Low-density Polyethylene Pellets Research Articles

The Use of Nonmetallic Fraction Particles with the Double Purpose of Increasing the Mechanical Properties of Low-Density Polyethylene Composite and Reducing the Pollution Associated with the Recycling of Metals from E-Waste

A restorative process, where the nonmetallic fraction from e-waste printed circuit boards is reused as a raw material for the conformation of a new polymer matrix composite with increased properties favoring its industrial applications, is proposed with a zero residues approach. Low density polyethylene pellets and nonmetallic fraction particles were mixed, and due to the generation of static electricity during the mixing process, the nonmetallic particles became attached to the polyethylene pellets; the blended material was fed into a screw extruder, producing filaments of the new composite. Mechanical properties increased as the particles content increased, presenting an ultimate tensile strength going from 20 for the raw low-density polyethylene to more than 60 MPa, and a yield strength that goes from 10 to 50 MPa on the composite with 6.0 wt.% particles. Also, the flammability of the composite improved, reducing its linear burning rate and increasing the time between detachment of two consecutive drops. Nonmetallic fraction particles were oriented in the extrusion direction and had a good adhesion with the polyethylene matrix. These composites can be employed for the production of prototypes using additive manufacture.

The tolerance of a keystone ecosystem engineer to extreme heat stress is hampered by microplastic leachates.

Plastic pollution and ongoing climatic changes exert considerable pressure on coastal ecosystems. Unravelling the combined effects of these two threats is essential to management and conservation actions to reduce the overall environmental risks. We assessed the capacity of a coastal ecosystem engineer, the blue mussel Mytilus edulis, to cope with various levels of aerial heat stress (20, 25, 30 and 35°C) after an exposure to substances leached from beached and virgin low-density polyethylene pellets. Our results revealed a significant interaction between temperature and plastic leachates on mussel survival rates. Specifically, microplastic leachates had no effect on mussel survival at 20, 25 and 30°C. In turn, mussel survival rates significantly decreased at 35°C, and this decrease was even more significant following an exposure to leachates from beached pellets; these pellets had a higher concentration of additives compared to the virgin ones, potentially causing a bioenergetic imbalance. Our results stress the importance of adopting integrated approaches combining the effects of multiple environmental threats on key marine species to understand and mitigate their potential synergistic effects on ecosystem dynamics and resilience in the face of the changing environment.

Polystyrene and low-density polyethylene pellets are less effective in arsenic adsorption than uncontaminated river sediment

The adsorption process of inorganic arsenic (As) plays an important role in its mobility, bioavailability, and toxicity in the river environment. In this work, the adsorption of dissolved arsenite (As(III)) and arsenate (As(V)) by microplastics (MPs) pellets (polystyrene (PS) and low-density polyethylene (LDPE)), river sediment, and their mixture were investigated to assess the adsorption affinities and mechanism. The adsorption kinetics showed slow and mild rising zones from the natural behavior of the chemical adsorption. The results indicated that both MP characteristics and water properties played a significant role in the adsorption behavior of inorganic As species. The As adsorption equilibrium was modeled well by both Langmuir and Freundlich isotherms and partly fitted with the Sips model suggesting that both mono-layer and multi-layer adsorption occurred during adsorption The spontaneous adsorption process for both As(III) and As(V) was evidenced by the adsorption thermodynamics. The maximum adsorption capacities of As(III) and As(V) reached 143.3 mg/kg and 109.8 mg/kg on PS in deionized water, which were higher than those on sediment-PS mixture (119.3 mg/kg, 99.2 mg/kg), which were all lower than on sediment alone (263.3 mg/kg, 398.7 mg/kg). The Fourier transform infrared spectroscopy analysis identified that As(III) and As(V) interaction with sediment surface functional groups was the main adsorption mechanism from surface complexation and coordination. Two functional groups of polystyrene (-NH2, -OH) were mainly involved in the adsorption of inorganic As species on PS, while -COO- and -OH functional groups contributed to the adsorption mechanism of inorganic As species on LDPE. The findings provide valuable insight on the adsorption behavior and mechanisms of As(III) and As(V) in river systems in the presence of MPs particles. Both PS and LDPE were shown to be less effective than river sediment in the adsorption of As species from water, which provides a different perspective in understanding the scale of MPs impact in pollutant transport in the aquatic environment.Graphical

Sustainable Filtering Systems to Reduce Microfiber Emissions from Textiles during Household Laundering.

During laundering, synthetic textiles (polyester, polyamide, etc.) can release small fiber debris with a length of <5 mm. These are a type of microplastics (MPs), usually referred to as microfibers (MFs), which are considered high-concern pollutants due to their continuous and cumulative entrance into the environment. Currently, as far as we know, there are no feasible alternatives to remove them. In this work, four new and sustainable filtering systems are proposed to retain the MFs emitted from domestic washing machines. The filters contain a replaceable cartridge partially filled with recycled low-density polyethylene pellets. The four designed filtering systems of different sizes were tested in a household washing machine determining the retention efficiency of the MFs after several washing cycles. It was found that all four assessed filter arrangements have a good performance for retaining MFs from the washers' effluents. Filter F1 (diameter of 4 cm and a height of 30 cm) started retaining more than 50% of the MFs, at the 10th washing cycle, the retention climbed to 66%, while in the 20th washing cycle, its retention was greater than 80%. MFs retention was higher for filter F2 (diameter of 6.3 cm and a height of 41 cm), achieving a performance greater than 90% in the 20th washing cycle. Filter F3 was arranged by turning the F1 model flow upside down and the retention efficiency is higher compared with filter F1 values, reaching a retention efficiency of almost 100% in the 15th washing cycle. Finally, filter F4 arrangement was developed using the existing washing machine filter, obtaining better performance than the F1 and F2 filters, reaching efficiencies higher than 90% at the 20th washing cycle. In summary, depending on the arrangement, the microfiber retention efficiency was estimated between 52% and 86% in the 1st washing cycle and up to 83% to 99% in the 20th. Additionally, all arrangements demonstrated that the cartridges may last for more than 30 washing cycles before needing to be replaced.

Insights into the mechanism of plastics’ fragmentation under abrasive mechanical forces: An implication for agricultural soil health

AbstractThe application of agricultural plastic products such as mulch, greenhouse covers, and silage films is increasing due to their economic benefits in providing an early and better‐quality harvest. However, mechanical abrasion of these plastic materials by soil particles could result in generation of microplastic (MP) pollutants that could harm soil organisms and impact food safety. This study aims to better understand the physicochemical mechanisms resulting in the fragmentation of low‐density polyethylene (LDPE). Herein, we used pellets and films to study the impacts of abrasive wear forces on their surface morphology variations and fragmentation behavior. An innovative laboratory approach was developed to abrade the plastic surface under controlled normal loadings and abrasion durations. The investigation of the plastics’ surface morphology variations due to the abrasion process revealed microcutting as the dominant process at low normal force (4 N). However, a combination of microploughing and microcutting occurred for new LDPE films by increasing the normal force to 8 N. Despite the significant surface morphology variations of the new LDPE film due to the abrasion process; the water contact angle did not alter. Furthermore, the fragmentation behavior of photodegraded LDPE pellets and films was compared to the new plastics. The extent of MPs (3 µm &lt; dp &lt; 162 µm) generation due to fragmentation was studied using fluorescence microscopy imaging. The localized stress and strains at the contact sites of plastic and sand particles resulted in abrasion of the plastic surface. According to the results, the normal loadings and duration of abrasion played a significant role in the degree of fragmentation of plastics. Increasing the normal loading applied during the abrasion process from 2 to 8 N linearly increased the number of generated plastic fragments by more than five times for pellets and more than three times for film. Photodegradation significantly enhanced the extent of MPs fragmentation. Moreover, the limitations of this study and the implications for agricultural soil health were discussed.

Pyrolysis of waste LDPE and waste PP plastics into fuel oil in a low-cost, lab-scale pyrolyzing unit

Plastics cause severe environmental and societal issues when post-consumer plastics are discarded in the environment without proper management. Pyrolysis of plastic waste is a promising method for plastic waste management due to its valuable by-products such as fuel oil. The objective of the present study was to pyrolysis waste polypropylene (PP) and waste low-density polyethylene (LDPE) plastics into fuel oil in a low-cost, lab-scale apparatus at the maximum temperatures of 330°C and 355°C, respectively, and in turn to assess the physical properties, gross calorific value, density, kinematic viscosity, flash point, ash content, and sulfur content, of resultant fuel oil. Commercially available, recycled grades of LDPE and PP pellets, 70.0 g of each, were obtained, and pyrolysis was done in a lab-scale, low-cost batch reactor. The experiment was triplicated, and the resultant fuel oil was analyzed for physical properties by ASTM standard methods. The properties of resultant fuel oil were also compared with diesel grade criteria. Results revealed that the highest yield of fuel oil was obtained from waste PP at 79.57 wt.% while the waste LDPE resulted at 74.06 wt.% of fuel oil. No wax formation was observed in the waste PP pyrolysis process, unlike in the waste LDPE pyrolysis. The gross calorific values of waste PP and waste LDPE were 12 016 kcal/kg and 11 961 kcal/kg, respectively. It was higher than the standard value of commercial diesel. The distillation results indicated that short-chain hydrocarbon content is higher in the waste PP fuel oil sample than in the waste LDPE fuel oil sample. The results indicated that the resultant fuel oil samples were nearly closer to the diesel grade criteria. Therefore, the fuel oil produced from waste plastics is a viable alternative to traditional fossil fuels, with potential applications in power generation and transportation.

Potential Adsorption Affinity of Estrogens on LDPE and PET Microplastics Exposed to Wastewater Treatment Plant Effluents.

Microplastics (MPs) are among the most common pollutants in the environment. Because of their small size, availability, and similarity to natural foods, they are commonly ingested by marine organisms. They can cause health problems in living organisms due to their bioaccumulation potential. It is, therefore, unknown whether endocrine-disrupting chemicals (EDCs), in particular estrogens, are capable of adhering to the diverse types of MPs found in water. Two MP polymers (low-density polyethylene (LDPE) and polyethene terephthalate (PET)) that could pose a threat to fish were tested for estrogen adsorption. The adsorption capacity of MP pellets was studied for 30 days in the effluent and influent of a wastewater treatment-plant. A laboratory simulation was conducted to validate the field and laboratory findings. We found that the concentrations of five types of estrogen ((diethylstilbestrol (DES), estrone (E1), 17β-estradiol (E2), estriol (E3), 17α-ethinyl estradiol (EE2)) were higher in the influent than the effluent streams. LDPE and PET MPs exposed to influent water in the laboratory had higher estrogen levels than wastewater treatment plants (WWTP) pellets. The PET pellets showed the highest adsorption affinity to EE2, while the LDPE pellets showed the highest affinity to E2. As a result, this study provided baseline data to investigate the estrogen adsorption capacity in MPs.

Laboratory investigation on the moisture susceptibility and fatigue resistance of hot mix asphalt modified with high- and low-density polyethylene plastic wastes

The demand for better management of plastic wastes all over the world is increasing. Polymers such as high-density polyethylene (HDPE) and low-density polyethylene (LDPE) are examples of these wastes. Studies showed that these could be used as polymer modifiers that could improve asphalt pavement performance. Although several studies had been conducted to evaluate the performance of asphalt mixtures with HDPE and LDPE, conflicting results had been seen. Additional research is still needed to find out the true effect of plastic on the performance of asphalt mixtures. Hence, this study assessed the performance of hot mix asphalt (HMA) modified with HDPE and LDPE pellets. The Marshall mix design was used to prepare, evaluate HMA mixtures and determine the optimum percentage of HDPE and LDPE that can be added to HMA. Moreover, wheel-tracking, and immersion-compression tests were used to evaluate rutting resistance and compressive strength of HMA mixtures, respectively. Results showed that the addition of 8% HDPE and 8% LDPE by weight of bitumen are the optimum contents. The performance of the HMA mixtures with HDPE and LDPE in terms of fatigue resistance and moisture susceptibility shows improved results. This proves the potential use of the materials as polymer modifiers in HMA. Moreover, HMA with HDPE when compared to the HMA with LDPE shows better results in reducing the moisture susceptibility and improving the fatigue resistance of HMA.

Studying the combined influence of microplastics’ intrinsic and extrinsic characteristics on their weathering behavior and heavy metal transport in storm runoff

The weathering and contaminant transport behavior of both primary (PMPs) and secondary microplastics (SMPs) are interrelated to their original physiochemical features and variations within the environment. This study examines the influence of PMPs' intrinsic characteristics (polymer structure and crystallinity) and SMPs' extrinsic features (surface oxidation and external sediments attachment) on the photodegradation kinetics, and subsequently Pb(II) and Zn(II) uptake from stormwater. For this purpose, high density polyethylene (HDPE) and low density polyethylene (LDPE) with different degrees of crystallinities were produced as PMPs, and their photodegradation behaviors were compared with original polymers. Furthermore, the SMPs generated by abrasion and surface oxidation of PMPs and the virgin PMPs underwent accelerated photodegradation, and the changes of their crystallinity, surface chemistry, and morphology were examined. Scanning electron microscopy (SEM) imaging and X-ray photoelectron (XPS) studies revealed the formation of cracks and different oxidized functionalities on MPs surface due to UV photodegradation. The vinyl and carbonyl indices calculated using Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) spectroscopy demonstrated an elevated photodegradation rate for SMPs compared to the PMPs. Moreover, the Differential Scanning Colorimetry (DSC) demonstrated an increasing percentage of crystallinity in all MPs due to the photodegradation. The percent crystallinity of HDPE pellets increased after photodegradation from 49.8 to 62.6 and it increased from 17.2 to 38.9 for LDPE pellets respectively. The greater level of increase in crystallinity for LDPE in comparison to HDPE upon photodegradation was referred to as LDPE's greater amorphous content and branched structure. A greater level of metal uptake was obtained for photodegraded LDPE pellets as 2526 μg/m2 for Pb(II) and 2028 μg/m2 for Zn(II) respectively.

Enhancing aromatics and olefins yields in thermo-catalytic pyrolysis of LDPE over zeolites: Role of staged catalysis and acid site density of HZSM-5

The present work deals with the thermo-catalytic pyrolysis of LDPE (low-density polyethylene) in lab-scale one- and two-stage test rigs over HZSM-5 catalysts featuring different acid site densities. In the first part of this work, the influence of catalyst-to-feed ratio and temperature (in conjunction with the acid site density of HZSM-5) on the product distribution was studied with an aim to identify the optimum operating conditions for the enhanced production of aromatics and light olefins. For this purpose, one-stage thermo-catalytic pyrolysis was performed in which catalysts were mixed with LDPE pellets for in-situ catalysis. In the one-stage catalytic pyrolysis, the catalyst sample with the highest acid site density gave the highest concentration of aromatics (ca. 55%) in the pyrolysis oil with a mono-aromatics fraction of over 50% that consisted mainly of BTEX (benzene, toluene, ethylbenzene and xylenes) compounds. The highest C2-C4 olefins concentration (ca. 65%) in the pyrolysis gas was obtained when the sample with the lowest acid site density was used. In the two-stage catalytic pyrolysis (ex-situ catalysis), the concentration of aromatics in the pyrolysis oil reached over 77% with a mono-aromatics fraction of ca. 72% that contained mainly BTEX compounds, when the most acidic catalyst was used. When the catalyst with the lowest number of strong acid sites was employed, the high content of C2-C4 olefins in the pyrolysis gas remained almost independent of the reactor configuration. These findings might provide important new insights for the chemical recycling of plastic wastes.

Recycling the low-density polyethylene pellets in the pervious concrete production

The main target of this study is to experimentally investigate the possibility of recycling of low-density polyethylene (LDPE) pellets as aggregate in pervious concrete manufacturing to achieve sustainable pervious concrete and contribute to plastic waste management. Therefore, two aggregate-to-cement ratios of 7 and 6 are chosen to produce two different pervious concrete series. Natural aggregate and LDPE pellets utilized in the production of pervious concrete are in a single size that remained on a 4.5-mm sieve and passed from 9.5-mm sieve. Natural aggregate was substituted with LDPE pellet at contents of 0, 10, 20, 30, 40, and 50% of total aggregate volume. Totally, 12 pervious concrete mixtures were designed. Basic engineering characteristics of pervious concrete were investigated in terms of permeability and compressive strength. Moreover, abrasion resistance and splitting tensile strength of concrete mixtures were also examined. Additionally, fresh/dry densities and void contents of produced pervious concrete mixtures were determined during the experimental study. The results showed that abrasion resistance of pervious concrete was enhanced by substituting natural aggregate with LDPE pellet whereas strength characteristics were adversely affected. In addition, reductions in fresh and dry densities, void content, and percolation rate of pervious concretes were observed due to the inclusion of the LDPE pellet.

Compressive Strength and Bulk Density of Concrete Hollow Blocks (CHB) Infused with Low-density Polyethylene (LDPE) Pellets

Infusing plastic waste to concrete and masonry structures is an increasingly common industry practice that has the potential to create an environment-friendly material that can improve some of the material’s properties, craft a novel means to repurpose plastic waste, and reduce the need for mining aggregates in the environment. This concept has been studied extensively in different forms of concrete, as shown by several studies; however, there is a dearth of studies focusing on the incorporation plastic waste in concrete hollow blocks (CHB). In this study, we aim to fill that gap by investigating on the effects of incorporating low-density polyethylene (LDPE), a commonly used plastic material, to CHB on its compressive strength and bulk density. Samples of varying percentages of LDPE replacement by volume (0, 10, 20, 30 and 40%) were fabricated and tested. Results showed a general trend of decreasing compressive strength and bulk density upon increasing the amount of LDPE pellets in CHB, which was also observed in previous studies. However, the compressive strength of CHB increased at 10% LDPE replacement, a result similar to a previous study. It was inferred that the strength of the plastic material could have a direct contribution to the compressive strength of CHB at low percentage of aggregate replacement. Statistical analysis showed that the mix with 10% LDPE pellets as replacement to sand was the best among the samples tested. It was shown that CHB infused with LDPE pellets has a higher compressive strength than what is normally used in the Philippines. It was concluded that based on compressive strength and bulk density, LDPE pellets is a viable material to use as partial replacement to sand in non-load bearing CHB.

Investigate the role of biofilm and water chemistry on lead deposition onto and release from polyethylene: An implication for potable water pipes

In this study, the influence of biofilm presence and water chemistry conditions on lead (Pb) deposition onto low density polyethylene (LDPE) surface was examined. The results demonstrated that biofilm presence on LDPE surfaces strongly and significantly enhanced Pb uptake, with the 13-fold greater equilibrium Pb surface loading when biofilm was present (1602 μg/m2) compared to the condition when it was absent (124 μg/m2). The kinetics of Pb adsorption onto LDPE surface when biofilm was present is best described by Pseudo 2nd order kinetic model. Pb adsorption onto new LDPE surfaces was significantly reduced from 1101 μg/m2 to 134 μg/m2 with increased aqueous solution’s ionic strength from 3 × 10−6 M to 0.0072 M. The presence of chlorine residual (2 mg/L) significantly reduced Pb adsorption onto LDPE surfaces by possible oxidation of Pb2+ to Pb4+ species. The kinetics of Pb release from LDPE surfaces was investigated under static and dynamic conditions through immediate exposure of Pb accumulated LDPE pellets to the synthetic water at pH 5.0 and 7.8. The results demonstrated a greater Pb release (86 %) at pH 5.0 compared to the pH 7.8 (58 %). An enhanced Pb release into the contact water was found under dynamic conditions compared to static conditions.

Development of a rapid micro-Raman spectroscopy approach for detection of NIAS in LDPE pellets and extruded films for food packaging applications

Identification and quantification of Non Intentionally Added Substances (NIAS) at low concentrations and eventually their distribution on Low Density Polyethylene (LDPE) films is an important issue. As Raman spectroscopy techniques are innovative and sensitive analytical methods and do not require pretreatment and manipulation of the sample, these were used for the identification of NIAS in LDPE pellet and films, which are commonly used for food packaging applications. The aggregation state of NIAS in LDPE were observed by Raman imaging with micrometric resolution. Four main NIAS compounds were identified in granule and film surfaces by confocal Raman spectroscopy: calcite (CaCO3), calcium sulphate (CaSO4), polystyrene (PS) and titanium dioxide (TiO2) in anatase form. By a semi-quantitative evaluation of the inorganic NIAS, 9.93 mg/kg of CaCO3, 1.62 mg/kg of CaSO4 and 0.17 mg/kg of TiO2 were estimated. The experimental findings achieved by Raman analysis were confirmed by the results obtained by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Moreover, the toxicity of the identified compounds was examined according to the Cramer rules.

Impact-Specific Essential Fracture Work of Banana Fiber Reinforced Low-Density Polyethylene Composites

The aim of this study is to investigate the behavior of banana fiber (BF)-low-density polyethylene (LDPE) composite fracture toughness. The LDPE pellets are transformed into powder form which is then functioned as a matrix reinforced with banana fiber (BF). The composites were formed by injection molding techniques which are followed by atmospheric-pressure annealing at 90°C for 24 hours. The composite fracture toughness behavior was evaluated using the essential work of fracture (EWF) approach. The results show that fracture toughness which is characterized by essential fracture work (we) value increases by the presence of BF up to 5 wt.%. However, the we value starts to decrease in the composite with BF content of 6 wt.%. There is a mismatch about the phenomenon of non-essential fracture work. Stress-whitened zones can be seen and observed but non-essential fracture work based on curves is a negative value.

Plastic waste management, a matter for the 'community'.

Plastic waste management, a matter for the 'community'.

INVESTIGATIONS ON THE CORN-STARCH MODIFIED LOW DENSITY POLYETHYLENE BLENDS

Investigations were carried out on the biodegradation properties of low-density polyethylene, modified with different concentrations by mass of corn-starch. Conventional Low-Density Polyethylene (LDPE) is widely used in all fields of life; therefore constitute the greatest municipal waste products, due to their inertness to biological attack, moisture, and weather conditions. Corn-starch which is a biofilter was characterized to ensure it’s suitability in the blending of synthetic plastics like LDPE. The percentage yield, moisture content, ash content, iodine test, etc were carried out on the extracted starch. The blended polyethylene sheets were injection molded at 150 0C after mixing 0, 2.50, 5.00, 7.50, 10.00, 12.50, and 15.00 wt. % by mass of the starch with a known weight of low-density polyethylene pellets. Mechanical tests and percentage weight-loss properties of the corn-starch modified low-density polyethylene were investigated before and after soil burial test. The evidence of biodegradation was exhibited on the reduced tensile strength, elongation at break, increased water absorption and other properties of the blended films as against the pure LDPE. Article DOI: http://dx.doi.org/10.20319/mijst.2016.21.0111 This work is licensed under the Creative Commons Attribution-Non-commercial 4.0 International License. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc/4.0/ or send a letter to Creative Commons, PO Box 1866, Mountain View, CA 94042, USA.

Photocatalytic Inactivation of Enterobacter cloacae and Escherichia coli Using Titanium Dioxide Supported on Two Substrates

The antibacterial photocatalytic activity of TiO2 supported over two types of substrates, borosilicate glass tubes (TiO2/SiO2-borosilicate glass tubes (BGT)) and low-density polyethylene pellets (TiO2-LDPE pellets), which were placed in a compound parabolic collectors (CPC) reactor, was evaluated against Enterobacter cloacae and Escherichia coli under sunlight. Three solar photocatalytic systems were assessed, suspended TiO2, TiO2/SiO2-BGT and TiO2-LDPE pellets, at three initial bacterial concentrations, 1 × 105; 1 × 103; 1 × 101 CFU/mL of E. coli and total bacteria (E. cloacae and E. coli). The solar photo-inactivation of E. coli was achieved after two hours with 7.2 kJ/L of UV-A, while total bacteria required four hours and 16.5 kJ/L of UV-A. Inactivation order of E. coli was determined, as follows, suspended TiO2/sunlight (50 mg/L) &gt; TiO2-LDPE pellets/sunlight (52 mg/L) &gt; TiO2/SiO2-BGT/sunlight (59 mg/L), the best E. coli. inactivation rate was obtained with TiO2-LDPE pellets/sunlight, within 4.5 kJ/L and 90 min. The highest total bacteria inactivation rate was found for TiO2/sunlight (50 mg/L) and TiO2-LDPE pellets/sunlight (52 mg/L), within 11.2 kJ/L and 180 min. TiO2 deposited over LDPE pellets was the most effective material, which can be successfully used for water disinfection applications. Bacterial regrowth was assessed 24 h after all photocatalytic treatments, none of those microorganisms showed any recovery above the detection limit (2 CFU/mL).

Investigation of the factors that influence lead accumulation onto polyethylene: Implication for potable water plumbing pipes

The influence of polymer aging, water pH, and aqueous Pb concentration on Pb deposition onto low density polyethylene (LDPE) was investigated. LDPE pellets were aged by ozonation at 85 °C. ATR-FTIR and X-ray photoelectron spectroscopy (XPS) analysis of aged LDPE surfaces showed that a variety of polar functional groups (>CO<, >CO, >COO) were formed during aging. These functional groups likely provided better nucleation sites for Pb(OH)2 deposition compared to new LDPE, which did not have these oxygen-containing functional groups. The type and amount of Pb species present on these surfaces were evaluated through XPS. The influence of exposure duration on Pb deposition onto LDPE was modeled using the pseudo-first-order equation. Distribution ratios of 251.5 for aged LDPE and 69.3 for new LDPE showed that Pb precipitates had greater affinity for the surface of aged LDPE compared to new LDPE. Aged LDPE had less Pb surface loading at pH 11 compared to loading at pH 7.8. Pb surface loading for aged LDPE changed linearly with aging duration (from 0.5–7.5 h). Pb surface loading on both new and aged LDPE increased linearly with increasing Pb initial concentration. Greater Pb precipitation rates were found for aged LDPE compared to new LDPE at both tested pH values.

DC Conductivity Measurements of LDPE: Influence of Specimen Preparation Method and Polymer Morphology

&lt;p&gt;DC conductivity measurements are important for gaining fundamental understanding of conduction mechanisms of insulation materials, as well as in the development of HVDC power system components, such as extruded cable systems. In this study, the influence of sample processing on the morphology and DC conductivity of low-density polyethylene (LDPE) has been studied. Direct compression moulding of LDPE pellets is commonly used in research laboratories for obtaining plaque samples, whereas extrusion is an additional commonly used technique for dispersion of particles in nanocomposites prior to the compression moulding process. In this study LDPE plaques have been obtained by either compression moulding directly from pellets, or by extrusion followed by compression moulding. The morphology obtained in the first case consisted of banded spherulites, whereas the latter method yielded a morphology of small axialites. The difference in sample processing had also an impact on the DC conductivity. The DC conductivity at 22 ­°C and 3.3 kV/mm was of the order of 4E-18 S/m for the plaques obtained by extrusion and compression moulding whereas the plaques obtained by direct compression moulding exhibited a conductivity of 1E-16 S/m. In addition, the reproducibility of the performed DC conductivity measurements was also verified in a round robin test performed between the Royal Institute of Technology and &lt;br /&gt;Chalmers Technical University.&lt;/p&gt;