In this study, the wall shear stress in the channel flow of polyacrylamide polymers was investigated through electrochemical experiments, and the effects of the polymer concentration were evaluated at different Reynolds numbers. The objective was to explore the relationship between the changes in the drag reduction and near-wall turbulence structure induced by the polymer. The experiments were conducted using polymer concentrations of 0, 20, 50, 100, and 150 ppm, and a drag reduction of approximately 23% was achieved at a bulk Reynolds number of Reb = 18 750. In the electrochemical method, the working electrode was arranged spanwise, and simultaneous measurements were performed for eight electrodes to discuss the scale of the near-wall low-speed streaks and burst events. A comprehensive analysis of the correlation of the wall shear stress in the streamwise direction and the cross-spectrum of two points in the spanwise direction revealed that large streamwise and spanwise scales of near-wall low-speed streaks were generated at high polymer concentrations. Furthermore, the results obtained using the variable interval time averaging technique indicated that polymer incorporation suppressed the wall shear stress fluctuations and weakened both the intensity and frequency of the bursting events.