Due to the high path loss of non-line-of-sight (NLOS) ultraviolet communications (UVC) channel, pulse modulation schemes, such as on-off keying (OOK) and M-ary pulse-position modulation (PPM), and photon-counting receivers are commonly adopted. Although M-ary PPM can be demodulated and decoded without the channel state information, its spectral efficiency is lower than OOK's. To improve the spectral efficiency of M-ary PPM in NLOS UVC, a power-domain multilayer-superposed transmission (MST) scheme with binary PPM (BPPM) is proposed in this work. Based on this scheme, the signal in each layer can be directly decoded without successive interference cancellation, which is necessary for other MST schemes in the power domain. Hence, a low complexity receiver in the NLOS UVC system can be realized. Additionally, the bit-error rate (BER) and achievable data rate (ADR) expressions of the proposed MST scheme are derived. Monte-Carlo simulations are performed to verify the analytical BER expression. The NLOS UVC system performance employing the proposed MST scheme is further demonstrated and compared with pure BPPM. The results indicate that with the optimal power allocation factor for each layer, the overall ADR of the NLOS UVC system with the proposed power-domain MST scheme can surpass that with pure BPPM.
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