Lu-Hf Data Research Articles

In situ Lu–Hf dating of allanite by LA-ICP-MS/MS: Implications for geochronology

Allanite is a common REE-rich accessory mineral found in various igneous and metamorphic rocks, and can record a variety of geological processes. Therefore, allanite geochronology has the potential to answer a range of important geological questions. Allanite U–Th–Pb geochronology is hampered by common open-system behavior in the system. In this study, we demonstrate the feasibility of in situ allanite Lu–Hf dating by LA–ICP–MS/MS. A total of nine allanite samples from different rock types (e.g., granite, pegmatite) were investigated. These allanite samples have ages ranging from ca. 2650 to ca.100 Ma, and Lu contents ranging from several to hundreds of μg g−1 levels and relatively high Lu/Hf ratios (> 30). At a mass shift of +82, the isobaric interferences 176Lu and 176Yb have extremely low reaction rates of ∼0.003 % and ∼ 0.0003 %, respectively, indicating the isobaric interference corrections are insignificant for the allanite samples (mean 175Lu/177Hf = ∼814; mean 172Yb/177Hf = ∼719). A two-step calibration strategy was proposed for the 176Lu/176Hf and 177Hf/176Hf ratio corrections using NIST SRM 610 (for instrument drift) and LE2808 (for matrix effect). The nine allanite samples contain common Hf contents (f176Hf) of ∼5 % to >90 %, and the data are plotted in inverse isochron diagrams. Unanchored inverse isochron ages exhibit a large deviation in accuracy (5–10 %), whilst anchored isochron ages have a better accuracy of <5 %. The uncertainty of anchor initial 176Hf/177Hf values was investigated and, in general, was insignificant (< 2.8 %) for samples with f176Hf < 80 %. Our results demonstrate that in situ allanite Lu–Hf dating by LA-ICP-MS/MS is feasible and can yield precise and accurate ages (< 5 %). Lu–Hf geochronometer captures the high-temperature process and may be more resistant during the late thermal event. Thus, it provides an alternative solution for those samples which are suffered by open-system behavior in U-Th-Pb system.

Generation and evolution of the Choiyoi granitic magmatism based on U-Pb zircon studies, Cordón del Portillo, Frontal Cordillera (Argentina)

Based on a relevant geochronological U-Pb zircon dataset (n = 47) from a sample (PBL-109) of the Cerro Punta Blanca pluton (CPB), which is part of a calc-alkaline suite, we corroborate the development of protracted magmatic activity with three major crystallization events for this Permian magmatism: 278 ± 1, 283 ± 2, and 289 ± 2 Ma, which outcrop in the Cordón del Portillo, Cordillera Frontal (CF) of Argentina. These ages can be assigned to the lower section of the magmatic record of the Choiyoi magmatism (ca., 290-265 Ma), while the age of 289 Ma represents the oldest known age for the Choiyoi, indicating the start of this magmatism during the Artinskiense. Considering these geochronological data, we postulate the presence of a deep mush reservoir where protracted magmatic activity permitted the prolonged crystallization of antecrysts (ca. 283–289 Ma). Migration of the parental magma from the mush reservoir zone occurred near the time of emplacement and culminated in the formation of an ephemeral magma chamber at shallow levels, where zircon autocrysts crystallized (ca. 278 Ma). Age spectra reported within individual samples support the idea of massive magma migration when conditions were favorable (e.g., thermally matured crust). In this view, the studied “older” Choiyoi magmatism represents a continuous magmatic event lasting 11 Ma and corresponds to a single magmatic episode rather than different periods of magmatic activity and subsequent emplacements. A later alkali-calcic magmatic event is recorded at 265 ± 4 Ma from a sample of the Cerro Bayo pluton (MH-0113), which could represent the end of the lower section of the Choiyoi magmatism. Whole-rock Sm-Nd, Rb-Sr, and Lu-Hf data in zircon, along with ages reported for the studied igneous and inherited zircon from the CPB; together with isotopic data and ages from the detrital zircon found in the Carboniferous accretionary complex of Chile, indicate that the source of the Permian parental magma in this region was a heterogeneous continental crust mainly formed by Devonian and Carboniferous rocks, related probably to a magmatic arc. However, some contribution from the Carboniferous accretionary complex of Chile to the parental magma should be consider.

First in situ Lu–Hf garnet date for a lithium–caesium–tantalum (LCT) pegmatite from the Kietyönmäki Li deposit, Somero–Tammela pegmatite region, SW Finland

Abstract. The in situ Lu–Hf geochronology of garnet, apatite, fluorite, and carbonate minerals is a fast-developing novel analytical method. It provides an alternative technique for age dating of accessory minerals in lithium–caesium–tantalum (LCT) rare-element (RE) pegmatites where zircon is often metamict due to alteration or radiation damage. Currently most dates from Finnish LCT pegmatites are based on columbite-group minerals (CGMs), but their occurrence is restricted to mineralised zones within the pegmatites. Accessory minerals such as garnet and apatite are widespread in both mineralised and unmineralised LCT pegmatites. Lu–Hf dating of garnet and apatite provides an exceptional opportunity to better understand the geological history of these highly sought-after sources for battery and rare elements (Li, Nb, Ta, Be) that are critical for the green transition and its technology. In this paper we present the first successful in situ Lu–Hf garnet date of 1801 ± 53 Ma for an LCT pegmatite from the Kietyönmäki deposit in the Somero–Tammela pegmatite region, SW Finland. This age is consistent with previous zircon dates obtained for the region, ranging from 1815 to 1740 Ma with a weighted mean 207Pb / 206Pb age of 1786 ± 7 Ma.

Laser ablation (in situ) Lu-Hf geochronology of epidote group minerals

Epidote group minerals, including allanite, clinozoisite and epidote are common in a range of metamorphic, igneous and hydrothermal systems, and are stable across a wide range of pressure–temperature (P–T) conditions. These minerals can incorporate substantial amounts of rare earth elements (REEs) during their crystallisation, making them potential candidates for Lu–Hf geochronology to provide age constraints on various geological processes. Here we report on a first exploration into the feasibility of in situ Lu–Hf geochronology for epidote group minerals from various geological settings and compare the results with age constraints from other geochronometers. Magmatic allanite samples from pegmatites and monzogranites in the Greenland anorthosite complex, Coompana Province and Qingling Orogen provided dates consistent with magmatic events spanning from c. 2660 to 1171 Ma. In the Qingling pegmatites, a younger phase of hydrothermal allanite was dated at c. 215 Ma, consistent with the timing of regional REE mineralisation. Allanite from the Yambah Shear Zone, Strangways Metamorphic Complex, yielded Lu–Hf age of c. 430 Ma. It predates the garnet and apatite growth at c. 380 Ma, suggesting the Lu–Hf system can be preserved in allanite during prograde amphibolite-facies metamorphism. Additionally, Lu–Hf dates for hydrothermal clinozoisite and epidote are consistent with the timing of hydrothermal alteration and mineralisation in a range of settings, demonstrating the utility of the technique for mineral exploration. Despite the current lack of matrix-matched reference materials, the successful application of laser ablation Lu–Hf geochronology to epidote group minerals offers valuable geochronological insights into various geological processes that can be difficult to access through other geochronometers.

In situ apatite and carbonate Lu-Hf and molybdenite Re-Os geochronology for ore deposit research: Method validation and example application to Cu-Au mineralisation

The development of laser ablation inductively coupled plasma quadrupole tandem mass spectrometry (LA-ICP-Q-MS/MS) opens new opportunities to rapidly date a variety of hydrothermal minerals. Here we present in situ Lu-Hf and Re-Os dates for hydrothermal apatite and molybdenite, respectively. We further report the first in situ Lu-Hf dates for bastnäsite, dolomite, and siderite, and assess their potential for constraining ore deposit geochronology. For method validation, we report isotope-dilution Lu-Hf dates for apatite reference material Bamble-1 (1102 ± 5 Ma) and calcite reference material ME-1 (1531 ± 7 Ma), enabling improved accuracy on matrix-matched calibration for LA-ICP-MS/MS Lu-Hf dating. The new methods are applied to the Vulcan Iron-Oxide Copper-Gold (IOCG) prospect in the Olympic Cu-Au Province of South Australia. Such deposits have been difficult to accurately date, given the general lack of reliable mineral geochronometers that are cogenetic with IOCG mineralisation. Hydrothermal apatite Lu-Hf dates and molybdenite Re-Os dates demonstrate that mineralisation at Vulcan largely occurred at ca. 1.6 Ga, contemporaneous with the world class Olympic Dam deposit. Our data also indicates that the Lu-Hf system in apatite is more robust than the U-Pb system for determining the timing of primary apatite formation in an IOCG system. We further demonstrate that dolomite can retain Lu-Hf growth ages over an extended time period (>1.5 billion years), providing constraints on the timing of primary ore mineral crystallisation during brecciation and IOCG mineralisation. Finally, late Neoproterozoic (ca. 589–544 Ma) and Carboniferous (ca. 334 ± 7 Ma) Lu-Hf dates were obtained for texturally late Cu-bearing carbonate veins, illustrating that the carbonate Lu-Hf method allows direct dating of Cu remobilisation events. This has important implications for mineral exploration as the remobilised Cu may have been transferred to younger deposits hosted in Neoproterozoic sedimentary basins overlaying the Olympic IOCG province.

The mafic–ultramafic roots of a Mesoarchean microblock in southern India: Insights from petrochemistry and isotope geochronology of the Coorg Block

The Coorg Block in southern India is an archive of Paleo-Mesoarchean arc magmatism and continental building in the early Earth. Here we investigate a suite of mafic and ultramafic rocks and associated lithologies to characterize the roots of this microcontinent. We present petrologic, geochemical, as well as U-Pb and Lu-Hf data on zircon and U-Pb data on monazite from these rocks which provide insights into the petrogenesis of the rocks as well as the timings of magmatism and subsequent metamorphism. The geochemical features of the mafic granulites indicate that the rock suite was derived from the fractionation of a sub-alkaline tholeiite magma. Most of the rocks correspond to arc setting in a subduction-related tectonic regime. The rocks exhibit relative enrichment in LILE, Pb, and LREE with depletion in HFSE such as Nb and Ta suggesting partial melting of a metasomatized mantle wedge. Their high LILE/HFSE and LREE/HFSE ratios indicate slab dehydration and mantle wedge melting in typical island arc settings. The overall trace element and REE patterns of the rocks indicate that the source magma of the ultramafic and mafic rocks might have been derived from a refractory mantle source followed by the metasomatic enrichment of lithospheric mantle wedge by incompatible elements through the influx of subduction-derived fluids/melts. We present comprehensive zircon U-Pb data and Lu-Hf data on a suite of mafic granulite, garnet-bearing granulite, tremolite actinolite schist, charnockite, and anorthositic gabbro as well as monazite U-Pb data from a charnockite sample. Most zircon grains show cores with magmatic crystallization features and many grains are mantled by metamorphic rims. The age data show a prominent peak at 3.1 Ga for most of the rocks suggesting that the major crustal building in the Coorg Block occurred during the Mesoarchean. Rocks on the margins of the block were affected by the younger (Neoarchean) tectonothermal event in the surrounding blocks. The Lu-Hf isotopic data on zircon grains with ca. 3.1 Ga ages show εHf(t) values ranging from −4.4 to + 3.7 (average + 0.3). In the εHf(t) versus 207Pb/206Pb age diagram, the plots are distributed close to the CHUR line suggesting Paleo-Eoarchean juvenile magma sources. The voluminous mafic lower crust at the root of the Coorg Block is consistent with addition of mafic magmas through slab melting induced by high mantle potential temperatures in the Archean, as well as the interaction of fluids/melts with the mantle wedge.

Testing in-situ apatite Lu–Hf dating in polymetamorphic mafic rocks: a case study from Palaeoproterozoic southern Australia

In mafic systems where primary mineral assemblages have witnessed moderate- to high-temperature hydrous overprinting and deformation, little is known about the retentivity of the Lu–Hf isotopic system in apatite. This study presents apatite laser-ablation Lu–Hf and U–Pb geochronology, zircon geochronology, and detailed petrological information from polymetamorphic mafic intrusions located in the central-western Gawler Craton in southern Australia, which records an extensive tectonometamorphic history spanning the Neoarchaean to the Mesoproterozoic. Zircon records magmatic crystallisation ages of c. 2479–2467 Ma, coinciding with the onset of the c. 2475–2410 Ma granulite-facies Sleafordian Orogeny. The amphibole-dominant hydrous assemblages which extensively overprint the primary magmatic assemblages are hypothesised to post-date the Sleafordian Orogeny. The Lu–Hf and U–Pb isotopic systems in apatite are used to test this hypothesis, with both isotopic systems recording significantly younger ages correlating with the c. 1730–1690 Ma Kimban Orogeny and the c. 1590–1575 Ma Hiltaba magmatic event, respectively. While the early Mesoproterozoic apatite U–Pb ages are attributed to thermal re-equilibration, the older Lu–Hf ages are interpreted to reflect re-equilibration facilitated primarily by dissolution-reprecipitation, but also thermally activated volume diffusion. The mechanisms of Lu–Hf isotopic resetting are distinguished based on microscale textures and trace element abundances in apatite and the integration of apatite-amphibole textural relationships and temperatures determined from the Ti content in amphibole. More broadly, the results indicate that at low to moderate temperatures, apatite hosted in mafic rocks is susceptible to complete recrystallisation in rocks that have weak to moderate foliations. In contrast, at higher temperatures in the absence of strain, the Lu–Hf system in apatite is comparatively robust. Ultimately, the findings from this study advance our understanding of the complex role that both metamorphism and deformation play on the ability of mafic-hosted apatite to retain primary Lu–Hf isotopic signatures.

Apatite Triple Dating (Lu–Hf, U–Pb, FT) Constrains Deformation and Cooling in the Coompana and Madura Provinces, Western Australia

Abstract Combined apatite Lu–Hf, U–Pb, and fission track (AFT) triple dating affords the opportunity to investigate the ~60 and 730°C thermal history of a study area. Here, we apply apatite triple dating to resolve the tempo of multiple thermo-tectonic events within the Precambrian basement rocks of the Coompana (COP) and Madura (MAP) Provinces, Western Australia. Apatite Lu–Hf dates for the western COP (~1.52 Ga) and MAP (~1.36 Ga) agree with published Mesoproterozoic magmatic crystallization ages. Younger apatite U–Pb dates (~1.16–1.12 Ga) for the western COP and MAP suggest isotopic decoupling and radiogenic-Pb loss by volume diffusion in response to metamorphism at that time. Further East in the COP, the apatite Lu–Hf, and U–Pb dates are within uncertainty of each other and are interpreted to reflect recrystallization at ~1.20–1.14 Ga, coinciding with the late Mesoproterozoic Maralinga thermomagmatic event. The imprints of such an event were more pervasive towards the eastern COP, resulting in a thermally weakened crust in this area. AFT results constrain the subsequent Phanerozoic low-temperature history which has contrasting thermal trajectories on either side of the Mundrabilla Shear Zone (MSZ). Thermal history modeling suggests an early Carboniferous rapid cooling pulse (~360–330 Ma) for the COP, east of the MSZ, that is contemporaneous with the intraplate Devonian–Carboniferous Alice Springs Orogeny. In contrast, the MAP, west of the MSZ, records a protracted monotonic cooling history since the Middle Devonian, implying long-term crustal stability. The differences in low-temperature thermal histories may be preconditioned by the extent of thermal weakening during the late Mesoproterozoic, as indicated by the Lu–Hf and U–Pb results. Here, we show the value of apatite triple dating applied to grains recovered from drill core samples, demonstrating opportunities for understanding other poorly accessible terranes.

Testing the reproducibility of in situ Lu[sbnd]Hf dating using Lu-rich garnet from the Tørdal pegmatites, southern Norway

In situ LuHf geochronology offers the potential for direct dating of garnet within petrographic context. However, the method requires matrix-matched standards to calibrate measured Lu/Hf ratios. In order to assess the accuracy of this calibration, as well as the reproducibility of the resulting LuHf dates, two Lu-rich (up to 1 wt% Lu) garnet samples from the Tørdal pegmatite field in southern Norway were analysed over six analytical sessions. Multi-session isochron LuHf dates of 930.3 ± 1.4 Ma (MSWD = 1.0, 164 analyses) and 930.3 ± 1.7 Ma (MSWD = 1.5; 125 analyses) were obtained, conform with previously published age constraints. The relative standard deviation of 0.1% between the analytical sessions indicates that the dates are highly reproducible. For each individual analytical session, age uncertainties of 0.3–0.6% were achieved by measuring high Lu count rates in analog detection mode. We further describe a calibration strategy that deals with LuHf datasets where Lu is measured in both pulse and analog detector mode. Given the high analytical precision and reproducibility, we suggest that the Tørdal garnets are suitable reference materials for future LA-ICP-MS/MS LuHf studies.

Investigating low dispersion isotope dissolution Lu-Hf garnet dates via in situ Lu-Hf geochronology, Kanchenjunga Himal

Re-examination of three specimens from the Kanchenjunga Himal of Nepal via in situ Lu-Hf garnet geochronology yields evidence of multiple garnet growth events. Spot analyses from grain cores in two specimens define Paleozoic regressions whereas analyses from grain rims in the same specimens define low-precision regressions consistent with the timing of Himalayan orogenesis. These dates contrast with previously published low dispersion, ca. 290 Ma isotope dissolution (ID) Lu-Hf garnet dates for the same rocks. Modelling of Lu and spot age distribution in representative grains from the specimens examined yields calculated dates that approximate the Permian-age regressions through the original ID data. These findings demonstrate that it is possible to generate low dispersion ID Lu-Hf data from multi-generational garnet with significantly different-age growth events when approximately equal proportions of the different age reservoirs are included in multi-component aliquots.

First demonstration of in situ Lu–Hf dating using LA-ICP-MS/MS applied to monazite

Monazite is a LREE-rich accessory mineral in various igneous and metamorphic rocks; therefore, monazite geochronology has the potential to answer a range of important geological questions.

High-P metamorphism in the Mesoproterozoic: Petrochronological insights from the Grenville Province

In the Grenville Province, high-P rocks that are discontinuously exposed along the margin of the allochthonous belt preserve the record of deep crustal processes and are an essential puzzle piece to understanding Mesoproterozoic geodynamics. The Manicouagan Imbricate zone (MIZ) is one of the three high-P domains from the Grenville Province. It is located in the Central Grenville between the Parautochthonous Belt to the North and the orogenic hinterland to the South, that were metamorphosed during the 1005–980 Ma Rigolet and 1080–1020 Ma Ottawan orogenic phases, respectively. In the western MIZ, the Lelukuau Terrane (LT) mostly consists of Labradorian-age (∼1650 Ma) mafic suites with a fringe of aluminous rocks at its southern edge. Metamafic samples from the Western and Eastern parts of the MIZ display a peak assemblage of garnet, clinopyroxene, plagioclase, rare pargasite or edenite, and quartz ± kyanite. Pseudosection modelling suggests high-P granulite peak conditions at ca. 14 to 16 kbar and 800–900 °C, with the scarcity of hydrous phases and quartz explaining the lack of evidence for partial melting. Zircon cores from the Western LT sample show a maximum magmatic age of ca 1.6 Ga. Lu–Hf and Sm–Nd dating on garnet from this sample yield ages of 1020 ± 7 Ma and 1005 ± 13 Ma, respectively, overlapping within error and inferred to represent peak metamorphic conditions followed by fast cooling. In the Eastern LT sample, garnet Lu–Hf dating yields two ages that are consistent with a petrographically preserved two stage growth, at 1033 ± 6 Ma and 1013 ± 6 Ma, while the Sm–Nd age indicates cooling at 1003 ± 8 Ma. The recorded high-P granulite facies conditions highlight a late Ottawan to Rigolet-age localized crustal thickening at the margin of the hinterland during the propagation of the orogen to the NW, with a possible younging of the high-P granulite-facies metamorphism from the Eastern to Western LT. These new results indicate that the high-P belt in the Central Grenville does not represent the exhumed base of an Ottawan age orogenic plateau, as previously proposed, and that no tectonic hiatus exists between the two orogenic phases, as generally thought. Finally, this publication highlights the diversity and diachronicity of the high-P domains in the Grenville Province.

Trondhjemites from the Western Dharwar Craton, Southern India: Implications for Mesoarchean crustal growth

Trondhjemite, together with tonalite and granodiorite (TTG) are important building blocks of the Archean continental crust and their studies provide insights into the formation of the early continents. The Western Dharwar Craton (WDC) in southern India contains voluminous TTG rocks that record prolonged Archean crustal evolution history with evidence for multiple episodes of magmatic accretion and metamorphic events from the Paleoarchean (∼3600 Ma) to Archean-Proterozoic transition (∼2500 Ma ago). In this study, we investigate trondhjemites from different typical locations in the WDC. Petrological, geochemical and zircon UPb, REE and LuHf data are presented and evaluated to understand the timing of magma emplacement and petrogenetic history. The trondhjemites in our study were generated from partial melting of juvenile hydrous basalt with arc features. The melting depth is variable, mainly shallow, while some melts originated at greater depths with variable plagioclase, amphibole with or without garnet, ilmenite or rutile in source residue. The age data presented here suggest that the crust accretion of the Mesoarchean Western Dharwar Craton occurred dominantly at 3.13–3.27 Ma followed by reworking of lower crustal basement 3.0–2.9 Ga.

Eoarchean to Paleoproterozoic Crust History in the Yakutian Diamond Province: Evidence from U–Th–Pb (LA-ICP-MS) and Lu–Hf Dating of Zircons from Crustal Xenoliths in Kimberlite Pipes

Abstract —Radiometric dating of zircon grains from crustal xenoliths in kimberlites of the Yakutian diamond province show that most of the Daldyn and Markha terranes were formed in Paleoarchean but preserve some fragments of Eaoachean and possibly even Hadean crust recycled in several tectonothermal events. The oldest zircons were crystallized about 3.2 Ga and recrystallized during later activity stages of 2.9, 2.8–2.7, and 1.9 Ga, whereby they gained radiogenic hafnium produced by 176Lu decay in the rock. The degrees crust rework and the tectonothermal stages varied across the Anabar tectonic province. The earliest events of 3.2 and 2.9 Ga left record in zircons from kimberlites in the Nakyn field, while the signatures of the 2.7 Ga activity are best pronounced in zircons from kimberlites sampled in the Upper Muna and Nakyn fields. On the other hand, zircons from lower crustal mafic granulite xenoliths in the Daldyn and Alakit-Markha kimberlites lack traces of the earliest crust history and only evidence of the last 1.9 Ga event, which remained mute in xenolith samples from the Upper Muna field. Zircons from felsic granulite and metadiorite xenoliths in the Udachnaya kimberlite, which represent middle and upper crust, show a peak at 2.6 Ga besides that of 1.9 Ga. The synthesized available data support several previous inferences: vertical and lateral heterogeneity of the crust in the Yakutian diamond province; absence of linkage between the crust recycling degree and major collisional zones of the Siberian craton; absence of the separate Markha terrane. Correlation of age peaks corresponding to thermal events in the crust history of the Anabar tectonic province with those of large igneous provinces allows a hypothesis that the revealed tectonothermal events may be related with the activity of superplumes.

Multiproxy provenance analyses in the Devonian Villavicencio Formation of the Mendoza Precordillera, Argentina: correlation and geotectonic implications for the SW Gondwana margin

Abstract This work focuses on the sedimentary provenance of the Villavicencio Formation of the Mendoza Precordillera and integrates the information obtained with previous work on other coeval units of the Precordillera Central of San Juan province (Gualilán Group: Talacasto and Punta Negra formations) in western Argentina. Multiproxy provenance analyses are carried out from different applied methodologies (petrography, geochemistry, morphological, and cathodoluminescence studies of detrital zircon grains, and analysis of U-Pb and Lu-Hf isotopes). The Villavicencio Formation is mostly composed of pelites and very fine-grained psammites. The major components are quartz, both monocrystalline and polycrystalline, and metamorphic lithics that associate this unit with a recycled orogen. Regarding geochemistry, the Chemical Index of Alteration (CIA) values are similar to the Post-Archean Australian Shales (PAAS), indicating a null to incipient degree of weathering. The ratios between different trace elements and rare earth elements (REEs) suggest the felsic composition of the source area. Th/U ratios differ, but a secondary uranium enrichment is inferred. The morphological analysis of the zircon grains reveals their mainly plutonic origin. The integration of U-Pb data with Lu-Hf data shows a juvenile-mantle origin in which the populations are dominantly Mesoproterozoic and ɛHf of positive values (up to 12), indicating poor differentiation. The Villavicencio Formation would be the product of deltaic deposits in which its components are dominantly from the Western Pampean Sierras associated with the Grenville orogen, assuming exhumation and erosion of the Mesoproterozoic basement. The data support the hypothesis of equivalence and correlation with the Punta Negra Formation in the Devonian depocenters of the south-central region of the San Juan Precordillera.

Monazite in the eclogite and blueschist of the Svalbard Caledonides: its origin and forming-reactions

High-pressure low-temperature rocks from Svalbard are an excellent target for studying metamorphic reactions in Phanerozoic subduction zones. This study reveals the presence of monazite in an eclogite and a blueschist from the Vestgötabreen Complex, southwestern Svalbard. In order to investigate the monazite-forming reaction, we obtained pressure–temperature estimates coupled with U–Pb and Lu–Hf dating. Combined geothermobarometry allows to constrain three evolutionary stages of garnet growth in the eclogite: nucleation (1.6 ± 0.3 GPa at 460 ± 60 °C), peak-pressure (2.3 ± 0.3 GPa at 507 ± 60 °C), and peak-temperature (2.1 ± 0.3 GPa at 553 ± 60 °C). A zircon age of 482 ± 10 Ma is interpreted to belong to the prograde part of the pressure–temperature path. Monazite forms inclusions within garnet rims, or it is surrounded by allanite and apatite, altogether forming pseudomorphs of a tabular shape in the matrix. Textures, geothermobarometry and geochronology support the conclusion the monazite formed under high-pressure conditions at 471 ± 6 Ma. We propose that the monazite crystallization in the eclogite happened due to a decomposition of accessory phases during the decompression after peak-pressure of the metamorphic cycle. Monazite in the blueschist occurs as inclusions in garnet cores and gives an indicative age of 486 ± 6 Ma, which is interpreted to reflect the prograde growth of the garnet. Lu–Hf garnet dating resolves an age of peak-pressure metamorphism in the blueschist at 471.1 ± 4 Ma under conditions of 2.0 ± 0.03 GPa and 500 ± 30 °C. The Vestgötabreen Complex provides evidence for an early Ordovician modern-style subduction system in the proximity of the Baltica margin. Hence, this study also supports the tectonic models that favour a mixed Baltican and Laurentian provenance of south-western Svalbard.

New evidence for crustal reworking and juvenile arc‐magmatism during the Palaeoproterozoic Eburnean events in the Suhum Basin, South‐east Ghana

Contrary to what is currently known, archetypal zircon samples from gneisses and intrusive leucogranites in the Palaeoproterozoic Suhum Basin, SE Ghana, suggest the involvement of Neoarchean crustal material in the formation of the Palaeoproterozoic juvenile crust of the Birimian terranes in Ghana. The zircons dated using U–Pb dating methods and subjected to Lu–Hf isotopic analysis suggest that crustal‐forming events from different contemporaneous magmatic episodes within the Suhum Basin took place over a time interval of 139 Ma from 2224 to 2085 Ma. Whole‐rock Lu–Hf data obtained for the gneissic and leucogranitic rocks gave model ages (TDM2) ranging from 2789 to 2456 Ma with ɛHf(t) values ranging from −1.1 to +5.4. These model ages imply that the magmas that formed these rocks were sourced from the early Palaeoproterozoic juvenile mantle with substantial Neoarchean crustal reworking.

Laser ablation (in situ) Lu-Hf dating of magmatic fluorite and hydrothermal fluorite-bearing veins

Fluorite (CaF2) is a common hydrothermal mineral, which precipitates from fluorine-rich fluids with an exceptional capacity to transport metals and Rare Earth Elements (REEs). Hence, the ability to date fluorite has important implications for understanding the timing of metal transport in hydrothermal systems. Here we present, for the first time, fluorite Lu-Hf dates from fluorite-carbonate veins from the Olympic Cu-Au Province in South Australia. The fluorite dates were obtained in situ using the recently developed LA-ICP-MS/MS Lu-Hf dating method. A fluorite-calcite age of 1588 ± 19 Ma was obtained for the Torrens Dam prospect, consistent with the timing of the formation of the nearby Olympic Dam iron-oxide copper gold Breccia Complex. Veins in the overlying Neoproterozoic successions were dated at 502 ± 14 Ma, indicating a temporal link between Cu-sulphide remobilisation and the Delamerian Orogeny. Additionally, we present a multi-session reproducible date for magmatic fluorite from a monzogranite in the Pilbara Craton (Lu-Hf age of 2866 ± 19 Ma). This age is consistent with a garnet Lu-Hf age from the same sample (2850 ± 12 Ma) and holds potential to be developed into a secondary reference material for future fluorite Lu-Hf dating.

Hf isotopes in detrital zircon grains of the Sierra Albarrana Domain (SW Iberian Massif): Eburnean v. Archean basement signatures

This study presents Lu–Hf data on detrital zircon grains from the Lower Paleozoic metasedimentary successions of the Sierra Albarrana Domain (SW Iberian Massif). We provide new information about their origin, record of continental crustal evolution and geological affinity. Previous detrital zircon U–Pb data in this terrane reveal two main age populations, with age peaks at c. 595 Ma and c. 1.90 Ga. The Ediacaran events are interpreted to represent a magmatic arc with input of juvenile magmas intruding into the Eburnean basement of Gondwana, and probably mixing with it. The different evolutionary stages of the arc were probably linked to the Cadomian Orogeny during Neoproterozoic–earliest Cambrian times. The Paleoproterozoic zircon population corresponds to the Eburnean Orogeny. The magmas derived from an Eburnean depleted mantle partly intruded an older basement, leading to an incipient mixing process. ε Hf isotopic compositions indicate a possible affinity with the Central Iberian Zone, suggesting a common geological setting during Ediacaran–Cambrian times but different settings during the Paleoproterozoic. Supplementary material: A dataset of Lu/Hf analyses and a regional comparison of the ε Hf( t ) dataset with published data for metasedimentary rocks of the Iberian Massif are available at https://doi.org/10.6084/m9.figshare.c.6420215

Cadomian to Cenerian accretionary orogenic processes in the Alpine basement: the detrital zircon archive

New whole-rock geochemical and detrital zircon U–Pb and Lu–Hf data of metasedimentary sequences of the Silvretta Nappe, Orobic Alps, Strona-Ceneri Zone, Gotthard Massif and Venediger Nappe are presented. These units seem to share a common early to middle Paleozoic geological record, which has alternatively been interpreted as the result of intraplate or orogenic processes. Detrital zircon data mainly indicate late Ediacaran to early Ordovician maximum sedimentation ages for the studied sequences, suggesting that they were intimately related to Cadomian and Cenerian orogenic processes along the northwestern Gondwana margin. The common presence of late Ediacaran to Cambrian Cadomian ages associated with variable subchondritic to suprachondritic Lu–Hf compositions points to recycling processes of Cadomian sequences, further supported by geochemical data indicating a relatively low to moderate maturity of sedimentary protoliths. The occurrence of Cenerian arc-related intrusions in Austroalpine and South Alpine basement unit points to an arc/back-arc position in the early Paleozoic Cenerian orogen, except for the Strona-Ceneri Zone, which was likely located closer to the forearc region, as indicated by the presence of high-pressure metamorphism. Younger sequences, such as the Landeck Quartz-phyllite, document post-Cenerian sedimentation, whereas those of the Venediger Nappe more likely record the early stages of Variscan subduction, as indicated by Devonian maximum deposition ages.