the grain boundaries. As a result, the propagating ultrasound attenuates. The mass density and the elastic anisotropy in each constituent grain govern the degree of heterogeneity in the polycrystalline aggregates. Existing elastodynamic models consider first-order scattering effects from grain boundaries. This paper presents the improved attenuation formulae, for the first time, by including the next order of grain scattering effects. Results from investigating 759 polycrystals reveal a positive correlation between the effects of higher-order scattering from grain boundaries and the degree of heterogeneity. Thus, higher-order grain scattering effects are now known. These results motivate further investigation into higher frequencies and strongly scattering alloys in the future.

Controlling Electrodeposition in Nonplanar High Areal Capacity Battery Anodes via Charge Transport and Chemical Modulation.

Controlling the morphological evolution of electrochemical crystal growth in battery anodes is of fundamental and practical importance, particularly towards realizing practical, high-energy batteries based on metal electrodes. Such batteries require highly reversible plating/stripping reactions at the anode to achieve a long cycle life. While conformal electrodeposition and electrode reversibility have been demonstrated in numerous proof-of-concept experiments featuring moderate to low areal capacity (≤3 mA h/cm2) electrodes, achieving high levels of reversibility is progressively challenging at the higher capacities (e.g., 10 mA h/cm2), required in applications. Nonplanar, "3D" electrodes composed of electrically conductive, porous substrates are conventionally thought to overcome trade-offs between reversibility and capacity because they hypothetically "host" the electrodeposits in an electronically conducting framework, providing redundant pathways for electron flow. Here, we challenge this hypothesis and instead show that a nonplanar substrate with moderate electrical conductivity (ideally, with an electrical conductance similar to the ionic conductance of the electrolyte) and composed of a passivated cathode-facing surface efficiently regulates electro-crystallization. In contrast, an architecture with a high intrinsic electrical conductivity or with a high electrical conductivity coating on the front surface results in dominantly out-of-plane growth, making the 3D architecture in effect function as a 2D substrate. Using Zn as an example, we demonstrate that interconnected carbon fiber substrates coated by SiO2 on the front and Cu on the back successfully ushers electroplated Zn metal into the 3D framework at a macroscopic length scale, maximizing use of the interior space of the framework. The effective integration of electrodeposits into the 3D framework also enables unprecedented plating/stripping reversibility >99.5% at high current density (e.g., 10 mA/cm2) and high areal capacities (e.g., 10 mA h/cm2). Used in full-cell Zn||NaV3O8 batteries with stringent N/P ratios of 3:1, the substrates are also shown to enhance cycle life.

Flexible polymer networks: rubber elasticity and segmental orientation

Abstract Thermoreversible networks are very attractive materials because of a large variety of suitable thermoreversible chemical bonds which can be used for crosslinking. In future, to certain extent, they may replace so far used irreversibly crosslinked networks and contribute to more sustainable material concepts also in the field of crosslinked elastomers. This paper gives some theoretical basis for understanding the elastic deformation properties of crosslinked polymers and presents some experimental tools for studying deformation behavior not only on a macroscopic length scale but also on a segmental scale. Basic knowledge of these two topics is useful for chemists and material scientists when designing new sustainable elastomeric polymer networks.

DNA Cryogels with Anisotropic Mechanical and Responsive Properties for Specific Cell Capture and Release.

Due to their programmable stimuli-responsiveness, excellent biocompatibility, and water-rich and soft structures similar to biological tissues, smart DNA hydrogels hold great promise for biosensing and biomedical applications. However, most DNA hydrogels developed to date are composed of randomly oriented and isotropic polymer networks, and the resulting slow response to biotargets and lack of anisotropic properties similar to those of biological tissues have limited their extensive applications. Herein, anisotropic DNA hydrogels consisting of unidirectional void channels internally oriented up to macroscopic length scales were constructed by a directional cryopolymerization method, as exemplified by a DNA-incorporated covalently cross-linked DNA cryogel and a DNA duplex structure noncovalently cross-linked DNA cryogel. Results showed that the formation of unidirectional channels significantly improved the responsiveness of the gel matrix to biomacromolecular substances and further endowed the DNA cryogels with anisotropic properties, including anisotropic mechanical properties, anisotropic swelling/shrinking behaviors, and anisotropic responsiveness to specific biotargets. Moreover, the abundant oriented and long macroporous channels in the gel matrix facilitated the migration of cells, and through the introduction of aptamer structures and thermosensitive polymers, an anisotropic DNA cryogel-based platform was further constructed to achieve the highly efficient capture and release of specific cells. These anisotropic DNA hydrogels may provide new opportunities for the development of anisotropic separation and biosensing systems.

Red-light-controlled supramolecular assemblies of indigo amphiphiles at multiple length scales

Amphiphilic molecules functionalized with photoresponsive motifs have attractive prospects for applications in smart functional bio-material ranging from cell-material interfaces to drug delivery systems owing to the precisely controllable functionality of self-assembled hierarchical supramolecular structures in aqueous media by a non-invasive light stimulation with high temporal- and spatial-resolution. However, most of reported photoresponsive amphiphiles are triggered by bio-damaging UV-light, which greatly limits the potential in bio-related applications. Herein, we present newly designed red-light controlled N,N’-diaryl-substituted indigo amphiphiles (IA), exhibiting excellent photoswitchablity and photostability with dual red-/green-light in organic media. Meanwhile, aqueous solutions of IA assembled into supramolecular structures in both microscopic and macroscopic length-scale, though the photoresponsiveness of IA is slightly compromised in aqueous media. At macroscopic length-scale, morphological changes of IA macroscopic scaffold prepared by a shear-flow method can be fine adjusted upon red-light irradiation. Moreover, the preferential attachment of live h-MSCs to IA macroscopic scaffold surface also indicates a good biocompatibility of IA macroscopic scaffold. These results provide the potential for developing the next generation of red-light controlled soft functional materials with good biocompatibility.

Tuning the order of poly(3-alkylthiophene) derivatives ultrathin films through side-chain polarity: From a short-range ordered monolayer to a highly crystalline bilayer

In order to pave the way for the formation of ultrathin electronically conductive organic films, we explored the structure and morphology of polythiophene derivatives in situ on the water surface. By changing the side chain end-group of poly(3-hexylthiophene) (P3HT) from methyl to carboxylic acid potassium salt, we showed that the film structure is drastically changed from a highly ordered bilayer to a short-range organized monolayer. Using a comprehensive experimental approach from macroscopic length scale to molecular organization as well as simulations of diffraction patterns, the detailed structure of the crystalline P3HT bilayer was determined. Some similarities with the structure measured on thicker films deposited on solid substrates were evidenced such as the π-stacking distance, the interlayer spacing, and the edge-on conformation. Some differences were also pointed out, in particular the in-plane packing along the polymer backbones and the shift of the upper monolayer with respect to the bottom one in this direction. Such observations highlighted the influence of both the forced two-dimensional confinement and the nature of the substrate (water) on the P3HT film structure. The presence of a carboxylic acid potassium salt at the end of the side chain induced completely different behavior. Indeed, high pressures were necessary to observe a π-stacking of the thiophene units, but only short-range, and although the polymer keeps a monolayer organization independently of the pressure, a deep change in the polymer conformation was evidenced with the pressure.

(Invited) Neutrons as a Powerful Tool for Better Understanding Electrochemistry on Various Length and Time Scales

Today, sophisticated methods are applied to gain a deeper understanding of processes in in-situ electrochemistry. There are few ways to study electrochemically relevant processes on different length and/or time scales without affecting the processes themselves. Probes that cover a sufficient volume of the sample non-destructively and are sensitive to the important charge carriers are in great demand. For such purposes, neutrons are an ideal candidate to perform this task because they have relatively high sensitivity to the light chemical elements, can distinguish neighboring elements of the periodic table, have a large beam cross-section, and possess high penetration depth for many types of materials.Therefore, many open questions are addressed to unique neutron techniques tailored to solve the open problems. This article gives an overview of some examples to show the advantages of using neutrons for special questions on different length and time scales [1]. For surface investigations of electrodes, the neutron depth profiling method (NDP) is suitable for characterizing the Li distribution up to the nano range [2]. Neutron diffraction is a powerful tool to better understand cylindrical cells at the atomic level, e.g. during the intercalation process [3]. Another strong field of neutrons is the monitoring of the wetting process during the electrolyte filling of prismatic hard case cells on the macroscopic length scale using the neutron imaging technique [4].

Measurements of stresses in β‐(Y,Yb)2Si2O7 environmental barrier coating layers using Raman spectroscopy

AbstractResidual stress measurements in environmental barrier coatings (EBCs) can help in understanding coating durability and potential damage mechanisms. We demonstrate the capability of Raman spectroscopy to measure average residual stresses in two different β‐RE2Si2O7 (RE = rare earth or Y3+, denoted as REDS) EBCs with a nominal (Yb,Y)2Si2O7 composition, focusing on macroscopic residual stresses acting at macroscopic length scales. Uniaxial compression measurements of dense β‐(Yb,Y)2Si2O7 ceramics are used for calibration curves for applied stress versus Raman peak shift. We use these calibration curves to evaluate the macroscopic thermoelastic residual stress in the (Yb,Y)2Si2O7 layers from coefficient of thermal expansion (CTE) mismatch of two different (Yb,Y)2Si2O7‐based EBCs on SiC‐based substrates. Microscopic stress contributions to Raman peak shifts are subtracted using reference free‐standing coatings and analytic estimates for inclusion stresses when (Yb,Y)2Si2O7 coatings have a high, variable volume fraction of (Yb,Y)2SiO5. The macroscopic thermal residual stress in these (Yb,Y)2Si2O7 EBCs is compressive, as expected from the smaller CTE of β‐REDS versus SiC. These thermal residual stresses can vary between different YbYDS EBC coatings by more than a factor of three with a measured layer residual stress of approximately –180 MPa (compressive) for a high modulus, low CTE coating, and our measured values generally agree with calculated estimates.

The effect of shape, polydispersity, charge, and fraction of crystallite bundles on the cholesteric pitch of cellulose nanocrystal suspensions

Using Onsager–Straley’s second-virial theory, we investigate the cholesteric pitch of cellulose nanocrystal (CNC) suspensions. We model the CNCs as hard chiral bundles of microfibrils and examine the effect of the shape of these chiral bundles, characterized by aspect ratio and chirality, on the cholesteric pitch. Additionally, we explore the impact of length polydispersity and surface charge on the cholesteric phase of CNCs. Furthermore, we consider binary mixtures of twisted bundles and achiral primary crystallites to provide a more realistic representation of CNC suspensions. Our findings reveal that the degree of bundle twisting significantly affects the helical twisting of the cholesteric phase. We also observe that the average particle length and length polydispersity have substantial effects on strongly twisted bundles but minimal effects on weakly twisted ones. Finally, our study indicates that as the range of electrostatic interactions increases, the transfer of chirality from the microscopic to macroscopic length scales becomes masked, resulting in an increase in the cholesteric pitch. In the case of binary mixtures, the bundles act as chiral dopants, and an increasing fraction of bundles progressively enhances the helical twisting of the cholesteric phase.

Laminar flow in a channel bounded by porous/rough walls: Revisiting Beavers-Joseph-Saffman

The fully developed, steady, incompressible, laminar flow in a channel delimited by rough and/or permeable walls is considered. The influence of the micro-structured bounding surfaces on the channel flow behavior is mimicked by imposing high-order effective boundary conditions which stem from homogenization theory and do not contain empirical parameters. A closed-form solution of the Navier–Stokes equations is found for the flow in the channel, with conditions at each virtual boundary linking the slip velocities to shear stress and streamwise pressure gradient. The boundary condition for the longitudinal velocity coincides with a little-noticed extension of the so-called Beavers-Joseph condition, first derived by Saffman (1971); it applies to both permeable and rough surfaces, including the case of separated flow (Couette-Poiseuille motion with adverse pressure gradient). The analytical solution obtained for the velocity distribution in the channel is validated against full feature-resolving simulations of the flow for either highly ordered or random textures, highlighting the accuracy and the applicability range of the model. The Stokes-based model used to identify slip and interface permeability coefficients in the effective boundary conditions is found to be reliable and accurate up to ϵReτ≈10, with ϵ ratio of microscopic to macroscopic length scales and Reτ the shear-velocity Reynolds number. Above this threshold, the coefficients must account for advective effects: a new upscaling procedure, based on an Oseen’s approximation, is thus proposed and validated, extending considerably beyond the Stokes regime.

Multiscale mechanical analysis of the elastic modulus of skin

The mechanical properties of the skin determine tissue function and regulate dermal cell behavior. Yet measuring these properties remains challenging, as evidenced by the large range of elastic moduli reported in the literature—from below one kPa to hundreds of MPa. Here, we reconcile these disparate results by dedicated experiments at both tissue and cellular length scales and by computational models considering the multiscale and multiphasic tissue structure. At the macroscopic tissue length scale, the collective behavior of the collagen fiber network under tension provides functional tissue stiffness, and its properties determine the corresponding elastic modulus (100–200 kPa). The compliant microscale environment (0.1–10 kPa), probed by atomic force microscopy, arises from the ground matrix without engaging the collagen fiber network. Our analysis indicates that indentation-based elasticity measurements, although probing tissue properties at the cell-relevant length scale, do not assess the deformation mechanisms activated by dermal cells when exerting traction forces on the extracellular matrix. Using dermal-equivalent collagen hydrogels, we demonstrate that indentation measurements of tissue stiffness do not correlate with the behavior of embedded dermal fibroblasts. These results provide a deeper understanding of tissue mechanics across length scales with important implications for skin mechanobiology and tissue engineering. Statement of SignificanceMeasuring the mechanical properties of the skin is essential for understanding dermal cell mechanobiology and designing tissue-engineered skin substitutes. However, previous results reported for the elastic modulus of skin vary by six orders of magnitude. We show that two distinct deformation mechanisms, related to the tension–compression nonlinearity of the collagen fiber network, can explain the large variations in elastic moduli. Furthermore, we show that microscale indentation, which is frequently used to assess the stiffness perceived by cells, fails to engage the fiber network, and therefore cannot predict the behavior of dermal fibroblasts in stiffness-tunable fibrous hydrogels. This has important implications for how to measure and interpret the mechanical properties of soft tissues across length scales.

Spin-mediated shear oscillators in a van der Waals antiferromagnet.

Understanding how microscopic spin configuration gives rise to exotic properties at the macroscopic length scale has long been pursued in magnetic materials1-5. One seminal example is the Einstein-de Haas effect in ferromagnets1,6,7, in which angular momentum of spins can be converted into mechanical rotation of an entire object. However, for antiferromagnets without net magnetic moment, how spin ordering couples to macroscopic movement remains elusive. Here we observed a seesaw-like rotation of reciprocal lattice peaks of an antiferromagnetic nanolayer film, whose gigahertz structural resonance exhibits more than an order-of-magnitude amplification after cooling below the Néel temperature. Using a suite of ultrafast diffraction and microscopy techniques, we directly visualize this spin-driven rotation in reciprocal space at the nanoscale. This motion corresponds to interlayer shear in real space, in which individual micro-patches of the film behave as coherent oscillators that are phase-locked and shear along the same in-plane axis. Using time-resolved optical polarimetry, we further show that the enhanced mechanical response strongly correlates with ultrafast demagnetization, which releases elastic energy stored in local strain gradients to drive the oscillators. Our work not only offers the first microscopic view of spin-mediated mechanical motion of an antiferromagnet but it also identifies a new route towards realizing high-frequency resonators8,9 up to the millimetre band, sothe capability of controlling magnetic states on the ultrafast timescale10-13 can be readily transferred to engineering the mechanical properties of nanodevices.