Loss Of Orientational Order Research Articles

Melting of a confined monolayer of magnetized beads

We present an experimental model system to study two-dimensional phase transitions. This system is composed of a monolayer of millimetric beads interacting through shor range magnetic dipole-dipole interactions. As the system is athermal, a mechanical agitation is used to produce an erratic motion of the beads. The two-dimensional melting scenario predicted by the Kosterlitz-Thouless-Halperin-Nelson-Young theory is observed. Each phase (liquid-hexatic-solid) has been highlighted with the use of both static and dynamic order parameters. Translational and orientational order are, respectively, estimated through the pair correlation function g(r) and both orientational correlation function g(6)(r) and its temporal counterpart g(6)(t). We observe two transitions by tuning the applied magnetic field H. First, a loss of translational order without loss of orientational order is observed. This is the signature of the transition from the solid phase to the so-called "hexatic" phase. Finally, the orientational order disappears, leading to a liquidlike structure.

Molecular Orientation, Aggregation, and Order in Rhodamine Films at the Fused Silica/Air Interface

We report optical second harmonic generation studies of the organic dye molecule rhodamine 6G spin cast on fused silica surfaces. The concentration dependence of the second harmonic response demonstrates oscillatory behavior with a period corresponding to the concentration required for monolayer surface coverage. This behavior reflects the formation of ordered molecular adlayers which persist for approximately five periods. Polarized SHG studies confirm orientational anisotropy of the dye molecules and allow the orientation within adjacent layers to be determined. Optical absorbance measurements of the films indicate the onset of rhodamine 6G aggregate formation at surface coverages of approximately one monolayer. However, the onset of dimer or aggregate fluorescence is observed to occur only at much higher surface coverages, consistent with the loss of orientational order within the adlayers. Our results indicate strong adsorbate−substrate interaction which gives rise to orientational anisotropy within t...