Low Energy Input Research Articles

Redescription of Euscorpius studentium Based on Adult Specimens; Updated Classification of Cavernicolous Euscorpiidae; and Review of Cavernicolous Scorpions in the Balkans

Cavernicolous scorpions are difficult to collect and study due to their often inaccessible habitats. Some have evolved unique morphological adaptations, known as troglomorphies, including reduced sclerotization and pigmentation, reduction and/or loss of eyes, attenuation and elongation of the appendages, which assist them to thrive in dark, humid and low-energy input environments. Cavernicolous scorpions are classified into accidentals, trogloxenes, troglophiles, and troglobites. The Balkans, and particularly the Dinaric Karst region, host a diverse cave-adapted fauna, including scorpions. Despite an 1895 report of a blind scorpion from Bosnia and Herzegovina, the first truly troglobitic European scorpion, Euscorpius studentium Karaman, 2020, was only described a few years ago, based on two immature specimens. In the present contribution, this unique species is redescribed based on the first adult specimens; the ecological classification of all currently known cavernicolous Euscorpiidae Laurie, 1896, is updated; a key to the identification of cavernicolous scorpions occurring in the Dinaric Karst is provided; and the historical and geographical factors affecting the distribution and conservation of cavernicolous scorpions in the Balkans is reviewed.

Statistical design approach enables optimised mechanical lysis for enhanced long-read soil metagenomics

Metagenomic analysis has enabled insights into soil community structure and dynamics. Long-read sequencing for metagenomics can enhance microbial ecology by improving taxonomic classification, genome assembly, and functional annotation. However, protocols for purifying high-molecular weight DNA from soil are not yet optimised. We used a statistical design of experiments approach to enhance mechanical lysis of soil samples, increasing the length of purified DNA fragments. Low energy input into mechanical lysis improved DNA integrity, resulting in longer sequenced reads. Our optimized settings of 4 m s−1 for 10 s increased fragment length by 70% compared to the manufacturer’s recommendations. Longer reads from low intensity lysis produced longer contiguous sequences after assembly, potentially improving a range of down-stream analyses. Importantly, there was minimal bias exhibited in the microbial community composition due to lysis efficiency variations. We therefore propose a framework for improving the fragment lengths of DNA purified from diverse soil types, improving soil science research with long-read sequencing.

Snap-through mechanism of a thin beam confined in a curved constraint

In this work, a novel snap-through mechanism of a thin beam confined in a curved constraint and driven by local loading curvature is investigated. The movable boundaries of the buckled thin beam enable it to output snap-through rotation at a lower energy input than the double-clamped beam structure. A theory is proposed to reveal the snap-through mechanism of the proposed structure based on the principle of minimum potential energy and saddle-node bifurcation, which uncovers the influences of loading positions, length ratio and constraint radius on the critical loading. Both theoretical and experimental results show that the large loading position and small constraint radius correspond to a large critical loading, while the length ratio hardly affects the critical loading. In addition, an experimental device is designed to output linear displacement based on the proposed snap-through mechanism. Due to lower energy input and snap-through response characteristics, the proposed bistable mechanism exhibits great prospects in energy harvesters, actuators, motors, pumps and robots.

Tailoring nanotwinned Cu interlayers for localizing anisotropic plastic deformation during low energy input ultrasonic welding of robust Cu-Cu joints

Ultrasonic welding, known for its severe plastic deformation, faces the challenge of balancing sufficient deformation at the welding interface with minimizing damage to the substrate. This study utilizes the anisotropic deformation mechanisms and mechanical properties of nanotwinned Cu (nt-Cu). Specifically, Cu coatings featuring nanotwin layers aligned parallel to the ultrasonic vibration direction were employed as interlayers in ultrasonic welding of Cu-Cu joints. The effects of the nt-Cu interlayer on the welding quality and the deformation mechanisms under the various welding pressures are investigated. Experimental and molecular dynamics simulations demonstrate that at low welding pressures, the nt-Cu interlayer undergoes deformation and detwinning primarily through twin boundary migration. This mechanism effectively mitigates work hardening during the welding process, localizes deformation at the welding interface, and significantly enhances the strengths of the Cu-Cu joints. The maximum enhancement proportion occurs at a welding pressure of 8 psi, up to 26.75% compared to conventional coarse-grained copper. As the welding pressure increases, the strengthening effect gradually weakens. The deformation mechanism of nt-Cu transitions to dislocation transverse and threading. The interaction between dislocations and twin boundaries forms incoherent twin boundaries and 9R phases, resulting in work hardening of the interfacial regions and reduction of the strengthening effect.

Enhancing carbamazepine degradation in electrochemical systems: The interplay of sulfur vacancies and absorbed peroxydisulfate in molybdenite electrodes

Achieving high reaction efficiency with low energy input is crucial for electrochemical water remediation processes, yet remains a significant challenge. This study reported a practicable method, utilizing natural molybdenite as particle electrodes in an electro-activated peroxydisulfate (PDS) process (3D system) to develop a cost-efficient electrocatalytic oxidation system. Molybdenite’s unique ability to generate sulfur vacancies during electrocatalysis significantly enhances system efficiency. The 3D system enhanced the rate constant of carbamazepine (CBZ) abatement sixfold compared to the system without molybdenite. Additionally, a substantial decrease in electrical energy per order (EE/O) from 7.13 kWh/m3 to 0.326 kWh/m3 indicates a near 22-fold increase in energy efficiency. Characterizations involving electron microscopies, electrochemical experiments and density functional theory calculations confirm that hydroxyl radicals (•OH) and adsorbed PDS(PDS*) are the main active species. Molybdenite’s surface with plenty of edge-S, released S vacancy during electrocatalytic oxidation, providing adsorption and activation sites for PDS and H2O. This led to more active sites and facilitating the generation of PDS*, lowering the energy barrier for •OH formation and boosting the oxidation performance of the 3D system. The results underscore the constructed 3D system is a robust and energy-efficient method for practical water treatment.

Recent advances in anion exchange membrane technology for water electrolysis: a review of progress and challenges

AbstractClean energy and environmental pollution are two key concerns of modern society and are pivotal necessities for the economic, social, and sustainable development of the world. Today around 80% of energy is generated using nonrenewable resources and fossil fuels (oil, gas, coal) which ultimately results in hazardous global emissions. As a clean substitute for fossil fuels, hydrogen has emerged as a promising and renewable energy resource. Utilization of this energy resource requires the development of active, stable, low‐cost environmentally friendly techniques. Water splitting electrolysis is a method for producing clean and efficient hydrogen using an environmentally benign technique that is currently at its most mature stage. Electrolysis is attracting ever‐increasing attention, as it is a promising electrochemical device for hydrogen production from water due to the high conversion efficiency and relatively low energy input required when compared to thermochemical and photocatalytic methods. This paper will outline the need, performance, and insight of anion exchange membrane (AEM) electrolyzer. Recent developments in the design and preparation of AEM. New strategies for activity, stability, and efficiency improvement of AEM. Membrane types, and factors affecting AEM performance in an electrolyzer. This review also discusses the effects, operating characteristics, and energy consumption of electrocatalysts in the AEM electrolyzer. Hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) pathways and mechanisms in acidic and alkaline media. This study seeks to provide a detailed overview of recent accomplishments in the field of the hydrogen economy, particularly electrolysis, to inspire further research and development to address the technology's obstacles.

Revealing the mechanism of bifunctional PtLa electrocatalyst for highly efficient methanol oxidation, hydrogen evolution, and coupling reaction

The development of clean energy solutions, such as fuel cells and hydrogen energy, is crucial for addressing the global energy shortage. Platinum (Pt)-based catalysts are widely used in fuel cells and hydrogen energy generation (for example, via water electrolysis). However, reducing the amount of Pt used while maintaining the catalytic performance of such catalysts is essential. Herein, PtLa catalysts (PtxLay/C) doped with rare earth element lanthanum (La) with different Pt/La atomic ratios were synthesized using a simple chemical reduction method, resulting in Pt65La35/C, Pt78La22/C, Pt97La3/C, and Pt100/C. These PtxLay/C catalysts exhibited excellent electrocatalytic activity and stability in methanol oxidation reaction (MOR), hydrogen evolution reaction (HER), and their coupling reaction as MOR||HER under alkaline conditions. The mechanism by which La doping enhances the electrocatalytic properties and stability of Pt-based catalysts was investigated using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), aberration-corrected scanning transmission electron microscopy (AC-STEM), in-situ Fourier transform infrared (FTIR) and operando Raman spectroscopy. For HER, La doping facilitated the adsorption and activation of H2O at Pt sites, improving water dissociation and *OH desorption and reducing Pt poisoning by *OH. This enhances both the catalytic performance and stability of PtxLay/C for HER. Pt78La22/C exhibited a considerably lower overpotential of only 111 mV at 100 mA cm−2 compared to commercial 20 wt% Pt/C (Pt/C-Johnson Matthey (JM)), which requires 153 mV. For MOR, La promotes CO bond cleavage and reduces CO adsorption at the Pt sites, thereby enhancing both the performance and stability of the catalysts. The mass activity (MA) of Pt78La22/C for MOR is 4.44 A mg−1Pt, which is 12.33 times higher than that of Pt/C-JM (0.36 A/mgPt), and surpasses those of Pt65La35/C, Pt97La3/C, and Pt100/C (2.93, 0.24, and 2.91 A mg−1Pt, respectively). Additionally, Pt78La22/C exhibited outstanding catalytic performance for MOR||HER, with a current density of 20 mA cm−2 at 1.030 V, demonstrating good stability with negligible voltage changes after a 15 h chronoamperometry (CA) testing. This study provides a new strategy for synthesizing Pt-based catalysts with enhanced efficiency and low-energy input for HER||MOR.

Regulating Local Electron Distribution of Cu Electrocatalyst via Boron Doping for Boosting Rapid Absorption and Conversion of Nitrate to Ammonia

AbstractThe electrochemical reduction of nitrate to ammonia (NO3RR) is an effective route to ammonia synthesis with the characteristics of low energy input. However, the complex multi‐electron/proton transfer pathways associated with this reaction may trigger the accumulation of competitive by‐products. Herein, boron (B)‐doped Cu electrode (denoted as B–Cu2O/Cu/CP) as “all‐in‐one” catalyst is prepared by one‐step electrodeposition strategy. Caused by the B doping, the charge redistribution and local coordination environment of Cu2O/Cu species are modulated, resulting in the exposure of active sites on the Cu2O/Cu/CP catalyst. In‐situ Fourier transform infrared spectroscopy and theoretical investigations demonstrate that both Cu2O and Cu sites modulated by B can effectively enhance the adsorption of NO3− and facilitate the conversion of intermediate by‐products, thus promoting the direct reduction of NO3− to NH3. Consequently, a remarkable Faradaic efficiency of 92.74% can be obtained on B–Cu2O/Cu/CP catalyst with minimal accumulation of by‐products. It is expected that this work, based on the heterogeneous B doping, will open a maneuverable and versatile way for the design of effective catalysts.

Incrimination and impact on recovery times and effects of BN nanostructures on antineoplastic drug-electronic density study.

By delivering the drug to the intended cell location, the use of nanomaterials in the drug delivery system may influence how the patient receives the medication and may assist in mitigating severe side effects. Density functional theory was used to assess the use of boron carbon nitride nanocages (BNCNCs), boron nitride (BNNSs), and boron carbon nitride nanosheets (BNCNSs) as melphalan (Mln) drug carriers in both the gaseous and fluid phases. We systematically examined the dipole moment, density of states, frontier molecular orbital, and optimal adsorption energy to understand the targeted drug delivery potential of these nanostructures. Adsorption energy analysis revealed that in both gas and water media, Mln drug adsorption takes place spontaneously on all the conjugated structures. The occurrence of adsorption energy as physisorbed energy suggests that the process is reversible, and desorption can take place with a much lower energy input. This physical contact is appropriate for the unquestionable unloading of Mln medications to the intended location. The reactivity is higher in BNNSs and BNCNSs, while the stability is higher in BNCNCs. The recovery time shows a shorter time for BNNSs and BNCNSs, while BNCNC shows a potential desorption time in higher temperature. These conclusions are corroborated by the results of the quantum theory of atoms in molecules (QTAIM). After the interaction analysis, it was observed that the BNCNCs can act as potential carriers for the melphalan. From dipole moment analysis, all three nanostructures show a high hydrophilic nature but quite higher in BNCNCs after doping in both media. Overall, all the structures show the potential carrier for melphalan drug. The quantum mechanical approach, or DFT, has been used to study the fundamental structural, electrical, thermodynamic, and other aspects of proposed structures to develop an acceptable Mln drug detector. The adsorbate and all adsorbents were optimized via the hybrid B3LYP functional and the 6-311G + + (2d, p) basis set approach prior to the adsorption process. The Gaussian 09 package was used at 298K as the constant temperature and 1 atm as the constant pressure. The structures are examined using the same functional models for solvation analysis-6-311 G + + (2d, p) and B3LYP-as well as the polarized continuum model (PCM) model as the foundation set. Density of states was studied using GaussSum 3.0 software. The interaction studies QTAIM and RDG were studied using VMD and Multiwfn software.

Enhanced Hydrophilicity of DAAQ-TFP COFs via Sulfonate Modification for Air Water Harvesting in Arid Environment.

The poor ability of covalent organic frameworks (COFs) based adsorbents at low relative humidity (RH) conditions limits their applications for air-water harvesting in arid environments. In the present work, the sulfonated COFs (DAAQ-TFP-SO3H@LiCl) composites are prepared through the functionalization of sulfonic acid and LiCl composite to improve its hydrophilicity. TheDAAQ-TFP-SO3H@LiCl composites exhibit a good adsorption performance, outperforming many other COF adsorbents developed so far. It can absorb 0.22±0.005g g-1 and 1.01±0.027g g-1 of water at room temperature under 20% RH and 90% RH, respectively while demonstrating good cyclic stability. Compared with the isotherm of the DAAQ-TFP, the introduction of the sulfonic acid group shifts the inflection point of the water isotherm toward low humidity, indicating that the sulfonic acid group effectively expends the working humidity range of the adsorbent and enables the effective water adsorption in an arid environment. Furthermore, the DAAQ-TFP-SO3H@LiCl composites display rapid kinetics during both the adsorption and desorption processes, reaching saturation within 60min in the equilibrium adsorption test and completing desorption within 12min at 50°C. This innovative approach provides a new method for designing adsorbent materials with low energy input requirements and high daily water consumption capabilities.

Energy Consumption in Wheat-Rice Cropping System in Punjab

Energy consumption for crop production depends on the availability of energy sources and the capacity of the farmers. This study analyzed energy sources used by farmers for wheat and rice production and identified agricultural operations where energy consumption can be reduced so that operational costs in wheat-rice production system can be lowered. Data on energy use in wheat and rice cropping system was collected by interviewing the farmers using specially designed questionnaire. Relevant information pertaining to human labour use, sources of irrigation, number of irrigations to each crop, quantity of farm inputs, utilization of mechanical power sources and grain yield etc. were collected. The average output energy of grain, input energy, energy ratio and specific energy for wheat crop in the state of Punjab were 68347 MJ ha-1, 15644 MJ ha-1, 8.4 and 3.08 MJ kg-1, respectively. The average output energy of grain, input energy, energy ratio and specific energy for rice were 115888 MJ ha-1, 16438 MJ ha-1, 14.8 and 2.09 MJ kg-1, respectively. For wheat-rice cropping system, the average output energy of grain, input energy, energy ratio and specific energy were 184234.4 MJ ha-1, 32081.4 MJ ha-1, 11.7 and 2.48 MJ kg-1, respectively. Energy ratio (output energy to input energy ratio) of rice is higher than the wheat, indicating rice efficiently utilized energy resources to convert into output of the harvested crop. Similarly, lower specific energy (input energy to yield ratio) of rice as compared to wheat also indicates lower energy consumption to produce per unit of rice. This analysis clearly indicates that rice production is more energy efficient than wheat production in rice-wheat production system. Further, the energy ratio, specific energy and energy productivity of wheat-rice cropping system were estimated as 11.6 to 11.9, 2.44 to 2.51 MJ kg-1 and 0.40 to 0.41kg MJ-1, respectively. This study will be helpful to identify the agricultural operations and implementing suitable interventions for improving energy use efficiency.

Effect of laser beam incident angle on welding of Ti6Al4V with fiber lasers

Laser beam welding (LBW) is widely used for welding Ti6Al4V alloys in aerospace applications. LBW has localized high-energy fluence with low-energy input compared to other fusion welding processes, resulting in narrower heat-affected zones. On the other hand, most metals are highly reflective when the laser beam impinges perpendicular to the surface, making the process inefficient. Hence, this work proposes to employ shallow angle incidence to reduce the reflectivity during the welding of Ti6Al4V material. To explore the potential of this idea, the current study focuses on studying the effect of laser incident angle (15°-90°), power (300 W-1500 W), and feed rate (10 mm/s-25 mm/s) on autogenous weld bead geometry. For this purpose, bead-on plate (BOP) LBW is conducted on mill-annealed Ti6Al4V material of dimensions 25 mm × 25 mm × 3 mm by employing a fiber laser source with a maximum power of 3 kW and a wavelength of 1080 nm. It is observed from the results that at a normal incident angle and low laser power (< 600 W), the penetration depth is too low to generate a weld bead. Analyzing the cross-section of the weld bead, obtained from SEM, perpendicular to the weld direction reveals that the increase in laser incident angle up to an optimal angle resulted in increased bead dimensions (width and height), and beyond that, the dimensions decreased. However, the optimal incident angle changed when the laser power was changed. The major finding of this study is that at 600 W and a normal incident angle, the laser could not penetrate and generate a weld bead due to low absorptivity, while at an incident angle of 300, 450, and 600, weld beads are generated because of increased absorptivity. Similarly, the increase in weld dimensions with the increase in laser power is observed. At higher laser power, underfill and oxide formation are observed. The feed rate is less predominant than the incident angle and the power.

Productivity and energetics of basmati rice-wheat cropping systems under different farming conditions in northwest India

ABSTRACT Basmati rice-wheat cropping systems have the potential to upscale organic agriculture in India because of the lower nutritional requirements and the geographical indication status of basmati rice. The energetics of organic production of basmati rice-wheat needs to be assessed to delineate its efficiency as compared with conventional production. An experiment with different management systems was conducted at Punjab Agricultural University Ludhiana, Punjab, India during 2018–19 and 2019–20 seasons to assess the productivity, economics and energetics of this cropping system in different organic and conventional management systems. The experiment was conducted in a randomised complete block design, replicated thrice, with nine treatments, including organic, chemical, natural farming, integrated nutrient management (INM) and integrated crop management (ICM). The highest basmati rice grain yield (3390 kg ha−1) was obtained with chemical management, which was statistically at par with ICM, INM and FYM treatments, but was significantly higher than that in the organic and natural farming treatments. The highest wheat grain yield (4450 kg ha−1) was recorded with ICM, which was statistically at par with INM and chemical management. Higher productivity in basmati rice was achieved with chemical and integrated management, but the highest net returns and benefit-to-cost ratio (2.89) were recorded under organic farming due to the price premium obtained for the produce. In wheat, despite higher cultivation costs, organic farming had lower returns, while chemical management had the highest net returns and benefit-to-cost ratio (2.9). Natural farming treatments were more energy efficient than the other systems because of low energy inputs.

A discrete CMUT self-biasing circuit towards implanted devices application

Wireless power transfer is an essential feature of biomedical engineering. It reduces the need for energy storage devices in medical implants. To recharge a body implanted battery, a convenient way is to transmit ultrasounds through the skin to a connected ultrasonic transducer. Lead-less, System-on-Chip compatible (SoC) and wideband, Capacitive Micromachined Ultrasonic Transducers (CMUT) are competitive with piezoelectric based technologies. However, their need for a high bias voltage is an obstacle to their use in implanted medical devices (IMDs). The voltage source required must meet precise specifications, such as reliability and volume, which the research community intends to respect. To meet this challenge, this work proposes an electronic circuit that allows a CMUT device to self-bias from a very low initial energy input. After presenting the electronic architecture and its main features, simulation and experimental results validate the solution’s working principle and operating points. With an electronic circuit made up of discrete components, a bias voltage of 60 V is built up from an implanted battery voltage of 2.2 V and an incident pressure of 120 kPa in water.

Study on no IMC Solid state bonding method for high-density 2.5D/3D integration

Abstract Chiplet integration is a new development direction for the continuation and even goes beyond Moore’s Law, and in order to achieve the high density, high reliability, high-speed Chiplet device, a new method of 2.5D/3D integration approach is needed to fulfill the needs to Chiplet heterogeneous devices. In this work, two dies were successfully bonded via low energy input with no IMC solid state bonding under 220°C and 5 MPa, which is much gentler than the other solid state bonding approaches. Each die had a matrix of 22500 Cu pillars with a diameter of 20 μm. This method was promising for the near future high-density 2.5D/3D integration.

Effective waste management through Co-pyrolysis of EFB and tire waste: Mechanistic and synergism analysis

Driven by the need for solutions to address the global issue of waste accumulation from human activities and industries, this study investigates the thermal behaviors of empty fruit bunch (EFB), tyre waste (TW), and their blends during co-pyrolysis, exploring a potential method to convert waste into useable products. The kinetics mechanism and thermodynamics properties of EFB and TW co-pyrolysis were analysed through thermogravimetric analysis (TGA). The rate of mass loss for the blend of EFB:TW at a 1:3 mass ratio shows an increase of around 20% due to synergism. However, the blend's average activation energy is higher (298.64 kJ/mol) when compared with single feedstock pyrolysis (EFB = 257.29 kJ/mol and TW = 252.92 kJ/mol). The combination of EFB:TW at a 3:1 ratio does not result in synergistic effects on mass loss. However, a lower activation energy is reported, indicating the decomposition process can be initiated at a lower energy requirement. The reaction model that best describes the pyrolysis of EFB, TW and their blends can be categorised into the diffusion and power model categories. An equal mixture of EFB and TW was the preferred combination for co-management because of the synergistic effect, which significantly impacts the co-pyrolysis process. The mass loss rate experiences an inhibitive effect at an earlier stage (320 °C), followed by a promotional impact at the later stage (380 °C). The activation energy needed for a balanced mixture is the least compared to all tested feedstocks, even lower than the pyrolysis of a single feedstock. The study revealed the potential for increasing decomposition rates using lower energy input through the co-pyrolysis of both feedstocks. These findings evidenced that co-pyrolysis is a promising waste management and valorisation pathway to deal with overwhelming waste accumulation. Future works can be conducted at a larger scale to affirm the feasibility of EFB and TW co-management.

Poly(3,4-ethylenedioxythiophene) (PEDOT) As an Electrocatalyst for Water Splitting: From Fundamental Insights to Practical Applications in Sustainable Hydrogen Production

Poly(3,4-ethylenedioxythiophene) (PEDOT) has recently emerged as a highly promising and versatile electrocatalyst for water splitting, a pivotal process in the realm of renewable energy conversion. This review comprehensively explores the multifaceted aspects of PEDOT's electrocatalytic prowess, covering its intrinsic properties, synthetic methodologies, catalytic mechanisms, and practical applications in the context of water electrolysis. PEDOT, [C2H4O2C4H2S]n a conductive polymer, exhibits unique features that render it particularly suitable for electrocatalysis. With its excellent electrical conductivity, notable stability, and facile synthesis, PEDOT stands out among its counterparts. These attributes make PEDOT an attractive candidate for addressing the challenges associated with the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER), the two half-reactions constituting water splitting.One of the key advantages of PEDOT lies in its high surface area, which allows for increased active sites for catalysis. The tunable redox states of PEDOT further contribute to its electrocatalytic versatility, enabling tailored catalytic performance through controlled doping and modifications. The efficient charge transport properties of PEDOT are crucial for facilitating electron transfer during the electrocatalytic processes, ensuring high catalytic activity. This review delves into the simple fabrication of PEDOT-based electrocatalysts. Researchers have explored various strategies, including morphological control, doping with heteroatoms, and integration into composite materials, to enhance the catalytic performance of PEDOT. The rational design of PEDOT structures has demonstrated the potential to surpass the limitations of traditional electrocatalysts and unlock new avenues for efficient water splitting.In elucidating the mechanistic aspects of PEDOT's catalytic activity, the review investigates the intricate interplay of surface interactions, redox reactions, and mass transport phenomena. Understanding the fundamental principles governing PEDOT's electrocatalytic behavior is essential for optimizing its performance and guiding further developments in this burgeoning field. Simple electrodeposition method is carried out to polymerize EDOT. Cyclic voltammetry method was used for synthesizing PEDOT on nickel foam. Then the sample was heated at differnet temperatures.Hydrogen Evolution Reaction (HER) Overpotential:An overpotential of 170 mV at 10 mA/cm² is observed for the HER which indicates that PEDOT as an effective in catalyzing the reduction of protons to form hydrogen gas. A lower overpotential implies that PEDOT facilitates the electrochemical reaction at a lower energy input, showcasing its efficiency as an electrocatalyst for hydrogen production.Oxygen Evolution Reaction (OER) Overpotential:The PEDOT exhibits an overpotential of 300 mV at 10 mA/cm² for the OER which suggests its enhanced performance in catalyzing the oxidation of water to produce oxygen gas. While this overpotential is higher than that for the HER, it is still within a range that indicates good catalytic activity for the challenging OER.Surpassing Many Catalyst Behaviors:PEDOT's performance, as indicated by its low overpotentials, exceeds that of many other catalysts commonly used for water splitting reactions. This could include traditional metal-based catalysts or other conductive polymers, highlighting PEDOT's potential as a superior electrocatalyst. More electrochemical studies have been taken to prove practical application for PEDOT while the reported overpotentials are promising, and additional research and experimentation are being conducted to validate and understand PEDOT's practical application in real-world scenarios. This involve studying its stability over time, scalability, and compatibility with alkaline electrolyte systems and operational conditions. Figure 1

Molecular Insights into Redox-Active Polymer Interfaces: Solvation and Ion Valency Effects on Metal Oxyanion Selectivity

Chemical separations are responsible for 10-15% of the world’s energy consumption. Minimizing energy and materials inputs in selective separations is imperative for a sustainable future. Ion-electrosorption mediated by redox-active metallopolymer interfaces has the unique advantage of selectively capturing and releasing metal oxyanions in a switchable manner by adjusting the applied potential, without any regenerants. Electrosorption addresses the need for selective separation approaches with low chemical and energy inputs. Previous studies on ferrocene metallopolymers have demonstrated the role of polymer structure and applied potential on selectivity—however, the ubiquitous role of solvation in redox-polymers has remained unexplored. Here, we investigate how solvation and ion valency influence selectivity of ReO4 - vs MoO4 2- for two redox-metallopolymers, poly(vinyl ferrocene) (PVFc) and poly(3-ferrocenylpropyl methacrylamide) (PFPMAm). Both polymers display time-dependent Re/Mo selectivity, with PVFc having higher selectivity compared to PFPMAm. Operando neutron reflectometry, ellipsometry, and electrochemical quartz-crystal microbalance show that both PVFc and PFPMAm swell in the presence of ReO4 - (with PFPMAm having higher solvation), but do not swell in contact with MoO4 2-. We find that the less solvated anion (ReO4 -) is preferably adsorbed by the more hydrophobic redox-polymer (PVFc). We expect that a deeper understanding of solvation and valency effects on selectivity mechanisms in redox interfaces will expedite the development of targeted selective ion-electrosorption systems. Figure 1

Micromorphic brachiopods from the early Permian (Kungurian) of Hidalgo, Mexico. Stratigraphic, paleoenvironmental and paleobiogeographic significance

This work describes for the first time a fauna of micromorphic brachiopods from Mexico. The biota comprises Permian species of the order Productida: Dyoros (Dyoros) extensiformis, Quadrochonetes girtyi, Rugaria hessensis, Fimbrinia ovata, as well as a productid indeterminate. The samples were located in the Calnali 2 section, belonging to the Tuzancoa Formation. The Kungurian (upper Cisuralian) relative age of the section was established by employing brachiopods, which were associated with bivalves, crinoids, trilobites, and bryozoans. The rocks with invertebrates are interbedded with strata bear plant remains. Sedimentological traits and preservation of brachiopods and associated fauna suggest that the marine community was deposited in a subtidal shallow and restricted environment with very low energy and continuous terrigenous input. On the other hand, the productid indeterminate is the largest brachiopod and displays the worst preservation, with evident traits suggesting that it was transported from a faraway region of the coast. Given that all taxa were previously identified in different units of Texas, considered a region where the Grandian Province was extended, it can be proposed that brachiopods of the Tuzancoa Formation also belonged to the same province. Thus, apart from New Mexico and Texas (USA), Huehuetenango (Guatemala), Palmarito (Venezuela), and Coahuila and Chiapas (Mexico), also Hidalgo's early Permian fauna could be included in the same biotic province.

Construction of Nano-Janus emulsion by phase inversion composition

Nano-Janus emulsion possesses excellent solubilization capabilities of both aqueous and organic materials, various liquid–liquid interfaces, and precisely controllable morphology. Successful construction of nano Janus droplets at mild conditions of room temperature and low-energy input will expand the industrial application. Two immiscible liquids of silicone oil (SO) and oleic acid (OA) are used as internal phases, and water is added dropwise at mild temperature. The topology of the nano-sized complex droplets is characterized by cryo-TEM, SAXS, and FF-TEM. Micro structure of lamellar liquid crystal (Lα), which is the critical transition phase, is investigated to reveal the formation mechanism. Topology adjustment including size range, volume ratio, and interface curvature is investigated. Complex nano droplets with snowman shape are successfully constructed in batch-scale at mild temperature of 30 °C and water-dripping rate of 1.0 mL/h. Formation of a four-component Lα phase is the critical point to the successful construction of the nano-Janus emulsion, which also creates additional freedom for structural regulation. The size of the complex droplets is freely alternated in the range of 50–500 nm and the morphology of one lobe is controlled from “crescent” to “half-moon”, and “moon with a hole”.