Lower Paleozoic Strata Research Articles

A special ore formation of the newly discovered Hamaling Au-Cu-Mo polymetallic deposit in the Tongling ore-cluster region: Constraints from geochronology and geochemistry

The Hamaling deposit represents the first discovery of a gold-copper-molybdenum deposit situated within the Ordovician strata of the Tongling ore-cluster region. It comprises three distinct types of ore, including porphyry-type Cu-Au ore found in granodiorite, skarn-type Cu-Au ore at the contact zone, and breccia-type Mo-Cu ore within the Ordovician strata. However, the exact mineralization age, ore genesis, and mineralization processes of the Hamaling deposit remain uncertain. To address these uncertainties, the present study employed LA-ICP-MS to date zircon in granodiorite and garnet in skarn, revealing ages of 139.3 ± 0.44 Ma and 142.3 ± 0.89 Ma, respectively. Additionally, the age of 140.0 ± 1.1 Ma was obtained through Re-Os dating of molybdenite from breccia-type ore. These findings suggest a connection between the Hamaling deposit and the early Cretaceous magmatic activity in the Tongling region. The granodiorite intrusion exhibits a high-potassium calc-alkaline affinity and formed under oxidized conditions at temperatures ranging from 721 to 832 °C (average 769 °C). The Hf isotope composition of the granodiorite implies its formation through the mixing of mantle-derived magma from an enriched lithospheric mantle with partially melted lower crustal source magma. The sulfur isotopes found in the ore minerals range from δ34S = 5.55 ‰ to 11.99 ‰, indicating a magmatic sulfur source. The H-O isotopic compositions of quartz during the quartz-sulfide stage suggest that the magmatic water was the primary component of the fluids responsible for ore formation, possibly with some contribution from meteoric water. The identification of the Hamaling deposit highlights the significant potential for mineral exploration within the Lower Paleozoic strata in the Tongling ore-cluster area and even the broader Middle-Lower Yangtze River Valley Metallogenic Belt (MLYB).

Aryl isoprenoids from the Lower Paleozoic in the Tarim Basin, NW China: Insight into deep ancient hydrocarbon exploration

The deep ancient hydrocarbon accumulation in the Tarim Basin was extremely complex. It was characterized by large deep burial, multistage accumulations, multistage adjustments, and multistage secondary alterations, affording limited effectiveness of steroid/terpene biomarkers used widely in oil-source correlation. Aryl isoprenoids (AIs), as a series of diagnostic biomarkers, have attracted increasing attention. For a detailed investigation of AIs from the Lower Paleozoic strata and its internal crude oil in the Tarim Basin, various experimental techniques have been employed. The m/z 133 and 134 mass chromatograms of the AIs confirmed their identification. The anomalously heavy compound-specific δ13C (up to ∼ −16‰) indicated the unequivocal precursor of green sulfur bacteria that was only developed under photic zone euxinia (PZE) conditions. AIs were detected in highly mature source rocks and the crude oils suffered secondary alterations, indicating that AIs might have strong stability and anti-secondary-alteration ability. Based on their widespread distribution in the Lower–Middle Ordovician Heituao Formation (O1-2h Fm) and the Lower Cambrian Yuertus Formation (Є1y Fm) shales, the discovery of AIs in almost all crude oils suggests that the O1-2h Fm and Є1y Fm shales were the primary source rocks for the remarkably abundant Lower Paleozoic deep petroleum resources. This reverses the previously held belief that the Middle-Upper Ordovician source rocks were the primary source rocks. In addition, AIs might induce the formation of organic-rich source rocks (the TOC was up to 29.8%) by promoting high-quality preservation conditions (containing H2S). Furthermore, unlike the H2S poisoning mechanism for the end-Permian mass extinction explained by AIs, regionally distributed AIs triggered by H2S from non-volcanic eruptions could explain the biological radiations (such as the early Cambrian radiation). Therefore AIs might provide important insights into the research on deep ancient petroleum exploration and its contemporaneous biological events.

Diagenesis- and thermal maturity-evolution of the Silurian unconventional hydrocarbon deposits (Tassili n’Ajjer plateau, Algeria): Clay mineralogy, graptolite reflectance, and K–Ar dating

The need for determining the thermal maturity of Lower Paleozoic rocks has increased with the intensified unconventional shale oil/gas resources exploration within North Africa, Arabian Peninsula, and the adjoining regions. Indeed, Lower Paleozoic strata represent an increasingly important resource that is related to the globally widespread occurrence of graptolite-bearing marine sediments in an expansive shelf area of the Gondwana. However, some crucial information for basin analysis remains poorly understood even across the largest hydrocarbon-producing province in Algeria.The present study provides a solid understanding of the diagenesis- and thermal maturity-evolution from the Tassili n’Ajjer plateau while involving multiple and independent approaches, such as clay mineralogy, petrography, graptolite reflectance, source rock maturity, as well as illite K−Ar geochronology. The combined use of X-ray analysis and field emission scanning electron microscope evidenced kaolinite, illite, and iron-rich chlorite as the main authigenic mineral phases. K−Ar data indicate that episodic in situ illite crystallization occurred at different times, the oldest illite at about 335 Ma and the youngest illite between 238 and 179 Ma, under diagenetic-to-hydrothermal conditions. Paleotemperature estimates (∼165–232 °C) derived from illite crystallinity (0.37–1.58 Δ°2θ), and graptolite reflectance (VReqv, 1.09–1.84%) values indicate deep diagenetic-low anchizone boundary conditions. This is broadly suggestive of late oil-to-dry gas zones of hydrocarbon generation and destruction, notably in the western sector of the study area.At least two heating events and diagenetic fluid flow processes are identified mainly in response to various tectonic events. They are largely due to fault reactivations, and migration of hot, potassium-rich, fluids throughout the Phanerozoic. Additionally, these events and processes had a later influence on the hydrocarbon maturation, migration, and/or entrapment, especially along the inherited N–S lineaments and Hoggar Massif mega-shear zones in the westernmost part of the Tassili n’Ajjer plateau.Lastly, it is important to highlight that the promising areas offering the highest potential for future unconventional hydrocarbon resource exploration could be most likely those bordering major lineaments, coupled with subsequent igneous activity, where unrestricted hydrothermal fluids are frequently reported, as well as the maturation, being much more advanced.

Foreland basin response to middle Cretaceous thrust belt evolution, southwestern Montana, USA

Abstract The middle Cretaceous Blackleaf Formation records the first major transgressionregression of the Western Interior Seaway into the southwestern Montana retroforeland basin. Although Blackleaf sedimentology is well documented, sediment provenance and potential linkages with regional tectonics are not. Recent characterization of hinterland tectonics, fold-thrust belt detrital zircon signatures, and advances in high-n detrital zircon analysis allow for significant provenance refinement. We present new detrital zircon ages (n = 5468) from ten samples from the upper Blackleaf Formation (Intervals C and D) in southwestern Montana. Based on maximum depositional ages, sedimentation spanned from 106 to 92 Ma. Jurassic and Cretaceous grains were primarily derived from the older portion of the Cordilleran magmatic arc in western Idaho. Triassic and older grains were recycled from older central Idaho sedimentary strata inboard of the arc. Three depositional stages are identified based on statistical modeling of detrital age distributions. Stage 1 (106–104 Ma) records sourcing from lower Paleozoic strata in central Idaho. Stage 2 (105–101 Ma) records initial unroofing of upper Paleozoic–Triassic strata via propagation of the fold-thrust belt into eastern Idaho, accommodating shortening of Mississippian and younger rocks above the Lemhi Arch. Stage 3 (102–100 Ma) records continued unroofing in central Idaho down to Cambrian stratigraphic levels and distal mixing of sources in the eastern part of the basin. Exhumation in the fold-thrust belt beginning at ca. 105 Ma is coincident with marginwide fault slip-rate increases. We infer that increased sedimentation rates and lowmagnitude flexural loading from shallow thrusting in eastern Idaho drove clastic wedge progradation across the basin.

Zircon (U-Th)/(He-Pb) double-dating constraints on the interplay between thrust deformation and foreland basin architecture, Sevier foreland basin, Utah

AbstractThe Cretaceous Cordilleran foreland basin strata exposed in the Book Cliffs of eastern Utah and western Colorado have motivated important concepts linking thrust belt deformation and foreland basin evolution largely on the basis of sequence stratigraphy, stratal architecture, and sediment provenance evolution. However, these methods and approaches generally cannot provide critical insights into the temporal or causal linkages between foreland basin architecture and thrust belt deformation. This is in part due to discrepancies in age resolution and lack of evidence with which to directly couple sediment supply and basin-fill evolution to thrust belt unroofing. New detrital zircon (DZ) geothermochronometric data from Upper Cretaceous proximal to distal foreland basin strata in the Book Cliffs provide new quantitative insights into sediment origin and dispersal in relation to thrust belt deformation and exhumation. Detailed DZ U-Pb and (U-Th)/He double dating reveals that the Book Cliffs foredeep detritus was mainly delivered by transverse routing systems from two major sources: (1) Neoproterozoic and Lower Paleozoic strata from the central Utah Sevier thrust belt, and (2) Permian–Jurassic and synorogenic Cretaceous strata recycled from the frontal part of the thrust belt. A dramatic increase in Sierran magmatic arc and Yavapai-Mazatzal DZ U-Pb ages, as well as Paleozoic DZ He ages, in the deeper marine portions of the foreland basin points to axial fluvial and littoral sediment input from the Sierran magmatic arc and Mogollon highland sources. Both transverse and axial transport systems acted contemporaneously during eastward propagation of the Late Cretaceous thrust belt. DZ He depositional lag time estimates reveal three distinct exhumation pulses in the Sevier thrust belt in the Cenomanian and Campanian. The exhumation pulses correlate with shifts in sediment provenance, dispersal style, and progradation rates in the foreland basin. These new data support conceptual models that temporally and causally link accelerated exhumation and unroofing in the thrust belt to increases in sediment supply and rapid clastic progradation in the foreland basin.

KINNEYIA-TYPE WRINKLE STRUCTURES ON SANDSTONE BEDS: NOT MICROBIALLY INDUCED BUT DEFORMATION FEATURES CAUSED BY SYNSEDIMENTARY EARTHQUAKES

ABSTRACT A category of wrinkle structures, often termed Kinneyia structure or Runzel marks, comprises bedding plane features consisting typically of anastomosing, low-relief, flat-topped ridges with intervening depressions. Topographic relief is usually less than a millimeter. They are locally common on the upper surfaces of fine- to medium-grained sandstone beds interbedded with mudstone deposited in offshore settings, especially in Precambrian and lower Paleozoic strata but as young as Cretaceous. For more than the last two decades these wrinkle structures have been widely regarded as due to microbial mats, and have been taken as evidence for dominance in the Proterozoic of microbially stabilized sediment and, in the Phanerozoic, a matground marine benthic ecology which gradually gave way to a mixground ecology. The detailed morphology and cross-cutting relationships demonstrated by a range of specimens of Proterozoic, Cambrian, and Silurian age, however, cast this interpretation into doubt. The relationship between the wrinkled surface and bioclasts such as shells and both prior- and later-formed scour surfaces, and horizontal and vertical burrows show that these wrinkles did not develop due to the surface topography of microbial mats or compaction of microbial mats during burial, but instead formed at the top of a sand bed at the interface with an overlying layer of mud. Deformation is ascribed to vibration from low-magnitude earthquakes. The presence in some units of small-scale sedimentary dikelets and crack arrays that formed later after some stiffening, along with locally associated seismites and other evidence for nearby faulting, show that syndepositional tectonic activity was not unexpected and support the interpretation that this category of wrinkle structures is a type of seismite.

Multi-scale evaluation of fractured carbonate reservoir and its implication to sweet-spot optimization: A case study of Tazhong oilfield, Central Tarim Basin, China

Ordovician limestone and Cambrian dolomite are the main oil and gas producing layers in eastern Tazhong field, Tarim basin. Industrial oil flow has been obtained from drilling in this zone, proving that the Lower Paleozoic strata is important for oil and gas exploration and development. However, the main controlling factors and distribution of high-quality reservoirs remain unclear. Based on the logging constrained seismic inversion , FMI (Fullbore Formation MicroImager) log interpretation and core analysis of six wells, the main controlling factors of Paleozoic carbonate reservoirs in the study area were investigated. The results reveal that the two buried cuestas control the distribution of the Cambrian and Ordovician strata, the ratio of mudstone in north buried cuesta (NBC) is more than that in south buried cuesta (SBC), and the average porosity of ▪3xq dolomite formation is more than that of O1−2y limestone formation. FMI logging interpretation results show that fracture density of well TZ-1 is significantly higher than that of well TZ-2, combined with core observation and microscopic analysis we can believe that reconstructed dolomite reservoir has developed dissolution pores and vugs. By the means of seismic impedance reconstruction, the most favorable production areas, so-called sweet-spots, are karst residual mounds that formed independent small anticlinal high points and have been depicted. Finally, total 28 traps in the Cambrian–Ordovician​ carbonate buried hill are characterized, covering an area of 66.4 km2. 17 anticline traps with an area of 26.9 km2 in dolomite reservoirs are optimized to be the next exploration targets.

Subsurface Characterization of the Quaternary Active Cheraw Fault in Southeastern Colorado Based on Seismic Imaging

AbstractThe subsurface structure of the late Quaternary active Cheraw fault is relatively unstudied. Vertical displacement estimates of faulted bedrock horizons, characteristics of bedrock structure (e.g., dip), potential association with dissolution of underlying Permian evaporite strata, and whether or not a postulated northeast extension of the topographic scarp is associated with Quaternary faulting have remained open questions. In this study, we assess six 2D seismic reflection profiles that cross the Cheraw fault scarp, demonstrate how Quaternary normal faulting has reactivated pre-existing structures along the northwest flank of the Las Animas arch, and provide new constraints for seismic hazard characterization. We map the fault to depths of at least 1.5–1.8 km into lower Paleozoic strata in which the continuity of the fault through Permian evaporite indicates that dissolution of those stratigraphic intervals has no role in Quaternary surface faulting. Interpretation of the seismic data reveals an ∼75°±5° northwest-dipping fault with ∼24–30 m vertical displacement of upper Cretaceous strata, which coincides with Quaternary scarps at the surface.

Geological conditions, reservoir evolution and favorable exploration directions of marine ultra-deep oil and gas in China

By analyzing the structural background, petroleum geological conditions, and typical regional (paleo) oil and gas reservoirs in marine ultra-deep oil and gas regions in China, this paper reveals the evolution processes of the marine ultra-deep oil and gas reservoirs and the key controlling factors of accumulation. The marine ultra-deep oil and gas resources in China are buried at depth of greater than 6000 m, and are mainly distributed in the Precambrian and Lower Paleozoic strata in the Sichuan, Tarim and Ordos cratonic basins. The development of marine ultra-deep source rocks in China is controlled by cratonic rifts and cratonic depressions with the background of global supercontinent breakup-convergence cycles. The source rocks in Sichuan Basin have the most developed strata, followed by Tarim Basin, and the development strata and scale of Ordos Basin needs to be further confirmed. The marine ultra-deep reservoir in China is dominated by carbonate rocks, and the reservoir performance is controlled by high-energy sedimentary environment in the early stage, superimposed corrosion and fracture in the later stage. The regional caprocks are dominated by gypsum salt rocks, shale, and tight carbonate rock. The ultra-deep oil and gas fields in China have generally experienced two stages of oil-reservoir forming, cracking (or partial cracking) of paleo-oil reservoirs, and late finalization of cracked gas (or highly mature to over mature oil and gas). The oil and gas accumulation is controlled by static and dynamic geological elements jointly. Major hydrocarbon generation center, high quality and large-scale reservoir resulted from karstification of high energy facies belt, thick gypsum rock or shale caprock, and stable trapping and preservation conditions are the key factors for accumulation of ultra-deep oil and gas. We propose three favorable exploration directions, i.e. the areas around intracratonic rift and intracratonic depression, and craton margin.

Reservoir forming conditions and exploration potential of Lower Paleozoic carbonate rocks in Gucheng area, Tarim Basin

The Gucheng region is oil and gas accumulation area of Tarim Basin，dominated by beach controlled lithologic oil and gas reservoirs，which has superior oil and gas accumulation conditions and broad exploration prospects. The lower Paleozoic strata in the Gucheng region are the Carboniferous, Ordovician, and Cambrian systems from top to bottom. The Silurian, Devonian, and Permian systems are missing. The lower Ordovician – Cambrian are the main exploration target layers in the area. There are four reservoirs: the Ordovician group, the Yingshan group, the Penglaiba group and the Cambrian group in The Gucheng region, The upper part of the Yijianfang formation and Yingshan formation are limestone reservoir, which is a set of potential reservoir. The lower part of the Yingshan formation, the Penglaiba formation, and the Cambrian formation developed three sets of dolomite reservoirs. The distribution of oil and gas in Gucheng region was mainly found in Yijianfang formation, Yingshan formation, Penglaiba formation and Cambrian of the Ordovician. The Yingshan group and the Hanwu group were the main exploration target layers. Yingshan formation and Cambrian are the main exploration targets, and Yijianfang formation and Penglaiba formation of Ordovician can be used as the concurrent exploration targets. Gucheng region can form two major realistic exploration areas: dolomite reservoir of Ordovician and reef beach of Cambrian. The Ordovician dolomite reservoirs are mainly searched for the inner shoal of the platform edge high-energy facies belt, and the Cambrian system is mainly search for the high-energy reef beach far away from the platform edge facies belt in the north of cherchen fault.

Reconstructing the Himalayan margin prior to collision with Asia: Proterozoic and lower Paleozoic geology and its implications for Cenozoic tectonics

Abstract Reconstructing the stratigraphic architecture of deposits prior to Cenozoic Himalayan uplift is critical for unravelling the structural, metamorphic, depositional and erosional history of the orogen. The nature and distribution of Proterozoic and lower Paleozoic strata have helped elucidate the relationship between lithotectonic zones, as well as the geometries of major bounding faults. Stratigraphic and geochronological work has revealed a uniform and widespread pattern of Paleoproterozoic strata >1.6 Ga that are unconformably overlain by <1.1 Ga rocks. The overlying Neoproterozoic strata record marine sedimentation, including a Cryogenian diamictite, a well-developed carbonate platform succession and condensed fossiliferous Precambrian–Cambrian boundary strata. Palaeontological study of Cambrian units permits correlation from the Indian craton through three Himalayan lithotectonic zones to a precision of within a few million years. Detailed sedimentological and stratigraphic analysis shows the differentiation of a proximal realm of relatively condensed, nearshore, evaporite-rich units to the south and a distal realm of thick, deltaic deposits to the north. Thus, Neoproterozoic and Cambrian strata blanketed the northern Indian craton with an extensive, northward-deepening, succession. Today, these rocks are absent from parts of the inner Lesser Himalaya, and the uplift and erosion of these proximal facies explains a marked change in global seawater isotopic chemistry at 16 Ma.

Application of PPS measurements to refine the 3D seismic interpretation based on the Lower Paleozoic strata example

Application of PPS measurements to refine the 3D seismic interpretation based on the Lower Paleozoic strata example

Seismicity Induced by Wastewater Injection in Washington County, Ohio: Influence of Preexisting Structure, Regional Stress Regime, and Well Operations

AbstractRecent seismicity in Washington County, Ohio, has been suggested to be induced by wastewater disposal operations despite injection ~2 km above the Precambrian basement. We investigated the relationships between disposal well locations and operational histories, spatiotemporal patterns of seismicity enhanced by waveform correlation, and mapped subsurface structures. We also analyzed proxies for in situ stress conditions to evaluate existing principal stress orientations and magnitudes. Double‐difference relocations of small (ML ≤ 2.1) seismicity revealed linear clusters defining a NE‐SW orientation that parallels the trend of small‐amplitude folds in Upper Paleozoic rocks within 1–2 km of the injection well. Hypocenter depths of ~3.1 to 4.3 km indicate seismicity occurred along faults below the Silurian injection interval in lower Paleozoic strata and Precambrian crystalline basement. Similar folds/faults imaged in nearby seismic reflection lines were associated with basement‐involved fault systems that cut the injection interval targeted by the injection well, providing permeability pathways for fluid pressure increases that initiated slip. Interpreted faults were also optimally oriented in the regional stress field for reactivation due to injection‐related decreases in effective stress. Well completion records suggest that during the recorded seismicity, the Long Run‐1 well was injecting disposal fluids close to or above the fracture pressure of the targeted Silurian injection interval. A comparison of observed seismicity rates and monthly injection records from the disposal well also indicate a close correspondence between earthquake frequency and injection rate. Taken together, these results provide a physical framework for understanding why wastewater disposal operations induced the Washington County seismic sequence.

Tectono-thermal Evolution of the Lower Paleozoic Petroleum Source Rocks in the Southern Lublin Trough: Implications for Shale Gas Exploration from Maturity Modelling

The Lower Paleozoic basins of eastern Poland have recently been the focus of intensive exploration for shale gas. In the Lublin Basin potential unconventional play is related to Lower Silurian source rocks. In order to assess petroleum charge history of these shale gas reservoirs, 1-D maturity modeling has been performed. In the Łopiennik IG-1 well, which is the only well that penetrated Lower Paleozoic strata in the study area, the uniform vitrinite reflectance values within the Paleozoic section are interpreted as being mainly the result of higher heat flow in the Late Carboniferous to Early Permian times and ~3500 m thick overburden eroded due to the Variscan inversion. Moreover, our model has been supported by zircon helium and apatite fission track dating. The Lower Paleozoic strata in the study area reached maximum temperature in the Late Carboniferous time. Accomplished tectono-thermal model allowed establishing that petroleum generation in the Lower Silurian source rocks developed mainly in the Devonian – Carboniferous period. Whereas, during Mesozoic burial, hydrocarbon generation processes did not develop again. This has negative influence on potential durability of shale gas reservoirs.

U–Pb geochronology and Hf-isotopes on detrital zircons of Lower Paleozoic strata from Hainan Island: New clues for the early crustal evolution of southeastern South China

Integrated in situ U–Pb dating and Hf-isotope analysis on detrital zircons from six sandstone samples from Hainan Island have been used to identify clastic sedimentary provenances, regional magmatic activity and crustal evolution processes. Four samples (2011XL-1, 2011JB-1, 09HN54 and 2011GB-1) are from previous mapped Silurian strata and the other two samples (2011TD-1 and 09HN39) belong to Ordovician and Cambrian strata, respectively. A total of 463 concordant U–Pb zircon analyses of the six samples define five major age populations: 2598–2320Ma (a peak of 2480Ma), 1944–1606Ma (peak-1750Ma), 1600–1406Ma (peak-1502Ma), 1288–902Ma (peak-957Ma), 470–427Ma (peak-442Ma) and two subordinate populations at 898–710Ma (peak-730Ma) and 618–513Ma (peak-578Ma). The combination of age peaks within the samples provide a record of igneous activity in the source region: the 2480Ma peak is consistent with those ages reported for Neoarchean global continental growth; the 1944–1606Ma population correlates with the time of assembly of the supercontinent Nuna (Columbia); the 1502Ma peak with documented magmatic activity on Hainan Island; and the 1288–902Ma and 898–710Ma populations with global tectonothermal activity associated with assembly and breakup of Rodinia. Our data also reveal a 618–513Ma population that may relate with the assembly of Gondwana. The distinctive age peak at 442Ma indicates input from a region affected by the Kwangsian orogeny. The combined ages and Hf-isotope data for each population suggest that generation of juvenile crust occurred at 1900–1400Ma, 940–740Ma and 470–430Ma. Most of the other age populations that display negative εHf(t) values suggest reworking of older crust.

Investigating fault continuity associated with geologic carbon storage planning in the Illinois Basin

Because the confinement of [Formula: see text] in a storage reservoir depends on a stratigraphically continuous set of seals to isolate the fluid in the reservoir, the detection of structural anomalies is critical for guiding any assessment of a potential subsurface carbon storage site. Employing a suite of 3D seismic attribute analyses (as opposed to relying upon a single attribute) maximizes the chances of identifying geologic anomalies or discontinuities (e.g., faults) that may affect the integrity of a seal that will confine the stored [Formula: see text] in the reservoir. The Illinois Basin, a major area for potential carbon storage, presents challenges for target assessment because geologic anomalies can be ambiguous and easily misinterpreted when using 2D seismic reflection data, or even 3D data, if only conventional display techniques are used. We procured a small 3D seismic reflection data set in the central part of the basin (Stewardson oil field) to experiment with different strategies for enhancing the appearance of discontinuities by integrating 3D seismic attribute analyses with conventional visualizations. Focusing on zones above and below the target interval of the Cambrian Mt. Simon Sandstone, we computed attribute traveltime slices (combined with vertical views) based on discontinuity computations, crossline-directed amplitude change, azimuth of the dip, shaded relief, and fault likelihood attributes. The results provided instructive examples of how discontinuities (e.g., subseismic scale faults) may be almost “invisible” on conventional displays but become detectable and mappable using an appropriate integration of 3D attributes. Strong discontinuities in underlying Precambrian basement rocks do not necessarily propagate upward into the target carbon storage interval. The origin of these discontinuities is uncertain, but we explored a possible strike-slip role that also explains the localization of a structural embayment developed in Lower Paleozoic strata above the basement discontinuities.

The relationship between dolomite textures and their formation temperature: a case study from the Permian-Triassic of the Sichuan Basin and the Lower Paleozoic of the Tarim Basin

Study of dolomite texture can contribute to understanding the process of dolomitization. This research reports textures and homogenization temperatures of dolomites from the Permian-Triassic strata in the Sichuan Basin and the Lower Paleozoic strata in the Tarim Basin, which provided insights into relationships between dolomite textures and their formation temperatures. Our results are summarized as follows: 1) dolomites with well-preserved texture indicate low dolomitization temperature. However, in certain diagenetic environments, the hydrothermal dolomitization may completely or partially preserve the original texture of dolomites. 2) The formation temperatures of non-planar dolomites are always higher than those of planar dolomites. 3) The formation temperatures of dolomite cements are generally higher than those of replacive dolomites. 4) Although the formation temperatures of saddle dolomite cements have a wide range, they show higher values than those of the planar subhedral to euhedral dolomite cements. Thus, saddle dolomites could generally be an indicator of high precipitation temperature. 5) The fluid Mg/Ca ratio is another element controlling dolomite morphology. Micritic dolomites, which precipitate from hypersaline fluids with a high Mg/Ca ratio in a subaerial environment could also have features of non-planar anhedral crystal shape because of rapid nucleation and crystallization during dolomitization.

Sedimentary facies of the upper Cambrian (Furongian; Jiangshanian and Sunwaptan) Tunnel City Group, Upper Mississippi Valley: New insight on the old stormy debate

New data from detailed measured sections permit a comprehensive revision of the sedimentary facies of the Furongian (upper Cambrian; Jiangshanian and Sunwaptan stages) Tunnel City Group (Lone Rock Formation and Mazomanie Formation) of Wisconsin and Minnesota. Heterogeneous sandstones, comprising seven lithofacies along a depositional transect from shoreface to transitional-offshore environments, record sedimentation in a storm-dominated, shallow-marine epicontinental sea. The origin of glauconite in the Birkmose Member and Reno Member of the Lone Rock Formation was unclear, but its formation and preserved distribution are linked to inferred depositional energy rather than just net sedimentation rate. Flat-pebble conglomerate, abundant in lower Paleozoic strata, was associated with the formation of a condensed section during cratonic flooding. Hummocky cross-stratification was a valuable tool used to infer depositional settings and relative paleobathymetry, and the model describing formation of this bedform is expanded to address flow types dominant during its genesis, in particular the importance of an early unidirectional component of combined flow. The depositional model developed here for the Lone Rock Formation and Mazomanie Formation is broadly applicable to other strata common to the early Paleozoic that document sedimentation along flooded cratonic interiors or shallow shelves.

Hydrothermal alteration of dolostones in the Lower Ordovician, Tarim Basin, NW China: Multiple constraints from petrology, isotope geochemistry and fluid inclusion microthermometry

Massive dolostones pervasively occur in the Lower Paleozoic strata in Tarim Basin, NW China. This study focuses on the hydrothermally-altered dolostones in the Lower Ordovician at Sancha, Bachu County where the hydrothermally-altered dolostones, marbles and diabase intrusions co-occur within a large-scale, NW trending strike-slip fault zone. Within this zone, the intrusive diabases mostly occur along the master border faults to the east and west, respectively. The limestones that got in contact with the intrusions commonly were marbleized and the antecedent dolostones were subject to intense hydrothermal alteration, particularly along fractured portions. Based on field investigations and petrographic examinations on the hydrothermally-altered dolostones, five distinctive fabrics of matrix and cement dolomites are distinguished. Two episodes of vein-filling calcites postdate the hydrothermally-precipitated saddle dolomites. Integrated isotopic geochemistry (C, O and Sr) and fluid inclusion microthermometry suggest that dolomite recrystallization and precipitation were associated with the hydrothermal activity induced by fracturing/faulting and intrusive magmatism. CAMECA SIMS U–Pb isotopic dating of zircon grains from the diabases yields an age of 290.5 ± 2.9 Ma in the Early Permian, which reconciles the relative timing revealed by the paragenetic history. The magmatic emplacement was thus linked to the large igneous province (LIP) of Early Permian in Tarim Basin. In this case, the widespread magmatic activities could have caused the thermal anomaly and fracturing in the strata that were penetrated by the intrusions, enhancing the thermal diffusion and hydrothermal fluid migration (although minor volumes of thermal fluids from the basic magmas) through the fracture/fault systems, thereby resulting in contact metamorphism (or marbleization), recrystallization of matrix dolomites and dolomite precipitation commonly in primary dolostone successions. This study provides a useful analogue to understand the dolomitization and relevant issues for the deeply-buried dolostones associated with tectono-magmatism within the Tarim Basin and elsewhere.

Blackened bioclasts and bituminous impregnations in the Koněprusy Limestone (Lower Devonian), the Barrandian area, Czech Republic: implications for basin analysis

Carbonate reef talus facies of the Koněprusy Limestone (Pragian, Lower Devonian, Barrandian) locally exhibit widespread impregnation by organic matter resulting in a partial to complete blackening of the limestones. Two contrasting types of impregnation are recognized: blackening of individual carbonate fossils and bioclastic layers within the limestone originated very early during diagenesis. The blackening is due to finely dispersed organic matter and possibly some iron sulphides and clay minerals that selectively adhered to the outer layers of corals, bryozoans, and crinoid fragments, leaving other fossils unaltered. These darkened fossils are similar to black pebbles—i.e., reworked, dark to black limestone clasts and bioclasts that are known to occur exclusively in shallow-water zones of both ancient and modern carbonates. The alteration of fossil fragments may have taken place in very shallow-water environments, possibly those of saline and reducing back-reef lagoons or supratidal-intertidal zones, with organic matter being derived from decayed algae and microbes, or early vascular terrestrial plant material. Following the coloration, the blackened fossils were removed from their original position by waves or storms and transported into relatively deeper-water reef slope settings to form graded, “salt-and-pepper”-colored bioclastic beds. The presence of blackened fossils in the carbonate succession may point to episodic emergence and indicates a vanished vegetated siliciclastic hinterland that may once have existed to the west or south from the present-day erosive edge of the Barrandian Devonian strata. Subvertical veins cutting the Koněprusy Limestone and filled with black solid bitumen and blackened calcite resulted from a subsequent but substantially later diagenetic event, which is a testament of aqueous and petroleum fluid migration through the succession during deeper burial. Microthermometric characteristics of the aqueous inclusions embedded in vein calcite indicate that the veins were precipitated by brines of low to moderate salinity (0.5–9.5 wt% NaCl equiv.) with temperatures in the range of 87–116°C. The bitumen in the veins is epi-impsonite (Rr = 0.70–1.90%), which is interpreted as degraded petroleum residuum that experienced thermal alteration at around 120°C. The AFT modeling combined with fluid inclusion microthermometry and wider geological considerations indicate that the veins originated during the Variscan orogeny, most probably upon deep burial of the Lower Paleozoic strata in Carboniferous time.