Low Load Research Articles

Investigation of the effect of load weight on the discharge capacity of lithium–o2 batteries using carbon-paper–based electrodes

We prepared carbon electrodes with nearly uniform thickness and varying loading weights using carbon paper (CP) as a support material and current collector for single-walled carbon nanotubes (SWCNTs). These electrodes were used as the positive electrode in a lithium–O2 battery, tested at a lower voltage limit of 2.4 V with a fixed current of 0.26 mA/cm2 (0.5 mA). Results demonstrated that the discharge gravimetric capacity (capacity normalized per weight of SWCNTs) did not change significantly for loading weights ≥0.42 mg/cm2. However, for loading weights <0.42 mg/cm2, the discharge gravimetric capacity exhibited an inverse correlation with weight. Analysis of the prepared electrodes revealed that at very low SWCNT loading weights, the sheets of SWCNTs became extremely thin, leading to occasional tears. Nonetheless, these structural changes had no significant impact on the specific surface area or contact resistance. Further analysis of the post-test electrodes using scanning electron microscopy and X-ray diffraction, along with considerations of the carbon paper's surface area as a percentage of the total electrode surface, led to the conclusion that at low loading weights, CP actively contributes to the discharge process and serves as a deposition site for Li2O2. Consequently, when the weight of the active material falls below a certain threshold, there is a risk of misperception, potentially leading to an overestimation of the discharge capacity.

Experimental study on GFRP-steel double-skin rubber concrete composite piers under mixed loading

To address the issues related to the insufficient compressive and shear strength of rubberized concrete and to enhance the deformation capacity and longevity of composite piers, a novel approach involving the confinement of rubberized concrete with glass fiber-reinforced polymer (GFRP) tube and steel tube has been proposed. This method aims to create a GFRP-steel double-skin rubberized concrete composite pier. Pseudo-dynamic and quasi-static tests were conducted on the composite pier to assess its seismic response and residual seismic performance. The study investigated the failure mode, hysteretic characteristics, ductility, energy dissipation, stiffness, and self-centering capability of composite piers. Additionally, a correction coefficient for the equivalent plastic hinge length was proposed. The results indicate that the specimen maintains its elastic state when subjected to frequent seismic events. However, when subjected to infrequent seismic events, the glass fiber layer may fracture, leading to the development of white stripes, while the steel tube experiences yielding, transitioning into a plastic state. The shock absorption and toughness of rubberized concrete were effectively utilized when subjected to horizontal low cyclic loading, thereby mitigating the appearance of more pronounced damage in seismic-damaged specimens. The hysteretic curve was complete, demonstrating a significant energy dissipation capacity. This confirmation indicates that the composite pier can be a viable solution for sea-crossing bridges and complex environments.

Impacts of meteorological conditions on the plummeting surface-reaching solar radiation over a sub-tropical station – Pune, India

The unprecedented rise of solar energy as a dominant power source is a remarkable feat, considering our historical struggle to establish its widespread adoption. However, the dynamics of solar radiation reaching the Earth's surface are greatly influenced by meteorological conditions such as clouds, aerosols, and wind speed. This study investigates the detailed changes in surface-reaching solar radiation within the subtropical region Pune from 1993 to 2022. By employing analytical methodologies including linear regression, wavelet coherence, and quantitative analysis, our study reveals a compelling and alarming pattern of plummeting solar radiation over Pune (also known as solar dimming). The total drop is ∼1.04 Wm−2 year−1 (0.21 % year−1), with a more steep decline registered from 2018 to 2022, providing an astonishing rate of ∼6.01 Wm−2 year−1 (1.21 % year−1). Moreover, wavelet coherence transform revealed an antiphase coherence between solar radiation and both clouds and aerosols, suggesting their substantial influence over a longer timeframe. Extensive analysis utilizing observational data is conducted to find the contributing elements to the significant decline during 2018 to June 2022. Analysis of solar radiation statistics showed that clouds led to a substantial reduction of ∼30.18 % compared to conditions with clear-skies. Similarly, the aerosols have a comparable effect, reducing radiation by ∼17.75 % compared to days characterized by low or negligible aerosol loading for the same period. Furthermore, a through statistical analysis investigates a notable anticorrelation (ρ = −0.64) between wind speed and solar radiation. These findings underscore the imperative of incorporating climatic variables while studying solar dimming trends and devising sustainable renewable energy strategies to ensure the long-term viability of solar energy source.

Power law dependence of unstable slip velocity on decreasing shear loading stiffness

Shear loading stiffness plays a critical role in conditioning the stability of slip on reactivated faults. However, a relationship linking peak slip velocities and shear loading stiffness is lacking. To explore this, we shear granite faults in double direct shear with shear loading stiffnesses spanning two orders to define the effects of shear loading stiffness in conditioning the transition from stable to unstable slip. Our results show that peak slip velocity and acceleration decrease as power law relationships with respect to the shear loading stiffness ratio, with identical exponent, and with a linear relationship between the peak slip velocity and acceleration. The maximum acceleration occurs during the velocity weakening process that limits the peak slip velocity. The power law exponent increases linearly with increasing normal stress. Experimental results also indicate that slip magnitude, stress drop and recurrence time of unstable slip events increase, and slip durations decrease with decreasing stiffness ratios. The spans of limit cycles of velocity versus shear stress decrease, and their shapes evolve from triangular to semicircular with increasing loading stiffness ratio. Stress drops mostly occur during deceleration. The deceleration phase dominates the unstable slip duration that decreases as peak slip velocity increases. Our results indicate that the average stress drop rates over a slip duration increase as a power law relationship with reducing shear loading stiffness, which also contributes to a lower shear loading stiffness producing increased slip velocities and accelerations. Our findings highlight that loading stiffness ratio is an underlying mechanism defining unstable slip behaviors with the normal stress merely conditioning the exponent. The present relationship of unstable slip velocity with shear loading stiffness suggests a way to evaluate hazard of an impending instability event based on the initial shear loading stiffness ratio that can be calculated through the linear-elastic behaviors at the early quasi-static phase.

Оценка нестабильности последовательных впрыскиваний топливной аппаратуры дизелей

The issues of uneven cyclic feed in sequential injections by diesel fuel equipment are considered, which is directly related to solving the problem of ensuring the quality of operation of engines of various types and purposes when operating at low loads and rotational speeds. The special importance of solving these problems from the standpoint of ensuring fuel efficiency, environmental pollution, solving issues of engine reliability and improving their operational properties was noted. The features of the formation of residual fuel pressure in the high-pressure pipeline are revealed. The periodic fluctuations of the cyclic feed and injection parameters from cycle to cycle are estimated. A study of possible options for the operation of fuel equipment in low fuel supply modes has been carried out. Based on the analysis, a criterion for evaluating the instability of successive injection cycles for diesel fuel equipment during its operation in various modes has been introduced. By studying numerical examples, the conditions of unstable fuel supply processes in successive injections of various characteristic modes are determined. The criterion determines the quality of the fuel equipment of marine diesel engines and diesel generators in terms of ensuring a minimum stable idle speed and the possibility of ensuring stable reduced fuel supplies. The variability of fuel supply processes in sequential feeds is the cause of increased exchange processes of electric power flow during parallel operation of diesel alternators and reduces the performance characteristics of diesels for various purposes when operating in partial modes. In the process of carrying out development work, scientific research and during the refinement of diesels, the instability criterion allows us to assess the quality of the fuel equipment precisely in partial modes. This is of particular importance for diesel engines of fishing vessels operating for a long time at shared loading modes and low idle speeds, as well as for engines of the tugboat fleet and auxiliary diesel generator sets of all types of facilities used.

Lysyl oxidase production by murine C3H10T1/2 mesenchymal stem cells is increased by TGFβs and differentially modulated by mechanical stimuli.

Tendons are frequently injured and have limited regenerative capacity. This motivates tissue engineering efforts aimed at restoring tendon function through strategies to direct functional tendon formation. Generation of a crosslinked collagen matrix is paramount to forming mechanically functional tendon. However, it is unknown how lysyl oxidase (LOX), the primary mediator of enzymatic collagen crosslinking, is regulated by stem cells. This study investigates how multiple factors previously identified to promote tendon formation and healing (transforming growth factor (TGF)β1 and TGFβ2, mechanical stimuli and hypoxia-inducible factor (HIF)-1α) regulate LOX production in the murine C3H10T1/2 mesenchymal stem cell (MSC) line. We hypothesized that TGFβ signaling promotes LOX activity in C3H10T1/2 MSCs, which is regulated by both mechanical stimuli and HIF-1α activation. TGFβ1 and TGFβ2 increased LOX levels as a function of concentration and time. Inhibiting the TGFβ type I receptor (TGFβRI) decreased TGFβ2-induced LOX production by C3H10T1/2 MSCs. Low (5 mPa) and high (150 mPa) magnitudes of fluid shear stress were applied to test impacts of mechanical stimuli, but without TGFβ2, loading alone did not alter LOX levels. Low loading (5 mPa) with TGFβ2 increased LOX at 7 days greater than TGFβ2 treatment alone. Neither HIF-1α knockdown (siRNA) nor activation (CoCl2) affected LOX levels. Ultimately, results suggest that TGFβ2 and appropriate loading magnitudes contribute to LOX production by C3H10T1/2 MSCs. Potential application of these findings includes treatment with TGFβ2 and appropriate mechanical stimuli to modulate LOX production by stem cells to ultimately control collagen matrix stiffening and support functional tendon formation.

High Strain Rate Hardening of Metallic Cellular Metamaterials

AbstractStrain rate hardening caused by the changed deformation mode is a fascinating phenomenon in cellular metamaterials where the material’s stiffness and energy absorption capabilities increase as the strain rate increases. This unique behaviour is attributed to a combination of micro-inertia effects, base material’s strain rate hardening and inertia effects. At high strain rates, the metamaterial’s inertia influences its deformation response, which changes to shock mode. This work briefly presents the geometry and fabrication of different metallic metamaterials. Then, it evaluates their mechanical response at different strain rates, ranging from quasi-static to intermediate dynamic and shock, determined by experimental and computational investigation. The three deformation modes can be separated into two critical loading velocities, unique for each metamaterial, which are also presented and compared in this work for various metamaterials. The investigations show that the deformation mode change in metallic metamaterials depends on their porosity. The critical velocities separating the deformation modes decrease with increasing porosity, i.e., decreased density of the metamaterial results in reduced critical loading velocities. The shock deformation mode in cellular metamaterials is thus attainable at much lower loading velocities than in homogeneous (nonporous) materials.

Atomically dispersed Iridium on Mo2C as an efficient and stable alkaline hydrogen oxidation reaction catalyst

Hydroxide exchange membrane fuel cells (HEMFCs) have the advantages of using cost-effective materials, but hindered by the sluggish anodic hydrogen oxidation reaction (HOR) kinetics. Here, we report an atomically dispersed Ir on Mo2C nanoparticles supported on carbon (IrSA-Mo2C/C) as highly active and stable HOR catalysts. The specific exchange current density of IrSA-Mo2C/C is 4.1 mA cm−2ECSA, which is 10 times that of Ir/C. Negligible decay is observed after 30,000-cycle accelerated stability test. Theoretical calculations suggest the high HOR activity is attributed to the unique Mo2C substrate, which makes the Ir sites with optimized H binding and also provides enhanced OH binding sites. By using a low loading (0.05 mgIr cm−2) of IrSA-Mo2C/C as anode, the fabricated HEMFC can deliver a high peak power density of 1.64 W cm−2. This work illustrates that atomically dispersed precious metal on carbides may be a promising strategy for high performance HEMFCs.

Indirect Head of the Rectus Femoris Tendon as a Graft for Segmental Hip Labral Reconstruction: An Anatomic, Radiographical, and Biomechanical Study in Comparison With Iliotibial Labral Reconstruction.

The indirect head of the rectus femoris (IHRF) tendon has been used as an autograft for segmental labral reconstruction. However, the biomechanical properties and anatomic characteristics of the IHRF, as they relate to surgical applications, have yet to be investigated. To (1) quantitatively and qualitatively describe the anatomy of IHRF and its relationship with surrounding arthroscopically relevant landmarks; (2) detail radiographic findings pertinent to IHRF; (3) biomechanically assess segmental labral reconstruction with IHRF, including restoration of the suction seal and contact pressures in comparison with iliotibial band (ITB) reconstruction; and (4) assess potential donor-site morbidity caused by graft harvesting. Descriptive laboratory study. A cadaveric study was performed using 8 fresh-frozen human cadaveric full pelvises and 7 hemipelvises. Three-dimensional anatomic measurements were collected using a 3-dimensional coordinate digitizer. Radiographic analysis was accomplished by securing radiopaque markers of different sizes to the evaluated anatomic structures of the assigned hip.Suction seal and contact pressure testing were performed over 3 trials on 6 pelvises under 4 different testing conditions for each specimen: intact, labral tear, segmental labral reconstruction with ITB, and segmental labral reconstruction with IHRF. After IHRF tendon harvest, each full pelvis had both the intact and contralateral hip tested under tension along its anatomic direction to assess potential site morbidity, such as tendon failure or bony avulsion. The centroid and posterior apex of the indirect rectus femoris attachment are respectively located 10.3 ± 2.6 mm and 21.0 ± 6.5 mm posteriorly, 2.5 ± 7.8 mm and 0.7 ± 8.0 mm superiorly, and 5.0 ± 2.8 mm and 22.2 ± 4.4 mm laterally to the 12:30 labral position. Radiographically, the mean distance of the IHRF to the following landmarks was determined as follows: anterior inferior iliac spine (8.8 ± 2.5 mm), direct head of the rectus femoris (8.0 ± 3.9 mm), 12-o'clock labral position (14.1 ± 2.8 mm), and 3-o'clock labral position (36.5 ± 4.4 mm). During suction seal testing, both the ITB and the IHRF reconstruction groups had significantly lower peak loads and lower energy to peak loads compared with both intact and tear groups (P = .01 to .02 for all comparisons). There were no significant differences between the reconstruction groups for peak loads, energy, and displacement at peak load. In 60° of flexion, there were no differences in normalized contact pressure and contact area between ITB or IHRF reconstruction groups (P > .99). There were no significant differences between intact and harvested specimen groups in donor-site morbidity testing. The IHRF tendon is within close anatomic proximity to arthroscopic acetabular landmarks. In the cadaveric model, harvesting of the IHRF tendon as an autograft does not lead to significant donor-site morbidity in the remaining tendon. Segmental labral reconstruction performed with the IHRF tendon exhibits similar biomechanical outcomes compared with that performed with ITB. This study demonstrates the viability of segmental labral reconstruction with an IHRF tendon and provides a detailed anatomic description of the tendon in the context of an arthroscopic labral reconstruction. Clinicians can use this information during the selection of a graft and as a guide during an arthroscopic graft harvest.

High-efficient electrooxidation of ethylene glycol and ethanol on PdSn alloy loaded by versatile poly(3,4-ethylenedioxythiophene)

Developing a novel catalyst with lower noble-metal loading and higher catalytic efficiency is significant for promoting the widespread application of direct alcohol fuel cells (DAFCs). In this work, poly(3,4-ethylenedioxythiophene) (PEDOT) supported the PdSn alloy (PdSn/PEDOT) were simply synthesized and their electrocatalytic performance toward the oxidation of ethylene glycol and ethanol (EGOR and EOR) were investigated in alkaline media, respectively. In comparison with other control catalysts, the optimized Pd4Sn6/PEDOT catalyst exhibits the highest mass activity (7125/4166 mA mgPd−1) and specific activity (26/15 mA cm−2) towards EGOR/EOR. The mass activity of Pd4Sn6/PEDOT for EGOR and EOR are 11.9 and 10.9 times higher than commercial Pd/C, respectively. Moreover, chronoamperometry (CA) and successive cyclic voltammetry (CV) tests show that the CO resistance ability and durability of the Pd4Sn6/PEDOT catalyst were superior to Pd4Sn6, Pd/PEDOT and commercial Pd/C catalysts, which can be attributed to the d-band center of Pd can be effectively downshifted and the interface strain effect between electrons caused by the conjugated structure between PEDOT groups. This work provides an effective strategy for the development of highly efficient anode catalysts of DAFCs.

Polydopamine-assisted immobilization of metallic nanoparticles confined regionally in bamboo microchannels as continuous-flow microreactors for enhanced catalysis

In contrast to conventional plant-based microreactors where the nanocatalyst is anchored on the inner walls of microchannel structures, this study presents a bamboo-based flow microreactor in which the metallic nanocatalyst is immobilized within polydopamine (PDA) region-modified bamboo microchannels. This novel design facilitates a large surface area for nanocatalyst loading, enhances mass transfer, and reduces nanocatalyst leaching. Firstly, the hierarchical PDA architecture was fabricated on the wall surface of required bamboo microchannels through an ammoniation-induced self-assembly process to serve as a nanocatalyst support layer. The thickness of PDA architectures was modulated by adjusting the flow duration. Secondly, the metallic nanoparticles (NPs), including Pd, Au, and Ag, were effectively immobilized within the hierarchical PDA architectures as highly efficient catalysts using a flow-assisted method with minimal chemical usage and low catalyst loading (Pd content: 0.011 wt%). The catalytic performances of the proposed Pd-PDA/bamboo microreactor were evaluated for the continuous hydrogenation of nitroaromatics under flow conditions, encompassing variations in Pd content, nitroaromatic concentration, and liquid flow rate. The optimized Pd-PDA/bamboo microreactor exhibited high average conversion (>97 %) of nitroaromatics during 20 days of continuous operation without any noticeable deactivation or loss in activity due to its excellent stability resulting from firm immobilization of active metallic NPs within hierarchical PDA architectures. Additionally, this bamboo microreactor demonstrated potential applicability in environmental pollution treatment through azo dye hydrogenation.

Biomass Burning Aerosol Observations and Transport over Northern and Central Argentina: A Case Study

The characteristics of South American biomass burning (BB) aerosols transported over northern and central Argentina were investigated from July to December 2019. This period was chosen due to the high aerosol optical depth values found in the region and because simultaneously intensive biomass burning took place over the Amazon. More specifically, a combination of remote sensing observations with simulated air parcel back trajectories was used to link the optical and physical properties of three BB aerosol events that affected Pilar Observatory (PO, Argentina, 31°41′S, 63°53′W, 338 m above sea level), with low-level atmospheric circulation patterns and with types of vegetation burned in specific fire regions. The lidar observations at the PO site were used for the first time to characterize the vertical extent and structure of BB aerosol plumes as well as their connection with the planetary boundary layer, and dust particles. Based mainly on the air-parcel trajectories, a local transport regime and a long transport regime were identified. We found that in all the BB aerosol event cases studied in this paper, light-absorbing fine-mode aerosols were detected, resulting mainly from a mixture of aging smoke and dust particles. In the remote transport regime, the main sources of the BB aerosols reaching PO were associated with Amazonian rainforest wildfires. These aerosols were transported into northern and central Argentina within a strong low-level jet circulation. During the local transport regime, the BB aerosols were linked with closer fires related to tropical forests, cropland, grassland, and scrub/shrubland vegetation types in southeastern South America. Moreover, aerosols carried by the remote transport regime were associated with a high aerosol loading and enhanced aging and relatively smaller particle sizes, while aerosols associated with the local transport pattern were consistently less affected by the aging effect and showed larger sizes and low aerosol loading.

Validation of the Mediated Learning Observation Instrument Among Children With and Without Developmental Language Disorder in Dynamic Assessment.

In this validation study, we examined the factor structure of the mediated learning observation (MLO) used during the teaching phase of dynamic assessment. As an indicator of validity, we evaluated whether the MLO factor structure was consistent across children with and without developmental language disorder (DLD). Two hundred twenty-four children (188 typically developing and 36 DLD) from kindergarten to second grade completed a 30-min individual mediated learning session on narrative production. Performance during the session was rated using the 12-item MLO by clinicians on affect, behavior, arousal, and elaboration. Exploratory and confirmatory factor analyses were conducted to establish the factor structure and reliability of the MLO. Factor analysis of the MLO suggested a stable three-factor model with adequate fit indices across kindergarten and school-age samples, across both typically developing and DLD subgroups with good to excellent reliability. The final 11-item MLO (one item was removed due to low factor loading) comprises three subscales including (a) cognitive factor, (b) learning anticipation, and (c) learning engagement. The MLO is a valid and reliable instrument for assessing language learning skills in children with and without DLD during dynamic assessment. Practical implications and suggestions for future research addressing the utilization of MLO in dynamic assessment are provided.

Improvement of hydrogen production via aqueous phase reforming of glycerol with Ni-Co catalysts synthesized through controlled urea matrix combustion

The effect of synthesis variable control during the combustion of urea in solution to obtain a Ni-Co/γ-Al2O3 catalyst with a low metallic loads for producting hydrogen by reforming glycerol was studied. Catalysts with the same urea/metal molar ratio but synthesized by controlled or uncontrolled urea matrix combustion were compared. It has been observed that adopting a urea/metal molar ratio between 2 and 6 and a heating rate of 10 °C∙min−1 results in a catalyst with an active surface and high Ni-Co interaction. This leads to significant improvements in H2 yield (from 34 to 50%), glycerol conversion (from 35 to 50%), and H2 selectivity (from 96 to 99%), while maintaining stability during 420 min of reaction. The repeatability of controlled synthesis has shown differences in results of less than 2%. Controlled synthesis is an attractive approach for scaling up the process for treating glycerinous waters, effluents in biodiesel plants.

Novel self‐doped Pd/Cu bimetals in CMC/PANI composites: Efficient heterogeneous catalyst for cooperative Sonogashira and Sonogashira‐cyclization tandem reactions

A new Pd/Cu bimetal catalyst supported on carboxymethylcellulose/polyaniline (CMC/PANI) composites (Pd/Cu@CMC/PANI) was fabricated to investigate the cooperative effect between Pd/Cu bimetals in Sonogashira reactions. This approach involves the self‐organization of aniline on CMC via H‐bond, enabling in situ oxidative polymerization using Pd(II) and Cu(II) ions as co‐oxidants. Subsequently, Pd and Cu are self‐deposited on the resulting CMC/PANI composites through the interaction of coordination and metathesis. The morphological and compositional analysis of the prepared catalyst was performed using various analytical tools such as ICP‐AES, FT‐IR, XPS, SEM, TEM, EDS, elemental mapping, and TGA. The Pd/Cu@CMC/PANI composite as a cooperative catalyst for the Sonogashira couplings exhibited high catalytic activity with relatively low Pd loading over its monometallic Pd counterpart, demonstrating the cooperative effect between Pd and Cu. Then, this bimetallic catalyst was successfully adapted for Sonogashira‐cyclization tandem reaction for the synthesis of benzofuran with excellent yields. Significantly, the Pd/Cu@CMC/PANI catalyst exhibited thermal stability under the reaction conditions and could be easily retrieved and reused repeatedly for five runs in the model reaction without significant discernible performance degradation.

Formulation and Characterization of Clozapine Nanosuspension as a Sublingual Film

Background: Clozapine (CLZ) is a potent antipsychotic drug that suppresses the symptoms of schizophrenia and mania. Clozapine falls into Class II (BCS); its poor bioavailability is attributed to low water solubility and an extensive first-pass effect. Objective: To prepare CLZ as a nanosuspension (NS) to improve its low water solubility and load it into a sublingual film to enhance oral bioavailability. Methods: CLZ nanosuspensions are prepared by the “solvent anti-solvent precipitation” method using Soluplus as a stabilizing agent. We evaluated the polydispersity index (PDI) and the particle size of the CLZ nanosuspension formulations. The optimized formula of CLZ nanosuspension is loaded directly onto a sublingual thin film, eliminating the need for freeze-drying for solidification by the solvent casting approach. The sublingual films were characterized by thickness, surface pH, folding endurance, disintegration time, and in vitro dissolution rate. Results: We selected the formula F1 sublingual film as the best, as it demonstrated a uniform thickness of 0.087mm, good flexibility, and a surface pH of 6.7. It disintegrated quickly in 13 seconds and had a faster in vitro dissolution rate (3 min) compared to the CLZ ordinary films. Conclusions: The results confirmed the success of CLZ NS as a sublingual thin film for dissolution rate enhancement, which may improve oral bioavailability.

The Effect of Icon Color Combinations in Information Interfaces on Task Performance under Varying Levels of Cognitive Load

In human–computer interaction interfaces, icons serve as highly symbolic elements that convey information and significantly influence the performance of visual search and other tasks. Thus, the selection of appropriate colors plays a crucial role in the design of human–computer interfaces. This study aimed to investigate the effects of icon color combinations on human visual search task performance across various cognitive load conditions. The experiment was divided into two parts, involving a cognitive load test experiment and an icon search task, wherein the former required participants to select the target icon from 16 de-colored icons, and the latter involved selecting the target icon from 16 color combinations of 8 colors (background colors: black, red, blue, and purple; foreground colors: white, yellow, green, and turquoise). A total of 20 participants (11 females and 9 males, all aged between 18 and 24 years) were recruited for this experiment to perform both tasks sequentially. Through a comprehensive consideration of factors such as the NASA-TLX scale, retrieval time, etc., the experimental results revealed that cognitive load increased with time pressure, resulting in varying optimal color combinations for different cognitive load levels. Additionally, background colors did not affect task response time under different cognitive loads, whereas white foreground color was superior to turquoise foreground color in a medium cognitive load environment. Meanwhile, our results recommend prioritizing white-on-black as the preferred color combination, given that it demonstrated excellent cognitive performance in all three cognitive load environments. Conversely, white-on-blue is not recommended as a color combination for the design of high cognitive load environments. Concerning medium cognitive load environments, yellow-on-red or white-on-purple color combinations were preferred. Finally, in low cognitive load environments, white-on-purple is recommended as the primary color combination. Overall, this study provides a theoretical reference for the future design of interactive interface icons across various contexts.

Investigating the parametric dependence of the impact of two-way coupling on inertial particle settling in turbulence

Tom et al. (J. Fluid Mech., vol. 947, 2022, p. A7) investigated the impact of two-way coupling (2WC) on particle settling velocities in turbulence. For the limited parameter choices explored, it was found that (i) 2WC substantially enhances particle settling compared with the one-way coupled case, even at low mass loading $\varPhi _m$ and (ii) preferential sweeping remains the mechanism responsible for the particles settling faster than the Stokes settling velocity in 2WC flows. However, significant alterations to the flow structure that can occur at higher mass loadings mean that the conclusions from Tom et al. (J. Fluid Mech., vol. 947, 2022, p. A7) may not generalise. Indeed, even under very low mass loadings, the influence of 2WC on particle settling might persist, challenging the conventional assumption. We therefore explore a much broader portion of the parameter space, with simulations covering cases where the impact of 2WC on the global fluid statistics ranges from negligible to strong. We find that, even for $\varPhi _m=7.5\times 10^{-3}$ , 2WC can noticeably increase the settling for some choices of the Stokes and Froude numbers. When $\varPhi _m$ is large enough for the global fluid statistics to be strongly affected, we show that preferential sweeping continues to be the mechanism that enhances particle settling rates. Finally, we compare our results with previous numerical and experimental studies. While in some cases there is reasonable agreement, discrepancies exist even between different numerical studies and between different experiments. Future studies must seek to understand this before the discrepancies between numerical and experimental results can be adequately addressed.

Using attentional guidance methods in virtual reality laboratories reduces students’ cognitive load and improves their academic performance

Learning in virtual reality laboratories (VR labs) has become an important method in experimental teaching but can increase individuals’ cognitive load compared with traditional laboratories. This study analysed the effect of introducing an attentional guidance mechanism into a VR lab on students’ cognitive load and academic performance. We designed and developed two VR labs, one with and one without this attentional guidance stimulus (a 3D yellow arrow). A quasi-experimental design was adopted, and the data obtained were analysed using one-way ANOVA and linear regression. The experiment was conducted with 80 students majoring in digital media art at two universities. The results indicated that the students in the VR lab with the attentional guidance mechanism included exhibited lower cognitive load and higher academic performance than the control group. The regression analyses revealed that cognitive load negatively predicted learning outcomes; that is, academic performance improved as cognitive load decreased. In conclusion, as VR labs are increasingly used in education, supplementing them with attentional guidance stimuli can improve students’ academic performance by reducing their cognitive load.

Preparation and Analysis of New Hybrid PAEK Nano-Composites Containing MWCNT, Inorganic and Organic Nano-Particles

In modern era light weight material with complex shape and high material properties is required for advanced applications at room temperature. In this concern, the experimental study analysis to observe the effect of different nanofiller material like GO, MWCNT, NH2 and COOH modified MWCNT as organic nanofiller and WS2 and MoS2 as inorganic nanofiller reinforced in pure PAEK. This experimental study focuses on incorporation of organic and inorganic nanofillers separately and combine as hybrid nanofiller nanocomposite. On preparation of PAEK nano-composite and hybrid nanocomposite the comparative study of mechanical properties like tensile, flexural and impact is carried out. The nano-composites were prepared by melt compounding method. Scanning Electron Microscopy confirm the homogenous dispersion and alignment of nanofilers. The hybrid nano-composites show highest tensile strength as compared to the organic and in-organic nanofiller nanocomposite. As the percentage of MWCNT increases from 0.2 to 1 wt% , the properties of nano-composites decreases due agglomeration tendency of MWCNT that results in low load transfer capacity of nanocomposite, therefore agglomeration tendency of MWCNT required to be controlled for preparation of nano-composite and this is achieved by reinforcing Hybrid nanofillers to pure PAEK matrix. However, organic filler shows 75 MPa to 83 MPa tensile properties and which is lower compared to in-organic and hybrid filler due agglomeration tendency of organic nanofiller confirmed by SEM analysis.