Longer Time Constants Research Articles

Measurement of temporal evolution of antiferromagnetic domain change in nickel oxide driven by 2TO phonon mode excitation via pump-probe experiment

The temporal evolution of antiferromagnetic domain pattern changes under resonant excitation of the second-order transverse optical phonon mode in nickel oxide was investigated using mid-infrared free electron laser (MIR-FEL) pulses and visible nanosecond probe laser pulses at room temperature. We visualized the domain patterns through magneto-optical polarized microscopy in transmission and observed their temporal variation after the phonon excitation via MIR-FEL. We evaluated the differences throughout the timeline using the structural similarity index measure technique from domain images with and without MIR-FEL irradiation. We found that the MIR-FEL irradiation induces significant structural changes in the domain patterns. The maximum difference was observed at the timing of the MIR-FEL irradiation and exponentially recovered with the time constant of 1.4 ± 0.2 ms. This rather long-time constant could be owing to the spin relaxation, whilst further investigation is needed to confirm the underlying mechanism.

Linking stem rehydration kinetics to hydraulic traits using a novel method and mechanistic model.

Despite the recognized importance of hydraulic capacitance as a mechanism used by plants to maintain hydraulic functioning during high transpiration, characterizing the dynamics of capacitance remains a challenge. We used a novel 'two-balance method' to investigate relationships between stem rehydration kinetics and other hydraulic traits in multiple tree species, and we developed a model to explore stem rehydration kinetics further. We found that: (1) rehydration time constants and the amount of water uptake occurring during rehydration differed significantly across species; (2) time constants did not change with declining water potential (Ψ), while water uptake increased at lower Ψ in some species; (3) longer time constants were associated with lower wood density, higher capacitance and less negative stem pressures causing 50 % loss of hydraulic conductivity (P50); (4) greater water uptake occurred in stems with lower wood density and less negative P50 values; and (5) the model could estimate the total hydraulic resistance of the rehydration path, which cannot be measured directly. Overall, the two-balance method can be used to examine rehydration dynamics quickly and thoroughly in detached woody stems. This method has the potential to improve our understanding of how capacitance functions across tree species, which is an often-overlooked component of whole-plant hydraulics.

Support-Free Thermally Insensitive Hollow Core Fiber Coil

Light traversing an optical fiber is subject to various local phase perturbations driven by temperature. This thermal phase sensitivity is undesirable in fiber interferometers and their applications which require that a fixed, stable phase be received after propagation. The use of hollow core fiber (HCF) has been shown to reduce this thermal phase sensitivity over solid core fibers and here we propose and demonstrate how coiling HCF to a prescribed geometry can further significantly reduce this sensitivity. Our proof-of-concept experiment shows reduction by a factor of ∼90 with respect to the uncoiled HCF, and over three orders of magnitude with respect to uncoiled solid core optical fiber. Our strategy exploits a nuance of the elastic properties of fiber coils whereby the constrained thermal expansion of the composite material (fiber + coating) can result in a coil having compressed inner layers and expanded outer layers. Thermal expansion is the dominant effect responsible for thermal phase sensitivity in HCFs, and in this scheme the compressed inner coil layers compensate the thermal expansion of the outer layers. In this study we design the coil parameters using finite element simulations, studying the relationship between coil performance and its key parameters. The proof-of-principle coil has 160 mm diameter and incorporates a 548 m length of HCF out of which a 230 m section shows almost zero (slightly negative) thermal phase sensitivity. Though the coil shows low thermal phase sensitivity over tens of hours, the long-time constant viscoelastic properties of the coating materials used in the HCF under study are shown to limit these benefits. To make this strategy practical for systems with fast temperature dynamics, a coating having more stable mechanical properties could be used. For precision timing systems in which long thermal time constants are already the norm, this scheme represents a low-cost and provides a significant reduction to thermal sensitivity which is immediately practicable.

Ventilatory response to added dead space in infants exposed to second-hand smoke in pregnancy

Maternal cigarette smoking in pregnancy can adversely affect infant respiratory control. In utero nicotine exposure has been shown to blunt the infant ventilatory response to hypercapnia, which could increase the risk of sudden infant death syndrome. The potential impact of maternal second-hand smoke exposure, however, has not yet been determined. The aim of this study was to assess ventilatory response to added dead-space (inducing hypercapnia) in infants with second-hand smoke exposure during pregnancy, in infants whose mothers smoked and in controls (non-smoke exposed). Infants breathed through a face mask and specialised “tube-breathing” circuit, incorporating a dead space of 4.4 ml/kg body weight. The maximum minute ventilation (MMV) during added dead space breathing was determined and the time taken to achieve 63% of the MMV calculated (the time constant (TC) of the response). Infants were studied on the postnatal ward prior to discharge home. Thirty infants (ten in each group) were studied with a median gestational age of 39 [range 37–41] weeks, birthweight of 3.1 [2.2–4.0] kg, and postnatal age of 33 (21–62) h. The infants whose mothers had second-hand smoke exposure (median TC 42 s, p = 0.001), and the infants of cigarette smoking mothers (median TC 37 s, p = 0.002) had longer time constants than the controls (median TC 29 s). There was no significant difference between the TC of the infants whose mothers had second-hand smoke exposure and those whose mothers smoked (p = 0.112). Conclusion: Second-hand smoke exposure during pregnancy was associated with a delayed newborn ventilatory response.What is Known:• Maternal cigarette smoking in pregnancy can adversely affect infant respiratory control.• The potential impact of maternal second-hand smoke exposure, however, has not yet been determined.What is New:• We have assessed the ventilatory response to added dead-space (inducing hypercapnia) in newborns with second-hand smoke exposure during pregnancy, in infants whose mothers smoked, and in controls (non-smoke exposed).• Maternal second-hand smoke exposure, as well as maternal smoking, during pregnancy was associated with a delayed newborn ventilatory response.

A novel capnogram analysis to guide ventilation during cardiopulmonary resuscitation: clinical and experimental observations

BackgroundCardiopulmonary resuscitation (CPR) decreases lung volume below the functional residual capacity and can generate intrathoracic airway closure. Conversely, large insufflations can induce thoracic distension and jeopardize circulation. The capnogram (CO2 signal) obtained during continuous chest compressions can reflect intrathoracic airway closure, and we hypothesized here that it can also indicate thoracic distension.ObjectivesTo test whether a specific capnogram may identify thoracic distension during CPR and to assess the impact of thoracic distension on gas exchange and hemodynamics.Methods(1) In out-of-hospital cardiac arrest patients, we identified on capnograms three patterns: intrathoracic airway closure, thoracic distension or regular pattern. An algorithm was designed to identify them automatically. (2) To link CO2 patterns with ventilation, we conducted three experiments: (i) reproducing the CO2 patterns in human cadavers, (ii) assessing the influence of tidal volume and respiratory mechanics on thoracic distension using a mechanical lung model and (iii) exploring the impact of thoracic distension patterns on different circulation parameters during CPR on a pig model.Measurements and main results(1) Clinical data: 202 capnograms were collected. Intrathoracic airway closure was present in 35%, thoracic distension in 22% and regular pattern in 43%. (2) Experiments: (i) Higher insufflated volumes reproduced thoracic distension CO2 patterns in 5 cadavers. (ii) In the mechanical lung model, thoracic distension patterns were associated with higher volumes and longer time constants. (iii) In six pigs during CPR with various tidal volumes, a CO2 pattern of thoracic distension, but not tidal volume per se, was associated with a significant decrease in blood pressure and cerebral perfusion.ConclusionsDuring CPR, capnograms reflecting intrathoracic airway closure, thoracic distension or regular pattern can be identified. In the animal experiment, a thoracic distension pattern on the capnogram is associated with a negative impact of ventilation on blood pressure and cerebral perfusion during CPR, not predicted by tidal volume per se.

Muscle Deoxygenation Rates and Reoxygenation Modeling During a Sprint Interval Training Exercise Performed Under Different Hypoxic Conditions.

This study compared the kinetics of muscle deoxygenation and reoxygenation during a sprint interval protocol performed under four modalities: blood flow restriction at 60% of the resting femoral artery occlusive pressure (BFR), gravity-induced BFR (G-BFR), simulated hypoxia (FiO2≈13%, HYP) and normoxia (NOR). Thirteen healthy men performed each session composed of five all-out 30-s efforts interspaced with 4 min of passive recovery. Total work during the exercises was 17 ± 3.4, 15.8 ± 2.9, 16.7 ± 3.4, and 18.0 ± 3.0 kJ for BFR, G-BFR, HYP and NOR, respectively. Muscle oxygenation was continuously measured with near-infrared spectroscopy. Tissue saturation index (TSI) was modelled with a linear function at the beginning of the sprint and reoxygenation during recovery with an exponential function. Results showed that both models were adjusted to the TSI (R2 = 0.98 and 0.95, respectively). Greater deoxygenation rates were observed in NOR compared to BFR (p = 0.028). No difference was found between the conditions for the deoxygenation rates relative to sprint total work (p > 0.05). Concerning reoxygenation, the amplitude of the exponential was not different among conditions (p > 0.05). The time delay of reoxygenation was longer in BFR compared to the other conditions (p < 0.05). A longer time constant was found for G-BFR compared to the other conditions (p < 0.05), and mean response time was longer for BFR and G-BFR. Finally, sprint performance was correlated with faster reoxygenation. Hence, deoxygenation rates were not different between the conditions when expressed relatively to total sprint work. Furthermore, BFR conditions impair reoxygenation: BFR delays and G-BFR slows down reoxygenation.

Proton Transfer from a Photoacid to a Water Wire: First Principles Simulations and Fast Fluorescence Spectroscopy.

Proton transfer reactions are ubiquitous in chemistry, especially in aqueous solutions. We investigate photoinduced proton transfer between the photoacid 8-hydroxypyrene-1,3,6-trisulfonate (HPTS) and water using fast fluorescence spectroscopy and ab initio molecular dynamics simulations. Photoexcitation causes rapid proton release from the HPTS hydroxyl. Previous experiments on HPTS/water described the progress from photoexcitation to proton diffusion using kinetic equations with two time constants. The shortest time constant has been interpreted as protonated and photoexcited HPTS evolving into an "associated" state, where the proton is "shared" between the HPTS hydroxyl and an originally hydrogen bonded water. The longer time constant has been interpreted as indicating evolution to a "solvent separated" state where the shared proton undergoes long distance diffusion. In this work, we refine the previous experimental results using very pure HPTS. We then use excited state ab initio molecular dynamics to elucidate the detailed molecular mechanism of aqueous excited state proton transfer in HPTS. We find that the initial excitation results in rapid rearrangement of water, forming a strong hydrogen bonded network (a "water wire") around HPTS. HPTS then deprotonates in ≤3 ps, resulting in a proton that migrates back and forth along the wire before localizing on a single water molecule. We find a near linear relationship between the emission wavelength and proton-HPTS distance over the simulated time scale, suggesting that the emission wavelength can be used as a ruler for the proton distance. Our simulations reveal that the "associated" state corresponds to a water wire with a mobile proton and that the diffusion of the proton away from this water wire (to a generalized "solvent-separated" state) corresponds to the longest experimental time constant.

Microscopic diffusion coefficients of dumbbell- and spherocylinder-shaped colloids and their application in simulations of crowded monolayers.

We explore the diffusion properties of colloidal particles with dumbbell and spherocylinder shapes using a hydrodynamic bead-shell approach and additional Brownian dynamics (BD) simulations. By applying the bead-shell method, we determine empirical formulas for the microscopic diffusion coefficients. A comparison of these formulas and established experimental and theoretical results shows remarkable agreement. For example, the maximum relative discrepancy found for dumbbells is less than 5%. As an application example of the empirical formulas, we perform two-dimensional (2D) BD simulations based on a single dumbbell or spherocylinder in a suspension of spheres and calculate the resulting effective long-time diffusion coefficients. The performed BD simulations can be compared to quasi-2D systems such as colloids confined at the interface of two fluids. We find that the effective diffusion coefficient of translation mostly depends on the sphere area fraction ϕ, while the effective diffusion coefficient of rotation is influenced by the aspect ratio and ϕ. Furthermore, the effective rotational diffusion constant seems to depend on the particle shape with the corresponding implementation of the interactions. In the resolution limit of our methods, the shape-dependent differences of the microscopic diffusion coefficients and the long-time diffusion constant of translation are negligible in the first approximation. The determined empirical formulas for the microscopic diffusion coefficients add to the knowledge of the diffusion of anisotropic particles, and they can be used in countless future studies.

Cardiorespiratory responses to exercise related to post-stroke fatigue severity

Physical deconditioning after stroke may induce post-stroke fatigue. However, research on this association is limited. Our primary objective was to investigate the associations of post-stroke fatigue severity with oxygen uptake (dot{mathrm{V}}O2) at peak exercise and the time constant of dot{mathrm{V}}O2 kinetics (τdot{mathrm{V}}O2) at exercise onset. The secondary objective was to examine the associations between fatigue and cardiorespiratory variables potentially affecting dot{mathrm{V}}O2 during exercise. Twenty-three inpatients from a subacute rehabilitation ward were enrolled in this study. The median (interquartile range) Fatigue Severity Scale (FSS) score, as a measure of fatigue, was 32 (range 27–42) points. The FSS score was not associated with dot{mathrm{V}}O2 at peak exercise during a symptom-limited graded exercise test (rho = − 0.264; p = 0.224), whereas it was significantly associated with τdot{mathrm{V}}O2 during a submaximal constant-load exercise test (rho = 0.530; p = 0.009). A higher FSS score also significantly correlated with a longer time constant of cardiac output (CO) kinetics (rho = 0.476; p = 0.022). Our findings suggest that severe post-stroke fatigue is associated with delayed increases in dot{mathrm{V}}O2 and CO at the onset of exercise. Our findings can contribute to the development of an appropriate rehabilitation programme for individuals with post-stroke fatigue.

Site-selective dynamics of azidolysozyme.

The spectroscopic response of and structural dynamics around all azido-modified alanine residues (AlaN3) in lysozyme are characterized. It is found that AlaN3 is a positionally sensitive probe for the local dynamics, covering a frequency range of ∼15 cm-1 for the center frequency of the line shape. This is consistent with findings from selective replacements of amino acids in PDZ2, which reported a frequency span of ∼10 cm-1 for replacements of Val, Ala, or Glu by azidohomoalanine. For the frequency fluctuation correlation functions, the long-time decay constants τ2 range from ∼1 to ∼10 ps, which compares with experimentally measured correlation times of 3 ps. Attaching azide to alanine residues can yield dynamics that decays to zero on the few ps time scale (i.e., static component Δ0 ∼ 0 ps-1) or to a remaining, static contribution of ∼0.5 ps-1 (corresponding to 2.5 cm-1), depending on the local environment on the 10 ps time scale. The magnitude of the static component correlates qualitatively with the degree of hydration of the spectroscopic probe. Although attaching azide to alanine residues is found to be structurally minimally invasive with respect to the overall protein structure, analysis of the local hydrophobicity indicates that the hydration around the modification site differs for modified and unmodified alanine residues, respectively.

Lifetime and Performance Assessment of Commercial Electric Double-Layer Capacitors Based on Cover Layer Formation.

The lifetime and performance of energy storage systems are essential characteristics for a major success of clean energy innovations, especially regarding the automotive sector. In this area, electric double-layer capacitors represent the cutting edge of nonfaradaic, high power, and long lifetime energy storages. Usually, degradation is neglected while operating or it is assessed by referring to simple rules of thumb. To better address the aging effects, commercial specimens have been investigated in-depth. The works can be split into two parts: first, extensive accelerated aging for more than 3 years to statistically analyze the degradation trend and significantly improve the current rules. Second, cell opening and surface characterization of the electrodes to gain a profound understanding of the ongoing processes and to correlate aging mechanisms to the statistics of the first part. It is found that a prominent cover layer forms during degradation on the positive electrode scaling with lost capacitance. The used methods for in-depth characterization include microscopy, X-ray diffraction, and thermogravimetric analysis with subsequent mass spectrometry. The newly formed layer consists of poly(tetrafluoroethylene) (also known as Teflon) that is still passable by charge carriers, albeit with a longer time constant. Additionally, the negative electrode shows corrosion and loss of contact. The composition of the cover layer has not been known yet. Thus, materials and especially electrolyte development can benefit from the results.

The velocity storage time constant: Balancing between accuracy and precision.

The velocity storage mechanism is often described in terms of the exponential decay in eye velocity in an upright subject who experiences a constant velocity yaw rotation after a rapid acceleration. The velocity storage time constant for this decay is roughly 6-30s, which means that for low-frequency head rotations, eye velocity and perceptions have large errors compared to actual motion. One may wonder if there would be benefits to having a longer time constant, which would improve accuracy. In this paper, simulations are used to highlight that improved accuracy may come at the cost of increased noise-i.e., reduced precision. Specifically, since the velocity storage mechanism extends the 5.7s time constant of the semicircular canal, it must be performing an integration process over a certain frequency range. In fact, all mathematical models of velocity storage include an integration. This integration would also integrate neural noise. Thus, increasing the velocity storage time constant would lead to integration over a wider range of frequencies, resulting in more noise in the brain's estimate of motion. Simulation results show this accuracy-precision tradeoff. Recent evidence is also reviewed supporting the hypothesis that the brain optimizes the velocity storage time constant to resolve this accuracy-precision tradeoff during aging and with variations in stimulus amplitude.

Dielectric relaxation in acetamide + urea deep eutectics and neat molten urea: Origin of time scales via temperature dependent measurements and computer simulations.

Dielectric relaxation (DR) measurements in the frequency window 0.2 ≤ ν(GHz) ≤ 50 for deep eutectic solvents (DESs) made of acetamide (CH3CONH2) and urea (NH2CONH2) with the general composition, [f CH3CONH2 + (1 - f) NH2CONH2] at f = 0.6 and 0.7, reveal three distinct relaxation time scales-τ1 ∼ 120 ps, τ2 ∼ 40 ps, and τ3 ∼ 5 ps. Qualitatively similar time scales have been observed for DR of neat molten urea, whereas the reported DR for neat molten acetamide in the same frequency window reflects two relaxation processes with no trace of ∼100 ps time scale. This slowest DR time scale (τ1) resembles closely to the long-time constant of the simulated structural H-bond relaxation (CHB(t)) involving urea pairs. Similarity in activation energies estimated from the temperature dependent DR measurements (335 ≤ T/K ≤ 363) and structural H-bond relaxations indicates that the structural H-bond relaxation overwhelmingly dominates the slowest DR relaxation in these DESs. Simulated collective reorientational correlation functions (C ℓ (t)), on the other hand, suggest that the second slower time scale (∼40 ps) derives contributions from both the single particle orientation dynamics and structural H-bond relaxation, leaving no role for hydrodynamic molecular rotations. The sub-10 ps DR time scale has been found to be connected to the fast reorientation dynamics of the component molecules (acetamide or urea). Fractional viscosity dependence for the longest DR times, , has been observed for these DESs with the fraction power p = 0.7. Subsequently, the temporal heterogeneity aspects of these media have been investigated by examining the simulated particle motion characteristics and substantiated by estimating the dynamically correlated time scales and length-scales through simulations of four-point susceptibilities and density correlations. These estimated dynamical time scales and length-scales assist in explaining the different inferences regarding solution heterogeneity drawn from different measurements on these DESs.

Computation predicts rapidly adapting mechanotransduction currents cannot account for tactile encoding in Merkel cell-neurite complexes.

Distinct firing properties among touch receptors are influenced by multiple, interworking anatomical structures. Our understanding of the functions and crosstalk of Merkel cells and their associated neurites—the end organs of slowly adapting type I (SAI) afferents—remains incomplete. Piezo2 mechanically activated channels are required both in Merkel cells and in sensory neurons for canonical SAI responses in rodents; however, a central unanswered question is how rapidly inactivating currents give rise to sustained action potential volleys in SAI afferents. The computational model herein synthesizes mechanotransduction currents originating from Merkel cells and neurites, in context of skin mechanics and neural dynamics. Its goal is to mimic distinct spike firing patterns from wildtype animals, as well as Atoh1 knockout animals that completely lack Merkel cells. The developed generator function includes a Merkel cell mechanism that represents its mechanotransduction currents and downstream voltage-activated conductances (slower decay of current) and a neurite mechanism that represents its mechanotransduction currents (faster decay of current). To mimic sustained firing in wildtype animals, a longer time constant was needed than the 200 ms observed for mechanically activated membrane depolarizations in rodent Merkel cells. One mechanism that suffices is to introduce an ultra-slowly inactivating current, with a time constant on the order of 1.7 s. This mechanism may drive the slow adaptation of the sustained response, for which the skin’s viscoelastic relaxation cannot account. Positioned within the sensory neuron, this source of current reconciles the physiology and anatomical characteristics of Atoh1 knockout animals.

A Reconstruction of the WAMS-Detected Transformer Sympathetic Inrush Phenomenon

The transformer-energization inrush phenomenon is to be expected in cases when a single transformer is connected to an ac voltage source. The most commonly employed mitigation technique is to use mechanisms that enable per-phase controlled switching based on a residual magnetic-flux estimation in the transformer’s ferromagnetic iron core. However, the time scale of the phenomenon is relatively short and imposes no extremely critical issues to wide-scale power-system operation. On the other hand, the sympathetic inrush phenomenon that might occur among several parallel transformers exhibits much longer time constants (several seconds and even tens of seconds). The resulting system impact becomes longer lasting. Recently, national wide area monitoring system (WAMS) measurements indicated that a sympathetic interaction occurred between two parallel 400/110-kV transformers in the Slovenian power system. The cause was the magnetization of a second transformer in parallel to the already operational and fully loaded one in the substation in electrical vicinity to a large power plant. Apart from the WAMS, the event was also captured by the transformer’s over-current protection relay. The specifics of the event are described in this paper together with a dynamic-simulation-based reconstruction that is very important for the operator’s understanding of on-line, WAMS-provided, and system measurements.

Autocorrelation Structure in the Macaque Dorsolateral, But not Orbital or Polar, Prefrontal Cortex Predicts Response-Coding Strength in a Visually Cued Strategy Task.

In previous work, we studied the activity of neurons in the dorsolateral (PFdl), orbital (PFo), and polar (PFp) prefrontal cortex while monkeys performed a strategy task with 2 spatial goals. A cue instructed 1 of 2 strategies in each trial: stay with the previous goal or shift to the alternative goal. Each trial started with a fixation period, followed by a cue. Subsequently, a delay period was followed by a "go" signal that instructed the monkeys to choose one goal. After each choice, feedback was provided. In this study, we focused on the temporal receptive fields of the neurons, as measured by the decay in autocorrelation (time constant) during the fixation period, and examined the relationship with response and strategy coding. The temporal receptive field in PFdl correlated with the response-related but not with the strategy-related modulation in the delay and the feedback periods: neurons with longer time constants in PFdl tended to show stronger and more prolonged response coding. No such correlation was found in PFp or PFo. These findings demonstrate that the temporal specialization of neurons for temporally extended computations is predictive of response coding, and neurons in PFdl, but not PFp or PFo, develop such predictive properties.

On current transients in MoS2 Field Effect Transistors

We present an experimental investigation of slow transients in the gate and drain currents of MoS2-based transistors. We focus on the measurement of both the gate and drain currents and, from the comparative analysis of the current transients, we conclude that there are at least two independent trapping mechanisms: trapping of charges in the silicon oxide substrate, occurring with time constants of the order of tens of seconds and involving charge motion orthogonal to the MoS2 sheet, and trapping at the channel surface, which occurs with much longer time constants, in particular when the device is in a vacuum. We observe that the presence of such slow phenomena makes it very difficult to perform reliable low-frequency noise measurements, requiring a stable and repeatable steady-state bias point condition, and may explain the sometimes contradictory results that can be found in the literature about the dependence of the flicker noise power spectral density on gate bias.

Positron Annihilation Lifetime Spectroscopy Application to &lt;i&gt;In Situ&lt;/i&gt; Monitoring of &lt;i&gt;n&lt;/i&gt;-Heptane Sorption in Mesopores

The dynamics of n-heptane adsorption and desorption on two silicas (Si-A and SBA-15) with different porosity was studied using positron annihilation lifetime spectroscopy (PALS). Simplified method of spectra analysis consisting in the summation of counts in the long-lived part of PALS spectra was used. It allowed to observe changes occurring in the minute time scale. The dependence of the number of counts on time could be fairly well approximated by exponential functions. It was found that the time required for reaching equilibrium in long cylindrical pores is up to ten times longer than in bell-mouthed interconnected ones. The longest time constants (ca. 5 min in Si-A and ca. 60 min in SBA-15) were observed for desorption in both samples.

Correlated rearrangements of disordered colloidal suspensions in the vicinity of the reentrant glass transition

We experimentally investigate correlated rearrangements (dynamic heterogeneity) in disordered colloidal suspensions as a function of increasing inter-particle attraction strength across the reentrant glass transition. Attractive interactions between constituent spheres are induced by polymer depletion forces at fixed particle volume fraction. We vary sample inter-particle attraction strength and concurrently measure particle trajectories by confocal microscopy at each attraction strength. The reentrant transition from repulsive glass to ergodic fluid and from ergodic fluid to attractive glass is readily observed. As the inter-particle attraction increases, we find that inter-particle bonding causes an increasing number of particles to undergo cooperative or correlated displacements; the length scale associated with these correlated rearrangements exhibits reentrant behavior. Other dynamical quantities such as the mean square displacement, the long-time diffusion constant, and the non-Gaussian parameter also exhibit changes as a function of attraction strength. Notably, the arrested (glass) states show small particle displacements at long lag times, whereas the fluid states exhibit fast dynamics over large length scales.

Control and Optimization of a Triple String Rotary Cement Kiln using Model Predictive Control

Abstract Pyro processing is one of the most important stages in cement manufacturing process. Control of pyro-processing is vital in improving the energy efficiency and enhancing the production assuring good quality. The complex nature of cement kilns with longer time constants, changing raw material characteristics, non-linear dynamics make them very difficult to control, in addition to that inclusion of various alternative fuels in burning makes the process more complex as the fuel characteristics remain inconsistent throughout the kiln operation. This paper describes a novel way of optimizing a triple string calciner kiln in a real plant using model predictive control and a fuzzy based real time optimizer. Compared to the conventional controllers the MPC handles the disturbances better resulting in improved productivity, lesser energy consumption and better quality.