Gas Loss Research Articles

Characteristics of Combustion and NOx Emission in a 600 MWe Wall-Fired Boiler Under Varying Coal Mill and Burner Damper Configurations

ABSTRACT To accelerate China’s transition toward providing capacity support and prioritizing electricity generation, detailed research is necessary regarding the continuous peak output of coal-fired boilers during peak periods. However, high-load operation of coal-fired boilers may lead to issues such as NOx emission and increased flue gas temperature. This study conducted industrial experiments on a 600 MWe wall-fired boiler operating under peak conditions (500 MWe), using different pulverized coal mill operating modes. The boiler was optimized by adjusting the damper openings of the burners. Experimental results showed coal powder ignited within 0.2 m of burner outlets, indicating good performance. With the reduction in the damper openings of the burners, the concentration of NOx decreased, and the flue gas temperature gradually dropped, with the maximum temperature differential being 179°C. The ABCEF pulverized coal mill case had high water consumption and flue gas loss, unfavorably affecting economic operation. The ABDEF case delayed temperatures by 100°C, with the lowest NOx concentration at 277 ppm, enhancing environmental friendliness. In addition, the ABCDE case exhibited optimal coal burnout, with 0.838% fly ash carbon content, and the lowest flue gas temperature at 111.49°C, reducing flue gas loss by 5.9% compared to the ABDEF case, showing good economic performance.

Reduction in Ammonia Volatilization from Pig Slurry Using Acidic Mechanisms

ABSTRACT Pig slurry can be used as an alternative source for nutrients, particularly nitrogen (N), for plants. However, after applying the pig slurry to the soil, gaseous loss of N this nutrient may occur, mainly in the form of ammonia. Hence this study aimed to evaluate the loss of N by volatilization after the application of pig slurry with an acidified pH. Ammonia volatilization was evaluated using pig slurry, with its pH modified to 5.0 using four acids (sulfuric acid, citric acid, ascorbic acid, and acetic acid). Additionally, pig slurry with natural pH and a control were also used. The work was conducted in a greenhouse, and collectors were used to capture the volatilized ammonia in a static free semi-open chamber. The application of pig slurry with natural pH (7.19) resulted in 61% loss of ammonia, whereas acidification with ascorbic acid (pH 5.0) caused a loss of only 26%. The application of pig slurry with pH above 7.0 caused N loss, indicating that using acids to maintain a pH of 5.0–6.0 could be an alternative to reduce N loss by ammonia volatilization.

Sunyaev–Zeldovich Signals from L* Galaxies: Observations, Analytics, and Simulations

We analyze measurements of the thermal Sunyaev–Zeldovich (tSZ) effect arising in the circumgalactic medium (CGM) of L* galaxies, reported by J. N. Bregman et al. (B+22) and S. Das et al. (D+23). In our analysis, we use the Y. Faerman et al. CGM models, a new power-law model (PLM), and the TNG100 simulation. For a given M vir, our PLM has four parameters: the fraction, f hCGM, of the halo baryon mass in hot CGM gas, the ratio, ϕ T , of the actual gas temperature at the virial radius to the virial temperature, and the power-law indices, a P,th and a n for the thermal electron pressure and the hydrogen nucleon density. The B+22 Compton-y profile implies steep electron pressure slopes (a P,th ≃ 2). For isothermal conditions, the temperature is at least 1.1 × 106 K, with a hot CGM gas mass of up to 3.5 × 1011 M ⊙ for a virial mass of 2.75 × 1012 M ⊙. However, if isothermal, the gas must be expanding out of the halos. An isentropic equation of state is favored for which hydrostatic equilibrium is possible. The B+22 and D+23 results are consistent with each other and with recent (0.5–2 keV) CGM X-ray observations of Milky Way mass systems. For M vir ≃ 3 × 1012 M ⊙, the scaled Compton pressure integrals, E(z)−2/3Y500/Mvir,125/3 , lie in the narrow range, 2.5 × 10−4–5.0 × 10−4 kpc2, for all three sets of observations. TNG100 underpredicts the tSZ parameters by factors ∼0.5 dex for the L* galaxies, suggesting that the feedback strengths and CGM gas losses are overestimated in the simulated halos at these mass scales.

Spatial-temporal patterns of foliar and bulk soil 15N isotopic signatures across a heterogeneous landscape: Linkages to soil N status, nitrate leaching, and N2O fluxes

The natural abundance of plant and bulk soil 15N isotopic signatures provides valuable insights into the magnitude of nitrogen cycling and loss processes within terrestrial ecosystems. However, 15N isotopic signatures are highly variable in space due to natural and anthropogenic factors affecting N cycling processes and losses. To date, most studies on foliar and bulk soil 15N isotopic signatures have focused on N-limited forest ecosystems at relatively large spatial scales, while similar studies in N-enriched ecosystems at finer spatial scales are lacking. To address this gap and evaluate links between soil 15N isotopic signatures and ecosystem N cycling and loss processes (plant N uptake, N leaching, and gaseous loss), this study quantified foliar and bulk soil 15N isotopic signatures, soil physicochemical parameters, gaseous (N2O), and hydrological (NO3) N losses at 80 sites distributed across a heterogeneous landscape (∼5.8 km2). To account for the spatial-temporal heterogeneity, the measurements were performed in four campaigns (March, June, September 2022, and March 2023) at sites that considered different land uses, soil types, and topography. Results indicated that foliar and bulk soil 15N isotopic signatures were significantly (P < 0.05) more enriched in arable and grassland ecosystems than forests, suggesting a more open N cycle with significant N cycling and losses due to higher N inputs from fertilizers. Similar to soil inorganic N, N2O fluxes, and NO3 leaching rates, landscape-scale foliar and soil 15N isotopic signatures varied widely spatially, particularly at grassland and arable land (−3 to 9.0‰), with bivariate and multivariate analyses also showing significant relationships between landscape-scale soil 15N isotopic signatures and the aforementioned parameters (r2: 0.29 to 0.82). Based on these relationships, our findings suggested that foliar and bulk 15N isotopic signatures may capture fine-scale areas with persistently high and low environmental N losses (N2O fluxes and NO3 leaching) within a heterogeneous landscape.

Elemental Abundances in And XIX from Coadded Spectra

With a luminosity similar to that of Milky Way dwarf spheroidal systems like Sextans, but a spatial extent similar to that of ultra-diffuse galaxies, Andromeda (And) XIX is an unusual satellite of M31. To investigate the origin of this galaxy, we measure chemical abundances for And XIX derived from medium-resolution (R ∼ 6000) spectra from the Deep Extragalactic Imaging Multi-Object Spectrograph on the Keck II telescope. We coadd 79 red giant branch stars, grouped by photometric metallicity, in order to obtain a sufficiently high signal-to-noise ratio to measure 20 [Fe/H] and [α/Fe] abundances via spectral synthesis. The latter are the first such measurements for And XIX. The mean metallicity we derive for And XIX places it ∼2σ higher than the present-day stellar mass–metallicity relation for Local Group dwarf galaxies, potentially indicating it has experienced tidal stripping. A loss of gas and associated quenching during such a process, which prevents the extended star formation necessary to produce shallow [α/Fe]–[Fe/H] gradients in massive systems, is also consistent with the steeply decreasing [α/Fe]–[Fe/H] trend we observe. In combination with the diffuse structure and disturbed kinematic properties of And XIX, this suggests tidal interactions, rather than galaxy mergers, are strong contenders for its formation.

Thermal regime of High Arctic tundra ponds, Nanuit Itillinga (Polar Bear Pass), Nunavut, Canada

Abstract. This study evaluates the seasonal and inter-seasonal temperature regime of small tundra ponds ubiquitous to an extensive, low-gradient wetland in the Canadian High Arctic. Pond temperatures can modify evaporation and ground thaw rates, impact losses of greenhouse gases, and control the timing and emergence of insects and larvae critical for migratory-bird feeding habits. We focus our study on thaw ponds with a range of hydrologic linkages and sizes across Nanuit Itillinga, formerly known as Polar Bear Pass (PBP), Bathurst Island, and compare their thermal signals to other Arctic ponds. Pond temperatures and water levels were evaluated using temperature and water level loggers and verified by regular manual measurements. Other environmental data collected included microclimate, frost table depths, and water conductivity. Our results show that there is much variability in pond thermal regimes over seasons, years, and space. Cumulative relative pond temperatures were similar across years, with ponds normally reaching 10–15 °C for short to longer periods, except in 2013, which experienced a cold summer season during which pond temperatures never exceeded 5 °C. Pond frost tables and water conductivities respond to variable substrate conditions and pond thermal patterns. This study contributes to the ongoing discussion on climate warming and its impact on Arctic landscapes.

Estimating Total Methane Emissions from the Denver-Julesburg Basin Using Bottom-Up Approaches

Methane is a powerful greenhouse gas with a 25 times higher 100-year warming potential than carbon dioxide and is a target for mitigation to achieve climate goals. To control and curb methane emissions, estimates are required from the sources and sectors which are typically generated using bottom-up methods. However, recent studies have shown that national and international bottom-up approaches can significantly underestimate emissions. In this study, we present three bottom-up approaches used to estimate methane emissions from all emission sectors in the Denver-Julesburg basin, CO, USA. Our data show emissions generated from all three methods are lower than historic measurements. A Tier 1/2 approach using IPCC emission factors estimated 2022 methane emissions of 358 Gg (0.8% of produced methane lost by the energy sector), while a Tier 3 EPA-based approach estimated emissions of 269 Gg (0.2%). Using emission factors informed by contemporary and region-specific measurement studies, emissions of 212 Gg (0.2%) were calculated. The largest difference in emissions estimates were a result of using the Mechanistic Air Emissions Simulator (MAES) for the production and transport of oil and gas in the DJ basin. The MAES accounts for changes to regulatory practice in the DJ basin, which include comprehensive requirements for compressors, pneumatics, equipment leaks, and fugitive emissions, which were implemented to reduce emissions starting in 2014. The measurement revealed that normalized gas loss is predicted to have been reduced by a factor of 20 when compared to 10-year-old normalization loss measurements and a factor of 10 less than a nearby oil and production area (Delaware basin, TX); however, we suggest that more measurements should be made to ensure that the long-tail emission distribution has been captured by the modeling. This study suggests that regulations implemented by the Colorado Department of Public Health and Environment could have reduced emissions by a factor of 20, but contemporary regional measurements should be made to ensure these bottom-up calculations are realistic.

Subsurface Drainage and Nitrogen Fertilizer Management Affect Fertilizer Fate in Claypan Soils

Sustainable nitrogen (N) fertilizer management practices in the Midwest U.S. strive to optimize crop production while minimizing N gas emission losses and nitrate-N (NO3-N) losses in subsurface drainage water. A replicated site in upstate Missouri from 2018 to 2020 investigated the influence of different N fertilizer management practices on nutrient concentrations in drainage water, nitrous oxide (N2O) emissions, and ammonia (NH3) volatilization losses in a corn (Zea mays, 2018, 2020)–soybean (Glyince max, 2019) rotation. Four N treatments applied to corn included fall anhydrous ammonia with nitrapyrin (fall AA + NI), spring anhydrous ammonia (spring AA), top dressed SuperU and ESN as a 25:75% granular blend (TD urea), and non-treated control (NTC). All treatments were applied to subsurface-drained (SD) and non-drained (ND) replicated plots, except TD urea, which was only applied with SD. Across the years, NO3-N concentration in subsurface drainage water was similar for fall AA + NI and spring AA treatments. The NO3-N concentration in subsurface drainage water was statistically (p &lt; 0.0001) lower with TD urea (9.1 mg L−1) and NTC (8.9 mg L−1) compared to fall AA + NI (14.6 mg L−1) and spring AA (13.8 mg L−1) in corn growing years. During corn years (2018 and 2020), cumulative N2O emissions were significantly (p &lt; 0.05) higher with spring AA compared to other fertilizer treatments with SD and ND. Reduced corn growth and plant N uptake in 2018 caused greater N2O loss with TD urea and spring AA compared to the NTC and fall AA + NI in 2019. Cumulative NH3 volatilization was ranked as TD urea &gt; spring AA &gt; fall AA + NI. Due to seasonal variability in soil moisture and temperature, gas losses were higher in 2018 compared to 2020. There were no environmental benefits to applying AA in the spring compared to AA + NI in the fall on claypan soils. Fall AA with a nitrification inhibitor is a viable alternative to spring AA, which maintains flexible N application timings for farmers.

Natural gas pipeline leak diagnosis based on manifold learning

Natural gas pipeline leakage is a common safety hazard, which can have a great impact on the economy and the environment. This paper proposed a novel manifold learning-enabled feature extraction method for natural gas pipeline leakage diagnosis. Firstly, the natural gas pipeline working condition signal is decomposed and denoised by Variational mode decomposition (VMD). Secondly, the denoised pipeline signals were constructed into a form expressed by the Symmetric positive definite matrix (SPD) using the VMD reconstruction technique, and the geodesic distance measurement method was applied to the SPD matrix to make the data located on the SPD manifold. Then feature extraction is carried out by Local linear embedding (LLE) method based on asymmetric distance. Finally, pattern recognition of the features extracted in this paper by Support vector machine (SVM) can achieve 100% recognition accuracy. By enabling faster and more accurate leak detection, the method minimizes gas loss, as well as mitigating the environmental risks caused by this potent greenhouse gas.

Biochar as an Alternative Litter Additive to Mitigate Gaseous Emissions from Broiler Housing and Subsequent Storage

Broiler farming is a significant source of gaseous emissions. The aim of this study was to assess the effects of different litter additives on the emission of NH3, N2O, CO2, and CH4 during broiler housing and subsequent manure storage. The gaseous emissions from the housing facilities were evaluated during one fattening cycle in environmentally controlled rooms with three different additives applied to the litter material (10% w/w aluminum sulphate or biochar and 2.50 mg m−2 urease inhibitor), as well as a control. A storage experiment was conducted under laboratory conditions for 90 days to evaluate the influence of these three additives on gaseous losses. During broiler housing, the results indicated that NH3 emissions were reduced significantly (40–60%) by litter additives, while global warming potential (GWP) emissions were reduced significantly (31%) by Alum. The addition of Biochar (a 58% reduction) had the same significant effect as Alum (a 60% reduction) to mitigate these losses. The re-application of Urease (a 41% reduction) may be required to reach an equal or higher reduction. During storage, NH3 and GWP emissions were not significantly affected by the litter additives. During broiler housing and subsequent manure storage, NH3 emissions were reduced significantly (22–41%) by litter additives, whereas GWP emissions did not decrease significantly. Globally, it can be concluded that Biochar appears to be a good alternative to Alum due to its equal effectiveness in mitigating NH3 losses, without increasing the GWP potential in the housing and avoiding pollution swapping.

Biotic regulation of nitrogen gas emissions in temperate agriculture

It is generally assumed that fertilizer addition is the prime driver of nitrogen (N) gas loss from modern cropping systems. This assumption has its basis in observations of nitrous oxide (N2O, an important greenhouse gas) emissions, and is contrary to theory from unmanaged ecosystems, where N losses are controlled by plant physiological influence on the soil environment. However, dinitrogen (N2) emissions are likely a major N loss pathway in both managed and unmanaged ecosystems, but these emissions are very difficult to measure. We directly measured N2 and N2O emissions from two temperate agricultural systems over the course of the growing season to test when total N gas losses are highest. We hypothesized that N2 emissions mirror those of N2O, with the largest flux immediately after fertilization, early in the growing season. Instead, we found that N2 emissions were highest at the end of the growing season, and were most strongly correlated with soil moisture, which increased after plant senescence. Dinitrogen emissions were an order of magnitude larger than N2O. Thus, while N2O emissions were highest following fertilization, overall N gas loss was greatest at the end of the growing season. These data suggest that total N gas losses are high and have different temporal patterns from N2O fluxes. Understanding the magnitude and controls over these losses are important for understanding and managing the N cycle of temperate agricultural systems.

Shale gas‐bearing capacity and its controlling factors of Wufeng–Longmaxi formations in northern Guizhou, China

Great progress has been made in marine shale gas of Wufeng–Longmaxi formations in the Sichuan Basin. However, shale gas exploration in the complex structural belt around the Sichuan Basin still faces great challenges. In this study, shales of Wufeng–Longmaxi formations collected from the northern Guizhou were taken as the studied target, organic matter (OM) characteristics, mineral composition, pore structure, methane adsorption capacity and in situ desorption gas content were measured, and the controlling factors of shale gas content were further discussed. The results indicated that the sedimentary facies of Wufeng–Longmaxi formations in north Guizhou varies from shallow‐water shelf facies to deep‐water shelf facies from south to north, and organic‐rich shales are primarily distributed in Daozhen‐Xishui areas, with a maximum thickness of about 80–100 m. Organic‐rich shales are characterized by high total organic carbon (TOC) content, high thermal maturation and type I–II1 kerogens, which can be comparable with those in commercially produced shale gas field in Sichuan Basin. High‐quality shale gas reservoirs generally have a high content of brittle minerals, making them easier to be fractured. OM pores are the dominanted pore type in the studied shales, followed by intergranular pores associated with brittle minerals, dissolution pores within carbonate grains and microcracks, while clay mineral‐related pores are poorly developed. The Wufeng–Longmaxi Formation shales generally have strong methane adsorption capacities, but these vary greatly across different areas. Shale gas adsorption capacity is primarily controlled by TOC content and thermal maturation level. Similarly, total gas content, including desorption gas and lost gas, varies greatly in different areas, and it is obviously lower than that in Fuling and Luzhou shale gas field, due to the loss of shale gas and low‐pressure coefficient in the complex structural zone. It is worth explaining that shale gas is not always low in northern Guizhou, which is determined by burial depth and the distance of great fractures. Shale gas content is relatively high in LY1 well and DY1 well in Xishui‐Daozhen area, and it is extremely low in TY1 well and AY1 well in Tongzi‐Zheng'an area. Shale gas content in the same structural unit is primarily influenced by TOC content, OM pore development degree and water saturation. However, different structural units have different shale gas contents, due to the differences in preservation conditions. Shale reservoirs with good preservation conditions, that is, wide and gentle structure, far from a large fault and great burial depth, generally have high shale gas contents.

Evaluation of chitosan and microbial inoculants on aerobic stability and fermentative profile pearl millet, corn and sorghum silages

ABSTRACT The objective of this study was to evaluate the effect of microbial inoculants, chitosan, and blend (microbial inoculants and chitosan) on chemical composition, in vitro degradability, fermentative profile, losses, aerobic stability, and microorganism counts of corn, pearl millet and sorghum silages. A randomised block design was used in a factorial arrangement of 3 × 4. Three crops (pearl millet, corn and sorghum) and four additives: Control (without additive), 2 g of microbial inoculants (for ton of forage), 10 g/kg chitosan per kg of ensiled material, and blend (chitosan [5 g/kg] plus microbial inoculants [2 g/ton forage]), with five replicates per treatment. Chitosan increases the CP levels of silages and improves the in vitro degradability of DM in sorghum silage. The microbial inoculants reduced the pH in pearl millet, corn and sorghum silages (P < 0.001). The additives affected (P < 0.05) the aerobic stability of silages throughout the evaluation period. However, when evaluating the chitosan, the average temperature of the pearl millet and corn silages remained stable for a longer period. Chitosan improved the nutritional quality of sorghum silage. Chitosan-treated silages pearl millet and corn silages show great efficiency in aerobic stability due to antifungal activity. The microbial inoculants show reduced gas losses compared to chitosan.

Montgomery Tracheal Tube - A Boon with a Challenge

Crico-tracheal resection and anastomosis are commonly used operative techniques in managing crico-tracheal stenosis grade III-IV. The Montgomery T-tube is used both as a tracheal stent and tracheostomy. Still, it poses various challenges to anaesthesiologists, like loss of anaesthetic gases through the open proximal end of the vertical limb and lack of standard anaesthesia circuit connectors. Here we present a case of 27 years old male with a history of gunshot injury to the neck three years ago with right vocal cord palsy with subglottic tracheal stenosis grade IV posted for microlaryngobronchoscopy (MLB) with crico-tracheal resection and anastomosis with Montgomery tracheal tube insertion. In this case, we used LMA proseal, which not only enabled us to stop the anaesthetic gas loss via the proximal vertical limb of the T-tube but also aided in checking airway patency and proper positioning of the T-tube via flexible bronchoscope through it.

Generation of cutting heat and simulation of core tube wall temperature during coring in primary structure coal seam

When the drilling core method is used to determine the coalbed gas content, the cutting heat generated by the core bit cutting coal will increase the core tube temperature, and the excessively high core tube temperature will have an heating effect on the coal core, which will accelerate the coal core gas desorption rate and increase the gas loss amount. The generation of cutting heat of core bit and the measurement of core tube temperature are the basis for grasping the gas desorption law of coal core and projecting the amount of gas loss. Firstly, the self-developed core tube temperature measurement device was used to conduct on-site core temperature measurement experiments at different cutting speeds. Then, the cutting temperature of core bit was solved by establishing thermodynamic model for cutting coal and heat transfer model of cutting edge. Finally, based on the thermal conductivity characteristics of the core tube, the core tube temperature at different cutting speeds was simulated, and the simulated temperature was compared with the on-site measured temperature to verify the reliability of the model. The results show that when coring in primary structural coal, the temperature change trend of core tube wall temperature measurement point at different cutting speeds is basically consistent, the temperature measurement point at the front end of the core tube mainly goes through a relatively stable period in the drilling process, a sharp rising period in the cutting process, a slow rise and cooling period in the withdrawal process. However, the temperature measurement point at the back end of the core tube wall mainly goes through a relatively stable phase and a slowly increasing phase. The temperature rise of the core bit and the core tube wall are significantly positively correlated with the cutting speed. When coring in hard coal seam and the core depth is not large, the cutting heat generated by the core bit and the coal body is the dominant factor for the temperature rise of the core tube. The core tube wall temperature calculated using the model matches well with the field measured temperature, and the error is small, which fully shows that the coring thermodynamic model is feasible. This study provides a basis for further research on the dynamic distribution characteristic of coal core temperature during coring, which is of profound significance to calculate the gas loss and coalbed gas content.

Analysis of methods of natural gas technical loss determination and technical loss norms in gas supply network

In modern times, the role of energy resources is very large. One of the important energy resources is natural gas. The biggest advantage of using natural gas as a fuel is its high heat capacity and complete combustion without the formation of harmful substances. The process of natural gas distribution in the gas supply network is observed with gas loss. This is an objective, natural situation and creates a number of difficulties for natural gas enterprises. The article focuses on gas consumption in technological processes in the gas supply network, gas purges from pipelines during pipeline repair works, gas flushing out from the pipeline and determination of gas technological losses during the removal of air from the pipeline. Determination of gas losses caused by non-hermeticity of external gas pipelines and equipment, gas pressure regulation station (GPRS), cabinet-type gas control points (GCP), universal pressure regulator (UPR) and gas losses occurring during repairing of other technological equipment are discussed. Also, the determination of technical losses of natural gas at meters, sampling nodes, safety valves, gas distribution stations (GDS) (from gas losses during the management of shut-off valves, during purge of process instrumentation and automatics, when taking gas samples, during purges proses of safety valves, apparatus and pulse lines) is discussed. The article describes the principle of formation of technical losses in the gas supply network. Technical loss sources of natural gas in the process of gas supply, methods of calculating loss norms, the amount of small loss of which is determined separately for each specified loss source, are mentioned. Keywords: gas supply; natural gas; technical losses; pipeline; GPRS; GCP; UPR; gas meters; safety valves; gas distribution station.

Dark-matter-free Dwarf Galaxy Formation at the Tips of the Tentacles of Jellyfish Galaxies

When falling into a galaxy cluster, galaxies experience a loss of gas due to ram pressure stripping. In particular, disk galaxies lose gas from their disks, and very large tentacles of gas can be formed. Because of the morphology of these stripped galaxies, they have been referred to as jellyfish galaxies. It has been found that star formation is triggered not only in the disk, but also in the tentacles of such jellyfish galaxies. The observed star-forming regions located in the tentacles of those galaxies have been found to be as massive as 3 × 107 M ⊙ and with sizes >100 pc. Interestingly, these parameters in mass and size agree with those of dwarf galaxies. In this work, we make use of the state-of-the-art magnetohydrodynamic (MHD) cosmological simulation IllustrisTNG-50 to study massive jellyfish galaxies with long tentacles. We find that, in the tentacles of TNG-50 jellyfish galaxies, the star formation regions (gas+stars) formed could be as massive as ∼2 × 108 M ⊙. A particular star-forming region was analyzed. This region has a star formation rate of 0.04 M ⊙ yr−1, it is metal-rich, has an average age of 0.46 Gyr, and has a half-mass radius of ∼1 kpc, typical of standard dwarf galaxies. Most importantly, this region is gravitationally self-bound. Overall, we identify a new type of dwarf galaxy being born from the gas tentacles of jellyfish galaxies that, by construction, lacks a dark matter halo.

Differential enrichment mechanism of helium in the Jinqiu gas field of Sichuan Basin, China

Helium is extensively utilized in aerospace, healthcare, electronics, semiconductors, advanced science, and renewable energy sectors, playing a pivotal role in the advancement of human technology. Presently, helium is primarily extracted from natural gas as an associated resource. The cost of extraction decreases with an increase in the helium concentration within the gases. Therefore, understanding the mechanisms involved in helium generation, migration, and accumulation underground is vital. This article delves into the differential enrichment mechanism of helium in the Jinqiu gas field, situated in the Sichuan Basin of China, by analyzing the molecular and isotopic composition characteristics of the major gases and noble gases, employing gas dissolution and diffusion models. Compared with other Jurassic gas reservoirs in the Sichuan Basin, the Jinqiu gas field contains a significantly higher helium concentration, displaying unique enrichment patterns within its area. The majority of hydrocarbon gases originate from the local underlying Triassic Xujiahe Formation source rocks. Specifically, the western section of the Jinqiu field is primarily supplied by the higher maturity Xujiahe Formation source rocks located in the western Sichuan Basin. Notably, there is no significant contribution of mantle-derived volatile components in the Jinqiu field. Helium and argon are primarily radiogenic, whereas neon primarily originates from atmosphere. The good linear correlation between 4He and 20Ne suggests that their transfer is primarily facilitated through groundwater. The solubility calculation reveals that the helium exsolved from the in-situ pore water of the reservoir, due to stratigraphic uplift during the Himalayan movement, comprises only 0.04%–0.11% of the existing reserves. This suggests that gas desolvation plays a relatively minor role in helium enrichment in the Jinqiu field. Additionally, the calculation results of gas diffusion indicate that diffusion's contribution to helium enrichment in the Jinqiu gas field remains minimal. Finally, our analysis of methane reserve changes suggests that the combined effect of differential loss and dilution of hydrocarbon gases is the primary mechanism for helium's differential enrichment in the Jinqiu field. Notably, methane and carbon dioxide depletion may be a significant factor in helium enrichment within the crustal natural gas system.

Transition of dome formation to sudden explosive eruptions at Popocatépetl, Mexico: magnetic indicators

Transitions from effusive to explosive activity can increase hazards making it crucial to define early indicators such as changes in the magnetic signals. After more than 80 cycles of crater-dome extrusion and destruction from 1996 on, Popocatépetl volcano (Mexico) experienced changes in its behavior from March 15 to 18 July 2019, when no lava domes were observed. Some of the domes behaved as contained lava flows within the crater floor (pancakes) while others were more irregular-shaped. Activity decreased considerably over this 2019 interval except for the unexpected explosions in March and June, that produced ash plumes reaching up to 14,000 m a.s.l. In order to investigate the causes of the transition from effusive to explosive behavior in March and June, we analyzed the time series from the magnetic monitoring network at Popocatépetl volcano between October 2018 and December 2019. The raw signals were analyzed by weighted differences (WD) based on the elimination of non-local changes from the total intensity values of the geomagnetic field and the discrete-time continuous wavelet transform was used to evaluate the local variations of energy within the time series. The high energy periods (linked to negative magnetic anomalies) are induced by magma ascent associated with movement within the conduit. They indicate that the sudden explosions were due to the ascent of several magma batches that were slowed during ascent and were not able to reach the surface. Changes in the rheology of the lava are linked to the influx of several batches of magma with different compositions as well as to compaction by gas loss when ascending andesitic magma pushed out overlying more viscous degassed magma clearing the conduit, which can explain why these sudden explosions were more energetic. Several geophysical data sets as well as tephra compositions were integrated to support this conclusion. The correlated multiparameters also confirm that geomagnetic volcano monitoring has been essential in understanding the processes that drive the observed changes in eruptive behavior. We present new evidence for the detection of transient events produced by magma ascent and changes in the feeding system of Popocatépetl volcano with wavelet analysis. Detailed vulcanomagnetic processing, especially when it is correlated with other monitoring parameters, provides information on ascending magma and several conduit processes that would otherwise be camouflaged. Ascending batches may precede an eruption but they can also ascend in several pulses indicating how dome growth occurs.

Rehydrated corn grain silage with wet brewery residue and different inoculants

The objective was to evaluate the effects of including different proportions of Wet Brewery Residue (WBR) using inoculants on rehydrated ground corn silage quality. The experiment was conducted in a completely randomized design in a 4 x 3 factorial scheme with four replications. Four combinations of WBR and ground corn were evaluated to achieve 45 (DM45), 50 (DM50), 55 (DM55), and 65% (DM65) of dry matter (DM) in the homogenized material before siling, and three types of inoculation: without inoculant, with L. plantarum + P. acidylactici (Homo) and with L. buchneri (L. B). Ensiling was done in experimental PVC silos (±4.0kg) and stored for 180 days. The variables obtained were analyzed by the analysis of variance and regression procedures (P&lt;0.05) using the R software. The percentage of real DM included in the treatments was 47%, 52%, 56%, and 66%. No impairment of the pH-reducing capacity of corn rehydrated with WBR was observed. Total dry matter losses were within the acceptable limit in silage with 52% DM (DM50), regardless of the type of inoculation. Gas losses were within the permissible limit only in the DM50 treatments with Homo inoculant and in the DM50 treatment without inoculation. Effluent losses were outside the tolerable limit in the treatment with 47% DM (DM45) in the presence of the inoculant LB. There was a significant interaction between the inoculant LB and the silages, with 47% (DM45) and 56% (DM55) DM for the Crude Protein (CP) levels. The ADF and NDF variables reduced linearly as a function of the increase in dry matter of the ensiled material, with a tendency for the lowest values to be found in treatments without inoculation. For all variables, an increase in energy levels (Non-Fibrous Carbohydrates, starch, Total Digestible Nutrients, and Net Energy gain) was observed with the increase in the DM content of the silage. It is concluded that silage with 52% DM (DM50) obtained the best results for fermentative losses. For bromatological and energetic characteristics, silage with 66% DM was the best, except for the CP variable, where 47% DM silage achieved superior results. In general, the addition of additives did not show any improvement in relation to treatments without inoculants.