Low Transformation Temperature Filler Materials Research Articles

Capability of martensitic low transformation temperature welding consumables for increasing the fatigue strength of high strength steel joints

Abstract The use of low transformation temperature (LTT) filler materials represents a smart approach for increasing the fatigue strength of welded high strength steel structures apart from the usual procedures of post weld treatment. The main mechanism is based on the effect of the low start temperature of martensite formation on the stress already present during welding. Thus, compressive residual stress formed due to constrained volume expansion in connection with phase transformation become highly effective. Furthermore, the weld metal has a high hardness that can delay the formation of fatigue cracks but also leads to low toughness. Fundamental investigations on the weldability of an LTT filler material are presented in this work, including the characterization of the weld microstructure, its hardness, phase transformation temperature and mechanical properties. Special attention was applied to avoid imperfections in order to ensure a high weld quality for subsequent fatigue testing. Fatigue tests were conducted on the welded joints of the base materials S355J2 and S960QL using conventional filler materials as a comparison to the LTT filler. Butt joints were used with a variation in the weld type (DY-weld and V-weld). In addition, a component-like specimen (longitudinal stiffener) was investigated where the LTT filler material was applied as an additional layer. The joints were characterized with respect to residual stress, its stability during cyclic loading and microstructure. The results show that the application of LTT consumables leads to a significant increase in fatigue strength when basic design guidelines are followed. This enables a benefit from the lightweight design potential of high-strength steel grades.

In situ measurement of phase transformations and residual stress evolution during welding using spatially distributed fiber-optic strain sensors* *This manuscript has been authored by UT-Battelle, LLC, under contract DE-AC05-00OR22725 with the US Department of Energy (DOE). The US government retains and the publisher, by accepting the article for publication, acknowledges that the US government retains a nonexclusive, paid-up, irrevocable, worldwide

Welding of high-strength steels can result in large tensile strains as the base metal and filler material cool from their molten state. To combat these large tensile strains, low-transformation-temperature (LTT) metal fillers have been proposed. These fillers undergo a martensitic phase transformation at a lower temperature which can ultimately reduce the tensile strain or can even introduce compressive strain adjacent to the weld metal. However, the process for optimizing the composition of the LTT material, as well as various weld parameters for each unique weld geometry, can be quite expensive, especially if the acceptance criterion requires using neutrons, x-ray beams, or destructive techniques to characterize residual stresses. This work describes a simple, low-cost method for quantifying residual stresses and phase transformations in situ during welding. Spatially distributed fiber-optic sensors were bonded to a cast iron plate, along with tack-welded thermocouples, to measure temperature and strain during multiple passes with LTT filler metals. Results show that the fiber-optic sensors can successfully resolve compressive strain adjacent to the weld region caused by the martensitic phase transformations in the LTT filler material.

Capability of martensitic low transformation temperature welding consumables for increasing the fatigue strength of high strength steel joints

Abstract The use of low transformation temperature (LTT) filler materials represents a smart approach for increasing the fatigue strength of welded high strength steel structures apart from the usual procedures of post weld treatment. The main mechanism is based on the effect of the low start temperature of martensite formation on the stress already present during welding. Thus, compressive residual stress formed due to constrained volume expansion in connection with phase transformation become highly effective. Furthermore, the weld metal has a high hardness that can delay the formation of fatigue cracks but also leads to low toughness. Fundamental investigations on the weldability of an LTT filler material are presented in this work, including the characterization of the weld microstructure, its hardness, phase transformation temperature and mechanical properties. Special attention was applied to avoid imperfections in order to ensure a high weld quality for subsequent fatigue testing. Fatigue tests were conducted on the welded joints of the base materials S355J2 and S960QL using conventional filler materials as a comparison to the LTT filler. Butt joints were used with a variation in the weld type (DY-weld and V-weld). In addition, a component-like specimen (longitudinal stiffener) was investigated where the LTT filler material was applied as an additional layer. The joints were characterized with respect to residual stress, its stability during cyclic loading and microstructure. The results show that the application of LTT consumables leads to a significant increase in fatigue strength when basic design guidelines are followed. This enables a benefit from the lightweight design potential of high-strength steel grades.

Solidification Cracking Assessment of LTT Filler Materials by Means of Varestraint Testing and µCT.

Investigations of the weldability of metals often deal with hot cracking, as one of the most dreaded imperfections during weld fabrication. The hot cracking investigations presented in this paper were carried out as part of a study on the development of low transformation temperature (LTT) weld filler materials. These alloys allow to mitigate tensile residual stresses that usually arise during welding using conventional weld filler materials. By this means, higher fatigue strength and higher lifetimes of the weld can be achieved. However, LTT weld filler materials are for example, high-alloyed Cr/Ni steels that are susceptible to the formation of hot cracks. To assess hot cracking, we applied the standardized modified varestraint transvarestraint hot cracking test (MVT), which is well appropriate to evaluate different base or filler materials with regard to their hot cracking susceptibility. In order to consider the complete material volume for the assessment of hot cracking, we additionally applied microfocus X-ray computer tomography (µCT). It is shown that by a suitable selection of welding and MVT parameter the analysis of the complete 3D hot crack network can provide additional information with regard to the hot cracking model following Prokhorov. It is now possible to determine easy accessible substitute values (e.g., maximum crack depth) for the extent of the Brittleness Temperature Range (BTR) and the minimum critical strain .

In situ analysis of the strain evolution during welding using low transformation temperature filler materials

ABSTRACTCompared to conventional welding consumables using low transformation temperature (LTT) filler materials is an innovative method to mitigate tensile residual stresses due to delayed martensite transformation of the weld. For the effective usage of LTT filler materials, a deeper understanding of the complex processes that lead to the final residual stress state during multi-pass welding is necessary. Transformation kinetics and the strain evolution of multi-pass welds during welding were investigated in situ at the beamline HEMS@PETRAIII, Germany. Compared to conventional welds, the total strain was reduced and compression strain was achieved when using LTT filler materials. For an optimal use of the LTT effect in the root of multi-pass welds, the alloying concept must be adapted taking care of dilution.

Confirmation of tensile residual stress reduction in electron beam welding using low transformation temperature materials (LTT) as localized metallurgical injection – Part 1: Metallographic analysis

Abstract For the reduction of the distortion and the residual tensile stresses in welded seams on carbon manganese steels, low transformation temperature materials (LTT) were developed. These materials use the volume expansion effect during martensitic transformation. The volume expansion counteracts volume shrinkage during cooling. The positive effects of the low transformation temperature alloys on the residual tensile stresses were demonstrated in various investigations. The low transformation temperature materials were, so far, used as filler material in arc welding processes in large volumes. The use of modular thermal fields of the electron beam welding processes offers the potential of a temporally activated use of compressive stress induction by phase transformation of the low transformation temperature alloys. The aim is to exert influence in situ on the welding residual stress state and thus on the distortion of complex parts. The metallographic analysis of an electron beam welded seam in unalloyed steel with low transformation temperature filler material is demonstrated. The evaluation is made via electron backscatter diffraction (EBSD) and is shown in the first part. The second part will show the effect on near surface residual stresses examined by hole-drilling method in combination with an optical evaluation by electronic speckle pattern interferometry.

Residual Stress Distributions at High Strength Steel Welds Prepared by Low Transformation Temperature (LTT) and Conventional Welding Consumables

Residual stress distributions in fillet welds in 8 mm 900 MPa steel have been mapped perpendicular and parallel to the weld line and also through the thickness in the vicinity of weld toe position. Measurements were carried out on four welds when two of them were performed with conventional and two with the so called LTT (low transformation temperature) filler materials. Both neutron and X-ray diffractions were used for determination of the residual stress distribution. Fatigue properties have also been evaluated for all test welds. Neutron diffraction measurements showed that the stress profiles perpendicular to the weld toe qualitatively did not depend on filler material type although the absolute stress levels differed. Trends were similar for positions 2, 4 and 6 millimetres below the surface for all three stress components; σx (direction perpendicular to the weld), σy (parallel to the weld) and σz (through the thickness). X-ray diffraction showed difference in residual stress level at the weld toe. Lower residual stress levels have been identified for LTT filler material when compared to the conventional consumable compositions. The effect of residual stress is discussed in relation to fatigue properties of all four welds. Remarkable higher fatigue strength has been measured for welds prepared by the LTT filler materials.

Residual Stress in Steel Fusion Welds Joined Using Low Transformation Temperature (LTT) Filler Material

Welding residual stress is of major concern for structural integrity assessment in industrial components. Shear and volume strains resulting from the austenite-martensite-transformation affect the development of residual stress during welding. Controlling the phase transformation allows adjustment of the welding residual stress. Low transformation temperature (LTT) weld filler materials exhibiting reduced MS-temperatures allow postponing the phase transformation. The associated strain arising from the delayed transformation compensates for the thermal contraction strains and as such may reduce tensile or even introduce compressive residual stress. In this article we discuss the tri-axial residual stress distribution in 15 mm S690Q steel plates joined with LTT filler materials with 10 wt% Cr and a Ni-content that varies from 8 to 12 wt%. Using complementary synchrotron X-ray and neutron diffraction stress analysis the macroscopic residual stress was derived from the phase specific lattice strain and phase fraction of martensite and retained austenite, respectively. The local phase specific unstrained lattice parameters were determined using stress relieved combs. The investigation revealed increasing phase fraction of retained austenite with increasing Ni-content. Further, independent of the Ni-content in each weld in the fusion zone, significant compressive residual stresses were found in the longitudinal direction, which are balanced by tensile residual stresses in the heat affected zone (HAZ). In the weld transverse and normal direction the stress distribution is qualitatively similar but less in magnitude. The increased amount of retained austenite reduces the compressive stress arising from shear and volume strains during the delayed phase transformation and therefore no significant increase in compression was observed for decreasing MS-temperatures.

Identification of Weld Residual Stresses Using Diffraction Methods and their Effect on Fatigue Strength of High Strength Steels Welds

It is well known that fatigue strength of welded joints does not depend on steel strength. Better fatigue strength of welded joints, e.g. longer life time of fatigue loaded weld structures, can be achieved with a smooth transition between the weld and the base material to minimize stress concentration. It has also been recognized that residual stresses play a critical role in the fatigue behaviour of welds. In the last decade an extensive research has been performed in order to increase the fatigue strength of high strength steel weldments. The martensite and bainite transformation start temperatures of weld metals have been shown to have a large effect on fatigue life time of high strength steel welds. This is of particular importance if the full potential of high strength steels is to be used in fatigue loaded constructions. A detailed investigation of the effect of phase transformation temperature on residual stress distribution in the vicinity high strength steel welds and its effect on fatigue life time has been performed. The transformation temperature of the weld metal was varied by changing the chemical composition of the filler material. Residual stress distributions have been measured by neutron as well as by X-ray diffraction and fatigue tests have been performed on the fillet welds. A strong effect of weld metal phase transformation temperature on residual stress level was observed. Fatigue strength increased approximately three times when an optimised low transformation temperature filler material was used in comparison to the application of conventional filler material.

Fatigue Strength Improvement of Welded Structures Using New Low Transformation Temperature Filler Materials

The results reported in this research study are part of a larger EU RFCS (Research Fund for Coal and Steel) project where the aim is to study the fatigue behavior of improved welds in high strength steels by utilizing different improvement techniques. In this particular study LTT (Low Transformation Temperature) weld filler material have been investigated and their possibility to improve the fatigue strength. The characteristic of these filler material is that they undergo phase transformation at temperature close to room temperature which will reduce the tensile residual stress in the weld and in some cases result in compressive residual stresses. Two different LTT alloy compositions have been developed, with different Ms (Martensite Start) temperatures in order to study the amount of tensile/compressive residual stresses produced by these wires. Welding residual stress measurements were carried out by X-ray diffraction technique. Plates with welded longitudinal attachments were fabricated in 700MPa and 960MPa steel grades using different LTT filler materials. These specimens were fatigue tested in constant and variable amplitude loading and the fatigue test results were compared with results from specimen welded with conventional weld filler material.

Assessment of hot cracking behaviour in welds

Abstract Hot crack assessment during production and processing of metallic materials is an essential prerequisite for the safety of welded structures. The hot cracking investigations presented here were carried out as part of a study aimed at the development of Cr/Ni low transformation temperature filler materials. Low transformation temperature alloys open up the possibility for welding high strength steels. The externally loaded Modified Varestraint Transvarestraint hot cracking test was employed in the experiments described. The hot cracking resistance was evaluated with the help of light microscopy applied at the specimen surface. The proportionality between hot cracking susceptibility and Cr/Ni alloy content was explained by the altered solidification kinetics and by the enlarged solidification interval. The internal crack paths and the three-dimensional structure of the crack net in the material volume were examined using X-ray computer tomography. The total crack lengths for different material depths and circumjacent rectangular volumes, respectively, were be determined. An increasing hot cracking susceptibility with increasing Cr/Ni alloy content was also be established for the specimen volume.

Design of weld fillers for mitigation of residual stresses in ferritic and austenitic steel welds

Residual stresses that arise as a result of welding can cause distortion, and also have significant implications for structural integrity. Martensitic filler metals with low transformation temperatures can efficiently reduce the residual stresses generated during welding, because the strains associated with the transformation compensate for thermal contraction strains during cooling. However, it is vital that a low weld transformation temperature is not obtained at the expense of other important material properties. This article outlines the alloy design process used to develop appropriate low transformation temperature filler materials for the mitigation of residual stresses in both low alloy ferritic and austenitic stainless steel welds. Residual stresses in single pass, 6 mm bead in groove welds, on 12 mm thick plates, have been measured and compared against those obtained with commercially available conventional austenitic and ferritic filler materials. The filler metals developed here exceeded requirements in terms of weld mechanical properties, while significantly reducing the maximum residual stress in the weld and heat affected zone.