Low Metal Concentrations Research Articles

Bifunctional Catalysts with Separated and Tunable Sites on Zeolites for Relay Catalysis of the Oxidative Dehydrogenation of Propane Using CO2

AbstractThe oxidative dehydrogenation of propane using CO2 (CO2‐ODH) technology has broad application prospects in the production of propylene and the utilization of CO2, and the development of efficient CO2‐ODH catalysts is of great significance. However, it remains a challenge to develop a highly efficient catalyst that can activate both C─H and C═O. Herein, a PtZn/Co@S‐1 catalyst with a very low precious metal content of 0.2 wt.% is reported. Benefiting from the PtZn4 nanoclusters dispersed on the surface of Silicalite‐1 zeolite and tetrahedrally coordinated Co2+ in the Silicalite‐1 zeolite framework via relay catalysis, the independent dual sites structure (PtZn/Co@S‐1) greatly promotes CO2‐ODH reaction with a high conversion rate of both C3H8 (59.7%) and CO2 (44.3%), and propylene selectivity of 94.9%, thus upsetting the equilibrium for direct dehydrogenation of propane. Experimental measurements and density functional theory calculations suggest that the PtZn4 and Co2+ interfaces are likely propane dehydrogenation and carbon dioxide hydrogenation active sites respectively.

Novel application of Ru-based catalysts on MgAl oxides alkaline adsorbents for cyclic CO2 methanation

This study explores the performances of Ru-based catalysts with a low metal content (2 wt%) supported on MgO and Mg-Al Oxides (MgAl) for cyclic CO2 adsorption and methanation at atmospheric pressure. Adsorption and desorption tests demonstrated that MgAl-based catalysts are more promising for CO2 capture due to their larger surface area and better distribution of active sites (Mg2+–O2-). Moreover, doping the MgAl support with K2CO3 further improves surface alkalinity and, consequently, capture performance. During cyclic operations, all the catalysts proved effective and selective for methane production. To simulate realistic conditions, both dry and wet CO2 adsorptions were conducted before the methanation stage. The presence of moisture positively influenced gas carbonation for all catalysts, increasing the overall amount of CO2 captured. Specifically, Ru/MgAl exhibited the best performance in terms of adsorption and conversion to methane (approximately 85 % after dry adsorption and 79 % after wet adsorption), with a maximum methane production of 183 and 220 μmolCH4 g−1, respectively. The reaction yield was further enhanced with Ru-K/MgAl, achieving 327 μmolCH4 g−1 after dry adsorption and 333 μmolCH4 g−1 after wet adsorption. However, this catalyst displays different conversion kinetics, attributed to slowed carbonate migration, low Ru dispersion, limited specific surface area, and excessive carbonation strength. Operando FTIR tests revealed differences in reaction intermediates between Ru/MgAl and Ru-K/MgAl, by going deeper into the kinetic differences observed. The study concludes that Ru/MgAl materials are highly promising catalysts for CO2 adsorption and methane production, supporting the development of technologies for CO2 abatement and renewable energy utilisation.

Application of selected indicators to assess contamination of municipal landfill leachate and its impact on groundwater

Leachate formation is one of the most important factors taken into account during the operation and long-term management of municipal waste landfills. Systematic assessment of groundwater and leachate contamination may be useful in selecting the appropriate method of leachate management or treatment processes. The use of indicators to quantify the contamination potential of leachate and groundwater in the vicinity of MSW could help landfill managers assess their quality. Therefore, the aim of the study was to assess the representativeness of selected indicator methods for analyzing the temporal variability of leachate and groundwater properties in the vicinity of two municipal waste landfills in a Central European country (Poland). The leachate pollution index (LPI), sub-LPI and adjusted leachate pollution index (r-LPI) were used to assess the quality of leachate water, while the landfill water pollution index (LWPI) was used to assess the variability of groundwater quality. The results confirmed that LWPI is an effective method for assessing the quality of groundwater in the vicinity of municipal waste landfills. The obtained results confirm the negative impact of landfills, despite the insulation used. LWPI showed poor quality of groundwater and visible impact of the landfill (landfill W, average LWPI - 2.34) and moderately polluted waters and minor impact of the landfill (landfill S, average LWPI - 1.37). In most cases, it was observed that two parameters, EC and TOC, are the main factors contributing to the deterioration of groundwater quality. The sub-LPI analysis showed that leachates from both landfills have a very low content of heavy metals, so they should not have a negative impact on the biological treatment process. The obtained r-LPI values were in all cases higher than the calculated LPI values. For landfill S, the average r-LPI was 26.3 (Z-1) and 25.7 (Z-2). However, the average LPI was 13.5 (Z-1) and 13.2 (Z-2). For landfill W, the average r-LPI was 14.6 and the average LPI was 11.4. Analysis conducted on multi-year leachate and groundwater data using specific indicators can help managers better understand the impact of MSW on surrounding areas and help avoid potential operational problems in the future.

Exploring the Plant Growth-Promotion Properties of Rhizospheric and Endophytic Bacteria Associated with Robinia pseudoacacia L. in Serpentine Soil.

Serpentine soils are characterized as a unique environment with low nutrient availability and high heavy metal concentrations, often hostile to many plant species. Even though these unfavorable conditions hinder the growth of various plants, particular vegetation with different adaptive mechanisms thrives undisturbed. One of the main contributors to serpentine adaptation represents serpentine bacteria with plant growth-promoting properties that assemble delicate interactions with serpentine plants. Robinia pseudoacacia L. is an invasive but adaptive species with phytoremediation potential and demonstrates extraordinary success in this environment. To explore more in-depth the role of plant growth-promoting serpentine bacteria, we isolated them and tested their various plant growth-promoting traits both from the rhizosphere and roots of R. pseudoacacia. Based on the demonstrated plant growth-promoting traits such as siderophore production, phosphate solubilization, nitrogen fixation, indole-3-acetic acid production, and ACC deaminase production, we sequenced overall 25 isolates, 14 from the rhizosphere and 11 from the roots. Although more efficient in exhibiting plant growthpromoting traits, rhizospheric bacteria showed a low rate of diversity in comparison to endophytic bacteria. The majority of the isolates from the rhizosphere belong to Pseudomonas, while isolates from the roots exhibited higher diversity with genera Pseudomonas, Bacillus, Staphylococcus, Lysinibacillus and Brevibacterium/Peribacillus/Bacillus. The capacity of the described bacteria to produce siderophores, solubilize phosphate, and fix nitrogen highlights their central role in enhancing nutrient availability and facilitating R. pseudoacacia adaptation to serpentine soils. The findings highlight the potential significance of serpentine bacteria, particularly Pseudomonas, in contributing to the resilience and growth of R. pseudoacacia in serpentine environments.

Long-term soil remediation using layered double hydroxides: Field evidence for simultaneous immobilization of both cations and oxyanions

Layered double hydroxides (LDHs) have great potential for immobilizing potentially toxic elements in soil. Nevertheless, their practical effectiveness under field conditions remains largely unknown. In this study, we conducted a 2.5-year field trial using pristine Mg-Al LDHs, Ca-Al LDHs, and iron (Fe)-modified LDHs to simultaneously immobilize both oxyanions (including As and Sb) and cations (including Cd and Pb) in historically contaminated soil affected by mining activities since the 1950s. The immobilization performance of LDHs was examined using various batch tests, including water and DTPA extraction, and by measuring metal(loid) concentrations in Coriandrum sativum (coriander). We found that both pristine and Fe-modified LDHs showed promising initial immobilization performance 7 days after application, achieving significant reductions in DTPA-extractable concentrations of As, Sb, Cd, and Pb by 45.6%–68.3%, 55.4%–94.2%, 11.2%–50.9%, and 62.9%–64.9%, respectively, compared to the control soil without amendment. Notably, pristine LDHs showed diminished immobilization performance in the long term, while Fe-modified LDHs exhibited long-term stability over 2.5 years. A conditional probability-based model was used to depict long-term metal(loid) leaching characteristics in LDH-amended soils. Temporal changes in metal(loid) concentrations in the aboveground edible parts (namely, stems and leaves) of coriander corroborated well with DTPA extraction results. Coriander grown in Fe-modified LDH-amended soils had much lower metal(loid) concentrations compared to those grown in pristine LDH-amended soils. As a result, reductions of 35.1%–42.2% for As, 54.4%–66.2% for Sb, 8.5%–22.8% for Cd, and 56.0%–62.7% for Pb concentrations in coriander were still observed 2.5 years after soil amendment with Fe-modified LDHs. To the best of our knowledge, this is the first field-based evidence using LDHs to simultaneously stabilize both cations and oxyanions in soil. The findings support the potential of LDHs for long-term immobilization of metal(loid)s in soil.

Comprehensive analysis of oils and remaining solid matrices from supercritical fluid extraction of salmon side streams: Fatty acids, bioactive peptides, minerals, and heavy metals

Atlantic salmon (Salmo salar) side streams (head, backbone, and viscera) are nutrient-rich and offer potential for valorization. This study evaluates supercritical fluid extraction (SFE) and solvent extraction (SE) methods for recovering oils, fatty acids, bioactive peptides, minerals, heavy metals, and antioxidants from these byproducts. Both the oil and the remaining solid resulting from the extraction process were analyzed. SFE was more effective in extracting fatty acids from heads and backbones. However, SE yielded a higher peptide content, with SE backbone solids containing 281 peptides, and SE viscera and heads containing 220 peptides each. In contrast, SFE-derived solids had significantly fewer peptides: 9 in heads, 129 in backbones, and 130 in viscera. The identified peptides exhibit potential functional properties, including antioxidant, anti-inflammatory, antithrombotic, immunomodulating, anticancer, and hypolipidemic effects. Mineral and heavy metal content in all extracts met safety standards. SFE-derived matrices had the highest calcium levels (49.7 mg/g in heads, 24.2 mg/g in backbones) and lower heavy metal concentrations than SE. Arsenic, cadmium, mercury, and lead levels were 1.8 mg/kg, 1.8 μg/kg, 55.0 μg/kg, and 25.7 μg/kg, respectively, for SFE, compared to SE's higher values (e.g., 3.5 mg/kg for arsenic). Both methods produced extracts with promising antioxidant activity.

Native Cryo-Correlative Light and Synchrotron X-ray Fluorescence Imaging of Proteins and Essential Metals in Subcellular Neuronal Compartments.

Essential metals such as iron, copper, and zinc are required for a wide variety of biological processes. For example, they act as cofactors in many proteins, conferring enzymatic activity or structural stability. Interactions between metals and proteins are often difficult to characterize due to the low concentration of metals in biological tissues and the sometimes labile nature of the chemical bonds involved. To better understand the cellular functions of essential metals, we correlate protein localization, using fluorescence light microscopy (FLM), and metal distribution with synchrotron X-ray fluorescence (SXRF), a high-sensitivity and high-spatial-resolution technique for metal imaging. Both chemical imaging modalities are implemented under cryogenic conditions to preserve native cell structure and chemical element distribution. As a proof of concept, we applied cryo-FLM and cryo-SXRF correlative imaging to cultured primary hippocampal neurons. Neurons were labeled under live conditions with fluorescent F-actin and tubulin dyes, then samples were flash-frozen and observed in a frozen hydrated state. This methodology, cryo-FLM combined to cryo-SXRF, revealed the distribution of iron, copper and zinc relative to F-actin and tubulin in the growth cones, dendrites, axons, and axonal en passant boutons of developing neurons.

Evaluating radionuclide mobility in groundwater recharge areas of fractured natural barrier systems using multiple isotopes and microbial indicators

The distribution of uranium (U) concentrations, which reached up to 322 µg/L, was found to correlate with the pattern of fractures within the natural barrier system (NBS). Analysis of the vertical distribution of dissolved oxygen (DO), dissolved organic carbon (DOC), tritium (3H), microbial communities, and H2O and SO42– isotopes revealed insights into oxic water infiltration within the heterogeneous fractured system. Their distribution showed that the average infiltration depth at the KURT site is 200 m, while in external areas with a high frequency of fractures, oxic conditions extended down to 495 m. The SO42– isotopes suggested the potential for microbial sulfate reduction to play a role in regulating radionuclide mobility in the deep geological system. At approximately 500 m, genera capable of thriving under harsh conditions of low DO and high heavy metal concentrations, such as Novosphingobium, Comamonadaceae_uc, and Desulfuromonas_g2, were identified. These findings indicate hydrogeological variability and microbial adaptation within the deep NBS, highlighting the importance of understanding the deep geological environment for evaluating microbiome performance in regulating toxic radionuclides within repository systems. Overall, this study emphasizes the pivotal role of age tracers, stable isotopes, and microbiome in enhancing the assessment of the long-term stability of fractured granite barriers.

Thermodynamic Analysis and Synthesis of Metallic Molybdenum Powder via the Solution Combustion Synthesis Process

ABSTRACT This study investigates the production of metallic molybdenum powder through the solution combustion synthesis (SCS) method. Despite thermodynamic challenges posed by potential back-oxidation under equilibrium conditions, the non-equilibrium nature of SCS facilitates the formation of metallic molybdenum. Experimental evidence suggests that Mo6+ actively participates as an oxidizer in the process, leading to the reduction of Mo6+ to Mo4+. Subsequent reduction of MoO2 is primarily driven by reactions with methane, a byproduct of the SCS process. Characterization of the gel precursor reveals the formation of a molybdenum-citric acid dimer. The resulting molybdenum powder exhibits a semi-amorphous structure with a developed specific surface area and low metallic impurity content but contains a significant amount of residual organic compounds. While heat treatment does not effectively remove these impurities, future research efforts should focus on developing purification strategies to minimize organic contamination.

Three-Dimensional Printing of Metallic Parts by Means of Fused Filament Fabrication (FFF)

Obtaining metallic parts via Additive Manufacturing can yield several advantages over using other traditional manufacturing methods such as machining. Material extrusion (MEX) can handle complex shapes with porous structures and, at the present time, much low-end and desktop equipment is available. In the present work, different industrial and medical applications of metallic Fused Filament Fabrication (FFF) parts are presented. First, an overview of the process, equipment, and of the metal-filled filaments currently available is provided. Then, the properties of parts and different applications are shown. For example, metal-filled filaments with a low metal content that can be used to obtain plastic parts with metallic appearance (with either steel, copper, or bronze), and filaments with a high metallic content allow obtaining metallic parts with high mechanical strength after a sintering operation. The present contribution aims to be an up-to-date panorama for current industrial and medical results and lessons learnt from the application of FFF to obtain metallic parts.

Optimizing reverse water gas shift catalysis: Minimizing metal loading and enhancing performance with Pt/ZrO2 catalysts through Rh incorporation

In this study, the optimization of catalysts for the reverse water gas shift reaction by minimizing metal loading and enhancing the performance of supported Pt catalysts through Rh incorporation was done. The catalysts were synthesized by the wet impregnation method, in which the metal noble load in bimetallic samples decreased by approximately one-third compared to the reference platinum catalyst, with varying Rh-Pt ratios. In all materials, m-ZrO2, obtained by the hydrothermal method, was used as support. In the catalytic tests in a continuous packed-bed flow reactor at atmospheric pressure, all samples were active to catalyze CO2 reduction between 200 and 300 °C. Bimetallic samples, particularly those with an Rh-Pt atomic ratio of 20–80, exhibited superior performance in the RWGS reaction despite their lower metal content. Based on the results of H2-TPR, FTIR in situ, and XPS, we propose that the enhanced CO production in bimetallic samples compared to Pt/ZrO2 catalysts can be attributed to Rh increasing the reduction extent of supported Pt. This enhancement facilitates the hydrogenation of bicarbonate species into formate species, which subsequently evolve into Pt0-CO and ultimately into CO. Additionally, Rh incorporation enables an alternative pathway for CO generation, where Pt0-carbonyls, known for their CO-producing capability, are formed via CO2 dissociation on the Pt0 surface. However, higher Rh concentrations favor the CO2 methanation rather than the RWGS reaction.

Effects of strain, pH and oxygen-deficient on catalytic performance of Ruddlesden-Popper oxide Srn+1RunO3n+1 (n=1, 2) for hydrogen evolution reaction

Due to low content of precious metals and good stability, Ruddlesden-Popper (R–P) structure oxides are considered as promising hydrogen evolution reaction (HER) catalysts. However, related research is scarce, hindering its further improvement. In this paper, effects of strain, pH, oxygen-deficient and layer numbers on HER catalytic performance of R–P structure oxides Sr2RuO4, Sr3Ru2O7 and Sr3Ru2O6 were comprehensively calculated for the first time. Our results confirm that oxygen-deficient R–P Sr3Ru2O6 is beneficial for its catalytic performance in alkaline environments. Ranking of catalytic performance in acidic environments: Sr2RuO4>Sr3Ru2O6>Sr3Ru2O7, relatively in alkaline environments: Sr3Ru2O6>Sr3Ru2O7>Sr2RuO4, which means pH actually affects the performance of R–P structure catalysts. In other words, acidic environments are conducive to the catalytic activity of Sr2RuO4, while alkaline environments are beneficial for Sr3Ru2O6 and Sr3Ru2O7. We also calculated the effects of tensile and compressive strains and found that 1% and 3% tensile strain can further enhance the HER catalytic performance of Sr3Ru2O6. Taking into account various practical factors, our work investigated the HER catalytic mechanism of R–P oxides, providing theoretical guidance for the development of R–P structure catalysts.

Precipitation–Flotation Process for Molybdenum and Uranium Separation from Wastewater

The mining of molybdenum and uranium ores inevitably results in the generation of large volumes of wastewater containing low concentrations of metals, which poses significant threats to the environment. This study presents a novel precipitation–flotation process for the simultaneous separation of molybdenum and uranium from wastewater. A systematic investigation was conducted on the impacts of the type of precipitant, flotation reagent type, and flotation parameters on the experimental results. Ferric salt served better as a precipitant than aluminum salt and humic acid did, and sodium dodecyl sulfate (SDS) was more suitable than sodium dodecyl benzene sulfonate for acting as a surfactant and foaming agent. Under specific conditions, including a pH of 6.6, an Fe3+ dosage of 0.6 mmol·L−1, an SDS dosage of 40 mg·L−1, an air flow rate of 25 mL·min−1, and a flotation time of 10 min, the removal efficiencies of molybdenum and uranium reached 96.6% and 93.6%, respectively. After flotation, the molybdenum concentration, uranium concentration, chemical oxygen demand, and turbidity of the treated water all meet the emission standards. Furthermore, the metal removal mechanisms, including the particle size distribution, functional group structure, surface element composition, microstructure, and element distribution, were elucidated on the basis of characterization of the precipitation–flotation products.

Changes in exposure to environmental contaminants in the aftermath of Hurricane Maria among pregnant women in northern Puerto Rico

Experiencing a hurricane during pregnancy is associated with increased risk of adverse birth outcomes and poor mental health. Pregnant people from marginalized communities are more susceptible to adverse effects, as they have fewer resources to overcome hardships at a time when shelter and nutrition are essential. When Hurricane Maria (HM) devastated Puerto Rico in September 2017, the archipelago was already burdened with high poverty, health disparities, environmental contamination, and fragile utility infrastructure. We aimed to compare biomarkers of environmental exposures among pregnant participants in the PROTECT cohort before and after HM and to identify hurricane-related sources of exposure. Metals, PAHs, phthalate metabolites, and phenols were measured in urine samples collected from participants at three prenatal visits (2011–2019). Samples were categorized as before, <3 months, 3–6 months, and >6 months after HM. Using linear mixed effects models, we found that in the 6 months after HM, participants had higher Co, Ni, and DEHPTP concentrations, indicating increased exposure, and lower concentrations of PAHs, several metals, and phthalates, suggesting decreased exposure, compared to pre-HM levels. Biomarkers were not associated with potential exposure sources assessed through questionnaire or previously measured tap water contaminants. This study provides insight into how extreme weather events may alter environmental exposures among pregnant people in Puerto Rico. As climate change has increased the frequency and magnitude of such events, additional research is needed to clarify the implications for maternal and child health and to identify sources of related environmental exposures within this vulnerable population.

Photosystems functioning, the content of chemical elements, flavonoids and brassinosteroids in leaves of chimera Cornus controversa

he formation of chimera is a well-known phenomenon in variegated ornamental and wild plants, but the biochemical peculiarities of this phenomenon are not well studied. The purpose of this work was to conduct a comparative study of the photosynthetic apparatus functioning, the content of macro-, microelements, flavonoids and brassinosteroids in the variegated and green leaves of the periclinal chimera Cornus controversa plant grown in the collection of M. M. Gryshko National Botanical Garden of the NAS of Ukraine. Sampling was made during the period from June to October 2022. The content of photosynthetic pigments and brassinosteroids was measured spectrophotometrically, autofluorescence of leaf tissues was studied using an inverted microscope with a multi-channel fluorescence imaging system, Normalized difference vegetation index (NDVI) – using GreenSeeker devices and fluorimeter, the level of macro- and microelements – using plasma emission spectrometer. Phenolic secondary metabolites were separated by HPTLC. To assess the protective capacity of flavonoids, a bioassay on the germination of radish seeds Raphanus in the presence of AlCl3 was used. It was shown that green leaves of C. controversa chimera, compared to variegated ones, had a twice as high NDVI index, maintained photosynthetic function longer in autumn, and had higher content of macronutrients (Mg, Ca and S) but lower concentration of toxic metals (Al, Cu, Fe, Zn, Ti). Instead, variegated leaves accumulated more brassinosteroids and phenolic metabolites, which were found not only to reduce the toxic effect of aluminum but also to have a growth-stimulating effect on the roots of radish seedlings. Such specialization of green and variegated leaves may contribute to better plant chimeras adaptation to environmental pollution. Keywords: brassinosteroids, Cornus controversa, macroelements, microelements, NDVI index, periclinal chimera, phenolic metabolites, photosynthetic pigments, tissue autofluorescence

Comparative study of silica-based porous materials in the purification of radioactive wastewater

A significant challenge in the treatment of low-level radioactive wastewater is the effective purification of low-concentration radionuclides. Silica-based adsorbents are advantageous for the deep-purification of low-concentration metal ions. This study investigates three primary types of silica-based adsorbents: functionalized mesoporous silica, various modified zeolites, and mesoporous calcium silicate hydrate (C-S-H). These adsorbents were synthesized and their deep-purification effects on heavy metals and radionuclides were compared. The results indicated that mesoporous silica showed relatively poor adsorption for most metal ions. Zeolites outperformed mesoporous silica, with Zn framework-modified zeolites showing enhanced adsorption for several metal ions. Notably, C-S-H displayed superior adsorption performance, achieving high adsorption capacities for various metal ions and radionuclides. Specifically, at a dose of 0.5 g/L, the adsorption efficiency of C-S-H for numerous radionuclides in nuclear power plant wastewater exceeded 92–99 %, highlighting its potential for practical applications. An in-depth analysis of the physical and chemical structure and the adsorption mechanisms of C-S-H revealed its large mesoporous structure and electrostatic attraction to cations across a wide pH range. Multivalent cations were removed through exchange with Ca2+ in C-S-H, whereas monovalent cations were removed through exchange with Na+ in C-S-H. The cyclic structure of silica-oxygen tetrahedra in C-S-H, which promotes large pore formation and provides abundant ion exchange sites, underpins its excellent adsorption properties. This study offers valuable insights for the selection and application of silica-based materials in radioactive wastewater treatment.

Groundwater Contamination by Heavy Metals in Malaysia: Sources, Transport, and Remediation Strategies

Groundwater contamination by heavy metals is a pressing environmental concern, particularly in regions highly dependent on groundwater as a freshwater source. While Malaysia primarily relies on river water, certain states and islands depend on groundwater for their supply. Research on heavy metal contamination in Malaysia’s groundwater remains limited, making it crucial to study the distribution and mobility of contaminants to develop appropriate remediation strategies. In addition to natural sources, anthropogenic activities such as landfills, mining, and the use of fertilizers contribute significantly to heavy metal pollution in groundwater. Factors like rainfall, fluctuating groundwater levels, and low soil pH can exacerbate heavy metal leaching into aquifers. Various models and techniques, including 2D resistivity imaging and MODFLOW, are used to assess groundwater flow and contaminant transport. These models suggest that contaminant concentrations decrease with increased depth and radial distance from pollution sources such as landfills and mining areas. The health risks associated with heavy metal exposure through groundwater consumption are significant, necessitating effective remediation strategies. Phytoremediation is an economical solution for groundwater containing low concentrations of heavy metals, while permeable reactive barriers may be suitable for more complex cases, pending detailed site investigation. This review aims to examine the current state of knowledge on heavy metal contamination in Malaysia’s groundwater, focusing on sources, distribution patterns, and movement of pollutants. It also seeks to evaluate existing remediation methods, including phytoremediation and permeable reactive barriers, while identifying gaps in research, particularly concerning risk assessments and heavy metal speciation.

Arsenic and Heavy Metals in Soils and Plants near Sulfide Mines: Implications for Phytoremediation and Phytomanagement.

The accumulation of heavy metals (i.e., As, Cu, Ni, Pb, and Zn) in soils and native plant species near copper, nickel, and pyrite mines in Vietnam was assessed. The highest soil As, Cu, Ni, Pb, and Zn concentrations recorded in mine soils were 42.3, 1570, 9870, 128, and 462 mg/kg, and those in agricultural soils were 11.4, 453, 94.9, 34.4, and 147 mg/kg, respectively. Pollution index (PI) values indicated heavy pollution (PI = 3.99-13.0) for mine soils, and unpolluted to severely polluted (PI = 0.65-2.84) for agricultural soils. Soil enrichment factors had a wide range, from minimal to extreme enrichment of heavy metals (EF = 0.03-91.4). Arsenic minerals may be the main source of high As concentrations in sulfide mines. The As, Cu, Ni, Pb, and Zn concentrations of 20 native plant species near three mines were in the ranges of 0.05-1150, 3.17-123, 0.47-291, 0.08-6.34, and 6.87-168 mg/kg (dry weight, DW), respectively. Based on the recorded hyperaccumulation levels (1150 mg/kg, DW), bioaccumulation factors (BAF = 2.4-90.0), biomass, and rapid growth, Pteris vittata L. is considered a promising plant for phytoextraction of As in soils. Bidens pilosa L. has potential for phytostabilization of sulfide-bearing soils, given its low concentrations of heavy metals in plant shoots, BAF values of <1, high biomass, and wide distribution. Integrated phytoremediation and phytomanagement are applicable to metal-contaminated soils. Phytomining, energy crops, and vegetation cover should be investigated for the phytomanagement of metal-contaminated soils in mining areas.

First full-scale application of barium carbonate as an effective dispersed alkaline substrate for sulfate removal from acid mine drainage

A full-scale passive treatment plant using barium carbonate (BaCO3), the mineral witherite, as a Dispersed Alkaline Substrate (DAS) for strongly contaminated acid mine drainage was implemented for the first time globally at Mina Concepción, located in the Iberian Pyrite Belt (SW Spain). The plant was monitored over a 105-day period, covering the wettest months of the hydrological year and with a mean flow around 4 L s−1. The AMD treated in the plant exhibits a high strength, with an average sulfate concentration around 1500 mg L−1 and net acidity close to 1000 mg L−1 as CaCO₃ equivalent. According to the above, the loading rate for SO4 and Fe was around 400 and 80 kg day−1, respectively. The treatment process produced an alkaline effluent with low metal content. Nearly complete removal of most metal(loid)s was achieved, with significant sulfate decrease to below 500 mg L−1 in the alkaline outflow of the barium carbonate tank. Barium carbonate demonstrated superior performance compared to magnesia, particularly in enhancing alkalinity and lowering net acidity and concentrations of sulfate and manganese. The high efficiency attained by the plant after the barium carbonate treatment is evidenced by compliance with environmental water quality standards for most contaminants.

Constraints of upper crust magmatic processes on the formation of Saindak porphyry Cu deposit: Insights from mineral geochemistry

Upper crustal magmatic processes play a crucial role in linking the magmatic and hydrothermal systems of porphyry deposits, ultimately controlling the generation of ore-forming fluids. Understanding these processes within a magma chamber is essential for deciphering the formation of porphyry deposits. The Saindak deposit, a large porphyry Cu system in the western Chagai belt, features coeval ore-forming and barren magma pulses, providing key insights into the characterization of porphyry systems. In this study, detailed petrographic observations and geochemical analyses of amphibole, plagioclase, and apatite were conducted to unravel the magmatic evolution at Saindak. Based on textural relationships and crystallization sequences, three distinct populations of amphibole in the ore-forming magma were identified. These amphiboles record the entire fractional crystallization process of magma that initially emplaced at a depth of ∼5 km to the connected magma system at ∼2 km. The study of amphibole and apatite reveals that the fertile magma underwent large-scale fluid exsolution in an open system. The simultaneous and rapid depletion of Cu, Cl, S, and H2O in the magma indicates that Cl and S were highly partitioned into the exsolved fluid phase. These elements formed complexes, which effectively concentrated metals in the fluid. Conversely, the barren magma was characterized by either low metal content or limited fluid exsolution within the magma chamber. Overall, we reconstruct the upper crustal magmatic processes at Saindak and conclude that efficient extraction of Cu through fluid exsolution is the key to porphyry deposit formation.