Low Energy Ion Research Articles

Observational Signatures of AGN Feedback in the Morphology and the Ionization States of Milky Way-like Galaxies

We make an in-depth analysis of different active galactic nuclei (AGN) jet models’ signatures, inducing quiescence in galaxies with a halo mass of 1012 M ⊙. Three jet models, including cosmic-ray-dominant, hot thermal, and precessing kinetic jets, are studied at two energy flux levels each, compared to a jet-free, stellar feedback-only simulation. Each of our simulations is idealized isolated galaxy simulations with AGN jet powers that are constant in time and generated using GIZMO and with FIRE stellar feedback. We examine the distribution of Mg ii, O vi, and O viii ions, alongside gas temperature and density profiles. Low-energy ions, like Mg ii, concentrate in the interstellar medium (ISM), while higher energy ions, e.g., O viii, prevail at the AGN jet cocoon’s edge. High-energy flux jets display an isotropic ion distribution with lower overall density. High-energy thermal or cosmic-ray jets pressurize at smaller radii, significantly suppressing core density. The cosmic-ray jet provides extra pressure support, extending cool and warm gas distribution. A break in the ion-to-mass ratio slope in O vi and O viii is demonstrated in the ISM-to-circumgalactic medium (CGM) transition (between 10 and 30 kpc), growing smoothly toward the CGM at greater distances.

Enhancement of copper nanoparticle yield in magnetron sputter inert gas condensation by applying substrate bias voltage and its influence on thin film morphology

Large-scale synthesis of high-purity nanoparticles is an intense topic of scientific research, with magnetron sputter inert gas condensation recognized as a promising, environmentally friendly technique avoiding wet chemical processes. This study explores the deposition of size-selected nanoparticles under varied substrate bias voltages and reports on a consequent increase in deposition rates up to 32 %. These alterations in substrate bias voltage induce a progressive change in the morphology of the resulting nanoparticle thin films, attributable to the increased kinetic energy of the nanoparticles. Comprehensive characterization via quadrupole mass spectroscopy of the nanoparticle flux, scanning electron microscopy, X-ray photoelectron spectroscopy, and low-energy ion scattering spectroscopy of the deposited nanoparticles corroborates the enhanced nanoparticle yield associated with increased substrate bias voltage. These findings signify a methodological advancement, enhancing the efficiency of magnetron sputter inert gas condensation and moving the technology a step further towards feasible industrial production.

Self-healing kinetics in monolayer graphene following very low energy ion irradiation

Monolayer graphene subjected to 13 and 90 eV Ar ion irradiation was probed by in-situ Raman spectroscopy. At 90 eV ion irradiation, a simple damage accumulation is seen. However, at 13 eV, immediately after damage formation, significant graphene self-healing is observed in real time. We argue that energy deposition through very-low-energy ion collisions can create vacancies and carbon adatoms which can diffuse easily on the surface and recombine afterward. The self-healing kinetics exhibit a fast (∼10 s) and a slow regime (∼30 min), which cannot result only from adatom-vacancy recombination. Based on a defect kinetic model, self-healing efficiency is revealed to be limited by dimer formation. Yet, the interplay between Stone-Wales defects and adatoms enables progressive release of the latter, and subsequent graphene self-healing on a longer time scale.

Atomistic simulations of low energy ion irradiation of 2D materials: From ab-initio molecular dynamics to simple binary collision model

Atomistic simulations of low energy ion irradiation of 2D materials: From <i>ab-initio</i> molecular dynamics to simple binary collision model

Thermal evolution of helium bubbles in tungsten by GISAXS and TDS

Grazing-incidence small-angle x-ray scattering (GISAXS) and thermal desorption spectroscopy (TDS) were used to study the thermal evolution of helium (He) bubbles in tungsten (W). W samples were exposed to a low ion energy (∼20 eV, sheath accelerated) He plasma at two sample temperatures: 573 K (low-temperature) and 1050 K (high-temperature). They were then annealed to temperatures of 773 K, 873 K and 998 K. GISAXS analysis showed an increase in the median bubble radius of the high-temperature samples from 6.42 Å to 12.87 Å as a result of annealing to 998 K. No changes in the bubble radii distributions were observed for the low-temperature samples and the median radius remained at ∼4 Å even after annealing. TDS showed that the desorption behaviour of He in W has a dependence on the sample temperature during plasma irradiation. The higher-temperature sample experienced a maximum desorption rate that is an order of magnitude larger than the low-temperature sample. The desorption profile of the high-temperature sample spanned a wider temperature range, 500 K - 1500 K, than the low-temperature sample, 500 K - 750 K. The formation and thermal evolution of He bubbles in W have a clear dependence on sample temperature during plasma exposure. The differences in annealing behaviour observed in this work agree with prior in-situ TEM annealing experiments and help explain macroscopic plasma-material interaction effects such as recrystallisation suppression.

Atomistic Simulation of Primary Radiation Damage Profiles in Fluorine-Doped Tin Oxide Thin Film Target Using SRIM Code

In this study, we investigated the discrepancy between the numbers of atomic displacements obtained from the Vac.txt method and those obtained from the Vac.dam method using SRIM-2013 operated in full cascade mode. The SRIM simulations also calculated energy partitioning, damage dose and distribution profiles of the implanted He, C and O ions at three different ion energies of 10 keV, 100 keV and 1 MeV. In all the simulations and at each ion energy value, the target thickness was increased until the entire ion beam was absorbed within the target. The simulated fluorine-doped tin oxide (FTO) thin film target stoichiometrically comprised 78.6% Sn, 16.4% O and 5.0% F, and a 6.013 g/cm3 bulk density. To achieve relatively good statistics with compromised computational time, each run followed 10 000 ion histories. The results indicated that, with increasing ion energies, the peaks of vacancy concentrations moved deeper into the material. For He ions, the vacancy profiles have peaks at ∼0.04, ~0.45 and ~2.9 µm at 10 keV, 100 keV and 1 MeV, respectively. Meanwhile, for C and O ions, the peaks were at ∼0.012, ~0.15 and ~1.23 µm for C ions and ∼0.01, 0.12 and 1.2 µm for O ions at 10 keV, 100 keV and 1 MeV, respectively. We also observed that for all the ions and at all ion energies considered, the Vac.txt method predicted more vacancies than the Vac.dam method, and the discrepancies generally increased with increasing Z by an average value of ∼1.21, ∼1.45 and 1.48 for He, C and O ions respectively. In addition, the electronic and nuclear partitioning profiles revealed that most of the energies of the ions were lost in collision with atomic electrons due to ionisation and excitations, and little to nuclear events. The simulations also revealed that nuclear stopping powers increase at low ion energies. This study also indicated that damage dose profiles strongly depend on the type of incident particle and its energy. A comparison of SRIM and iradina calculated vacancies and incident ion distribution profiles generally indicated perfect agreements between the two codes. FTO thin film remains a promising material for thermal control applications in future spacecraft. However, further analyses are still necessary to comprehensively understand its evolution under intense radiation environments comprising various ions and at different energies.

Ultrahigh Concentration Hydrogen Doping into TiO2.

We investigate ultrahigh concentration doping of hydrogen (H) into rutile-TiO2 (100) single crystals by low-energy (2.5 keV) hydrogen ion beam irradiation at low temperature (LT). While the hydrogen concentration was limited to H0.3TiO2 at 300 K, in situ nuclear reaction analysis (NRA) revealed ultrahigh concentration doping of hydrogen up to H1.2TiO2 by the LT irradiation at 50 K. The large (∼8.2%) expansion of the out-of-plane lattice constant suggests that hydrogen occupies interstitial sites in rutile TiO2. Hydrogens of early stage irradiation act as electron donors and induce a large increase in conductivity, which is consistent with theoretical studies in the dilute limit. The nature of excess H was investigated in situ by transport and photoemission measurements. After LT excess H doping and postannealing to room temperature, unusual electrical transport properties were observed while maintaining the ultrahigh H concentration. In situ photoemission measurements show that the excessively doped hydrogens by LT irradiation generate a deeper in-gap state (IGS) of metastable nature. Density functional theory predicts the formation of double neighboring interstitial hydrogens as a possible mechanism for the deeper IGS.

Automated image acquisition and analysis of graphene and hexagonal boron nitride from pristine to highly defective and amorphous structures

Defect-engineered and even amorphous two-dimensional (2D) materials have recently gained interest due to properties that differ from their pristine counterparts. Since these properties are highly sensitive to the exact atomic structure, it is crucial to be able to characterize them at atomic resolution over large areas. This is only possible when the imaging process is automated to reduce the time spent on manual imaging, which at the same time reduces the observer bias in selecting the imaged areas. Since the necessary datasets include at least hundreds if not thousands of images, the analysis process similarly needs to be automated. Here, we introduce disorder into graphene and monolayer hexagonal boron nitride (hBN) using low-energy argon ion irradiation, and characterize the resulting disordered structures using automated scanning transmission electron microscopy annular dark field imaging combined with convolutional neural network-based analysis techniques. We show that disorder manifests in these materials in a markedly different way, where graphene accommodates vacancy-type defects by transforming hexagonal carbon rings into other polygonal shapes, whereas in hBN the disorder is observed simply as vacant lattice sites with very little rearrangement of the remaining atoms. Correspondingly, in the case of graphene, the highest introduced disorder leads to an amorphous membrane, whereas in hBN, the highly defective lattice contains a large number of vacancies and small pores with no indication of amorphisation. Overall, our study demonstrates that combining automated imaging and image analysis is a powerful way to characterize the structure of disordered and amorphous 2D materials, while also illustrating some of the remaining shortcomings with this methodology.

Low current iodine-fed hollow cathode discharge: insights from fluid model

Abstract As one of the fundamental components, hollow cathodes using noble gas propellant are widely used in electric thrusters. Iodine has become one of the ideal alternative propellants due to its economy and good chemical properties, while due to the complex reactions, characteristics and proper functioning of iodine-fed hollow cathodes are still unknown. Therefore, a model is needed to understand the physical-chemical process of the iodine-fed hollow cathode discharge. In this work, a self-consistent two-dimensional fluid model of the low-current iodine-fed hollow cathode discharge with detailed non-equilibrium plasma chemistry is developed and verified by the voltages of the keeper and anode obtained in the experiments. Simulations show that the electron impact ionization with iodine atoms dominates the discharge process as the density of iodine atoms is much higher than that of iodine molecules due to the electron impact dissociation and thermal dissociation. Moreover, the power balance analysis shows the heating of electrons contributed by the electric field mainly takes place near the keeper and the orifice. Ion current heating contributes significantly to the gas heating compared with the heating by the electron elastic collisions with I and I2 and the heat release or consumption during the neutral reactions. Furthermore, the influence of electronegativity on plasma characteristics is analysed. Simulations involving I− ions bring higher values of ionization degree, discharge power as well as maximum electron and gas temperatures compared with those without I−. This is similar to the differences in the plasma properties between the iodine-fed and xenon-fed hollow cathode to which the low ionization energy, large collision ionization cross-section and the electronegativity of iodine contribute together. In all, these findings can better predict the plasma behaviours in the iodine-fed hollow cathode discharge and may promote the development of the electric propulsion system using iodine propellant.

Low energy ion irradiation effects in MgO: Optical property study

Irradiation of MgO pellets with ion beams results in the formation of vacancies and their aggregates. The irradiated MgO pellets are characterized by optical absorption and photoluminescence studies. 100 keV helium ion irradiation of MgO pellets results in the formation of F or F+ defects, F22+ defects, and F2 type defects. When irradiated with 100 keV oxygen ion beam, surface oxygen vacancies and F22+ defects are formed in the MgO lattice. Various PL emission peaks occur in the irradiated sample and in particular, emissions at 3.1 and 2.79 eV are found to be related to oxygen vacancies created by ion irradiation in the MgO target. The surface morphology of the irradiated samples is investigated with scanning electron microscopy.

Role of Interfacial Hydrogen in Ethylene Hydrogenation on Graphite-Supported Ag, Au, and Cu Catalysts.

A combined surface science/microreactor approach was applied to examine interface effects in ethylene hydrogenation on carbon-supported Ag, Au, and Cu nanoparticle catalysts. Turnover frequencies (TOFs) were substantially higher for supported catalysts than for (unsupported) polycrystalline metal foils, especially for Ag. Spark ablation of the corresponding metals on highly oriented pyrolytic graphite (HOPG) and carbon-coated grids yielded nanoparticles of around 3 nm size that were well-suited for characterization by X-ray photoelectron spectroscopy (XPS), high-resolution (scanning) transmission electron microscopy (HRTEM/STEM), and energy dispersive X-ray spectroscopy (EDX). Polycrystalline metal foils characterized by scanning electron microscopy (SEM), EDX, electron backscatter diffraction (EBSD), XPS, and low-energy ion scattering (LEIS) served as unsupported references. Employing a UHV-compatible flow microreactor and gas chromatography (GC) allowed us to determine the catalytic performance of the model catalysts in ethylene hydrogenation up to 200 °C under atmospheric pressure. Compared to the pure metal foils, the HOPG-supported metal nanoparticles exhibited not only strongly increased activity but also higher stability (slower deactivation) and differing reaction orders. For the most active Ag catalysts, DFT calculations were carried out to determine the adsorption energies of the reacting species on single-crystal surfaces as well as on carbon-supported and unsupported Ag nanoparticles. Adsorption of molecular hydrogen was very weak on all unsupported Ag surfaces, resulting in hydrocarbon-"poisoned" surfaces. However, when a carbon support was present, the adsorption strength of H2 on Ag nanoparticles increased on average by -0.5 eV, driven by changes in Ag-Ag distances near the metal-carbon three-phase boundary (whereas subsurface carbon lowers hydrogen bonding). On Cu particles, the interface effect was calculated to be somewhat weaker than for Ag particles. H2/D2 scrambling experiments on Ag catalysts then corroborated a facilitated hydrogen activation for carbon-supported metals. Thus, the carbon support effect is attributed to an improved hydrogen availability at the metal-carbon interface, controlling performance.

Heavy Ion Escape at Mars during the Disappearing Solar Wind Event in 2022 December

A unique event known as the disappearing solar wind (DSW), characterized by an extremely low-density solar wind stream, occurred at Mars on 2022 December 26–27. As this stream flowed past Mars, several properties of the Mars–solar wind interaction changed in response to the density drop. We utilize in situ plasma measurements from the Mars Atmosphere and Volatile EvolutioN spacecraft to examine heavy ion escape during this event. We find that escaping ions with energies above and below 30 eV responded differently to the reduction in solar wind density. High-energy ions experienced a decrease in flux, whereas low-energy ions experienced an increase, regardless of whether they were escaping through the plume or tailward channel. Furthermore, we observe a net reduction in the flux of plume escaping ions during the DSW period, primarily due to a considerable reduction in the high-energy component, which typically dominates plume escape. In contrast, the overall flux of tailward escaping ions increased during this period. These variations in heavy ion escape are mainly attributed to substantial reductions in solar wind dynamic pressure and momentum density. This paper provides new insights into the dynamics of heavy ion escape under an exceptional state of the Mars–solar wind interaction.

Electron-impact ionization of water molecules at low impact energies.

The electron-impact ionization of water molecules at low impact energies is investigated using a theoretical approach named M3CWZ. In this model, which considers exchange effects and post-collision interaction, the continuum electrons (incident, scattered, and ejected) are all described by a Coulomb wave that corresponds to distance-dependent charges generated from the molecular target properties. Triple differential cross-sections for low impact energy ionization of either the 1b1 or 3a1 orbitals are calculated for several geometrical and kinematical configurations, all in the dipole regime. The M3CWZ model is thoroughly tested with an extensive comparison with available theoretical results and COLTRIMS measurements performed at projectile energies of Ei = 81eV [Ren et al., Phys. Rev. A 95, 022701 (2017)] and Ei = 65eV [Zhou et al., Phys. Rev. A 104, 012817 (2021)]. Similar to other theoretical models, an overall good agreement with both sets of measured data is observed for the angular distributions. Our calculated cross-sections' magnitudes are also satisfactory when compared to the other theoretical results, as well as to the cross-normalized relative scale data at 81eV impact energy. The 65eV set of data, measured on an absolute scale, offers a further challenging task for theoretical descriptions, and globally the M3CWZ performs fairly well and comparably to other theories. The proposed approach with variable charges somehow allows to capture the main multicenter distortion effects while avoiding high computational costs.

Influence of temperature gradients on helium diffusion and clustering in tungsten: A molecular dynamics study

Tungsten and its alloys, used as plasma-facing materials in fusion reactors, endure high-flux, low-energy helium ion irradiation and temperature gradients induced by thermal load and shocks. This study utilizes molecular dynamics (MD) simulations to explore the diffusion and clustering behavior of helium (He) in tungsten (W) under temperature gradients. The migration behavior of isolated helium atoms, small helium clusters, and helium self-interstitial atom (He-SIA) clusters within tungsten is analyzed. It is revealed that both helium and He-SIA clusters tend to migrate towards higher temperature regions, exhibiting negative thermophoresis. The nucleation of helium clusters, the formation of Frenkel pairs, and the interactions between self-interstitial clusters and helium clusters are also investigated. The results indicate that helium concentration significantly impacts He nucleation behavior. Directional diffusion may lead to areas of high concentration over time, potentially promoting the formation of He clusters and bubbles. These insights enhance the understanding of tungsten's performance and durability as a plasma-facing component in fusion reactors.

Characterizing the surface compositions of supported bimetallic PtSn clusters: Effects of cluster-support interactions and surface adsorbates

PtSn bimetallic clusters on TiO2(110) and highly oriented pyrolytic graphite (HOPG) surfaces have been characterized by scanning tunneling microscopy, low energy ion scattering (LEIS), X-ray photoelectron spectroscopy, and temperature programmed desorption (TPD); density functional theory (DFT) calculations have also been performed to better understand adsorption of CO and D2 on the PtSn surfaces. On TiO2 at coverages of 2 ML of Pt and 2 ML of Sn, exclusively bimetallic clusters are formed for both orders of deposition because clusters of the first metal completely cover the surface such that all atoms of the second metal are incorporated into the existing clusters. In contrast, on HOPG, the high mobility and weak cluster-support interactions on HOPG result in much larger 2 ML monometallic clusters (∼30 Å high) that do not completely cover the surface, and deposition of the second metal produces larger clusters as well as smaller ones. Despite the difference in cluster morphologies for the different orders of deposition and supports, the LEIS experiments demonstrate that in all cases, the PtSn clusters are rich in Sn at the surface, as expected based on the lower surface free energy for Sn compared to Pt. Furthermore, the +0.2 eV shift in the Sn(3d5/2) binding energy observed on all surfaces in the presence of Pt is consistent with PtSn alloy formation. Deposition of 2 ML of Sn on TiO2 produces two-dimensional clusters with oxidation of Sn and reduction of titania at the cluster-support interface, but addition of Pt to the Sn clusters causes Sn to diffuse away from this interface, leaving Sn in the metallic state. TPD experiments on 2 ML Pt/TiO2 with increasing coverages of Sn show that the number of adsorption sites for D2 sharply decreases to nearly zero at 0.5 ML, while CO adsorption decreases to zero only at much higher Sn coverages of 2 ML. DFT studies for Sn modified Pt surfaces and bulk structures demonstrate that for CO adsorption at low Sn coverages (≤0.25 ML), the strong Pt-CO interactions induce diffusion of Pt to the cluster surface and the formation of a bulk Pt3Sn alloy, whereas D2 adsorption does not lead to interactions with the Pt surface that are strong enough to induce alloy formation. A single Sn adatom prevents D2 adsorption on four neighboring Pt atoms via site-blocking and the donation of electron density to Pt.

Insight into Carrier and Phonon Transports of PbSnS2 Crystals.

The simultaneous optimization of n-type and p-type thermoelectric materials is advantageous to the practical application of the device. As an emerging thermoelectric material, PbSnS2 exhibits highly competitive thermoelectric properties due to its unique carrier and phonon transport characteristics. To promote the utilization of this low-cost thermoelectric material, p-type PbSnS2 crystals are synthesized and optimized through Na doping and Se alloying. The resulting thermoelectric transport properties differ significantly from those reported for n-type crystals, prompting us to compare and analyze both n-type (Cl-doped) and p-type (Na-doped) PbSnS2 crystals from various perspectives. Cl doping is subject to weaker "Fermi pinning" and lower impurity ionization energy compared with Na doping, leading to higher doping efficiency. The different optimal performance directions in n-type and p-type crystals can be attributed to the distinct charge density distributions near the conduction band minimum (CBM) and the valence band maximum (VBM). Additionally, both n-type and p-type crystals exhibit ultralow lattice thermal conductivity due to the low symmetry of their twisted NaCl structure combined with the strong anharmonicity. This comprehensive analysis of PbSnS2 crystals provides a solid foundation for further performance optimization and device assembly, while also sheds light on the investigation of layered thermoelectric materials.

An ion soft-landing apparatus for ion transport study with surface potential measurement.

An apparatus for explorations of ion transport in a medium and across an interface has been constructed. The ion soft-landing technique is used to deposit low-energy ions onto a pre-adsorbed medium layer on a metal substrate. The designed low-energy ion source can produce a mass-filtered ion beam with tens of nanoampere from solid sources such as bulk metals and salts. The kinetic energy of the ion beam can be lower than 1.0eV, enabling the ions to be soft-landed onto the medium at the surface. A Kelvin probe with a resolution of less than 32 mV is incorporated to measure the surface potential (SP) variation of the ion-landed sample to monitor the ion transport process in the medium. Temperature-programmed SP measurements on an Ag+-adsorbed ice film prepared on Pt(111) reveal that the temperature threshold for the Ag+-induced SP change of the ice film is about 110K. The apparatus performance demonstrates its potential in studies of ion transport and related phenomena at both macroscopic and microscopic levels.

Low-Energy Xe Ion Beam-Mediated Defect Engineering in Optical, Electronic, Structural, and Morphological Properties of Sputtered MoS2 Thin Films

Low-Energy Xe Ion Beam-Mediated Defect Engineering in Optical, Electronic, Structural, and Morphological Properties of Sputtered MoS2 Thin Films

Low-energy argon ion beam irradiation for the surface modification and reduction of graphene oxide: Insights from XPS

Developing environmentally friendly methods for reducing graphene oxide (GO) is essential. This study investigates the surface modification and reduction of GO films using 200 eV argon ion (Ar+) beam irradiation. X-ray Photoelectron Spectroscopy (XPS) analysis reveals significant chemical changes on the GO surface. GO was irradiated with a 200 eV Ar+beam for varying times (0–80 s). XPS survey spectra showed the presence of carbon and oxygen, with an increasing carbon atomic percentage over time. High-resolution XPS spectra of C 1s revealed peaks corresponding to sp2, C–OH, O–C–O, CO, and O–CO bonds. In the O 1s spectra, CO, O–C–O, and C–OH groups were observed. Upon irradiation, the CO peak consistently decreased, the O–C–O peak fluctuated, and the C–OH peak increased, indicating effective reduction of CO groups, dynamic changes in O–C–O functionalities, and the formation of additional C–OH groups. The C/O ratio increased from ∼2.4 to 2.7, underscoring the reduction process and enhanced carbon content. This method proves to be an efficient approach for producing reduced graphene oxide (rGO) with improved properties for advanced applications.

Plasma sources sputtering nanoscale contaminants with low-energy ion flux on front-end mirrors in ITER optical diagnostics

New plasma sources are proposed to clean optical mirrors in diagnostic instruments of the ITER experiment considering RF discharges operating at low pressures (1–10 Pa) in inert gases. There are nearly twenty optical diagnostics where the front-end optical mirrors may require plasma cleaning. The mirrors vary in size and would need up to 400 W in the discharge to form ion fluxes capable of removing Be- and W-containing contaminants to restore the optical performance with tolerable damage to the mirror. The plasma sources suggested to clean contaminants include a vacuum matching circuit placed close to the mirror and a quarter wavelength band stop notch filter when mirror water cooling is needed. Long-term operation stability and cleaning homogeneity may employ a driving frequency variation to tune the circuit and a phase shift for RF voltages to clean two mirrors simultaneously. In this paper, the plasma sources based on 40 MHz RF discharge to clean first mirrors are studied experimentally for two ITER optical instruments: the Edge Thomson Scattering and the Visible Spectroscopy Reference System. Frequency tuning and phase shifting are studied in realistic configurations prototyping diagnostic port plug geometries.