Low Regeneration Temperature Research Articles

Carbon dioxide capture from open air using covalent organic frameworks.

Capture of CO2 from the air offers a promising approach to addressing climate change and achieving carbon neutrality goals1,2. However, the development of a durable material with high capacity, fast kinetics and low regeneration temperature for CO2 capture, especially from the intricate and dynamic atmosphere, is still lacking. Here a porous, crystalline covalent organic framework (COF) with olefin linkages has been synthesized, structurally characterized and post-synthetically modified by the covalent attachment of amine initiators for producing polyamines within the pores. This COF (termed COF-999) can capture CO2 from open air. COF-999 has a capacity of 0.96 mmol g-1 under dry conditions and 2.05 mmol g-1 under 50% relative humidity, both from 400 ppm CO2. This COF was tested for more than 100 adsorption-desorption cycles in the open air of Berkeley, California, and found to fully retain its performance. COF-999 is an exceptional material for the capture of CO2 from open air as evidenced by its cycling stability, facile uptake of CO2 (reaches half capacity in 18.8 min) and low regeneration temperature (60 °C).

Experimental evaluation of a hydrogel composite desiccant wheel for dehumidification with high water uptake and low regeneration temperature

Rotary dehumidification, a key method for continuous solid adsorption dehumidification, is extensively utilised in various industrial and practical applications. The performance of the adsorbent within the desiccant wheel is a major determinant of its energy efficiency in practical applications. While studies on Metal Organic Frameworks (MOFs) and polymer desiccant wheels exist, the majority of rotary dehumidification systems continue to employ traditional adsorbents like silica gel and zeolite, which are plagued by low dehumidification capacity and high energy consumption issues. Super hygroscopic hydrogel, enhanced with a hygroscopic agent, has gained prominence in air treatment because of its outstanding hygroscopicity and low regeneration temperature. With the goal of integrating advanced materials into practical engineering applications and mitigating the heat and mass transfer loss and adsorption/desorption performance degradation due to volume expansion and viscous agglomeration post-water uptake in large-scale super hygroscopic hydrogel applications, this study successfully developed a hydrogel wheel, measuring 350 mm in diameter and 200 mm in thickness, using a honeycomb-shaped glass fibre paper substrate. Experimental findings demonstrate that the hydrogel desiccant wheel outperforms both the MOF and commercial low-temperature silica gel wheels under all tested environmental conditions. This advantage is particularly noticeable at 15 °C and 30 % Relative Humidity (RH), where the moisture content differential (Δd) in the hydrogel system is 2.96 g/kg, 1.89 times greater than the MOF system’s 1.56 g/kg and 5.19 times higher than the silica gel’s 0.57 g/kg. Furthermore, the controlled variable method was used to assess the impact of each operational parameter on the hydrogel wheel’s performance in both low and high moisture conditions, offering design insights for engineering applications.

Open-cycle thermochemical energy storage for building space heating: Practical system configurations and effective energy density

Salt-hydrate thermochemical materials (TCM) are promising candidates for energy storage systems for building space heating due to their high theoretical energy density and the need for low regeneration temperature. However, water vapor is required to drive the hydration process of the TCM reactor, which poses a challenge during winter when water vapor is typically scarce. Using indoor air directly lowers the building's humidity to an unconformable level in practice, while the cold outdoor air contains limited moisture. Here we consider different integration strategies for open-cycle TCM reactors in buildings and develop a model to simulate their thermal performance across diverse buildings and climates, specifically for building space heating. The potential energy densities and the levelized cost of storage of the TCM reactor are evaluated in practical scenarios to demonstrate the load-shifting potential of TCM systems for heating applications. We use a strontium chloride (SrCl2)-based composite as the baseline and explore the impact of various reactor and material changes to the energy density and levelized cost of storage.

A low-temperature regenerable catalyst for stable and selective propylene production from ethylene using Ni and P-supported SSZ-13 zeolite

Due to the increasing demand for propylene, highly selective propylene production from ethylene using small pore zeolite has received significant attention. However, rapid catalyst deactivation due to coke deposition on the catalyst impedes effective propylene production in industry. Therefore, it is essential to develop a low-temperature regeneration ethylene-to-propylene (ETP) catalyst with stable catalytic activity. To achieve such a catalyst, various hydrocracking metal species and phosphorus-supported SSZ-13 were prepared and evaluated using a one-pass ETP and ETP-Regen test. The optimized catalyst NiO(1.0)-P(0.6)-SSZ-13 exhibited a constant, excellent propylene yield of over 70 wt% with 90 wt% of propylene selectivity over ETP reaction and consecutive ETP-Regen cycles. The unprecedented catalytic performance of NiO(1.0)-P(0.6)-SSZ-13 was ascribed to the synergistic effect of NiO and P components, where nickel is responsible for catalyst recovery through effective coke removal, while phosphorus plays an essential role in size-selective diffusion.

Real biofuel and fossil-fuel soot combustion activities in active and passive regeneration of diesel/gasoline particulate filters under different O2/NOx concentrations.

In this work, we aim to investigate and compare the combustion reactivities of real biofuel soot and fossil-fuel soot in the active and passive regeneration conditions of DPF and GPF through temperature-programmed oxidation (TPO). Higher reactivity of biofuel soot is achieved even under GPF conditions with extremely low oxygen concentration (~ 1%), which provides a great potential for low-temperature regeneration of GPF. Such a result is mainly attributed to the low graphitization and less surface C = C groups of biofuel soot. Unfortunately, the presence of high-content ashes (~ 47%) and P impurity in real biofuel soot hinder its combustion reactivity. TPO evidences that the O2/NOX-lacking conditions in GPF are key factors to impact the combustion of soot, especially fossil-fuel soot. This work provides some useful information for understanding real biofuel and fossil-fuel soot combustion in GPF and DPF regeneration and further improvement in filter regeneration process.

Impact of pipe resistance on performance of supercritical carbon dioxide Brayton cycle system

This study develops a system simulation model based on the megawatt-class supercritical carbon dioxide Brayton cycle unit in Hengshui, China, to examine the effect of pipe section resistance on system performance. The results indicate that increased pressure loss in pipe sections significantly reduces power generation efficiency and power supply efficiency. Specifically, a 100 % increase in pressure loss results in 3.290 % and 4.377 % decreases in power generation efficiency and power supply efficiency, respectively. Moreover, higher pressure loss leads to increased CO2 mass flow rate at design power generation load. When the pressure loss is doubled, it requires a 17.593 % increase in CO2 mass flow rate to achieve the design power. Pressure loss in high-pressure section has minimal impact on system performance, while resistance in low-pressure section significantly affects it. For instance, a 100 % increase in pressure loss from the compressor outlet to the low temperature regenerator inlet causes a 0.37 % decrease in system power supply efficiency, and a similar increase from the high temperature regenerator outlet to the low temperature regenerator inlet leads to a 0.76 % decrease. These findings provide meaningful guidance for component design and piping layout optimization for similar systems.

CO2 Capture with Polyethylenimine Supported on 3D-Printed Porous SiO2 Structures.

Amines supported on porous solid materials have a high CO2 adsorption capacity and low regeneration temperature. However, the high amine load on such substrates and the substrate itself may lead to substantial pressure drop across the reactor. Herein, we compare the CO2 adsorption capacity and pressure drop of fumed silica powder to 3D-printed monolithic fumed silica structures, both functionalized by polyethylenimine (PEI), and find a drastically reduced pressure drop for 3D-printed substrates (0.01 bar vs. 0.76 bar) in the sorption bed with equal CO2 adsorption capacity. Furthermore, the effect of 3D-printing nozzle diameter and PEI loading on the adsorption capacity are investigated and the highest capacities (2.0 mmol/g at 25 °C with 5000 ppm CO2) are achieved with 0.4 mm nozzle size and 34 wt% PEI loading. These high capacities are achieved since the 3D printing and subsequent sintering (700 °C) of monolithic samples does not compromise the surface area of the fumed silica. Finally, the comparison between 3D-printed monoliths and extruded granulate of varying diameter reveals that the ordered channel system of 3D-printed structures is superior to randomly oriented granulate in terms of CO2 adsorption capacity.

Heat and mass transfer analysis of desiccant-coated heat exchanger with desiccants and metal-organic framework for bus air conditioning applications

Desiccant-coated heat exchangers (DCHEs) in air conditioning offer advantages like independent temperature and humidity control, reduced energy consumption, and high performance. However, the availability of desiccants with high water adsorption and low thermal energy requirements is limited. The present study proposes that aluminum fumarate (Al-Fum) MOF-coated heat exchangers will outperform conventional desiccants, especially at low regeneration temperatures (around 50°C). In order to evaluate this hypothesis, the performance of DCHEs was evaluated with a validated analytical model for different solid desiccant coatings: silica gel, zeolite, and Al-Fum MOF. Water vapor sorption characteristics, heat and mass transfer, and adsorption and desorption capacities were determined. The results showed that the Al-Fum MOF-coated heat exchanger outperformed silica gel and zeolite at low regeneration temperatures under adiabatic conditions. The MOF exhibited superior water uptake capacity (0.39 g/g) between 20% and 80% RH compared to the other studied conventional desiccants. Moreover, the MOF achieved the lowest outlet air temperature. At 19.5 g/kgda, the MOF demonstrated higher adsorption rates (4 % and 0.3 %) than zeolite and silica gel. These findings highlight the potential of Al-Fum MOFs as energy-efficient solutions for controlling indoor air humidity, particularly for latent-sensible heat separation systems with conventional vapor compression bus air-conditioning systems.

Solar regenerated carbon-based composite desiccant coated heat exchangers for air dehumidification

Desiccant dehumidification can realize decoupling of latent and sensible heat loads in dehumidified air conditioning, thereby reducing energy consumption. This paper proposes a solar regenerated carbon-based composite desiccant coated heat exchangers (DCHE) for air dehumidification. Carbon-based composite desiccant is electrostatically sprayed onto the surface of the heat exchanger to form a dehumidification coating. An experimental system for evaluating the dehumidification and regeneration performance of DCHE is established. The Taguchi method is employed to evaluate the impact of operating parameters such as air velocity, water flow rate, and regeneration temperature on the dehumidification and regeneration efficiency of DCHE. The result shows that air velocity is the primary factor impacting the dehumidification performance of DCHE, with regeneration temperature and cooling water flow rate following in importance. With the faster air velocity and the lower cooling water flow rate, DCHE shows the better dehumidification performance. Moreover, excessively both high and low regeneration temperatures can result in a degradation in the dehumidification performance of DCHE. Under optimal operating conditions, the dehumidification rate (EDE) and thermal coefficient of performance (COPth) of DCHE can reach 7.5 kg/h and 2.3, respectively. The moisture content of the air reduces from 19.6 g/kg to 8.0 g/kg.

Dual-template synthesis of SFO-type aluminophosphate with enhanced water-sorption-driven cooling performance

Water-based adsorption chillers (ADC) driven by low-grade thermal energy are environment-friendly alternatives to the traditional compression ones to realize the net zero carbon target. Aluminophosphates molecular sieve (AlPOs) is an excellent material for water-based adsorption applications. However, AlPOs suffers from relatively high cost attributed to the extensive use of expensive structure direct agents (SDAs). This study employed a dual-template method, using cheap organic amine as a dual-template, to synthesize low-cost and excellent adsorbent AlPOs with SFO topology (AlPO-SFO). AlPO-SFO synthesized with dual templates shows high crystallinity, large micropore volume, excellent water uptake, and low regeneration temperature. AlPO-SFO guided by 4-dimethylaminopyridine (4-DMAPy) and diethanolamine (DEOA) molar composition of 0.4 and 0.1 exhibits large microporous volume (0.30 ml g−1), high water uptake (0.26 g g−1 at P/P0 = 0.25) and low regeneration temperature (65 °C). Importantly, this AlPO-SFO exhibits a high coefficient of performance (COP) of 0.89 for cooling at a low driven temperature of 64 °C. The additive amine providing alkaline medium ensures the practical synthesis of AlPO-SFO when expensive 4-DMAPy decreases, endowing the 42 % reduction of the raw material cost. The results provide a cheaper synthesis route of AlPO-SFO, which is conducive to its large-scale production as a distinguished adsorbent for adsorption chillers.

Coke Formation and Regeneration during Fe-ZSM-5-Catalyzed Methane Dehydro-Aromatization

Coke formation poses a significant obstacle in the direct conversion of methane into valuable chemicals such as ethylene, benzene, and hydrogen via methane dehydro-aromatization (MDA). At the elevated temperatures necessary for this reaction, coke is the thermodynamically favored product, causing rapid catalyst deactivation and hence necessitating frequent catalyst regeneration. Successful industrial implementation of MDA requires the advancement of catalyst regeneration processes and a comprehensive understanding of coke formation to enhance catalyst performance. Here, we examined the types of coke generated during MDA over a Fe-ZSM-5 catalyst and their impact on deactivation. By combining reactivity studies using catalysts with carefully controlled coke populations with the characterization of the catalyst via XRD, H2-TPR, and pyridine FTIR, we find that soft coke is formed at the Brønsted acid sites, resulting in loss of selectivity, while hard coke is formed at the metal sites causing a loss of activity. While soft coke can be removed at low regeneration temperatures, the removal of hard coke requires harsh conditions which compromise catalyst stability. An investigation into the use of CO2 as an alternative, mild oxidant for catalyst regeneration, however, shows that the mild oxidation strength of CO2 requires even higher regeneration temperatures and hence irreversible loss of Brønsted acid sites.

Evaluation on novel Kalina power generation system through exergoenvironmental analysis

First law analysis assesses the performance of the system considered for investigation in the energy aspect. Low-temperature power generation system suitable to recover waste heat from a renewable source is investigated in the present work. The system is adopted to work at hot sink conditions and investigation on performance assessment is carried out in exergy aspect. Exergy analysis in both conventional and advanced methods proposes the system components which need improvements in themselves and associated with other components more properly. Exergoenvironmental analysis using the Life cycle assessment (LCA) method is examined in the system under the same sink conditions. Exergy analysis reveals that the component with a high source will yield more losses resulting in higher irreversibility. Hence turbine and evaporator need investigation in improving the system’s performance. Exergoenvironmental investigation suggests that the highest impact results in the low-temperature regenerator (LTRGN). The improvement in these components' designs and limitations in the characteristics of the material chosen and the manufacturing methods involved will favor a higher performance of the system. LTRGN has resulted in with high relative cost difference value of 23.85 % and seeks improvement. The exergy destruction is in a larger amount in the components evaporator and turbine with 70.66 kW and 30.99 kW respectively. Avoidable exergy destruction value of evaporator, condenser results 51.11 $/hr and 16.64 $/hr respectively. The LTRGN has an environmental effect rate of 54.83 mPts/hr and device-related environmental effects of 45.16 mPts/hr. The (ĖD/ĖP), (Ẏ/ĖP) and (Ż/ĖP), values at 85% pump efficiency results 2.16, 0.00946 and 0.30871.

Unraveling a Stable 16-Ring Aluminophosphate DNL-11 through Three-Dimensional Electron Diffraction for Atmospheric Water Harvesting.

Sorption-based atmospheric water harvesting (AWH) is a promising solution for addressing water scarcity. Developing cost-effective and stable water adsorbents with high water uptake capacity and a low-temperature regeneration requirement is a crucially important procedure. In this Communication, we present a novel and stable aluminophosphate (AlPO) molecular sieve (MS) named DNL-11 with 16-ring channels synthesized by using an affordable and commercialized organic structure directing agent (OSDA), whose crystallographic structure is elucidated by three-dimensional electron diffraction (3D ED). DNL-11 exhibits a significant water uptake capacity (189 mg/g) at a very low vapor pressure (5% relative humidity at 30 °C). In addition, most of the adsorbed water can be effortlessly removed by purging N2 at 25 °C under ambient pressure conditions. This may expand the possibility of AWH under extreme drought conditions.

Asymmetric double-layer design of LiCl@CC/PAM for highly efficient water uptake from atmosphere

Water scarcity has become a global problem and caused a lot of conflicts. Atmospheric water harvesting (AWH) is a promising way to address water shortage issue. However, traditional adsorbent materials such as silica gels and zeolites suffer from low water productivity and high regeneration temperature. Hygroscopic salts like LiCl are regarded as a perspective substitution. Salt-modified metal organic frameworks (MOFs) and hydrogels are employed to alleviate the salt aggregation but they are limited to expensive fabrication or sluggish adsorption kinetics. Herein, we demonstrate an asymmetric double-layer design of LiCl@CC (carbon cloth)/PAM with separated function of water adsorption/desorption and water storage in different layer. This double-layer design not only enhances the mechanical properties but also shows an improved water adsorption kinetics compared to common salt-composite hydrogels. In experimental test, the LiCl@CC/PAM exhibits excellent water uptake of 1.5 g g−1 under 60 % RH in 4 h and fast water desorption under sunlight in 1.5 h. In outdoor test, LiCl@CC/PAM based device presents a daily water uptake of 5.12 g g−1 day−1. Meanwhile, all the materials used and fabrication process are feasible to scale up, which provides a possible solution to the global crisis of water scarcity.

Experimental microwave assisted CO2 desorption of a solid sorbent in a fluidized bed reactor

In this study, a novel method has been applied to regenerate CO2 from a solid sorbent (Zeolite 13X) using a mono-mode microwave unit under fluidization conditions. Several parameters have been varied to investigate their effect on the desorption characteristics as well as on the energy consumption. While flow rate varied between 200 Nml/min to 1,000 Nml/min, regeneration temperature changed from 40 °C to 100 °C. Microwave initial forward power also varied from 15 W to 30 W.Volumetric heating of microwave led to desorption of CO2 from the sorbent effectively while fluidization enhanced the heat transfer within the sorbent by providing homogeneous heat transfer with lower desorption time and absorbed energy. The most dominant parameters on the desorption time and energy consumptions were found to be flow rate and regeneration temperature, respectively. Under different conditions, the energy consumptions to regenerate a kg CO2 varied between 2.84 MJ and 27.17 MJ. Even though the lowest energy consumption was obtained when the flow rate was 200 Nml/min at 40 °C; the time for a complete desorption found to be quite high with this flow rate. Therefore, a minimum energy consumption of 3.87 MJ/kg CO2 within a short period of regeneration time can be achieved under the fluidization regime with the flow rate of 1,000 Nml/min at 40 °C. While an increase in the flow rate also caused a slight increase in the energy consumption for low regeneration temperatures, it resulted in a significant decrease under higher regeneration temperatures. Furthermore, the main drawback of low flow rate conditions is that most of the energy was consumed to remove the last 10 % of CO2 from the sorbent. Therefore, fluidization plays a significant role on the removal of CO2, especially between the 90 % and 100 % regeneration percentages.This work is the first study in the literature that has investigated the effects of fluidization on the desorption characteristics of CO2 under mono-mode microwave conditions. It was proved that fluidization reduced the energy consumption of CO2 desorption with higher microwave efficiency.

Enhanced high temperature cyclic CO2 capture on Li4SiO4 sorbent from two-dimensional SiO2 nanomeshes

The Li4SiO4-based sorbent, noted for its high sorption capacity and lower regeneration temperature, is promising for high-temperature CO2 capture. However, its slower sorption rate and poor cycle stability limit practical applications. In this study, Li4SiO4 was synthesized with various Li/Si molar ratios to serve as CO2 sorbents. The synthesis employed the mechanochemical activation method, effectively addressing challenges like growth, agglomeration, and structural degradation that typically occur during the CO2 sorption process. The results indicate that a smaller Li/Si molar ratio significantly enhances both the kinetic sorption rate and cyclic stability of the Li4SiO4 sorbent. When the Li/Si molar ratios are 6.2, 4.2, and 3.2 respectively, the maximum adsorption capacities of the three corresponding sorbents are 0.39, 0.36, and 0.29 gCO2/gadsorbent, respectively. At a temperature of 700 °C, the times required for the sorbents to achieve adsorption equilibrium were 15 min, 2 min, and 1.6 min, respectively. Additionally, after 20 adsorption/desorption cycles, the corresponding retention rates of adsorption capacity were 29.4 %, 62.8 %, and 93.9 %, respectively. These results demonstrate the excellent CO2 sorption performance and the significant potential for wide application of this novel Li4SiO4-based high-temperature CO2 sorbent.

Tunable Low-Pressure Water Adsorption in Stable Multivariate Metal-Organic Frameworks for Boosting Water-Based Ultralow-Temperature-Driven Refrigeration.

The green water-based adsorption refrigeration is considered as a promising strategy to realize near-zero-carbon cooling applications. Although many metal-organic frameworks (MOFs) have been developed as water adsorbents, their cooling performance are commonly limited by the insufficient water uptakes below P/P0 = 0.2. Herein, the development of multivariate MOFs (MTV-MOFs) is reported to highly modulate and boost the low-pressure water uptake for improving coefficient of performance (COP) for refrigeration. Through ligand exchange in the pristine MIL-125-NH2 , a series of MTV-MOFs with bare nitrogen sites are designed and synthesized. The resulting MIL-125-NH2 /MD-5% exhibits the significantly improved water uptake of 0.39g g-1 at 298 K and P/P0 = 0.2, which is three times higher than MIL-125-NH2 (0.12g g-1 ) and comparable to some benchmark materials including KMF-1 (0.4g g-1 ) and MIP-200 (0.36g g-1 ). Combined with its low-temperature regeneration, fast sorption kinetics and high stability, MIL-125-NH2 /MD-5% achieves one of the highest COP values (0.8) and working capacities (0.24g g-1 ) for refrig-2 under an ultralow-driven temperature of 65°C, which are higher than some best-performing MOFs such as MIP-200 (0.74 and 0.11g g-1 ) and KMF-2 (0.62 and 0.16g g-1 ), making it among the best adsorbents for efficient ultralow-temperature-driven refrigeration.

Evaluation of potassium glycinate as a green solvent for direct air capture and modelling its performance in hollow fiber membrane contactors

Current direct air capture (DAC) technology is largely cost-prohibitive for large scale implementation due to the excessive energy required to operate a combined absorption–desorption cycle. As the desorption process consumes much of the supplied energy, there is a demand to find more sustainable sorbent materials that maintain high absorptive capacities yet can be regenerated at lower working temperatures. This work evaluates potassium glycinate (GlyK) as one such alternative absorbent. Through conducting vapor–liquid equilibria and wetted wall column kinetic studies, GlyK is found to have comparable working capacities and liquid mass transfer coefficients to those reported for the industrial standard, monoethanolamine (MEA), yet outperforms it with regards to its distinctly low regeneration temperature. To further understand how GlyK would perform in an industrial scale DAC system, an Aspen Custom Modeler® (ACM) model is developed that integrates the experimentally obtained equilibria and kinetic data with the performance characteristics of a gas-solvent hollow fiber membrane contactor (HFMC). Full-scale simulations show that via implementing a 20°–90 °C absorption–desorption cycle, GlyK can capture up to 83 % of the CO2 in atmospheric air and be 55 % regenerated within a single membrane contactor pass. As these low working temperatures vastly outperform the conventional ∼ 40°–140 °C temperature swing currently implemented in industrial CO2 processing, GlyK is concluded to be a viable and sustainable option for use within energy-efficient DAC technology whereby renewable heat sources can be used.

Enhancement of CO2 adsorption performance and widening of adsorption temperature window by co-doping different valence state metals on the Li4SiO4 (010) surface

Lithium silicate (Li4SiO4) has good stability, high theoretical carbon dioxide (CO2) adsorption capacity, and low regeneration temperature. It has great potential in the field of CO2 adsorption. However, it is difficult to achieve the theoretical value in practical applications and a narrow temperature window for adsorption. Therefore, further research in this area is urgently needed. In this study, experimental and simulation methods were used to investigate the effects of single doping and co-doping with K, Na, Be, Ca, and Al metals on the adsorption performance and adsorption temperature window of Li4SiO4. Single doping with K, Na, or Al makes CO2 easier to be adsorbed on the Li4SiO4 (010) surface by increasing the charge transfer from the Li4SiO4 surface to CO2. Co-doping with K and Al increases the adsorption energy of CO2 on the Li4SiO4 (010) surface, enhances hybrid peaks, and broadens the temperature range for CO2 adsorption on the Li4SiO4 surface. It exhibits stable cyclic adsorption performance under low CO2 (15% CO2, N2 balance) concentration, and more electron transfer facilitates the formation of carbonate species on the Li4SiO4 (010) surface at lower temperatures, thereby improving its CO2 adsorption performance.

Accelerated Water Desorption of Oligomeric Poly(ethylene glycol) by Addition of Poly(propylene glycol) for Energy-Efficient Water Recovery Systems.

Adsorbents are used to recover water vapor from the atmosphere in desiccant air conditioning (DAC) and atmospheric water harvesting (AWH) systems. Solid adsorbents have been conventionally used in these systems, though liquid adsorbents are considered to be more effective for energy-efficient fluidic thermosystems because of their low regeneration temperatures (45-70 °C). While most previous studies have focused on improving the adsorption performance, the desorption performance of adsorbents can also be a critical factor in improving the energy efficiency of these systems. Thus, this study aimed to improve the water desorption efficiency, focusing on the liquid adsorbents. We found that mixing hydrophobic molecules into a liquid adsorbent decreases the desorption temperature and increases the water-desorption efficiency. Oligomeric poly(ethylene glycol) (PEG), a common moisture-adsorbing liquid oligomer used in detergents and cosmetics, was selected as the liquid adsorbent. Oligomeric poly(propylene glycol) (PPG), which has a structure analogous to PEG and lower hygroscopicity, was selected as the hydrophobic molecule. Water adsorption and desorption experiments showed that the mixture of PPG with PEG promoted the desorption of water molecules beyond that of PEG, while thermogravimetric differential thermal analysis revealed a decrease in the water desorption temperature with increasing PPG content. The improved desorption efficiency was ascribed to the likely water adsorption equilibrium between PEG and PPG in the blend; water molecules are preferentially desorbed from PPG, which has weaker water-adsorbate interactions. The proposed concept is expected to be incorporated into various hygroscopic liquids to develop energy-efficient liquid adsorbents for DAC and AWH.