Loop-current Order Research Articles

Intertwined Van Hove Singularities as a Mechanism for Loop Current Order in Kagome Metals.

Recent experiments on kagome metals AV_{3}Sb_{5} (A=Cs,Rb,K) indicated spontaneous time-reversal symmetry breaking in the charge density wave state in the absence of static magnetization. The loop current order (LCO) is proposed as its cause, but a microscopic model explaining the emergence of LCO through electronic correlations has not been firmly established. We show that the coupling between van Hove singularities with distinct mirror symmetries is a key ingredient to generate LCO ground state. By constructing an effective model, we find that when multiple van Hove singularities with opposite mirror eigenvalues are close in energy, the nearest-neighbor electron repulsion favors a ground state with coexisting LCO and charge bond order. It is then demonstrated that this mechanism applies to the kagome metals AV_{3}Sb_{5}. Our findings provide an intriguing mechanism of LCO and pave the way for a deeper understanding of complex quantum phenomena in kagome systems.

Orbital gravitomagnetoelectric response and orbital magnetic quadrupole moment correction

We propose a fully quantum-mechanical formalism for the temperature-gradient-induced orbital magnetoelectric effect in systems without spatial inversion symmetry, $\mathcal{P}$, and time-reversal symmetry $\mathcal{T}$. The effect consists of two parts, i.e., an extrinsic part and an intrinsic part. We demonstrate that for the intrinsic part, a correction from the orbital magnetic quadrupole moment besides the usual Kubo formula, is necessary to avoid an unphysical divergence at zero temperature and to satisfy the Mott relation. Furthermore, we show the classification table with the magnetic point group for the intrinsic and extrinsic effects. Finally, we analyze the intrinsic part in a $\mathcal{PT}$-symmetric model exhibiting an orbital magnetization order, i.e., a loop-current order, and demonstrate the enhancement near Dirac points. We believe these results will contribute to the detection and application of orbital magnetic moments beyond spin moments.

Nematic single-component superconductivity and loop-current order from pair-density wave instability

We investigate the nematic and loop-current type orders that may arise as vestigial precursor phases in a model with an underlying pair-density wave (PDW) instability. We discuss how such a vestigial phase gives rise to a highly anisotropic stiffness for a coexisting single-component superconductor with low intrinsic stiffness, as is the case for the underdoped cuprate superconductors. Next, focusing on a regime with a mean-field PDW ground state with loop-current and nematic $xy$ (B$_{2g}$) order, we find a preemptive transition into a low and high-temperature vestigial phase with loop-current and nematic order corresponding to $xy$ (B$_{2g}$) and $x^2-y^2$ (B$_{1g}$) symmetry respectively. Near the transition between the two phases, a state of soft nematic order emerges for which we expect that the nematic director is readily pinned away from the high-symmetry directions in the presence of an external field. Results are discussed in relation to findings in the cuprates, especially to the recently inferred highly anisotropic superconducting fluctuations [W{\aa}rdh {\em et al.}, ``Colossal transverse magnetoresistance due to nematic superconducting phase fluctuations in a copper oxide'', arXiv:2203.06769], giving additional evidence for an underlying ubiquitous PDW instability in these materials.

Quantum theory of the intrinsic orbital magnetoelectric effect in itinerant electron systems at finite temperatures

Magnetization can be induced by an electric field in systems without inversion symmetry $\mathcal{P}$ and time-reversal symmetry $\mathcal{T}$. This phenomenon is called the magnetoelectric (ME) effect. The spin ME effect has been actively studied in multiferroics. The orbital ME effect also exists and has been mainly discussed in topological insulators at zero temperature. In this paper, we study the intrinsic orbital ME response in metals at finite temperature using the Kubo formula. The intrinsic response originates from the Fermi sea and does not depend on the dissipation. Especially in systems with $\mathcal{PT}$ symmetry, the extrinsic orbital ME effect becomes zero, and the intrinsic ME effect is dominant. We apply the response tensor obtained in this work to a $\mathcal{PT}$-symmetric model Hamiltonian with antiferromagnetic loop current order, demonstrating that the intrinsic ME effect is enhanced around the Dirac points.

Pair density wave and loop current promoted by Van Hove singularities in moiré systems

We theoretically show that in the presence of conventional or higher order Van Hove singularities (VHS), the bare finite momentum pairing, also known as the pair density wave (PDW), susceptibility can be promoted to the same order of the most divergent bare BCS susceptibility through a valley-contrasting flux $3\ensuremath{\phi}$ in each triangular plaquette at $\ensuremath{\phi}=\ensuremath{\pi}/3$ and $\ensuremath{\pi}/6$ in moir\'e systems. This makes the PDW order a possible leading instability for an electronic system with repulsive interactions. We confirm that it indeed wins over all other instabilities and becomes the ground state under certain conditions through the renormalization group calculation and a flux insertion argument. Moreover, we also find that a topological nontrivial loop current order becomes the leading instability if the Fermi surface with conventional VHS is perfectly nested at $\ensuremath{\phi}=\ensuremath{\pi}/3$. Similar to the Haldane model, this loop current state has the quantum anomalous Hall effect. If we dope this loop current state or introduce a finite next-nearest-neighbor hopping ${t}^{\ensuremath{'}}$, the chiral $d$-wave PDW becomes the dominant instability. Experimentally, the flux can be effectively tuned by an out-of-plane electric field in moir\'e systems based on graphene and transition metal dichalcogenides.

Loop currents in quantum matter

In many quantum materials, strong electron correlations lead to the emergence of new states of matter. In particular, the study in the last decades of the complex phase diagram of high temperature superconducting cuprates highlighted intra-unit-cell electronic instabilities breaking discrete Ising-like symmetries, while preserving the lattice translation invariance. Polarized neutron diffraction experiments have provided compelling evidences supporting a new form of intra-unit-cell magnetism, emerging concomitantly with the so-called pseudogap state of these materials. This observation is currently interpreted as the magnetic hallmark of an intra-unit-cell loop current order, breaking both parity and time-reversal symmetries. More generally, this magneto-electric state is likely to exist in a wider class of quantum materials beyond superconducting cuprates. For instance, it has been already observed in hole-doped Mott insulating iridates or in the spin liquid state of hole-doped 2-leg ladder cuprates.

Thermal Hall conductivity of electron-doped cuprates

Measurements of the thermal Hall conductivity in hole-doped cuprates have shown that phonons acquire chirality in a magnetic field, both in the pseudogap phase and in the Mott insulator state. The microscopic mechanism at play is still unclear. A number of theoretical proposals are being considered, including skew scattering of phonons by various defects, the coupling of phonons to spins, and a state of loop-current order with the appropriate symmetries, but more experimental information is required to constrain theoretical scenarios. Here we present our study of the thermal Hall conductivity $\kappa_{\rm {xy}}$ in the electron-doped cuprates Nd$_{2-x}$Ce$_x$CuO$_4$ and Pr$_{2-x}$Ce$_x$CuO$_4$, for dopings across the phase diagram, from $x$ = 0, in the insulating antiferromagnetic phase, up to $x$ = 0.17, in the metallic phase above optimal doping. We observe a large negative thermal Hall conductivity at all dopings, in both materials. Since heat conduction perpendicular to the CuO$_2$ planes is dominated by phonons, the large thermal Hall conductivity we observe in electron-doped cuprates for a heat current in that direction must also be due to phonons, as in hole-doped cuprates. Measurements with a heat current perpendicular to the CuO$_2$ planes confirm that phonons are responsible for this thermal Hall signal, as in hole-doped cuprates. However, the degree of chirality, measured as the ratio $|\kappa_{\rm {xy}}$ / $\kappa_{\rm {xx}} |$, where $\kappa_{\rm {xx}}$ is the longitudinal thermal conductivity, is much larger in the electron-doped cuprates. We discuss various factors that may be involved in the mechanism that confers chirality to phonons in cuprates, including short-range spin correlations.

Photocurrent response in parity-time symmetric current-ordered states

There is growing interest in the photo-induced generation of rectified current, namely photocurrent phenomenon. While the response was attributed to noncentrosymmetric structures of crystals, the parity violation accompanied by the magnetic ordering, that is, magnetic parity violation, is recently attracting attention as a platform for a photocurrent generator. In this paper, we investigate the photocurrent response in the current-ordered phase, realizing the magnetic parity violation without the spin degree of freedom, although prior studies focused on the parity-violating spin structure. The loop-current order breaks the inversion symmetry while preserving the parity-time-reversal symmetry. With a model of Sr$_2$IrO$_4$, we demonstrate the linearly and circularly polarized light-induced photocurrent responses in the current-ordered state. Each photocurrent has a distinct tolerance of the scattering rate according to the mechanism for the photocurrent creation. The predicted photocurrent response is comparable to that in prototypical semiconductors. We propose a probe to detect the hidden-ordered phase in Sr$_2$IrO$_4$ by the photocurrent response.

Odd-parity spin-loop-current order mediated by transverse spin fluctuations in cuprates and related electron systems

Unconventional symmetry-breaking phenomena due to nontrivial order parameters attract increasing attention in strongly correlated electron systems. Here, we predict theoretically the occurrence of nanoscale spontaneous spin-current, called the spin loop-current (sLC) order, as a promising origin of the pseudogap and electronic nematicity in cuprates. We reveal that the sLC is driven by the odd-parity electron-hole condensation that are mediated by transverse spin fluctuations around the pseudogap temperature $T^*$. At the same temperature, odd-parity magnon pair condensation occurs. The sLC order is "hidden" in that neither internal magnetic field nor charge density modulation is induced, whereas the predicted sLC with finite wavenumber naturally gives the Fermi arc structure. In addition, the fluctuations of sLC order work as attractive pairing interaction between adjacent hot spots, which enlarges the d-wave superconducting transition temperature $T_c$. The sLC state will be a key ingredient in understanding the pseudogap, electronic nematicity as well as superconductivity in cuprates and other strongly correlated metals.

Thermal Hall effect in the pseudogap phase of cuprates

The conjecture made recently by the group at Sherbrooke, that their observed anomalous thermal Hall effect in the pseudo-gap phase in the cuprates is due to phonons, is supported on the basis of an earlier result that the observed loop-current order in this phase must induce lattice distortions which are linear in the order parameter and an applied magnetic field. The lowered symmetry of the crystal depends on the direction of the field. A consequence is that the elastic constants change proportional to the field and are shown to induce axial thermal transport with the same symmetries as the Lorentz force enforces for the normal electronic Hall effect. Direct measurements of elastic constants in a magnetic field are suggested to verify the quantitative aspects of the results.

Incipient loop-current order in the underdoped cuprate superconductors

There are growing experimental evidence which indicate discrete symmetry breaking like time-reversal ($\mathcal{T}$), parity ($\mathcal{P}$) and C$_{4}$ lattice rotation in the pseudo-gap state of the under-doped copper-oxide based (cuprate) superconductors. The discrete symmetry breaking manifests a true phase transition to an ordered state. A detailed thermodynamic understanding of these orders can answer various puzzles related to the nature of the transition at the pseudo-gap temperature T$^*$. In this work, we investigate thermodynamic signature of $\mathcal{T-P}$ symmetry breaking considering superconductivity (SC) and bond-density wave (BDW) as two primary orders. The BDW can generate both modulating charge and current densities. This framework takes into account an intricate competition between the ubiquitous charge density wave and SC, which is prominent in various cuprates in the under-doped regime. We demonstrate that within mean-field approach of competing BDW and SC orders, a $\mathcal{T-P}$ breaking ground state of coexisting BDW and SC can be stabilized, provided the BDW itself breaks $\mathcal{T}-\mathcal{P}$. But this ground state ceases to occur at higher temperatures. However, we show that fluctuations in SC and BDW can drive emergence of a new unusual translational symmetry preserving order due to a preemptive phase transition by spontaneously breaking $\mathcal{T-P}$ at a higher temperature before the primary orders set in. We refer this order to be magneto-electric loop current (MELC) order. We present possible nature of phase transition for this new incipient MELC order and discuss some experimental relevance.

Pseudogap and Fermi arcs in underdoped cuprates

The proposed loop-current order in cuprates cannot give the observed pseudogap and the Fermi-arcs because it preserves translation symmetry. A modification to a periodic arrangement of the four possible orientations of the order parameter with a large period of between about 12 to 30 lattice constants is proposed and shown in a simple and controlled calculation to give one-particle spectra with every feature as in the ARPES experiments. The results follow from (1) the currents at the boundaries of the periodic domains with similar topology as the Affleck-Marston flux phase, and (2) the mixing introduced by the boundary currents between the states near the erstwhile Fermi-surface and the ghost Fermi-surfaces which are displaced from it by mini-reciprocal vectors. The proposed idea can be ruled out or verified by high resolution diffraction or imaging experiments. It does not run afoul of the variety of different experiments consistent with the loop-current order as well as the theory of the marginal Fermi-liquid and d-wave superconductivity based on quantum-critical fluctuations of the loop current order.

18aAL-7 1次元3成分冷却原子ガスにおける新しい密度積型秩序とループ流秩序(18aAL 量子エレクトロニクス(Bose粒子系の理論),領域1(原子・分子,量子エレクトロニクス,放射線物理))

18aAL-7 1次元3成分冷却原子ガスにおける新しい密度積型秩序とループ流秩序(18aAL 量子エレクトロニクス(Bose粒子系の理論),領域1(原子・分子,量子エレクトロニクス,放射線物理))

Phase diagram and correlation functions of the two-dimensional dissipative quantum XY model

The two-dimensional dissipative quantum XY model is applicable to the quantum-critical properties of diverse experimental systems, ranging from the superconductor to insulator transitions, ferromagnetic and antiferromagnetic transitions in metals, to the loop-current order transition in the cuprates. We solve the re-expression of this model in terms of topological excitations: vortices and a variety of instantons, by renormalization group methods. The calculations explain the extraordinary properties of the model discovered in Monte-Carlo calculations: the separability of the quantum critical fluctuations (QCF) in space and time, the spatial correlation length proportional to logarithm of the temporal correlation length near the transition from disordered to the fully ordered state, and the occurrence of a phase with spatial order without temporal order. They are intimately related to the flow of the metric of time in relation to the metric of space, i.e. of the dynamical critical exponent $z$. These properties appear to be essential in understanding the strange metallic phase found in a variety of quantum-critical transitions as well as the accompanying high temperature superconductivity.

Coexistence ofΘII-loop-current order with checkerboardd-wave CDW/PDW order in a hot-spot model for cuprate superconductors

We investigate the strong influence of the $\Theta_{II}$-loop-current order on both unidirectional and bidirectional d-wave charge-density-wave/pair-density-wave (CDW/PDW) composite orders along axial momenta $(\pm Q_0,0)$ and $(0,\pm Q_0)$ that emerge in an effective hot spot model departing from the three-band Emery model relevant to the phenomenology of the cuprate superconductors. This study is motivated by the compelling evidence that the $\Theta_{II}$-loop-current order described by this model may explain groundbreaking experiments such as spin-polarized neutron scattering performed in these materials. Here, we demonstrate, within a saddle-point approximation, that the $\Theta_{II}$-loop-current order clearly coexists with bidirectional (i.e. checkerboard) d-wave CDW and PDW orders along axial momenta, but is visibly detrimental to the unidirectional (i.e. stripe) case. This result has potentially far-reaching implications for the physics of the cuprates and agrees well with very recent x-ray experiments on YBCO that indicate that at higher dopings the CDW order has indeed a tendency to be bidirectional.

Evidence of an odd-parity hidden order in a spin–orbit coupled correlated iridate

A rare combination of strong spin-orbit coupling and electron-electron correlations makes the iridate Mott insulator Sr$_2$IrO$_4$ a promising host for novel electronic phases of matter. The resemblance of its crystallographic, magnetic and electronic structures to La$_2$CuO$_4$, as well as the emergence upon doping of a pseudogap region and a low temperature $d$-wave gap, has particularly strengthened analogies to cuprate high-$T_c$ superconductors. However, unlike the cuprate phase diagram that features a plethora of broken symmetry phases in a pseudogap region that include charge density wave, stripe, nematic and possibly intra-unit cell loop-current orders, no broken symmetry phases proximate to the parent antiferromagnetic Mott insulating phase in Sr$_2$IrO$_4$ have been observed to date, making the comparison of iridate to cuprate phenomenology incomplete. Using optical second harmonic generation, we report evidence of a hidden non-dipolar magnetic order in Sr$_2$IrO$_4$ that breaks both the spatial inversion and rotational symmetries of the underlying tetragonal lattice. Four distinct domain types corresponding to discrete 90$^{\circ}$ rotated orientations of a pseudovector order parameter are identified using nonlinear optical microscopy, which is expected from an electronic phase that possesses the symmetries of a magneto-electric loop-current order. The onset temperature of this phase is monotonically suppressed with bulk hole doping, albeit much more weakly than the N\'eel temperature, revealing an extended region of the phase diagram with purely hidden order. Driving this hidden phase to its quantum critical point may be a path to realizing superconductivity in Sr$_2$IrO$_4$.

Strong competition betweenΘII-loop-current order andd-wave charge order along the diagonal direction in a two-dimensional hot spot model

We study the fate of the so-called $\Theta_{II}$-loop-current order that breaks both time-reversal and parity symmetries in a two-dimensional hot spot model with antiferromagnetically mediated interactions, using Fermi surfaces relevant to the phenomenology of the cuprate superconductors. We start from a three-band Emery model describing the hopping of holes in the CuO$_{2}$ plane that includes two hopping parameters $t_{pp}$ and $t_{pd}$, local on-site Coulomb interactions $U_{d}$ and $U_{p}$ and nearest-neighbor $V_{pd}$ couplings between the fermions in the copper [Cu$(3d_{x^{2}-y^{2}})$] and oxygen [O$(2p_{x})$ and O$(2p_{y})$] orbitals. By focusing on the lowest-energy band, we proceed to decouple the local interaction $U_{d}$ of the Cu orbital in the spin channel using a Hubbard-Stratonovich transformation to arrive at the interacting part of the so-called spin-fermion model. We also decouple the nearest-neighbor interaction $V_{pd}$ to introduce the order parameter of the $\Theta_{II}$-loop-current order. In this way, we are able to construct a consistent mean-field theory that describes the strong competition between the composite order parameter made of a quadrupole-density-wave and $d$-wave pairing fluctuations proposed in Efetov \emph{et al.} [Nat. Phys. \textbf{9}, 442 (2013)] with the $\Theta_{II}$-loop-current order parameter that is argued to be relevant for explaining important aspects of the physics of the pseudogap phase displayed in the underdoped cuprates.

Local quantum criticality in the two-dimensional dissipative quantum XY model

We use quantum Monte-Carlo simulations to calculate the phase diagram and the correlation functions for the quantum phase transitions in the two-dimensional dissipative XY model with and without four-fold anisotropy. Without anisotropy, the model describes the superconductor to insulator transition in two-dimensional dirty superconductors. With anisotropy, the model represents the loop-current order observed in the under-doped cuprates and its fluctuations, as well as the fluctuations near the ordering vector in simple models of itinerant antiferromagnets. These calculations test an analytic solution of the model which re-expressed it in terms of topological excitations - the vortices with interactions only in space but none in time, and warps with leading interactions only in time but none in space, as well as sub-leading interactions which are both space and time-dependent. For parameters for which the proliferation of warps dominates the phase transition, the critical fluctuations as a function of the deviation of the dissipation parameter $\alpha$ from its critical value $\alpha_c$ are scale-invariant in imaginary time $\tau$ as the correlation length in time $\xi_{\tau} = \tau_c e^{|\alpha_c/(\alpha_c-\alpha)|^{1/2}}$ diverges. On the other hand, the spatial correlations develop with a correlation length $\xi_x \approx \xi_0 \log{(\xi_{\tau})}$, with $\xi_0$ of the order of a lattice constant. The dynamic correlation exponent $z$ is therefore $\infty$. These results are consistent with the phenomenology proposed for the strange metal properties of the cuprates. The Monte-Carlo calculations also directly show warps and vortices. Their density and correlations across the various transitions in the model are calculated and related to those of the order parameter in the original model.

Emergent loop current order from pair density wave superconductivity

There is evidence that the pseudogap phase in the cuprates breaks time-reversal symmetry. Here we show that pair density wave (PDW) states give rise to a translational invariant nonsuperconducting order parameter that breaks time-reversal and parity symmetries, but preserves their product. This secondary order parameter has a different origin, but shares the same symmetry properties as a magnetoelectric loop current order that has been proposed earlier in the context of the cuprates to explain the appearance of intracell magnetic order. We further show that, due to fluctuations, this secondary loop current order, which breaks only discrete symmetries, can preempt PDW order, which breaks both continuous and discrete symmetries. In such a phase, the emergent loop current order coexists with spatial short-range superconducting order and possibly short-range charge density wave (CDW) order. Finally, we propose a PDW phase that accounts for intracell magnetic order and the Kerr effect, has CDW order consistent with x-ray scattering and nuclear magnetic resonance observations, and quasi-particle properties consistent with angle-resolved photoemission scattering.

Tilted loop currents in cuprate superconductors

The paper briefly surveys theoretical models for the polar Kerr effect (PKE) and time-reversal symmetry breaking in the pseudogap phase of cuprate superconductors. By elimination, the most promising candidate is the tilted loop-current model, obtained from the Simon–Varma model by tilting one triangular loop up and another one down toward the apical oxygens. The model is consistent with the PKE, spin-polarized neutron scattering, and optical anisotropy measurements. Spontaneous currents in this model flow between the in-plane and apical oxygens in such a manner that each oxygen belongs to one current loop. This loop-current pattern is similar to the spin order in the magnetoelectric antiferromagnet Cr2O3, where the PKE is observed experimentally. By analogy, it should be possible to train the PKE sign in the cuprates magnetoelectrically. Several experiments are proposed to confirm the loop-current order: the magnetic-field-induced polarity, the nonlinear anomalous Hall effect, and the second-harmonic generation.