Lower Volcanic Sequence Research Articles

Characteristics and genesis of diachronous Carboniferous volcano-sedimentary sequences: insights from geochemistry, petrology and U–Pb dating in the North Junggar basin, China

ABSTRACTThe subduction of oceanic lithosphere during the Carboniferous Period contributed to the formation of widely distributed subduction-related volcanic rocks within the Junggar basin. These volcanic rock associations contain significant clues for understanding the subduction of the Keramaili oceanic lithosphere and the filling of the remnant oceanic basin. Here, we report regional gravity and magnetic data, petrology, geochemistry, and U–Pb dating for Carboniferous volcanic rocks from the North Junggar basin (NJB). Using samples from well Y-1, we distinguish upper and lower volcanic sequences on the basis of selected geochemical data. An isochronous stratigraphic framework of Carboniferous volcano-sedimentary sequences is then constructed and the petrogenesis of these volcanic rocks is discussed. Finally, we propose an explanation for the genesis of these diachronous Carboniferous volcano-sedimentary sequences. The results show that various volcanic rocks are distributed in different areas of the NJB, and mainly consist of calc-alkaline basalt–andesite–dacite assemblages and alkaline basalt–basaltic andesite–andesite assemblages. The geochemical data also demonstrate a binary nature of the Carboniferous volcanic rocks. In the eastern NJB, the lower and upper volcanic sequences are formed during the early and late Carboniferous, respectively. However, all of these volcano-related sequences in the western of the NJB are formed during the late Carboniferous. These volcano-sedimentary sequences exhibit a ‘ladder-style’ of temporospatial evolution from east to west. The geochemical results also indicate that the upper volcanic rocks include island arc components formed in an extensional setting, whereas the lower volcanic rocks were derived from deep crustal cycling metasomatism by various mantle components in a continental arc environment. Earlier closure of the Keramaili oceanic basin and slab roll-back of the Junggar oceanic lithosphere in eastern versus western Junggar basin led to the formation of these diachronous volcano-sedimentary sequences.

Neoproterozoic subducted materials in the generation of Mesozoic Luzong volcanic rocks: Evidence from apatite geochemistry and Hf–Nd isotopic decoupling

A combined study including apatite geochemistry, zircon U–Pb, Lu–Hf isotopes and whole-rock geochemistry including Nd isotopes was carried out for the late Mesozoic volcanic rocks from the Luzong Basin, in the lower Yangtze River region, South China. Whole-rock geochemistry indicates the enrichments of large ion lithophile elements (LILE) and light rare earth elements (LREE) as well as depletions of Nb, Ta and Ti. The extremely low Cl contents in apatites strongly contrast with the rather high-K contents in whole rocks. Potential loss of Cl during syn- and post-magmatic processes having been ruled out, Cl–K decoupling is attributed to be a feature inherited from the primary magma, which indicates the involvement of highly dehydrated sediments and altered oceanic crust in the mantle source. A calculation based on apatite and whole-rock geochemistry further illustrates that the source was composed of four end-members in the perspective of Cl/K, Cl/Nb and F/K ratios. The Hf–Nd isotopes are decoupled for the basaltic trachytes from the lower volcanic sequences in the Luzong Basin, with rather low ε Hf (t) values (mean = − 10.3) and inconsistent Hf–Nd model ages (Hf ~ 1.8 Ga, Nd ~ 1.3 Ga), which indicate the “zircon effect” that in turn requires the incorporation of continental detritus in the source via subduction. However, Hf and Nd isotopes are nearly coupled for the rocks from the upper volcanic sequences in the Luzong Basin. Late-Mesoproterozoic two-stage Hf and Nd model ages (ca. 1.2 Ga) of rocks from the upper volcanic sequences in the Luzong Basin are similar to those of the Neoproterozoic igneous rocks from the Jiangnan orogen, suggesting their relationship with the same subduction event. Based on the combined apatite geochemistry and Hf–Nd isotopes, this work suggests that the source of Luzong volcanic rocks might incorporate Neoproterozoic subducted slab fragments and detrital sediments that had been blocked in the deep lithospheric mantle below the Luzong area since the Neoproterozoic assembly between the Yangtze and Cathaysia blocks. The partial melting may be triggered by the back-arc lithospheric extension related to the subduction of Paleo-Pacific plate in the late Mesozoic.

The Tertiary evolution of the prolific Nanpu Sag of Bohai Bay Basin, China: Constraints from volcanic records and tectono-stratigraphic sequences

The Bohai Bay Basin, located on the eastern Asian margin, is the second largest oil-production basin in China. It contains numerous depressions and sags, among which Nanpu Sag has become particularly important because of significant oil discoveries in recent years. Geologically and tectonically, however, the rifting mechanism and geodynamic evolution of the basin remain uncertain. This paper uses detailed volcanic and stratigraphic records obtained through extensive drilling and sampling in Nanpu Sag to interpret tectono-stratigraphic sequences and discuss basin dynamic evolution and crust-mantle interactions of the Bohai Bay Basin. Nanpu Sag contains voluminous volcanic rocks of dominantly alkaline basalts. Drill core samples, well logs, and seismic profiles reveal three volcanic cycles between the Eocene and Miocene Epochs. These basalts were created during a transition from garnet- to spinel-peridotite. Five tectono-stratigraphic sequences produced by episodic continental rifting have been identified, each composed of a basal coarse clastic sequence, a lower volcanic sequence, a middle deep-water clastic sequence, and an upper infilling sequence. Tectonically, Nanpu Sag experienced four evolutionary phases. The first three corresponded to three rifting events revealed by cyclic volcanism and sedimentary depositional features. The fourth phase was marked by extreme thermal subsidence and prograding fluvial deposition followed by tectonic inversion. A diapiric upper-mantle upwelling model is proposed to explain the dynamics that controlled the multiple rifting processes, the cyclic volcanism, and the periodic tectonic evolution of Nanpu Sag and the greater Bohai Bay Basin.

Metallogenesis of the Carajás Mineral Province, Southern Amazon Craton, Brazil: Varying styles of Archean through Paleoproterozoic to Neoproterozoic base- and precious-metal mineralisation

Abstract The Itacaiunas Belt of the highly mineralised Carajas Mineral Province comprises ca. 2.75 Ga volcanic rocks overlain by sedimentary sequences of ca. 2.68 Ga age, that represent an intracratonic basin rather than a greenstone belt. Rocks are generally at low strain and low metamorphic grade, but are often highly deformed and at amphibolite facies grade adjacent to the Cinzento Strike Slip System. The Province has been long recognised for its giant enriched iron and manganese deposits, but over the past 20 years has been increasingly acknowledged as one of the most important Cu–Au and Au–PGE provinces globally, with deposits extending along an approximately 150 km long WNW-trending zone about 60 km wide centred on the Carajas Fault. The larger deposits (approx. 200–1000 Mt @ 0.95–1.4% Cu and 0.3–0.85 g/t Au) are classic Fe-oxide Cu–Au deposits that include Salobo, Igarape Bahia–Alemao, Cristalino and Sossego. They are largely hosted in the lower volcanic sequences and basement gneisses as pipe- or ring-like mineralised, generally breccia bodies that are strongly Fe- and LREE-enriched, commonly with anomalous Co and U, and quartz- and sulfur-deficient. Iron oxides and Fe-rich carbonates and/or silicates are invariably present. Rhenium–Os dating of molybdenite at Salobo and SHRIMP Pb–Pb dating of hydrothermal monazite at Igarape-Bahia indicate ages of ca. 2.57 Ga for mineralisation, indistinguishable from ages of poorly-exposed Archean alkalic and A-type intrusions in the Itacaiunas Belt, strongly implicating a deep magmatic connection. A group of smaller, commonly supergene-enriched Cu–Au deposits (generally The highly anomalous, hydrothermal Serra Pelada Au–PGE deposit lies at the north-eastern edge of the Province within the same fault corridor as the Archean and Paleoproterozoic Cu–Au deposits, and like the Cu–Au deposits is LREE enriched. It appears to have formed from highly oxidising ore fluids that were neutralised by dolomites and reduced by carbonaceous shales in the upper sedimentary succession within the hinge of a reclined synform. The imprecise Pb–Pb in hydrothermal phosphate age of 1861 ± 45 Ma, combined with an Ar/Ar age of hydrothermal biotite of 1882 ± 3 Ma, are indistinguishable from a Pb–Pb in zircon age of 1883 ± 2 Ma for the adjacent Cigano A-type granite and indistinguishable from the age of the Paleoproterozoic Cu–Au deposits. Again a magmatic connection is indicated, particularly as there is no other credible heat or fluid source at that time. Finally, there is minor Au–(Cu) mineralisation associated with the Formiga Granite whose age is probably ca. 600 Ma, although there is little new zircon growth during crystallisation of the granite. This granite is probably related to the adjacent Neoproterozoic (900–600 Ma) Araguaia Fold Belt, formed as part of the Brasiliano Orogeny. Thus, there are two major and one minor period of Cu–Au mineralisation in the Carajas Mineral Province. The two major events display strong REE enrichment and strongly enhanced LREE. There is a trend from strongly Fe-rich, low-SiO2 and low-S deposits to quartz-bearing and more S-rich systems with time. There cannot be significant connate or basinal fluid (commonly invoked in the genesis of Fe-oxide Cu–Au deposits) involved as all host rocks were metamorphosed well before mineralisation: some host rocks are at mid- to high-amphibolite facies. The two major periods of mineralisation correspond to two periods of alkalic to A-type magmatism at ca. 2.57 Ga and ca. 1.88 Ga, and a magmatic association is compelling. The giant to world-class late Archean Fe-oxide Cu–Au deposits show the least obvious association with deep-seated alkaline bodies as shown at Palabora, South Africa, and implied at Olympic Dam, South Australia. The smaller Paleoproterozoic Cu–Au–W–Sn–Bi deposits and Au–PGE deposit show a more obvious relationship to more fractionated A-type granites, and the Neoproterozoic Au–(Cu) deposit to crustally-derived magmas. The available data suggest that magmas and ore fluids were derived from long-lived metasomatised lithosphere and lower crust beneath the eastern margin of the Amazon Craton in a tectonic setting similar to that of other large Precambrian Fe-oxide Cu–Au deposits.

Magmatic relationships and ages between adakites, magnesian andesites and Nb-enriched basalt-andesites from Hispaniola: Record of a major change in the Caribbean island arc magma sources

Located in the Cordillera Central of the Dominican Republic, the Late Cretaceous Tireo Fm (TF) records a major change of the magma sources in the Caribbean island arc. It comprises a > 3 km thick sequence of arc-related volcanic and volcano-sedimentary rocks with variable geochemical characteristics. Combined detailed mapping, stratigraphy, geochemistry and U–Pb/Ar–Ar geochronology show that the volcanic rocks of the Tireo Fm include two main volcanic sequences. The lower volcanic sequence is dominated by monotonous submarine vitric–lithic tuffs and volcanic breccias of andesite to basaltic andesite, with minor interbedded flows of basalts and andesites. Fossil and (U–Pb and 40Ar– 39Ar) geochronological data show that arc magmatism in the lower sequence began to accumulate before ∼ 90 Ma, from the Aptian to Turonian. These rocks constitute an island arc tholeiitic suite, derived from melting by fluxing of a mantle wedge with subduction-related hydrous fluids. The upper volcanic sequence is characterized by a spatial and temporal association of adakites, high-Mg andesites, and Nb-enriched basalts, which collectivelly define a shift in the composition of the subduction-related erupted lavas. A dacitic to rhyolitic explosive volcanism with subaerial and episodic aerial eruptions, and sub-volcanic emplacements of domes, characterize mainly this stratigraphic interval. The onset of this volcanism took place at Turonian–Coniacian boundary and continued in the Santonian to Lower Campanian, with minor events in the Late Campanian. Adakites represent melts of the subducting slab, magnesian andesites the product of hybridization of adakite liquids with mantle peridotite, and Nb-enriched basalts melts of the residue from hybridization. We propose a model of oblique ridge subduction at ∼ 90 Ma and possibly subsequent slab window formation, as principal cause of magmatic variations recorded in the Caribbean island arc, above a southwestern-dipping subduction zone.

PETROGENESIS AND TECTONO-MAGMATIC SIGNIFICANCE OF THE ALBANIDE - HELLENIDE SUBPELAGONIAN OPHIOLITES

The Mirdita-Subpelagonian ophiolites of the Albanide-Hellenide orogen are parts of a continuous belt extending from the former Yugoslavia to Greece, and share common geological, litho-stratigraphical, geochemical, and metallogenic features. In the Albanian sector, two distinct ophiolitic belts can be clearly identified: the Western Belt, mainly composed of mid-ocean ridge (MORB) ophiolites, and the Eastern Belt characterized by supra-subduction zone (SSZ) ophiolites with prevalent island arc tholeiitic (IAT) and minor boninitic affinity. In the easternmost border of the Western Belt (Central Mirdita), a transitional zone with MORB/IAT intermediate basalts and boninitic dykes also occur. In the Greek sector, a definite distinction into two ophiolitic belts cannot be made, and MORB-type ophiolites (western type) are subordinate, being represented only by the intrusive and lower volcanic sequences of the Pindos Massif. By contrast, SSZ- ophiolites (eastern type) are predominant and well-represented by the IAT and boninitic sequences of the Vourinos Massif, as well as by MORB/IAT intermediate basaltic-andesitic suites and boninites of the upper part of the Pindos volcanic sequence. Petrological and geochemical modelling suggest that the different Albanide -Hellenide ophiolitic sequences originated from distinctly different parental magmas by partial melting of mantle sources progressively depleted by previous melt extractions. MORB may have derived from 10 - 20% partial melting of an undepleted lherzolitic source, while MORB/IAT intermediate basalts may have generated by ca. 10% of H2O-assisted partial melting of a cpx-poor lherzolite that had previously experienced MORB extraction. IAT magmas and boninites may, in turn, have derived from 10 – 20 % and ca. 30% partial melting of the same source, variably enriched by subduction-derived fluids and related incompatible elements. The favoured tectono-magmatic model for the genesis of the Albanide-Hellenide ophiolites implies a low plate-convergence velocity with: 1) intra-oceanic subduction within a pristine MORB lithosphere, resulting in SSZ magmatism with IAT affinity, and generation of a nascent arc by nearly open-system supply of undifferentiated basalts (sheeted dyke complexes); 2) progressive slab sinking and retreat coupled with mantle diapirism and extension from the arc axis to the forearc region, with generation of boninites and/or very low-Ti tholeiites from depleted sub-arc sources, leaving highly depleted harzburgitic residua; 3) contemporaneous generation at the spreading axis of IAT/MORB intermediate basalts resulting from the interference of MORB-source diapirs with suprasubduction mantle sources; 4) convergence processes leading to obduction of large and relatively intact lithospheric sections of SSZ ophiolites onto the Pelagonian continental margin, often with the interposition of metamorphic soles. The latter have prevalent MORB affinity and represent relics of the pristine MORB lithosphere overthrust by the still hot ophiolitic slab.

Geochemistry and petrogenesis of Archean mafic volcanic rocks of the southern Abitibi Belt, Québec

The Blake River Group of the late Archean Abitibi Greenstone Belt is characterized by the abundance of differentiated lava series as well as by the presence of coeval tholeiitic and calc-alkaline eruptives. Differentiated tholeiites from this group are interpreted as the product of magma mixing between asthenospheric tholeiites and subduction-related calc-alkaline basaltic andesites. From the lower to the upper southern Abitibi Belt, chemical variations recorded in tholeiites are indicative of a major change in the geodynamic regime. Tholeiites from the lower volcanic sequence were produced by a high degree of partial melting of adiabatically rising diapirs below a rifted lithosphere. Uncontaminated tholeiites from the upper part of the belt reflect a lower degree of partial melting probably due to decreasing lithospheric stretching. This may be related to the closure of the rift-related volcanic basins at the begining of the Kenorean deformational events in the Southern Abitibi Belt.