Low-density Phase Research Articles

On the Nature of the C IV-bearing Circumgalactic Medium at z~1

This paper presents a detailed study of the physical properties of seven C IV absorbers identified at z_abs = 0.68-1.28 along the line of sight toward QSO PG 1522+101 (z_QSO = 1.330). The study leverages high-quality QSO spectra from HST COS and STIS, and Keck HIRES to resolve component structures and to constrain the gas density and elemental abundances of individual components. Under the assumption of photoionization equilibrium (PIE), five of the 12 C IV components require a mixture of high- and low-density phases to fully explain the observed relative abundances between low-, intermediate-, and high-ionization species. In addition, galaxy surveys carried out using VLT MUSE and Magellan LDSS3C are utilized to characterize the galaxy environments. The results of this analysis are summarized as follows: (1) no luminous galaxies (> 0.1 L*) are found within 100 kpc in projected distance from the C IV absorbers; (2) the C IV selection preferentially targets high-metallicity (near solar) and chemically-evolved gas (~ solar [C/O] elemental abundances) in galaxy halos; (3) the observed narrow line widths of individual C IV components, places a stringent limit on the gas temperature (< 5e4 K) and supports a photoionization origin; (4) additional local ionizing sources beyond the UV ionizing background may be necessary for at least one absorber based on the observed deficit of He I relative to H I; and (5) a PIE assumption may not apply when the gas metallicity exceeds the solar value and the component line width implies a warmer temperature than expected from PIE models.

Enhanced pozzolanic reactivity in hydrogen-form zeolites as supplementary cementitious materials

Pozzolans rich in silica and alumina react with lime to form cementing compounds and are incorporated into portland cement as supplementary cementitious materials (SCMs). However, pozzolanic reactions progress slower than portland cement hydration, limiting their use in modern construction due to insufficient early-age strength. Hence, alternative SCMs that enable faster pozzolanic reactions are necessary including synthetic zeolites, which have high surface areas and compositional purity that indicate the possibility of rapid pozzolanic reactivity. Synthetic zeolites with varying cation composition (Na-zeolite, H-zeolite), SiO2/Al2O3 ratio, and framework type were evaluated for pozzolanic reactivity via Ca(OH)2 consumption using ion exchange and in-situ X-ray diffraction experiments. Na-zeolites exhibited limited exchange reactions with KOH and Ca(OH)2 due to the occupancy of acid sites by Na+ and hydroxyl groups. Meanwhile, H-zeolites readily adsorbed K+ and Ca2+ from a hydroxide solution by exchanging cations with H+ at Brønsted acid sites or cation adsorption at vacant acid sites. By adsorbing cations, the H-zeolite reduced the pH and increased Ca2+ solubility to promote pozzolanic reactions in a system where Ca(OH)2 dissolution/diffusion was a rate limiting factor. High H-zeolite reactivity resulted in 0.8 g of Ca(OH)2 consumed per 1 g of zeolites after 16 h of reaction versus 0.4 g of Ca(OH)2 consumed per 1 g of Na-zeolite. The H-zeolite modulated the pore fluid alkalinity and created a low-density amorphous silicate phase via mechanisms analogous to two-step C-S-H nucleation experiments. Controlling these reaction mechanisms is key to developing next generation pozzolanic cementitious systems with comparable hydration rates to portland cement.

Application and mechanistic insights of a washing/microwave/ultrasonic ternary pretreatment for enhancing barite flotation in waste drilling fluids

A quantity of recoverable barite exists in high-density waste drilling fluid. Based on the inefficiencies and complexities of existing recycling methods, a novel pre-treatment approach which includes clean-breaking, high-speed washing, ultrasonic dispersion, and microwave heating and a new depressant (Gellan Gum) was proposed. The floatability, separation efficiency and mechanism were discussed by SEM, adsorption capacity, zeta potential measurements and contact angle tests. The results of reverse flotation experiments results indicated that secondary water washing proves highly effective in enriching a significant quantity of barite solid phase. Subsequent microwave-ultrasonic and flotation can obtain barite of high quality with recovery and density reaching 81.5% and 4.238 g/cm3, respectively. It can be utilized directly in the preparation of drilling fluid. Mechanism studies shown that the per-treatments substantially enhances the barite grade while effectively eliminating low-density solid phases adhering to the barite surface, thus exposing additional contact points between the constituents so as to improve flotation separation. This new recovery scheme has environmental advantages and great reference value for the separation of barite within high-density waste drilling fluids.

Generalized denoising network LGCT-Net for various types of ESPI wrapped phase patterns

In this paper, we propose a generalized network based on our proposed Local-Global Channel Transformer (LGCT) module for denoising various types of ESPI wrapped phase patterns (including low-density, medium-density, high-density, variable-density, and discontinuous phase patterns). The Conv + BN + ReLU layer consists of convolution (Conv), batch normalization (BN), and the rectified linear unit (Relu) in series. The generalized network LGCT-Net interleaves four LGCT modules with five Conv + BN + ReLU layers in a dense connection manner. We propose the LGCT Module by stacking three Dilated-Group Convolution blocks (DGC block), a Contextual Transformer block (CoT block), and an Efficient Channel Attention block (ECA block). The LGCT module simultaneously leverages the local context extraction capability of convolutions and the powerful global information extraction capability of a transformer. Additionally, it performs feature extraction in both spatial and channel dimensions. We also create a diverse ESPI wrapped phase pattern denoising dataset with various densities, shapes, noise levels, and discontinuity. We successfully train the LGCT-Net without any preprocessing or postprocessing steps. We evaluate the performance of our method on simulated and experimental ESPI wrapped phase patterns with discontinuity and different densities. Then we compare it with previously published denoising methods PEARLS, HDCNN, ADCNN, and DBDNet quantitatively and qualitatively. The results show that our method facilitates the reduction of speckle noise and the enhancement of fine details while preserving structure and shape, outperforming the compared methods. In the end, we apply our method to dynamic measurements of nuclear graphite ESPI phase patterns at different times. And then performing phase unwrapping on the filtered phase patterns, we achieve successful results.

Evidence of ferroelectric features in low-density supercooled water from ab initio deep neural-network simulations

Over the last decade, an increasing body of evidence has emerged, supporting the existence of a metastable liquid-liquid critical point in supercooled water whereby two distinct liquid phases of different densities coexist. Analyzing long molecular dynamics simulations performed using deep neural-network force fields trained to accurate quantum mechanical data, we demonstrate that the low-density liquid phase displays a strong propensity toward spontaneous polarization, as witnessed by large and long-lived collective dipole fluctuations. Our findings suggest that the dynamical stability of the low-density phase, and hence the transition from high-density to low-density liquid, is triggered by a collective process involving an accumulation of rotational angular jumps, which could ignite large dipole fluctuations. This dynamical transition involves subtle changes in the electronic polarizability of water molecules which affects their rotational mobility within the two phases. These findings hold the potential for catalyzing activity in the search for dielectric-based probes of the putative second critical point.

Tailoring the Molecular Structure of 6-Gingerol for Targeting the Phase Separation in Human Lysozyme.

Human lysozyme undergoes a phase-separation process to form insoluble amyloid-architects that cause several pathologies including systemic amyloidosis. Here we have tailored 6-gingerol by extending its molecular framework with active functional groups to specifically target lysozyme phase-transition events. Aggregation assay revealed that tailored 6-gingerol with 4-aromatic moieties (MTV4) substantially suppressed the conversion of the lysozyme low-density liquid phase (LDLP) to solid-phase structured amyloids. The data obtained from biophysical, computational, and microscopic imaging tools suggest direct intervention of MTV4 with the liquid-liquid phase separation. The CD data suggest that MTV4 was able to retain the native conformation of lysozyme. Both biomolecular and computational data reveal the interference of MTV4 with the aggregation-prone hydrophobic stretches within the lysozyme, thereby retaining the native structure and reversing the misfolded intermediates to active monomers. Also, MTV4 was able to induce rapid dissolution of preformed-toxic amyloid fibrils. These results reinforce the importance of the aromatic-aromatic interaction in preventing human lysozyme phase separation.

Sequence dependence of critical properties for two-letter chains.

Histogram-reweighting grand canonical Monte Carlo simulations are used to obtain the critical properties of lattice chains composed of solvophilic and solvophobic monomers. The model is a modification of one proposed by Larson et al. [J. Chem. Phys. 83, 2411 (1985)], lowering the "contrast" between beads of different types to prevent aggregation into finite-size micelles that would mask true phase separation between bulk high- and low-density phases. Oligomeric chains of lengths between 5 and 24 beads are studied. Mixed-field finite-size scaling methods are used to obtain the critical properties with typical relative accuracies of better than 10-4 for the critical temperature and 10-3 for the critical volume fraction. Diblock chains are found to have lower critical temperatures and volume fractions relative to the corresponding homopolymers. The addition of solvophilic blocks of increasing length to a fixed-length solvophobic segment results in a decrease of both the critical temperature and the critical volume fraction, with an eventual slow asymptotic approach to the long-chain limiting behavior. Moving a single solvophobic or solvophilic bead along a chain leads to a minimum or maximum in the critical temperature, with no change in the critical volume fraction. Chains of identical length and composition have a significant spread in their critical properties, depending on their precise sequence. The present study has implications for understanding biomolecular phase separation and for developing design rules for synthetic polymers with specific phase separation properties. It also provides data potentially useful for the further development of theoretical models for polymer and surfactant phase behavior.

Influence mechanism of hydrocyclone main diameter on separation performance

The main diameter of hydrocyclone (HC) has significant effects on separation performance. However, the differences of flow field characteristics within different HCs have not been understood well yet, which makes it impossible to grasp the influence mechanism of the main diameter on the separation performance. Through the study of the migration trajectories of particles, it is found that the greater the diameter and the finer the particles, the more particles escape from the overflow outlet. The relationships between the longest residence time and the HC main diameter for particles with 10 and 15 μm were, respectively, clarified. The high-speed video and particle image velocimetry experiments were performed and found although the main diameter of a large-HC (LHC) is twice that of a mini-HC (MHC), its air-core diameter is much larger than twice that of MHC, which is not beneficial for separations. The axial velocity around the central axis area in LHC is higher than that of the MHC, which helps separate low-density discrete phases from the overflow outlet at a faster speed but not for the separations of high-density discrete phases from the underflow outlet. The angle of the locus of zero vertical velocity in MHC is larger than that of LHC, which is anticipated to enhance the separation efficiency for the high-density discrete phase. This study first reveals the influence mechanism of the HC main diameter on its separation performance from the perspective of the flow field characteristics, which would hopefully provide significant references for the applications of HCs.

Low density phases of TiO2 by cluster self-assembly

The interest in titanium dioxide (TiO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}) phases is growing due to the number of applications in cosmetics, food industry and photocatalysis, an increase that is driven by its exceptional properties when engineered at the nanoscale like in the form of nanoparticles. Our goal is to discover unknown low-density phases of TiO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}, with potential for applications in various fields. We then use well-known TiO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document} clusters as fundamental building blocks to be self-assembled into unique structures to study their distinct characteristics. Density functional calculations are employed to relax the structures and identify the most stable TiO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document} structures within an energy range of 0.1 eV per atom from the rutile and anatase phases, which are confirmed, validating our methodology. Going beyond conventional phases, we found two-dimensional TiO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document} structures, previously explored in separate studies, and showing typical structures of transition metal dichalcogenide layers, that forge a bridge between different TiO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document} structures. It is noteworthy that our investigation uncovered an entirely novel class of TiO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document} structures featuring hexagonal cages like beehive channels, opening novel phases with huge potential. These discovered low-density phases are interesting, particularly the hexagonal cage structures with remarkable large gaps, because they introduce other dimensions for uncharted applications in the ever-growing TiO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document} landscape.

Askey–Wilson Signed Measures and Open ASEP in the Shock Region

Abstract We introduce a family of multi-dimensional Askey–Wilson signed measures. We offer an explicit description of the stationary measure of the open asymmetric simple exclusion process (ASEP) in the full phase diagram, in terms of integrations with respect to these Askey–Wilson signed measures. Using our description, we provide a rigorous derivation of the density profile and limit fluctuations of open ASEP in the entire shock region, including the high and low density phases as well as the coexistence line. This in particular confirms the existing physics postulations of the density profile.

Traveling fronts in vibrated polar disks: At the crossroad between polar ordering and jamming.

We investigate experimentally the collective motion of polar vibrated disks in an annular geometry, varying both the packing fraction and the amplitude of the angular noise. For low enough noise and large enough density, an overall collective motion takes place along the tangential direction. The spatial organization of the flow reveals the presence of polar bands of large density, as expected from the commonly accepted picture of the transition to collective motion in systems of aligning polar active particles. However, in our case, the low density phase is also polar, consistent with what is observed when jamming takes place in a very high density flock. Interestingly, while in that case the particles in the high density bands are arrested, resulting in an upstream propagation at a constant speed, in our case the bands travel downstream with a density-dependent speed. We demonstrate from local measurements of the packing fraction, alignment, and flow speeds that the bands observed here result both from a polar ordering process and a motility induced phase separation mechanism.

Mixing times and cutoff for the TASEP in the high and low density phase

Mixing times and cutoff for the TASEP in the high and low density phase

Liquid-liquid transition in a simple model fluid with competitive interactions

The possible existence of low-density and high-density fluid phase equilibria in fluids with a simple potential consisting in a combination of a square shoulder and a square well is explored by means of perturbation theory and histogram-reweighting grand canonical Monte Carlo simulation. Theory is useful as a simple and computationally inexpensive way to explore large sets of potential parameters to search for potential shapes susceptible to present multiple fluid phases, later confirmed or discarded from computer simulation. It is found that some combinations of the length and energy parameters of the potential actually give rise to such behaviour.

Structure and equation of state of Ti-bearing davemaoite: new insights into the chemical heterogeneity in the lower mantle

Abstract Davemaoite (CaSiO3 perovskite) is considered the third most abundant phase in the pyrolytic lower mantle and the second most abundant phase in the subducted mid-ocean ridge basalt (MORB). During the partial melting of the pyrolytic upper mantle, incompatible titanium (Ti) becomes enriched in the basaltic magma, forming Ti-rich MORB. Davemaoite is considered an important Ti-bearing mineral in subducted slabs by forming a Ca(Si,Ti)O3 solid solution. However, the crystal structure and compressibility of Ca(Si,Ti)O3 perovskite solid solution at relevant pressure and temperature conditions were not systematically investigated. In this study, we investigated the structure and equations of state of Ca(Si0.83Ti0.17)O3 and Ca(Si0.75Ti0.25)O3 perovskites at room temperature up to 82 GPa and 64 GPa, respectively, by synchrotron X-ray diffraction (XRD). We found that both Ca(Si0.83Ti0.17)O3 and Ca(Si0.75Ti0.25)O3 perovskites have a tetragonal structure up to the maximum pressures investigated. Based on the observed data and compared to pure CaSiO3 davemaoite, both Ca(Si0.83Ti0.17)O3 and Ca(Si0.75Ti0.25)O3 perovskites are expected to be less dense up to the core-mantle boundary (CMB), and specifically ~1-2 % less dense than CaSiO3 davemaoite in the pressure range of the transition zone (15-25 GPa). Our results suggest that the presence of Ti-bearing davemaoite phases may result in a reduction in the average density of the subducting slabs, which in turn promotes their stagnation in the lower mantle. The presence of low-density Ti-bearing davemaoite phases and subduction of MORB in the lower mantle may also explain the seismic heterogeneity in the lower mantle, such as large low shear velocity provinces (LLSVPs).

Impact of LuxS on virulence and pathogenicity in Klebsiella pneumoniae exhibiting varied mucoid phenotypes.

How the LuxS/AI-2 quorum sensing (QS) system influences the pathogenicity of K. pneumoniae is complicated by the heterogeneity of the bacterial mucoid phenotypes. This study aims to explore the LuxS-mediated regulation of the pathogenicity of K. pneumoniae with diverse mucoid phenotypes, including hypermucoid, regular-mucoid, and nonmucoid. The wild-type, luxS knockout, and complemented strains of three K. pneumoniae clinical isolates with distinct mucoid phenotypes were constructed. The results revealed the downregulation of virulence genes of regular-mucoid, and nonmucoid but not hypermucoid strains. The deletion of luxS reduced the pathogenicity of the regular-mucoid, and nonmucoid strains in mice; while in hypermucoid strain, luxS knockout reduced virulence in late growth but enhanced virulence in the early growth phase. Furthermore, the absence of luxS led the regular-mucoid and nonmucoid strains to be more sensitive to the host cell defense, and less biofilm-productive than the wild-type at both the low and high-density growth state. Nevertheless, luxS knockout enhanced the resistances to adhesion and phagocytosis by macrophage as well as serum-killing, of hypermucoid K. pneumoniae at its early low-density growth state, while it was opposite to those in its late high-density growth phase. Collectively, our results suggested that LuxS plays a crucial role in the pathogenicity of K. pneumoniae, and it is highly relevant to the mucoid phenotypes and growth phases of the strains. LuxS probably depresses the capsule in the early low-density phase and promotes the capsule, biofilm, and pathogenicity during the late high-density phase, but inhibits lipopolysaccharide throughout the growth phase, in K. pneumoniae.IMPORTANCECharacterizing the regulation of physiological functions by the LuxS/AI-2 quorum sensing (QS) system in Klebsiella pneumoniae strains will improve our understanding of this important pathogen. The genetic heterogeneity of K. pneumoniae isolates complicates our understanding of its pathogenicity, and the association of LuxS with bacterial pathogenicity has remained poorly addressed in K. pneumoniae. Our results demonstrated strain and growth phase-dependent variation in the contributions of LuxS to the virulence and pathogenicity of K. pneumoniae. Our findings provide new insights into the important contribution of the LuxS/AI-2 QS system to the networks that regulate the pathogenicity of K. pneumoniae. Our study will facilitate our understanding of the regulatory mechanisms of LuxS/AI-2 QS on the pathogenicity of K. pneumoniae under the background of their genetic heterogeneity and help develop new strategies for diminished bacterial virulence within the clinical K. pneumoniae population.

Hybrid stars and the stiffness of the nuclear equation of state in light of the HESS J1731-347 remnant

The recent observation of the extremely compact neutron star in the HESS J1731-347 remnant has challenged our understanding concerning the nature of dense nuclear matter. In particular, the low radius of the aforementioned compact object favors soft nuclear equations of state. However, the neutron skin thickness of 208Pb extracted from the long-awaited PREX-II experiment favors stiff equations of state which may be associated with larger radii for low mass stellar configurations. In this contribution we present our recent work on the possible reconciliation of the HESS J1731-347 observation in the framework of hybrid stars, under the assumption of a stiff low-density phase which may be favored by the PREX-II results. In addition, we examine the compatibility of the resulting hybrid models with recent constraints based on the observation of PSR J0030+0451, PSR J0952-0607 and GW190814.

Coexistence of two coacervate phases of polyglycine in water suggested by polymer reference interaction site model theory.

Mixing Gibbs energy and phase equilibria of aqueous solutions of polyglycine were studied theoretically by means of polymer reference interaction site model integral equation theory combined with the Gibbs-Duhem method. In addition to the ordinary liquid-liquid phase separation between dilute and concentrated solutions, the theoretical calculation predicted the coexistence of two coacervate phases, namely, the lower- and higher-density coacervates. The relative thermodynamic stabilities of these two phases change with the polymerization degree of polyglycine. The higher-density coacervate phase was rapidly stabilized by increasing the polymer length, and the lower-density phase became metastable at large polymers. The hydrogen bonds between the peptide chains were strengthened, and water was thermodynamically destabilized in the higher-density coacervate. A possible relation with the formation of amyloid fibril within a liquid droplet is also discussed.

How observations from automatic hail sensors in Switzerland shed light on local hailfall duration and compare with hailpad measurements

Abstract. Measuring the properties of hailstorms is a difficult task due to the rarity and mainly small spatial extent of the events. Especially, hail observations from ground-based time-recording instruments are scarce. We present the first study of extended field observations made by a network of 80 automatic hail sensors from Switzerland. The main benefits of the sensors are the live recording of the hailstone kinetic energy and the precise timing of the impacts. Its potential limitations include a diameter-dependent dead time, which results in less than 5 % of missed impacts, and the possible recording of impacts that are not due to hail, which can be filtered using a radar reflectivity filter. We assess the robustness of the sensors' measurements by doing a statistical comparison of the sensor observations with hailpad observations, and we show that, despite their different measurement approaches, both devices measure the same hail size distributions. We then use the timing information to measure the local duration of hail events, the cumulative time distribution of impacts, and the time of the largest hailstone during a hail event. We find that 75 % of local hailfalls last just a few minutes (from less than 4.4 min to less than 7.7 min, depending on a parameter to delineate the events) and that 75 % of the impacts occur in less than 3.3 min to less than 4.7 min. This time distribution suggests that most hailstones, including the largest, fall during a first phase of high hailstone density, while a few remaining and smaller hailstones fall in a second low-density phase.

Detectability of a phase transition in neutron star matter with third-generation gravitational wave interferometers

ABSTRACT Possible strong first-order hadron-quark phase transitions in neutron star interiors leave an imprint on gravitational waves, which could be detected with planned third-generation interferometers. Given a signal from the late inspiral of a binary neutron star (BNS) coalescence, assessing the presence of such a phase transition depends on the precision that can be attained in the determination of the tidal deformability parameter, as well as on the model used to describe the hybrid star equation of state. For the latter, we employ here a phenomenological meta-modelling of the equation of state that largely spans the parameter space associated with both the low-density phase and the quark high density compatible with current constraints. We show that with a network of third-generation detectors, a single loud BNS event might be sufficient to infer the presence of a phase transition at low baryon densities with an average Bayes factor B ≈ 100, up to a luminosity distance ($\mathcal {D}_\mathrm{ L} \lesssim$ 300 Mpc).

Tidal deformability doppelgänger: Implications of a low-density phase transition in the neutron star equation of state

Tidal deformability doppelgänger: Implications of a low-density phase transition in the neutron star equation of state