Low Sr Contents Research Articles

Coupled Effects of Paleofluid Evolution on Ultra-deep Microbialite Reservoir Modification: A case study of the upper Ediacaran Deng-2 Member within the Penglai area of central Sichuan Basin, SW China

Paleofluid-rock interaction results in the modification of the ultra-deep reservoir quality, but the coupling effects of the paleofluid evolution on reservoir quality modification are still underestimated. Here, the multi-stage dolomite cements have been studied by means of core observations, thin section identification, fluid inclusions, and in situ elements and isotopic analyses in order to reaveal the paleofluid evolution processes and their effects on the reservoir quality. The fibrous dolomite cement (FDC) and bladed dolomite cement (BDC) both have similar geochemical properties and homogenization temperature (Th) to the matrix dolostone. Subsequent early silicification occurs (QZ1). However, silt- to fine-sized crystalline dolomite cement (CD2) has higher concentration of Fe and medium rare earth element, more negative δ18O than for FDC and BDC, and 103.4 to 150.2 °C in Th. The first petroleum charge episode solid bitumen 1 (SB1) followed the CD2. The medium to coarse sized crystalline dolomite cement (CD3) is characterized by the higher Mn and lower Sr concentration than CD2, positive δEu anomaly, negative δ13C and δ18O, high 87Sr/86Sr ratio and 138.9 °C to 184.3 °C in Th. The solid bitumen 2 (SB2) occurs after CD3. Subsequently, the saddle dolomite (SD) has higher Fe and Mn concentration and lower Na and Sr than others cement, δEu positive anomaly, negative δ13C and δ18O, high 87Sr/86Sr ratio and 177.5 °C to 243.6 °C in Th. Eventually massive silicification (QZ2) took place. The FDC, BDC, QZ1 and SB1 formed in the early diagenetic stage and have little negative effect on the reservoir quality. But the CD2 and CD3 dramatically decreased the reservoir quality related to a quantity of hydrothermal fluids entrance in the mesodiagenetic stage along the strike-slip faults and the unconformity surface at top of the Deng-2 Member during the late stage of the Caledonian orogeny. The reservoir spaces were retained and enlarged during the late diagenetic stage when the peak petroleum charge occurred, massive silicification and thermochemical sulphate reduction took place with SB2, SD and QZ2 being formed. The research outcome may update our understanding on the retention mechanism and the insights for further hydrocarbon exploration of Precambrian ultra-deep microbial reservoirs.

Geochemical features of deluvial-lacustrine sedimentogenesis in the basin of lake Chistoye, Northern Priokhotsk area

The results of the geochemical study of loose sediments of the catchment basin and bottom sediments of Lake Chistoye, located in the Northern Priokhotye, showed that the lake was formed at the beginning of the early Holocene about 11200 cal. years ago. Terrigenous sedimentation dominates in it, i. e. the geochemical characteristics of sediments are determined by the particle sizes. Thin grain size sediments have low SiO2, Na2O, K2O, CaO, and Sr contents; and are enriched with Al2O3, TiO2, MgO, Fe2O3, and V. Changes in the nature of sedimentation may be due to climatic reasons and may be associated with cold Bond events. In the Early Holocene, mostly thin silts were deposited in Lake Chistoye. The impulse of “coarse-grained” sediments (140 microns) enriched with silica occurred (9760–9650) and 8810 cal. years ago. A noticeable accumulation of relatively coarse-grained sediments occurred at the very beginning of the Middle Holocene 8540–6920 cal. years ago, as well as 6140 and 4450 cal. years ago. For the Late Holocene, the input of detrital material with increased SiO2 contents was noted in the range of 3470–850 cal. years ago.

Li-mineralized pegmatite of anatectic origin: Constraints from Li[sbnd]Hf isotopes and geochemical modeling

Pegmatites are important reservoirs of lithium resources. There is an ongoing debate as to whether Li-mineralized pegmatites were generated from evolved granitic systems via extreme differentiation or by direct melting of metasedimentary rocks. The Chinese Altay is one of the largest pegmatite provinces in the world, and includes many rare-metal pegmatites (e.g., Koktokay, Kelumute, Kaluan and Azubai). However, they display significant differences in formation ages and isotopic compositions compared with the neighbouring or potential parental granites. In this contribution, we present a case study of the Kaluan Li ore deposit in the Chinese Altay, elucidating the origins of pegmatites and related Li mineralization. The Kaluan Li-mineralized pegmatites are characterized by high SiO2, K2O, Na2O, Li, Cs, Ta, and Rb contents; low Fe2O3T, MgO, Ba, and Sr contents; and peraluminous signatures. They have homogeneous HfLi isotopic compositions (εHf (t) = −0.6 to +2.5; δ7Li = +1.6 to +5.8‰) that are within the range of HfLi isotopic compositions of the Kulumuti Group schists (εHf (t) = −2.8 to +7.5; δ7Li = −8.6 to +10.8‰). In addition, the chemical compositions of the melt derived from the partial melting of the Kulumuti Group by phase equilibrium modeling are compatible with our analyses of the Kaluan Li-mineralized pegmatites. These similarities suggest that the Kaluan Li-mineralized pegmatites were derived from the partial melting of the Kulumuti Group schists at depths during the Triassic, in a post-orogenic and extensional setting. The generation of these pegmatites was mostly controlled by biotite dehydration melting at relatively high temperatures, rather than by the low-temperature melting of muscovite. Trace elements modeling results show that approximately 33–36% partial melting of the average Kulumuti Group schist may produce melts with maximum Li concentrations ranging from 664 to 751 ppm. Subsequently, a high degree of fractionation exceeding 85%, was required for the Li concentration of the residual melt to reach concentrations suitable for crystallization into albite-spodumene pegmatites. Based on our research, an anatectic origin model may have general applicability in explaining the genesis and mineralization of rare-metal pegmatites in the Chinese Altay.

Geochemical Characteristic of the Carbonaceous Sediments of the Upper Paleozoic Kuantan Group, Malaysia

The geochemical parameters discussed in this paper are based on the analysis of twelve outcrop carbonaceous samples, mainly black shales, using X-Ray Fluorescence (XRF) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) techniques. These samples are representative of the Charu, Sagor, and Permian formations. The aim of this study is to define and discuss their characteristics, the distribution abundance of major and minor elements, investigate the dominant mineralogical composition, and reconstruct the depositional environment for these sediments. The bulk chemical results showed that the average values of the major elements are 65.83%, 64.82%, and 71.4% SiO?; 18.27%, 22.2%, and 15.66% Al?O?; 1.53%, 0.99%, and 2.49% Fe?O?; and 4.06%, 6.25%, and 3.66% K?O for the Charu, Sagor, and Permian formations, respectively. The minor elements recorded values of 524.4 ppm, 758.8 ppm, and 446.3 ppm Ba; 366 ppm, 399.3 ppm, and 257.3 ppm Rb; 88 ppm, 67.3 ppm, and 47.3 ppm Sr; and 308 ppm, 288.8 ppm, and 327 ppm Zr for the Charu, Sagor, and Permian formations, respectively. The major oxides reflect the dominant mineralogical composition of quartz and other silicate minerals (e.g., illite, kaolinite, smectite) and a deficiency in carbonates. The high Rb/K ratio suggests a brackish marine environment or rapid deposition that prevented equilibrium between Rb and K in these shales. The high Rb/Sr ratios of 4.16, 5.89, and 5.44 for the Charu, Sagor, and Permian formations, respectively, are possibly attributed to the low Sr content due to reducing conditions prevailing during the deposition of these sediments.

Geochemistry and origin of the Late Carboniferous ultramafic, mafic, and felsic plutonic rocks (NW Iran)

The Late Carboniferous Gharabagh-Mamkan-Mingol plutonic complex (GMMP) consists of a variety of ultramafic, mafic, felsic intrusive rocks, including the 325–315 Ma Gharabagh gabbroic, granitic, and monzonitic rocks and Mamkan-Mingol 320–315 Ma massive appinites (hornblende-rich gabbros) and 300–295 Ma layered mafic-ultramafic (gabbro, appinitic gabbro, and appinite) rocks in the northwestern Sanandaj-Sirjan zone, Iran. The relationships between various rock types in the plutonic complex are unknown. To address these issues, we conducted a detailed petrologic and geochemical study of the complex, and its country rocks.The abundance of major and trace elements and isotopic ratios of 87/86Sr (0.70379–0.70428) and 143/144Nd (0.51228–0.51245) systems showed that the Gharabagh gabbros formed from a metasomatized amphibole-bearing spinel lherzolite from an ancient subduction-modified mantle source with OIB characteristics including high contents of light rare earth elements (LREEs), Ti, Nb, Ta, and Ba, as well as low concentrations of Sr, Hf, and Zr. The geochemical data show that monzonites had high concentrations of LREEs, Ba, U, K, Hand Zr, and the low contents of Th, Nb, Ta, Sr, P, and HREEs and Eu-positive anomalies and originated from the melting of the continental crustal base in the subducted mantle wedge. The granites are similar to monzonites, with their difference being in the high concentrations of Th and Eu-negative anomalies. Combining petrographic, petrological, geochemical, and isotopic data suggests that Gharabagh plutonic rocks were formed as a result of Paleo-Tethys slab break-off, and slab sinking, during trans-tensional collision between the Central Iranian microplate and Gondwanaland during the Late Carboniferous. As a result of this event, decompression melting began in the upwelling mantle, coeval with the formation of the pull-apart basin, during major strike-slip faulting, leading to a hydrous mafic melt with about 10–12% partial melting.The Mamkan-Mingol massive and layered masses have a tholeiitic affinity. The Mamkan-Mingol rocks are characterized by different trace element patterns, especially in the concentrations of REEs and high field strength elements (HFSEs) such as Nb, Ta, Hf, Zr, and P and large-ion lithophile elements (LILEs) such as Th, U, Sr, K, Rb, and Ba. The massive and layered rocks mostly show a variably developed negative anomaly in HFSEs, and widely varying ratios of (La/Yb)n (1.0–5.2). Massive appinites and layered gabbros of GMMP originated due to different partial melting in the upwelling zone of metasomatized OIB-like amphibole-bearing spinel lherzolite and a less hydrous- to dry upwelling mantle zone, respectively, in an environment associated with the initiation of rifting, where the remnants of the Paleo-Tethys subducted slab plunges deep into the mantle. Contrasting Nd isotopic ranges are present between the massive appinites (ɛNd = +0.39) and different types of mafic-ultramafic rocks in layered outcrops (ɛNd = +1.12 to +2.07) of the complex. Based on the geochemical and isotopic (ratios of Sr, Nd, and Pb) data, we suggest that variations in of contribution of slab-derived fluids or crustal components in the primary melt caused the generation of massive appinites and different types of layered gabbros.

Strontium isotopes and rare earth elements in terrestrial hot-spring deposits: Characterization and geothermal implications

Identifying geothermal reservoir rock types is fundamental in geothermal exploration, but the absence of active surface geothermal manifestations (especially hot springs) in blind geothermal systems makes this identification difficult. Nevertheless, blind geothermal systems may develop early-formed hot-spring deposits. As (bio-)chemical precipitate, these deposits may retain geochemical signatures of spring waters and thus provide insights into reservoir rock types. To assess their geothermal implications, the 87Sr/86Sr and rare earth elements + yttrium (REE + Y) characteristics of hot-spring deposits in two geothermal systems were investigated and compared with those of their reservoir rocks. Results showed relatively uniform 87Sr/86Sr values in hot-spring deposits within each system, but occasional 87Sr/86Sr contamination induced by exogenous detritus input was also observed. The amount of detritus input relates to the potential for interaction with surrounding soils/rocks and is thus environmentally controlled. Hot-spring deposits with high Sr concentrations showed greater 87Sr/86Sr contamination resistance than those with low Sr concentrations, revealing the influence of Sr concentration in hot-spring deposits on detrital 87Sr/86Sr contamination. The detritus input also influenced the REE + Y signatures of the hot-spring deposits, underscoring the necessity of contamination assessment before geochemical interpretation. Excluding samples with significant 87Sr/86Sr and/or REE + Y contamination, the remaining samples closely mirrored their respective reservoir rocks in terms of 87Sr/86Sr, with partial overlap in REE + Y signatures. This suggests that the 87Sr/86Sr and REE + Y characteristics of hot-spring deposits provide valuable insights into reservoir rock types. However, variations in 87Sr/86Sr or REE + Y compositions between some hot-spring deposits and corresponding reservoir rocks indicate additional influencing factors beyond reservoir rock types. Therefore, a comprehensive understanding of reservoir rock types requires integrated geochemical characterization, probably including 87Sr/86Sr, REE + Y, and other parameters. These findings underscore the potential of geochemical characterization of hot-spring deposits for identifying geothermal reservoir rock types, and this geochemical approach can complement geological and geophysical data to improve exploration efficiency, especially in blind geothermal systems.

Multi-stage magmatism and Sn-polymetallic mineralization in the Shuicheng Region, SW China

The economically important tin‑tungsten mineralization in southwestern China has attracted much interest in recent years, yet its age, tectonic setting, and genetic relationship to the host granites remain uncertain in most regions. Our focus in this study is the Shuicheng tin-polymetallic deposit, situated in the western sector of the Diantan Batholith, within the northern Tengchong Block. The granites in this area consist of two intrusive units, i.e., 1) biotite monzogranite (T1), with LA-ICP-MS zircon UPb ages ranging from 76.88 ± 0.43 Ma to 74.69 ± 0.57 Ma, whole-rock εNd(t) values ranging from −9.75 to −8.11, and zircon εHf(t) values from −12.19 to −8.85; and 2) alkali-feldspar granite (T2), with an LA-ICP-MS zircon UPb age of 52.16 ± 0.23 Ma, whole-rock εNd(t) values of −10.15 to −8.25, and zircon εHf(t) values of −9.64 to −8.06. These two intrusive events have been linked to prolonged low-angle subduction and retreat of the subducting Neo-Tethys Ocean Plate, respectively. The Shuicheng granites exhibit high concentrations of SiO2 and Al2O3, contrasted with low levels of FeOT, CaO, MgO, TiO2, and P2O5, suggesting that they are highly fractionated S-type granites. High abundances of Rb, K, U, and Hf, along with low contents of Ba, Sr, and Ti, further indicate significant fractionation and crystallization processes during magma evolution. Importantly, a transition from purely magmatic conditions to a magmatic-hydrothermal state occurred during the latter stages of magmatic evolution. This transition, associated with an amplified potential for tin mineralization, provides fresh insight into the role of magmatic processes in ore genesis, enriching our understanding of the tin‑tungsten mineralization history of the Tengchong region.

Diagenetic evolution and origin of cements of the Cretaceous carbonates in the Akal Block, southeast Gulf of Mexico

The Cretaceous succession of deep marine facies (580 m-thick) of the Akal Block, southeast of the Gulf of Mexico, is dominated by lime mudstones that have been extensively affected by dolomitization. Petrographic examination, including cathodoluminescence (CL), and microthermometry reveal three phases of dolomitization that occurred as replacement and pore-/fracture-filling cements. These are (1) an early replacement dolomicrite (D1, <50 μm) with dull orange CL, (2) eu-to subhedral dolomite (D2, 60 μm–150 μm) with distinctive cloudy cores (dull CL) and clean edges (non-luminescent to dull CL), and intercrystalline porosity (6 %), and (3) anhedral vug-/fracture-filling dolomite (D3, 200 μm–500 μm) exhibiting CL zonation. The mean δ18O values of those dolomites show a trend of slight decrease from D1 to D3 (D1 = 0.0 ± 1.3‰ VPDB, D2 = −0.2 ± 1.1‰ VPDB, D3 = −1.2 ± 1.6‰ VPDB), which reflects the influence of progressive burial. The low Sr contents (101 ± 29 ppm) of D1, along with its near-micritic grain size and estimated δ18OD1fluid of parent dolomitizing fluid (−3.6‰–1.9‰ SMOW), support early-stage dolomitization at low temperature of near-surface conditions from solutions of mixed meteoric and seawaters. The higher estimated δ18Ofluid values of D2 and D3 (3.0–13.9‰ SMOW) are expected for fluids in burial settings of high temperatures. The homogenization temperatures of the primary two-phase fluid inclusions of D2 (Th = 99.1 ± 7.9 °C) and D3 (Th = 89.5 ± 11.2 °C) suggest precipitation at deeper burial settings, which is also consistent with their lower Sr contents (80 ± 14 ppm and 98 ± 33 ppm, respectively). The lower mean Th value of D3 than that of D2 likely reflects the influence of tectonic uplift that affected the Akal Block. The shale-normalized (REESN) patterns of the dolomites mimic that of modern seawater and those of D1 and D2, in particular, coincide with that of the lime mudstones (C1), thus suggesting that C1 was their precursor and also D3 originated almost from the same parent fluid that its geochemical composition evolved with progressive burial. The latest fracture-filling calcite cement (C2) postdated D3. The investigation of the products of burial diagenesis, such as fracturing, dissolution, and dolomitization events and their relationship with the tectonic uplift of the Akal Block allows a better understanding of the factors controlling the quality of Cretaceous reservoir rocks.

Predictors of urinary heavy metal concentrations among pregnant women in Jinan, China

BackgroundToxic heavy metal exposure and insufficiency or excess of essential heavy metals may have negative effects on pregnant women’s health and fetal growth. To date, the predictors of pregnant women’s heavy metal exposure levels remain unclear and vary with different regions. The study intended to explore potential predictors of exposure to heavy metals individually and high co-exposure to heavy metal mixtures. MethodsWe recruited 298 pregnant women in first trimester from prenatal clinics in Jinan, Shandong Province, China, and collected spot urine samples and questionnaire data on their demographic characteristics, lifestyle habits, consumption of food and dietary supplement, and residential environment. All urine samples were analyzed for seven heavy metals: cobalt (Co), molybdenum (Mo), strontium (Sr), arsenic (As), cadmium (Cd), lead (Pb) and mercury (Hg). ResultsFactors associated with single heavy metal concentration were as follows: a) urinary As, Sr and Cd increased with women’s age respectively; b) pregnant women with higher monthly household income per capita had lower Sr and Mo levels; c) pregnant women with intermittent folic acid supplementation and those not taking tap water as domestic drinking water had lower Sr concentrations; d) Cd was positively linked with consumption frequency of rice; e) Hg was adversely related to consumption frequency of egg and the women who took purified water as domestic drinking water had lower Hg exposure. In addition, pregnant women’s age was positively associated with odds of high co-exposure to Co, As, Sr, Mo, Cd and Pb; while those with an educational level of college had lower odds of high exposure to such a metal mixture compared with those whose educational levels were lower than high school. ConclusionPredictors of single urinary heavy metal concentration included pregnant women’s age (As, Sr and Cd), monthly household income per capita (Sr and Mo), folic acid supplementation (Sr), rice consumption frequency (Cd), egg consumption frequency (Hg) and the type of domestic drinking water (Sr and Hg). Pregnant women with older age, lower educational level tended to have high co-exposure to Co, As, Sr, Mo, Cd and Pb.

Can the Gondwana, Oligocene, and Palaeocene-Eocene coals of India be used as a strontium isotope chronometer?

Strontium isotope data of the Gondwana, Oligocene, and Palaeocene-Eocene coals of India has been compiled for the first time in this report. The Gondwana coals of peninsular India from the Talcher, Ib, Rajmahal, Wardha, and Korba coalfields have the highest mean 87Sr/86Sr value of 0.731762 ± 0.000034 (2σ). Compared with the high radiogenic 87Sr content of the non-marine Gondwana coals, the Oligocene coals from the Makum coalfields in Assam and the Palaeocene-Eocene coals of Meghalaya in North East India had mean 87Sr/86Sr values of 0.708998 ± 0.000029 (2σ) and 0.716335 ± 0.000032 (2σ) respectively. The Sr concentration (mg/kg) of the three types of coal decreased in the order of Oligocene (170.6 mg/kg) > Palaeocene-Eocene (45 mg/kg) > Gondwana (35.6 mg/kg). The one-way ANOVA test done on the strontium data of the three types of coal showed significant differences (at p < 0.05) in the mean 87Sr/86Sr values of the Gondwana and Palaeocene-Eocene coals but homogeneity in the Oligocene coals. The high 87Sr/86Sr and low Sr content in the Gondwana coals can be attributed to silicate weathering products in these coals. In the coals of Meghalaya, the 87Sr/86Sr ratios are influenced by both silicates and carbonates. The Rb/Sr versus 87Sr/86Sr plots for both the Gondwana and Palaeocene-Eocene coals showed a weak positive correlation in contrast to the Oligocene coals. The mean 87Sr/86Sr value of the Oligocene coals was similar to the range of 87Sr/86Sr values obtained in marine-derived gypsum in the Miles coal of China and therefore, provides an opportunity for the construction of a strontium isotope chronometer.

Formation of Fe4+ based on the Fe-O bond lengths in perovskite Eu1-xSrxFeO3

The physical properties of high oxidation state of transition metal oxide compounds have attracted many research interest for its potential applications. A systematic investigation of Fe4+ in Eu1-xSrxFeO3 with x = 0, 0.1, 0.2, 0.3, and 0.4 has been carried out in polycrystalline form obtained using sol-gel method. The single phase of Eu1-xSrxFeO3 is observed up to x = 0.3. The X-Ray powder pattern for low Sr content of x = 0.1, is best refined by using EuFeO3 crystal structure with Sr occupied the Eu-site. On the other hand, for higher Sr contents, two phases of EuFeO3 and Eu1/3Sr2/3FeO3 are required to obtained the best refinement. The result of the refinements shows that the volume and the average bond lengths of Fe-O decreases as increasing the Sr content. These results are consistent to support the existence of Fe4+ upon Sr doping in Eu1-xSrxFeO3. For the Sr content of x = 0.1, an anomalous change of the volume is observed.

Analyses of fin ray types to detect strontium markers in juvenile blunt-snout bream Megalobrama amblycephala

BackgroundRestocking by introducing hatchery-reared fish into wild habitats aids in the restoration of fishery aquatic ecosystems and reefs to increase the abundance of fish resources, restore the ecological balance of water bodies, and enhance ecosystem functioning. Accurately, rapidly, and effectively evaluating the success of restocking using chemical markers (e.g., strontium [Sr]) remains challenging for fisheries management. Consequently, for non-lethal fish sampling, hard tissues, such as fin rays, have received increasing attention as a target for marking method. However, data on the differences in marking different types of fin rays remain limited. Therefore, we exposed juvenile blunt snout bream individuals (Megalobrama amblycephala) to 0 (control group) or 800 mg/L of SrCl2·6H2O (marked group) for 5 days and transferred them into normal aerated water for post-immersion culture. We sampled their pectoral, dorsal, ventral, anal, and caudal fin rays. The Sr marks among the fin types were sampled at 0 and 20 days post-immersion and evaluated using an electron probe micro-analyzer (EPMA) for the five-day Sr/Ca ratios, along with line transect and Sr mapping analyses.ResultsSr marking signatures were observed in all fin types in the marked group, with a success rate of up to 100%. Although marking efficiency varied among the different fin ray types, the highest Sr/Ca ratios were most often detected in the dorsal fin. Cross-sectional Sr concentration maps of all fin rays sampled showed high-Sr domains in the marked group; in contrast, the entire cross-sections of the control group displayed low Sr contents, indicating successful marking efficiency.ConclusionsFin ray Sr marking is a successful method for juvenile M. amblycephala, with the advantages of non-lethality and negligible sampling injuries, facilitating the rapid and effective evaluation of Sr marking in restocking M. amblycephala.

Genesis of the Nuri Cu‐W‐Mo Deposit, Tibet, China: Constraints from in situ Trace Elements and Sr Isotopic Analysis of Scheelite

AbstractThe Nuri deposit is the only Cu‐W‐Mo polymetallic deposit with large‐scale WO3 resources in the eastern section of the Gangdese metallogenic belt, Tibet, China. However, the genetic type of this deposit has been controversial since its discovery. Based on a study of the geological characteristics of the deposit, this study presents mineralization stages, focusing on the oxide stage and the quartz‐sulfide stage where scheelite is mainly formed, referred to as Sch‐A and Sch‐B, respectively. Through LA‐ICP‐MS trace element and Sr isotope analyses, the origin, evolutionary process of the ore‐forming fluid and genesis of the ore deposit are investigated. Scanning Electron Microscope‐Cathodoluminescence (SEM‐CL) observations reveal that Sch‐A consists of three generations, with dark gray homogenous Sch‐A1 being replaced by relatively lighter and homogeneous Sch‐A2 and Sch‐A3, with Sch‐A2 displaying a gray CL image color with vague and uneven growth bands and Sch‐A3 has a light gray CL image color with hardly any growth band. In contrast, Sch‐B exhibits a ‘core‐rim’ structure, with the core part (Sch‐B1) being dark gray and displaying a uniform growth band, while the rim part (Sch‐B2) is light gray and homogeneous. The normalized distribution pattern of rare earth elements in scheelite and Sr isotope data suggest that the early ore‐forming fluid in the Nuri deposit originated from granodiorite porphyry and, later on, some country rock material was mixed in, due to strong water‐rock interaction. Combining the O‐H isotope data further indicates that the ore‐forming fluid in the Nuri deposit originated from magmatic‐hydrothermal sources, with contributions from metamorphic water caused by water‐rock interaction during the mineralization process, as well as later meteoric water. The intense water‐rock interaction likely played a crucial role in the precipitation of scheelite, leading to varying Eu anomalies in different generations of scheelite from the oxide stage to the quartz‐sulfide stage, while also causing a gradual decrease in oxygen fugacity (fO2) and a slow rise in pH value. Additionally, the high Mo and low Sr contents in the scheelite are consistent with typical characteristics of magmatic‐hydrothermal scheelite. Therefore, considering the geological features of the deposit, the geochemical characteristics of scheelite and the O‐H isotope data published previously, it can be concluded that the genesis of the Nuri deposit belongs to porphyry‐skarn deposit.

Fluid-rock interactions recorded by bulk-rock and mica compositions in the Xiuwacu granite-related quartz-vein W–Mo deposit, western Yunnan Province, China

The Xiuwacu deposit is a typical granite-related quartz-scheelite-molybdenite vein type deposit hosted within sandstones and sandy slates in the southern Yidun Terrane, western Yunnan Province, China. The Xiuwacu complex comprises the Late Triassic biotite granite and Late Cretaceous monzogranite porphyry (MGP) and aplite granite. Extensive and intensive alteration including potassic, propylitic, phyllic, silicic and argillic alteration developed within the Late Cretaceous monzogranite porphyry. Greisenization and pegmatization occurred in the roof of the Xiuwacu complex, suggesting large-scale fluid-rock interactions. However, the effects of fluid-rock interactions on the elemental exchange and ore-forming processes at Xiuwacu still remained unclear. This study firstly reported whole-rock major and trace elements of representative altered rocks and in situ major and trace elements of micas from fresh and altered rocks, and quantitively constrained the mobilization of elements by normalized isocon diagrams. The altered MGP are characterized by higher loss on ignition (LOI) values (>2), lower light rare earth elements (LREEs) and variable large ion lithophile elements (LILEs) contents, with higher Cs, K, Rb and Ba contents and lower Sr content than fresh MGP. The classification diagram based on mica composition shows that magmatic biotites from the Late Triassic biotite granite and Late Cretaceous monzogranite porphyry belong to Fe biotites. Hydrothermal micas from pegmatoid and greisen belong to Li-phengites and zinnwaldites, and hydrothermal micas from quartz-molybdenite vein are classified as zinnwaldites. Li-phengites and zinnwaldites have relatively lower F contents, higher W, Sn, Li, Cs contents than biotites, intergrown with calcite and ankerite, suggesting CO2-rich, F-poor and rare metal-rich nature of hydrothermal fluids. Based on a compilation of fluid inclusions, H–O–S-Sr isotopes, scheelite geochemistry from previously published literatures and compositions of altered rocks and micas from this study, the tungsten ore-forming processes at Xiuwacu could be concluded as follows: (1) the initial moderately-oxidized, F-rich fluids exsolved from parental magmas of MGP form fluorite-quartz assemblages (pegmatoid; 400–300 °C); (2) the F-poor, W-rich, moderately acid fluids cause the breakdown of Ca-rich plagioclases, which consumes H+ and provides Ca2+ for the precipitation of early-stage scheelites (greisen; approximately 300 °C); the evolved nearly neutral and medium- to low-temperature fluids (300–150 °C) drive the fluid-rock interactions to supply Ca2+ for the deposition of main-stage scheelites. The deposition of Mo was not determined by the fluid-rock interactions, but by the ore-forming fluids transformed from oxidized to reduced nature.

Geochemical Constraints on the Evolution of Late- to Post-Orogenic Granites in the Arabian Shield, with a Specific Focus on Jabal Al Bayda Area in the Central Hijaz Region, Saudi Arabia

The Jabal Al Bayda, located in the Hijaz terrain of northwest Saudi Arabia, comprises magmatic rocks that represent the ending phase in the Precambrian development of the Arabian Shield. Two granitic suites have been studied petrologically and geochemically, the monzogranite and alkali granite suites, to gain knowledge about their origin and geotectonic implications. The geochemical characteristics of the monzogranites align with their formation in a subduction-related environment. These rocks have a composition that is rich in strontium and barium, and low in rubidium, and displays a high-K calc-alkaline to shoshonitic nature. In contrast, alkali granites typically have lower concentrations of Sr and Ba, and higher rubidium contents. The differences in geochemical composition between monzogranites and alkali granites found in Jabal Al Bayda indicate differences in their origin and geotectonic environment. The evolution of granitoid magmatism in the Jabal Al Bayda area is linked to the Hijaz orogenic cycle, during which northwest-dipping subduction led to the formation of the Midyan, Hijaz, and Jeddah arc assemblage, followed by the collision and accretion of these arcs along the Yanbu and Bir Umq sutures. Due to crustal thickening during the subduction-related stage, the deeper parts of the overlying metagraywackes and metatonalites contribute melt to the early crustal magma, which eventually solidifies to form monzogranites. Later on, during the post-orogenic stage, anatexis of metapelites can occur, leading to the generation of magmas that give rise to alkali granites.

Origin of the Permian high silica A-type granites in Halajun, South Tienshan, NW China: Implications for crystal-liquid segregation and rare metal fertilization

High silica A-type granites (HSAGs) are important carriers of rare metal elements. Formation of HSAGs by crystal-liquid segregation would facilitate fertilization of rare metals and rare earth elements (REE). In this work, we present detailed petrology, whole-rock geochemistry, and in-situ zircon UPb ages and HfO isotopic compositions of the Halajun HSAGs in the South Tienshan Orogenic Belt (STOB). In combination with the previous study of the Halajun syenite and monzonite, we unravel the genetic connection of these granitoids and further explore the metallogenetic potentiality of HSAGs along the STOB in China. The Halajun granites have geochemical affinities of HSAGs with high SiO2 contents (> 70 wt%), whole-rock zirconium saturation thermometry (680–860 °C), high Ga/Al ratios and high field strength elements (HFSE) contents. The HSAGs (273–279 Ma), monzonite (280 Ma) and syenite (283 Ma) have similar formation ages, identical mineral assemblages, and consistent variations in major elements, implying a common magma reservoir of their parental magma. The Tamu and Huoshibulake HSAGs have high SiO2 (74.5–78.1 wt%) contents, low Sr (5–28 ppm) and Ba (7–60 ppm) contents, high Rb/Sr ratios (11.6–87.5), and strong negative Eu anomalies (0.01–0.08). Combined with the petrographic features, these geochemical variations suggest that they are the extracted melt. Conversely, the geochemical (high Sr and Ba concentrations, and Eu/Eu* near unity) and petrographic features of monzonite and syenite represent the residual silicic cumulate (crystals ± trapped melt). The Kezi'ertuo and Halajun II HSAGs have SiO2 (71.9–76.5 wt%) contents, Sr (35–101 ppm) and Ba (60–541 ppm) contents, Rb/Sr ratios (1.9–8.9), and negative Eu anomalies (0.04–0.43), indicating the intermediate component (extracted melt + fractional crystals) in the consecutive system of crystal-liquid segregation. In-situ zircon HfO isotopes for the Halajun granitoids indicate a complex trans-crustal magmatic process involving crystal-liquid segregation and wall-rock assimilation. The long-time span of Tarim Large Igneous Province (TLIP) sustained injection of mantle-derived magma and/or advective heat to the magma chamber (> 1 Ma). Owing to the prolonged magma evolution, the highly fractionated silicic magma with high incompatible elements and F contents was extracted from the magma mush, and formed the HSAGs.

Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block, NW China and their geological significance: Constraints from drill cores geochronology and geochemistry studies

As a micro-continent lying at the junction of the North China, Yangtze, and Tarim Cratons in northwest China, the composition and tectonic-thermal history of the Qaidam Block not only are crucial for determining its tectonic attribute and relationships with surrounding cratons, but also can provide key constraints on convergence, fragmentation, and paleogeographic reconstruction of Columbia and Rodinia. In this study, systematic petrology, geochemistry, and zircon U–Pb–Hf isotope analyses were conducted on newly discovered Meso-Neoproterozoic granitic rocks from drill cores in the Qaidam basin and three stages granitic magmatism at ca. 1420 Ma, ca. 900 Ma and 780–750 Ma are yielded. The ca. 1420 Ma granitic rocks exhibit characteristics of highly fractionated I-type granites, with high Yb but low Sr contents, low Sr/Y and La/Yb ratios, high zircon saturation temperatures (774–831 ℃), and positive εHf(t) values (–0.04 to +11.35) with TDM2 values of 2178–1468 Ma, suggesting that they were mainly derived from the ancient crust with mantle magma input under an extensional setting. The ca. 900 Ma granitic rocks have high A/CNK values (1.01–1.21) and variable zircon εHf(t) values (–1.93 to + 6.58) with TDM2 ages between 1402 and 1910 Ma, indicating they are S-type granites formed by partial melting of sedimentary rocks in thickened crust. The ca. 780–750 Ma granites have high Zr + Nb + Ce + Y contents, 10000* Ga/Al ratios, and crystallization temperatures (mean = 808 ℃), belonging to the A1-type granite formed in a continental rift setting.Combined with the previous researches, the Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block can be divided into three stages, 1.8–1.1 Ga, 1.0–0.9 Ga and 850–750 Ma, corresponding to the fragmentation of Columbia, and the assembly and breakup of Rodinia, respectively. Comparing the Qaidam Block with the surrounding blocks and the major cratons in Columbia and Rodinia, it is considered that the Qaidam Block was splited from the Tarim Craton and they may have occupied an interior position in Columbia but a peripheral position in Rodinia, connecting to the India and East Antarctica.

Evaluation of photobiomodulation therapy (PBMT) on salivary flow and composition in head and neck cancer patients undergoing radiation therapy

Assess the impact of photobiomodulation therapy (PBMT) on xerostomia, salivary flow rate (SFR) and composition in patients undergoing radiotherapy (RT) for head and neck cancer (HNC). Thirty patients undergoing RT (65 Gy) for HNC were enrolled. Saliva and xerostomia evaluations collected pre- and post-PBMT-RT. PBMT involved irradiation of extra and intraoral points, 15-20 sessions, 2-3 times/week. SFR, trace elements, total protein, alkaline phosphatase, xerostomia, and pH were analyzed. The average age was 60.7 years. After treatment, there was not a significant reduction in SFR and there was no difference on xerostomia. Significant reductions in Al, Cd, Fe, Ni, P, and Sb concentrations were observed, along with a significant increase in Mg concentration. Sample data were organized into 3 groups based on a self-organizing map. Low concentrations of Al, As, Co, Cr, Cu, Fe, Mn, Mo, S, Sr, and Zn were the primary discriminatory factors for group A, while group B consisted of post-PBMT-RT samples with high concentrations of Ca, K, Mg, Na, and S. PBMT prevented a significant reduction in SFR and xerostomia induced by radiation therapy. These findings suggest that PBMT prevents salivary gland damage minimizing the decline in salivary flow.

Petrogenesis of the U-rich Permian Akkulen syenite intrusion, Tien Shan, Kyrgyzstan: insights into its magmatic evolution and geodynamic setting

ABSTRACT Permian alkaline granitoids are widely distributed throughout the Tien Shan Orogen and adjacent region of the southern Central Asian Orogenic Belt. However, their petrogenesis and related tectonic setting remain equivocal. A detailed mineralogical, U-Pb zircon dating, in situ elemental and Sr-Nd-Hf isotopic studies of the uranium-rich Akkulen syenite intrusion in the Northern Tien Shan of Kyrgyzstan were undertaken to better understand its magmatic processes and geodynamic evolution. Four independent oxygen barometers have shown that the oxygen fugacity of the Akkulen syenitic magma evolved from initial low fO2 (<NNO +1, where NNO is the nickel-nickel oxide buffer) to relatively high fO2 (>NNO +1) during magma ascent and cooling; Apatite geochemical characteristics also indicate that the magma is relatively high F (2.9–5.1 wt.%), with low Cl (0.053–0.13 wt.%) and anhydrous (<4 wt %) contents. According to whole-rock geochemical data, the syenite samples have abnormally high U (38.5–57.1 ppm) and Th (96.2–137 ppm) concentrations, we suggest that high F content and moderate oxygen fugacity are beneficial for uranium enrichment. Zircon grains from a syenite sample yielded a weighted 206Pb/238U age of 283.5 ± 2.6 Ma. The intrusion has an A-type granite affinity with high alkali (Na2O + K2O) contents and Fe/(Fe+Mg) ratios, high LREE/HREE (~5), and low Sr, Ba, and Eu contents. They have negative εNd(t) (−5.2 to −3.6) values with Mesoproterozoic two-stage model ages (T DM2 = 1.35–1.47 Ga), and variable εHf(t) values (−4.6 to +2.4) with Mesoproterozoic two-stage model ages (T DM2 = 1. 2–1.59 Ga), which suggest these rock derivations from the relatively old crustal with minor contribution from juvenile crustal melts. In comparison with regional available dataset, we propose that the alkaline Permian granitoids in Kyrgyz Northern Tien Shan may have been originated from large-scale partial melting of Mesoproterozoic metamorphic basement with minor juvenile crustal material in a post-extensional setting. In contrast, the Early Permian granitoid magmatism in the Tarim Craton may have been caused by the partial melting of Neoproterozoic basement rocks associated with Permian mantle plume activities.

Mid-Mesoproterozoic (ca. 1.37 Ga) anorogenic magmatism in the Dabie orogen, northern Yangtze Craton: Response to the breakup of Columbia

It is evident that the Yangtze Craton was involved in the formation and breakup of the Columbia supercontinent. However, due to the scarcity of Mesoproterozoic geological records and reliable paleomagnetic data, little is known about the timing, paleogeographic position, and geological processes of the Yangtze Craton. We conducted detailed geological mapping, petrographic, geochemical, and in situ zircon U-Pb and Lu-Hf isotopic investigations on newly recognized Mesoproterozoic quartz syenite and monzogranite in the Dabie orogen, northern Yangtze Craton. The results show that the quartz syenite and the monzogranite were emplaced at 1369 ± 12 Ma and 1372 ± 5 Ma, respectively. Both rocks are high in total alkali (K2O + Na2O) content and FeOt/(FeOt + MgO), with elevated diagnostic 10,000*Ga/Al ratios and Zr + Nb + Ce + Y concentrations, and enrichment in light rare earth elements. They are also depleted in heavy rare earth elements with significant negative Eu anomalies but remarkably low Sr, Cr, and Ni contents. These compositions define affinity to A1-type granite. In addition, the quartz syenite displays variable zircon Hf and homogeneous whole-rock Nd isotopic compositions with positive εHf(t) values of +0.7 to +5.7 (average +2.4) and εNd(t) values of −0.1 to +2.5 (average +1.0). In contrast, the monzogranite has homogeneous zircon Hf and whole-rock Nd isotopic compositions with negative εHf(t) values of −5.7 to −2.6 (average −4.8) and εNd(t) values of −3.5 to −1.5 (average −2.2). We propose that the quartz syenite was likely generated by the partial melting of juvenile, crust-derived melt with involvement of minor mantle-derived material, while the monzogranite was likely derived from the partial melting of ancient crust in an extensional tectonic regime (e.g., continental rift). Based on the newly recognized ca. 1.37 Ga granitic magmatism and previously reported magmatic events, we argue that the mid-Mesoproterozoic (ca. 1.37 Ga) magmatism in the Yangtze Craton occurred in response to the breakup of Columbia, and represents the separation of the Yangtze Craton from Columbia. Furthermore, according to comparable magmatic and sedimentary events, we propose that the Yangtze Craton, along with central Hainan Island, may have been linked to northwestern Laurentia, southwestern Siberia, and northeastern Australia during 1.6−1.4 Ga.