Low-temperature Condensation Research Articles

Cryochemical Synthesis of Hybrid Nanoforms Based on Silver and Antibacterial Drug Dioxidine by the Low-Temperature Condensation of Vapor from the Gas Phase

Cryochemical Synthesis of Hybrid Nanoforms Based on Silver and Antibacterial Drug Dioxidine by the Low-Temperature Condensation of Vapor from the Gas Phase

Bio-methanol with negative CO2 emissions from residual forestry biomass gasification: Modelling and techno-economic assessment of different process configurations

The paper presents a techno-economic comparison among five alternative process configurations for bio-methanol production from the gasification of residual forestry biomass. Process design and simulations are performed in Aspen Plus for mass and energy balance calculation, followed by preliminary sizing and economic analysis. Process schemes include a gasification island (state-of-the-art low-pressure gasification compared against a high-pressure gasifier) with syngas conditioning and compression, heat recovery, syngas composition adjustment (by CO2 capture or addition of hydrogen produced by electrolysis), methanol synthesis and purification and a heat recovery cycle for power generation. CO2 capture is performed with conventional chemical absorption in the benchmark cases, while low-temperature partial condensation of CO2 is modeled in the advanced scenario. Methanol output is 14–15 kt/y in the CO2 capture cases and 36 kt/y in the H2 addition option.Configurations with a pressurized gasifier and phase-change-based CO2 separation are the most efficient ones, with a primary energy efficiency of 50 % and a Levelized Cost of Methanol (LCOM) of 700 €/tMeOH. In comparison, LCOM increases to 730 €/tMeOH in the case with conventional capture or between 792 €/tMeOH and 831 €/tMeOH (depending on the CCS technology) if the gasification pressure is conservatively reduced to 2.5 bar. In the H2 addition scenario, LCOM increases to 821 €/tMeOH due to the significant impact of the electricity consumption for H2 production, (only partly compensated by the increased methanol production). Scenarios with CO2 capture feature negative CO2 emissions, in the range −1.64 to −1.84 tCO2eq/tMeOH, as a result of the capture and storage of biogenic CO2 (BECCS approach).

Numerical study on efficiency and robustness of wave energy converter-power take-off system for compressed air energy storage

The unpredictable fluctuations of wave lead to an imbalance between energy supply and demand. This article proposes a wave-driven compressed air energy storage system, which uses wave mechanical energy instead of electrical energy as the direct driving force for the compressors. Compressed air energy storage solves the problem of stability of wave energy output by accumulating and storing wave energy and then releasing it in a centralized manner. Due to the significant change in load damping compared to the generator, the damping force of the power take-off with compressed air energy storage load is analyzed. And a robust strategy with adjustable buoy draft and load compressor number is proposed, and the highest capture width ratio of 26.71 % and wave energy to compressed air energy conversion efficiency of 13.00 % are achieved under regular wave conditions. Surface seawater is used for heat supplementation in the expansion phase, and a closed-loop system is designed to avoid the damage of low-temperature condensation, the round-trip efficiency of the system is 11.26 %. This research provides a potential power generation path for wave energy and surface seawater heat. And it may beneficial to provide stable and relatively cheap power supply for coastal and offshore users.

Aramid-Reinforced UV Curable Adhesive Resins for Use As an Interlayer in Laminated Glass.

Colorless, transparent, and mechanically robust aramid polymers are synthesized from two diamine monomers with strong electron-withdrawing groups, using low-temperature solution condensation with diacid chloride. The aramids dissolved very well in the liquid acrylamide monomers. When N,N-dimethylacrylamide (DMA) is used as a reactive diluent, films with the desired features are produced from the hybrid aramid-DMA resins via ultraviolet (UV)curing. The hybrid films are colorless and transparent in the visible region and showed an increase in the glass transition temperature, tensile strength, and elastic modulus in proportion to the aramid content. Laminated glass is manufactured using the hybrid resin as an interlayer, which exhibits very strong adhesion between the two sheets of glass, is not easily broken by an external impact, and do not scatter fragments. Moreover, the laminated glass do not distort images and functioned very effectively in UV blocking, soundproofing, and suppressing changes in the ambient temperature. Heat treatment further improves the light transmittance and impact resistance of the laminated glass. Laminated glass specimens with various fluorescence colors are also manufactured. Aramid-reinforced films prepared using N,N-diethylacrylamide as a reactive diluent underwent thermally induced phase separation in a wet state, providing smart glass with a privacy protection function.

Techno-economic comparison of organic fluid between single- and dual-flash for geothermal power generation enhancement

The geothermal energy has become a research focus due to its unique advantages as the renewable energy source. Organic Rankine cycle (ORC) is one of the important technologies for geothermal power generation, but ORC has a large irreversible loss and a low overall efficiency. The organic Rankine single-stage flash cycle (ORSFC) and organic Rankine dual-stage flash cycle (ORDFC) are proposed in this paper, and the corresponding mathematical models are established. The influence of operating parameters on techno-economic performance of three power generation systems is studied. Additionally, the comparison of the techno-economic performance of three power generation systems is conducted. The results show that the lower condensation temperature and pinch point temperature difference of heat exchangers improve the power generation performance. The evaporation temperature and flash temperature can be regarded as equivalent temperatures. Compared with the ORC system, the average increase in net output power of ORSFC and ORDFC systems is 22.87 % and 31.71 %, respectively, while the economic performance decreased by 0.98 % and 6.48 %, respectively. Therefore, it is recommended to use ORSFC as the incomplete evaporation power generation system. The R245fa is the optimal choice for ORC system, while the R601 and R601a are more suitable for ORSFC and ORDFC systems.

Heating and cooling challenges for electric vehicles: A comprehensive experimental study

An efficient mobile air conditioning (MAC) system using a safe and climate-friendly refrigerant is necessary for human comfort, increasing the vehicle’s energy performance, and reducing the fuel/electricity consumption. In the current work, we perform a drop-in experimental comparison for low GWP alternatives to R134a in reversible MAC systems. The study compares two lower global warming potential (GWP) refrigerants; R456A, a non-flammable refrigerant for R134a direct MAC replacement, and R1234yf, an ultra-low GWP and mildly flammable refrigerant that is the standard for new MAC systems. The system’s operational and energy performance is investigated, simulating a wide range of indoor and outdoor steady-state conditions. The measurements are recorded operating a fully monitored vapour compression test rig that uses secondary circuits to set the target conditions. In the heating mode (heat pump), the evaporation temperatures are set at −10 °C, −5 °C, and 0 °C, and condensation temperatures at 40 °C, 50 °C, and 60 °C. In cooling mode (air conditioning), the condensation temperatures are 37.5 °C, 45 °C, and 52.5 °C and are combined with evaporation temperatures of −7.5 °C, 0 °C, and 7.5 °C. In the heating mode, R456A presented a competitive COP to R134a with a reduction of less than 5 %, more remarkable at lower evaporation temperatures. In the cooling mode, R456A showed the lowest COP at a low condensation temperature. R456A and R1234yf COP are comparable at a higher condensation temperature, which suits the T3 climate conditions.

Spatiotemporal dynamics of stable isotopes of different water sources in western Himalayas: Insights into regional hydrological processes

The spatiotemporal variations in stable isotope ratios are primarily related to atmospheric moisture transport. However, the isotopic composition of stream water is significantly influenced by the diverse landscape of glaciated and snow-dominated basins. The present study investigates the spatiotemporal variation of the isotopic composition of stream water and potential water sources such as rain, snowmelt, glacier melt, lakes, and groundwater in the Upper Jhelum River Basin (UJRB). Our findings reveal that the significant seasonal variability of precipitation is mainly associated with the transition between westerlies (WDs) and the Indian Southwest Monsoon (ISWM), each conveying distinct moisture to the UJRB. The isotopic signature in rain is actively controlled by the combined effect of temperature (T) and relative humidity (RH) during WDs. However, the impact of “amount effect” with lower condensation temperature is dominant during the latter half of ISWM. Seasonal variations in δ18O and d-excess in stream water are distinct, influenced by different contributing sources and topographic controls. A linear relationship is observed between δ18O vs. altitude and glacier area ratio (GAR). Lower δ18O in stream water and higher d-excess values are observed in the southwest at higher elevations in glacier-fed tributaries. On the northern side, higher δ18O in stream water indicates contributions from non-glacier fed tributaries and enhanced groundwater contributions rather than merely following the lower δ18O of precipitation along the strengthened WDs gradient. The δ18O isotopic lapse rate (ILR) of rain (−0.19‰/100 m) is higher compared to ILR for the river (−0.05‰/100 m), reflecting the mixing of water sources in river water. However, both are lower than the global average (−0.28‰/100 m). This study helps in understanding the influence of meteorological, topographic factors, and other water sources on stream water, a prerequisite for projecting a potential future change in the complex Himalayan region.

Small-Scale Power Plants Based on Organic Rankine cycle (ORC) using Low-Boiling Fluorocarbon Working Fluids when Operating at High Initial Cycle Conditions

The purpose of the work is to develop and analyze the operation of a thermal circuit based on the organic Rankine cycle (ORC) using low-boiling working substances of the fluorocarbon class when operating at high initial cycle parameters. This goal is achieved by energy analysis of single- and multi-stage thermal circuits of power plants with a turbine circuit operating on low-boiling fluorocarbon work-ing substances, such as octafluoropropane C3F8 and decafluorobutane C4F10. It is proposed to integrate the ORC thermal circuit as an extension to a small-capacity gas turbine power plant (GTU), operating on synthesis gas after a biomass gasifier. The most important results of the work are the possibility of implementing a cycle with a low condensation temperature of the medium, which allows, when using low-boiling working fluids, to significantly reduce the temperature of the heat removal process and, consequently, increase the efficiency of the cycle. The possibility of using the listed working substances in power plants with a turbine circuit, which until now have been used mainly as refrigerants for refrig-eration and heat pump systems, has been shown. The significance of the results of the work lies in the fact that, based on the analysis of the energy complex, a circuit solution has been proposed and justified that can increase the energy efficiency of the power supply complex, increasing the volume of generated electrical power and providing a number of technological and environmental advantages.

Impact of low-fusion gutta-percha cones used in variations of the continuous wave condensation technique with filling sealers based on bioceramic compounds on the quality of root canal filling.

To evaluate the impact on the quality of filling with of low-fusion and conventional gutta-percha cones. Thirty-six maxillary canines were prepared and divided into three groups: I-conventional cone with Downpack at 200°C at 4mm from the WL; II-low-fusion cone with Downpack at 100°C up to 4mm from the WL; III-low-fusion cone with Downpack at 100°C up to 7mm from the WL. Temperature variations were measured in thirds on the external surface of the root. The bond strength was evaluated using the push-out test. The adhesive interface was analyzed by scanning electron microscopy. The bond strength and the temperature variation data were analyzed using analysis of variance and the failure type using the chi-square test. The low-fusion cone group with 7mm Downpack showed higher bond strength (4.2 ± 2.7) compared with conventional cones (2.8 ± 1.6) and low-fusion cones with 4mm Downpack (2.9 ± 1.6) (p < 0.05), with occurrence of a higher number of adhesive failures to the filling material and mixed failures. Relative to temperature variation, there was less temperature change in the apical third, in the low-fusion cone with Downpack 7mm (1.0 ± 1.0) (p < 0.05). The use of low-fusion cones allowed the continuous wave condensation technique to be performed at a lower depth of Downpack at 100°C at 7mm, with less heating in the apical third, without compromising the quality of filling. Using gutta-percha cones with low fusion, which permits a lower condensation temperature and reduced Downpack depth, maintains the quality of filling, in order to minimize possible damage to the periapical tissues.

Study on separation of CO2 condensation from natural gas based on cellular automaton method

ABSTRACT The CO2-containing natural gas is increasing, and there is an urgent need for green treatment of natural gas containing CO2 to realize the utilization of natural gas. Conventional natural gas decarbonization methods have drawbacks such as non-environmental friendliness, and the low-temperature condensation separation of carbon dioxide (snowing-separation) method as a green method of carbon capture is proposed in this paper. Aiming at the characteristics of CO2 condensation in the snowing-separation process, the growth process of CO2 crystals is obtained by simulation using the CA (Cellular Automata) method and finds that the effect of supersaturation on the growth of CO2 crystals is exponential. The snowing-separation process at .5 MPa is analyzed, and it is found that the condensation range is 158.51 K–173.86 K, the upper limit of CO2 mole fraction in natural gas is 10.1%, and the minimum separation time is 8.65 × 10−8s. Analyzing the influencing factors of CO2 separation efficiency, combining the simulation results with the experimental results, the maximum relative error is 13.93%, which can better predict the snowing-separation technology of CO2 in natural gas, and then promote the development of efficient low-temperature carbon capture process.

Preparation and Properties of Mechanically Robust, Colorless, and Transparent Aramid Films.

In this study, various diamine monomers were used to synthesize aramid polymer films via a low-temperature solution condensation reaction with diacid chloride. For diamines with relatively high basicity, the reaction system became opaque because amine salt formation inhibited polymer synthesis. Meanwhile, low-basicity diamines with strong electron-withdrawing groups, such as CF3 and sulfone, were smoothly polymerized without amine salt formation to provide highly viscous solutions. The acid byproduct HCl generated during polymerization was removed by adding propylene oxide to the reaction vessel and converting the acid into highly volatile inert substances. The resulting solutions were used as varnishes without any additional purification, and polymer films with an excellent appearance were easily obtained through a conventional casting and convection drying process. The films neither tore nor broke when pulled or bent by hand; furthermore, even when heated up to 400 °C, they did not decompose or melt. Moreover, polymers prepared from 2,2-bis(trifluoromethyl)benzidine (TFMB) and bis(4-aminophenyl)sulfone (pAPS) did not exhibit glass transition until decomposition. The prepared polymer films showed a high elastic modulus of more than 4.1 GPa and a high tensile strength of more than 52 MPa. In particular, TFMB-, pAPS-, and 2,2-bis(4-aminophenyl)hexafluoropropane-based polymer films were colorless and transparent, with very high light transmittances of 95%, 96%, and 91%, respectively, at 420 nm and low yellow indexes of 2.4, 1.9, and 4.3, respectively.

On the chemical abundance differences between the solar twin visual binary system 16 Cygni A and B

AbstractThe visual binary system 16 Cyg A+B consists of similar solar twins, but a planetary companion is detected only in B. An intensive spectroscopic differential analysis is carried out to the Sun, 16 Cyg A, and 16 Cyg B, with particular attention being paid to (i) precisely establishing the differential atmospheric parameters/metallicity between A and B, and (ii) determining the important CNO abundances based on the lines of CH, NH, and OH molecules. The following results are obtained. (1) The Fe abundances (relative to the Sun) are [Fe/H]A = +0.09 and [Fe/H]B = +0.06 (i.e., A is slightly metal‐rich than B by +0.03 dex). This lends support to the consequences of recently published papers, while the conclusion once derived by the author (almost the same metallicity for A and B) is acknowledged to be incorrect. (2) The differential abundances ([X/H]) of volatile CNO with low (condensation temperature) are apparently lower than those of refractory Fe group elements of higher , leading to a positive gradient in the [X/H] versus relation being more conspicuous for A than B. This is qualitatively consistent with previous studies, though the derived slope is quantitatively somewhat steeper than that reported by other authors.

Application of response surface methodology and desirability approach to optimize the performance of an ultra-low temperature cascade refrigeration system

In this paper, multi-objective optimization of an ultra-low temperature cascade refrigeration system is presented using response surface methodology and desirability approach. Evaporation temperature, high-temperature circuit and low-temperature circuit condensation temperature, cascade temperature difference, and superheat degrees of the compressor suction are chosen as the variables, whereas COP, total exergy destruction and exergy efficiency are adopted as the responses that simultaneously maximizing COP and exergy efficiency while minimizing the exergy destruction. The quadratic models for three responses are obtained after the analysis of variance. The interactive influences of the variables on the responses are indicated. The results present that the maximum deviations between the predicted and actual values for the COP and exergy efficiency are 0.84% and 0.96%, whereas the deviations for the exergy destruction are within ± 2% accounting for 96% of the samples. Evaporator temperature, condenser temperature, cascade temperature difference, ect. are found to be important parameters which cause great conflicts among the objective functions. A group of optimum values for the input variables are selected and validated. The derivations between predicted modeling and simulation values for the COP, total exergy destruction, and exergy efficiency are −0.604%, 2.886%, and 0.0452%, respectively, indicating that the method is efficient to optimize the performance.

Thermodynamic design and experimental study of a condensation recovery system for VOCs

During the storage and transportation process of crude oil on tankers, the light hydrocarbon components in liquid form have the tendency to evaporate and vaporize easily, resulting in wasted resources and environmental pollution. The current petroleum volatile organic compounds (VOCs) recovery system such as absorption and membrane separation applied to crude oil tankers is unable to fulfil the requirements of existing VOCs emission standards. In contrast, the condensation method of VOCs recovery technology has the benefit of a straightforward process principle, and the recovered liquid hydrocarbons can be utilized directly. It is thus vital to develop a condensation recovery system for petroleum VOCs that is compatible with crude oil tankers. To attain the condensation and recovery of the non-azeotropic gases, such as CH4, C2H6, C3H8, and N2 in the feed gas, this paper proposes a low-temperature VOCs condensation recovery system with graded cooling and liquefaction separation for crude oil tankers. The proposed system initially utilizes a R404A/R23 double-stage cascade refrigeration cycle to cool the VOCs below −75 ℃ to liquefy most heavy hydrocarbons. Then, a low-temperature nitrogen expansion cooling cycle is utilized to cool the VOCs to approximately −160 °C to recover the remaining light hydrocarbons. The condensation process is simulated by Aspen HYSYS to study the variable operating conditions. The recovery of total hydrocarbons in the outlet tail gas in the simulation results is analyzed and found to be up to 95.50 %. Under identical refrigeration capacity circumstances, decreasing the inlet pressure, increasing the inlet flow rate, and increasing the methane mole fraction in VOCs component, all lead to declining trends of total hydrocarbon recovery and methane recovery rate. Specifically, the effects of four different hydrocarbon component ratios on total hydrocarbon recovery and total cooling load are investigated at a constant nitrogen content and refrigeration capacity. Furthermore, the optimal design and analysis process for the flow path section of the turbine expander under the cryogenic conditions is discussed. The results demonstrate that the outlet temperature through the turbine expander is at least −172.1 °C, and the cooling capacity can be up to 4.5 kW with a margin of 80 %. Finally, through the comprehensive VOCs condensation recovery experiments, the proposed system successfully achieves the liquefied separation and recovery of CH4, C2H6, and other hydrocarbons. The recovery rate of the total hydrocarbons in the outlet tail gas reaches 96.21 %, conforming to the VOCs emission standards and regulations. The findings of this study provide a viable technical resolution in the field of petroleum VOCs recovery from crude oil tankers.

Mathematical Modeling of Cryochemical Formation of Medicinal Substances in Nanoforms. The Role of Temperature and Dimensional Parameters

The work is aimed at creating a mathematical model of cryochemical synthesis of nanoforms of pharmaceutical substances. The therapeutic efficacy of pharmaceutical substances largely depends on the size and morphology of the particles. Reducing the particle size of pharmaceutical substances to nanoscale makes it possible to obtain highly effective drugs, which makes it possible to use smaller doses of drugs and, thus, reduce side effects and toxicity. Cryochemical synthesis is one of the most powerful methods for obtaining nanoforms of medicament. The method, which is completely new, is based on sublimation or evaporation of the initial pharmaceutical substance under high vacuum conditions and the introduction of the resulting vapors into an inert gas stream, followed by low-temperature condensation of the flow of molecules of the substance from the gas phase on the cooled surface. The first step in the mathematical modeling of cryochemical synthesis processes is the calculation of the temperature field in the carrier gas flow interacting with the cooled surface. For this purpose, a stationary equation of thermal conductivity with mass transfer is used for the one-dimensional case. We prove existence and uniqueness theorems of the solution. Analytical solutions of the equation for Dirichlet, Neumann and Robin boundary conditions are found.

An efficient optimization strategy for vapor compression–absorption-based cascaded refrigeration system using various evolutionary techniques

ABSTRACT A novel optimization strategy for a compression-absorption cascaded refrigeration system (CACRS) consisting of a single effect vapor absorption system (VARS) and vapor compression system (VCRS), which employs several absorbent solution-refrigerant-refrigerant pairs to consider the combination of absorbent solution-refrigerant in VARS and refrigerants in VCRS as an optimization variable, is successfully implemented using various evolutionary optimization techniques. This article analyzes three different absorbent solution-refrigerant in the VARS with eleven different refrigerants in the VCRS. A nonlinear objective function is formulated based on exergy and environmental analysis, which is minimized using 10 different evolutionary optimization techniques. The proposed novel strategy reduces the complexity of using optimization techniques to select the best optimum absorbent-refrigerant-refrigerant pair. Differential evolution with multi-population-based ensemble of mutation strategies determined the minimum total annual cost as 13,137.78 US$/year for (CaCl2-LiBr-LiNO3-)-H2O-R152a. Lower condenser temperature and higher temperature difference in the cascade-condenser resulted in a minimum value for the total annual cost.

Thermodynamic analysis of a modified booster-assisted ejector heat pump cycle with dual condensers

This paper proposes a modified booster-assisted ejector heat pump (MBEHP) cycle with dual condensers for heat pump dryer applications. Based on a basic booster-assisted ejector heat pump (BEHP) cycle, a low-temperature condenser is introduced between the conventional condenser (i.e. high-temperature condenser) and the evaporator to realize the dual-pressure condensation that can provide heat duty at two different temperatures for heating up dryer air. In this case, improvement on cycle performance could be achieved through the use of such dual condensers in the MBEHP cycle. The benefits from the MBEHP cycle are evaluated by using the first and second laws of thermodynamics, and performance comparisons with the BEHP cycle are also presented. The results show that when R134a is used as the refrigerant, the heating coefficient of performance COPhw and COPh of MBEHP cycle under the typical operating condition increase by 50.34 % and 16.97 % compared with those of BEHP cycle, respectively. The performance of MBEHP cycle is superior to that of BEHP cycle under all given operating conditions, especially under severe operating conditions such as high condensing temperature and low evaporating temperature. In typical operating condition, the total exergy destruction of MBEHP cycle is 12.70 % lower than that of BEHP cycle, but the ejector has the maximum optimization potential. Moreover, the heating capacity Qc and the COPhw of MBEHP cycle are 42.49 % and 12.79 % higher using R1234ze(Z) than using R134a, hence R1234ze(Z) is the most suitable refrigerant to replace R134a in the MBEHP cycle among R1234yf, R1234ze(E) and R1234ze(Z).

Design optimization of compact gas turbine and steam combined cycles for combined heat and power production in a FPSO system–A case study

This case study aims to cover a wide range of relevant aspects related to combined cycle design, mechanical integrity and operational reliability for cogeneration of heat and power in FPSO systems. The methods consist of combined optimization of combined cycle thermodynamic design and geometry of steam generator; vibration analysis for flow induced vibrations; and thermal stress estimation of casings during cold start-stop scenarios. Challenges and opportunities for reliable water treatment systems are explored. The results show that small tubes, a compact tube bundle and a low condensation temperature reduces the once-trough steam generator (OTSG) weight. The vibrations numerical simulations in this work support the standard recommendations of using 35 times tube OD as upper limit for the unsupported tube length, which could be used as a reasonable design criterion. Thermal stresses analysis indicates that the design of beam arrangement, location, and stiffness of beams has a major impact on thermal stresses, and can be optimized to different plate thicknesses in order to avoid fatigue damage. Focus should be on reducing leaks of deaerator, steam turbine and condenser. It is recommended to add Na sensors after condenser and investigating the use of Electrodeionization (EDI) technology for make-up water production from seawater.

Immobilization of Phosphamide on the TiO2 Surface for Heterogeneous Phase Catalytic Appel Reaction

Global consumption of triphenylphosphine (Ph3P) for phosphorus-mediated organic synthesis and production of the dead-end triphenylphosphine oxide (Ph3PO) waste is exceptionally high. Recycling Ph3PO and/or use of it as a reaction mediator gained significant attention. On the other end, phosphamides, traditionally used as a flame redundant, are stable analogues to Ph3PO. Herein, via a low temperature condensation reaction of methyl 4-(aminomethyl)benzoate (AMB) and diphenyl phosphinic chloride (DPPC), methyl 4-((N,N-diphenylphosphinamido)methyl)benzoate (1) has been synthesized and hydrolysis of the ester functional group of 1 leads to a phosphamide with a carboxylate terminal, 4-((N,N-diphenylphosphinamido)methyl)benzoic acid (2). The presence of phosphamide functionality (NH─P═O) in 2 can be confirmed by its characteristic Raman vibration at 999 cm-1 with expected P-N and P═O bonds distances from the single-crystal X-ray structure. In-situ hydrolysis of [Ti(OiPr)4] in the presence of 2 followed by hydrothermal heating results in immobilization of 2 on a ca. 5 nm TiO2 surface (2@TiO2). The covalent attachment of 2 via coordination through the carboxylate terminal to the TiO2 nanocrystal's surface has been established via multiple spectroscopic and microscopic studies. 2@TiO2 is further used as the heterogeneous mediator for the catalytic Appel reaction, halogenation of alcohol (typically mediated by phosphine), with a fair catalytic conversion and a recorded TON up to 31. The major advantage of the heterogeneous approach studied herein is the recovery of used 2@TiO2 from the reaction mixture via centrifugation only leaving the organic product in the supernatant, which is limiting in Ph3P-mediated homogeneous catalysis. Time-resolved Raman spectroscopy confirms amino phosphine as the active species formed in-situ during the catalytic Appel reaction. Post-catalytic characterization of the material recovered after catalysis from the reaction mixture confirms the chemical integrity and that can further be utilized for another two catalytic runs. The developed reaction scheme showcases the use of a phosphamide as a reactive analogue to Ph3PO for an organic reaction in a heterogeneous approach, and the same strategy can be explored further as a general scheme for other phosphorus-mediated reactions.

Evaluation and optimization of a novel cascade refrigeration system driven by waste heat

Direct discharge of waste heat from internal combustion engines (ICEs) is unfavorable for the efficient and clean fuel utilization. Here, a novel combined absorption-compression cascade refrigeration cycle is proposed to efficiently capture low-grade waste heat and supply cooling capacity for food freezing in vessels or refrigerated trucks. The intention of this work lies in: i) Comprehensively evaluating the performances of the proposed system; ii) Gaining the optimal operating conditions of the system. Aimed that, analysis models of energy, exergy, economy, and environment are set up to evaluate the sweeping performances. Further, multi-objective optimization is introduced to obtain the optimal operating parameters including evaporation and condensation temperature of the low-temperature stage, generation temperature and condensation temperature of the high-temperature stage, and cascade temperature differences. By applying multi-objective optimization, the coefficient of performance and exergy efficiency of the system are elevated from 1.283 to 1.547, and 0.222 to 0.246, respectively, the discharge amount of carbon dioxide are reduced from 71.40 to 59.57 tons year−1, and annual total cost are decreased from 16,028 to 15,055 $ year−1 compared to initial operating conditions.