Localized Bands Research Articles

The deformation mechanisms responsible for strain localization in nanotwinned nickel alloys

Nanotwinned Ni-Mo-W alloys possess a combination of unique mechanical and thermal properties, such as ultrahigh strength and microstructural stability, which are correlated with the presence of densely packed growth twins. In a previous study, the ultrahigh compressive strength of Ni84Mo11W5 (atomic percent) micropillars was associated with the formation of highly localized shear bands, but the trigger for such localized plasticity was not identified. Here, Ni86Mo3W11 (atomic percent) micropillars were carefully compressed to various levels to uncover the nanoscale deformation mechanisms that trigger the strain localization. Post-mortem transmission electron microscopy investigations of pillars after the first measurable strain burst revealed ∼50 nm thick shear bands consisting of reoriented and twin-free grains, while the columnar grains adjacent to the shear bands were partly detwinned. More importantly, unlike the Mo-rich pillars, the W-rich pillars showed discernible plasticity before the first strain burst. Close inspection made before the formation of a mature shear band revealed a detwinning region of ∼30 nm thickness that aligned more parallel to the coherent twin boundaries, and multiple nanotwins truncated with incoherent twin boundaries were resolved between the detwinning band and the nanotwinned grains. These observations strongly suggest detwinning, facilitated by migration of incoherent twin boundaries, to be the precursor to strain localization and the intensive shear banding observed in nanotwinned Ni-Mo-W alloys. Comparing the present results with the literature further highlights the general role of detwinning in governing the plastic behavior of nanotwinned alloys with a wide range of stacking fault energy.

Theoretical insights of 2D Fe3GeTe2/In2Se3 multiferroic vdW heterostructure based gas sensors for high-performance NO detecting

The impact of the harmful gas NO on the atmospheric environment cannot be ignored, so it is necessary to develop efficient gas sensors to detect and absorb NO at room temperature. In this work, we systematically explored the electron transport properties and gas sensing properties of Fe3GeTe2, In2Se3 monolayers and its multiferroic van der Waals (vdW) heterostructures of Fe3GeTe2/In2Se3 for detecting NO by using density functional theory and nonequilibrium Green's function methods. The calculated adsorption energies, electron localisation functions, band structures and density of states indicate that its a chemisorption for the adsorption of NO on Fe3GeTe2 and a physisorption on In2Se3, while the specific adsorption style is highly dependent on the stacking and molecular adsorption sites of different Fe3GeTe2/In2Se3 structures. In addition, the pristine Fe3GeTe2 monolayer and Fe3GeTe2/In2Se3 based nanodevices realized a significant anisotropy for electron transport along the zigzag and armchair directions, and their anisotropic maximum current ratios in the zigzag to armchair directions were 1.90 and 1.89. Meanwhile, the NO sensitivity ratio of Fe3GeTe2 and Fe3GeTe2/In2Se3 based gas sensors can be up to 79 % and 107 %, respectively. This highlights a notably superior gas-sensitive performance of the Fe3GeTe2/In2Se3 heterostructure compared to the Fe3GeTe2 monolayer gas devices. These findings provide valuable references for the application of multiferroic heterostructures in the field of gas sensors.

Self-Assembly of Soft and Conformable Broadband Absorbing Nanocellulose-Gold Nanoparticle Composites.

Broadband light-absorbing materials are of large interest for numerous applications ranging from solar harvesting and photocatalysis to low reflection coatings. Fabrication of these materials is often complex and typically utilizes coating techniques optimized for flat and hard materials. Here, we show a self-assembly based strategy for generating robust but mechanically flexible broadband light-absorbing soft materials that can conform to curved surfaces and surface irregularities. The materials were fabricated by adsorbing large quantities of gold nanoparticles (AuNPs) on the nanofibrils of hydrated bacterial cellulose (BC) membranes by tailoring the interaction potential between the cellulose nanofibrils and the AuNPs. The highly efficient self-assembly process resulted in very dense multilayers of AuNPs on the nanofibrils, causing extensive broadening of the localized surface plasmon resonance band and a striking black appearance of the BC membranes. The nanocomposite materials showed an absorptance >96% in both the visible and the near-infrared wavelength range. The AuNP-functionalized BC membranes demonstrated excellent conformability to curved and structured surfaces and could adopt the shape of highly irregular surface structures without any obvious changes in their optical properties. The proposed self-assembly based strategy enables the fabrication of soft and conformable broadband light-absorbing nanocomposites with unique optical and mechanical properties using sustainable cellulose-based materials.

Experimental investigation of the compressive behavior of epoxy nanocomposites reinforced with straight and helical carbon nanotubes

AbstractThis paper is aimed at an experimental investigation of the effect of straight and helical carbon nanotubes on the compressive behavior of epoxy nanocomposites. The epoxy nanocomposites are fabricated with varying levels of SCNT and HCNT, each with two different fabrication techniques viz. high shear mixing and ultrasonication. In samples made using high shear mixing, the compressive strength is found to actually decrease, due to poor dispersion of the CNTs, resulting in voids and clumps, which can adversely affect the strength. Ultrasonic homogenization is found to better disperse the CNTs within the epoxy resin with nearly a 10‐fold decrease in the heterogeneity size. Compression tests conducted on the ultrasonically homogenized CNT‐epoxy nanocomposites indicate a modest increase in the compressive strength. The best increase of 5% is obtained with 1% SCNT. On the other hand, the HCNT samples show a higher post‐peak residual stress suggesting an improved mode II/III fracture toughness. The high shear mixed samples exhibit a bulging deformation with no clear evidence of shear localization. On the other hand, the ultrasonic homogenization (UH) samples bulge and eventually show a clear localized shear band, likely due to a smaller heterogeneity size. Some samples with relatively poor dispersion exhibit an axial splitting failure and a comparatively low compressive strength. In addition, it is demonstrated that using acetone as a solvent during dispersion can affect the curing kinetics, which results in a nanocomposite with a rubbery consistency with low stiffness and strength, but high deformability.Highlights Straight and helical CNTs impact the compressive behavior of epoxy nanocomposites High shear mixing reduces compressive strength due to poor CNT dispersion Ultrasonication improves CNT dispersion but modest rise in compressive strength HCNTs cause higher post‐peak residual stress suggesting higher toughness Using acetone affects curing, leading to rubbery, deformable nanocomposites.

Ultrahigh Thermal Robustness of High‐Entropy Spectrally Selective Absorbers for Next‐Generation Concentrated Solar Power System

AbstractSpectrally selective absorbers (SSAs) are a critical component in concentrated solar power (CSP) systems, as they maximize sunlight absorption while suppressing heat radiative loss. Despite various SSAs being demonstrated, the challenges remain on the limitations of thermal instability at elevated operating temperatures especially above 650 °C due to component oxidation and diffusion in the absorption layer. To address these challenges, herein a high‐entropy strategy is resorted. By utilizing high‐entropy nitride film as an absorption layer, a double‐layer SSA is prepared by a facile magnetron sputtering method. High‐entropy engineering intensifies and complicates the localized electronic bands, concurrently exhibiting relatively flat bands around the Fermi level, which can significantly enhance 3d interband transition. The resultant SSA delivers the desired spectral selectivity (α/ɛ82 °C = 92.7%/8.4%). Benefitting from the high‐entropy effect, the SSA maintains outstanding optical properties (α/ɛ82 °C = 93.3%/9.4%) even after a 750 °C vacuum thermal treatment for 120 h. Under 1 kW m−2 simulated illumination, the surface temperature of the absorber can easily rise to 95.3 °C, suggesting its remarkable solar‐thermal performance. Furthermore, its effectiveness in parabolic trough collectors (PTCs) is validated. All these competitive performances make the high‐entropy SSA a potentially promising candidate for PTCs.

498. LATROGENIC ESOPHAGEAL DISEASE POST OBESITY TREATMENT: SEVERE ESOPHAGEAL DILATATION RELATED TO ADJUSTABLE GASTRIC BANDING (AGB)

Abstract Iatrogenic Esophageal Disease post obesity treatment: severe esophageal dilatation related to adjustable gastric banding (AGB) Introduction Obesity is considered one of the biggest epidemics of the 21st century, which pushes us as health professionals to seek for solutions to this pathology. Within the medical-surgical approach, the most used techniques are gastric bypass, vertical gastrectomy and adjustable gastric banding (AGB). Even though they are frequently used, they are not free of complications. In this communication based on a case we would like to comment on the main complications of the use of the gastric band. These side effects has being between 0.5-5% to 20%: stoma stenosis, band slippage, intraluminal erosion, gastric volvulus and perforation. Clinical Case 54-year-old woman underwent surgery 20 years ago for obesity using a restrictive technique with adjustable gastric banding. The patient began 18 years later with retrosternal pain, epigastric pain, vomiting and dysphagia. Endoscopic tests revealed esophageal dilation with retention of food remains, tortuous and macerated mucosa; said achalasia was caused by a gastroesophageal stenosis. Among the diagnostic tests, an esophageal-gastric-duodenal barium transit was performed, showing a decrease in peristalsis with diffuse esophageal dilation of up to 7cm in diameter. Stenosis was observed in the lower esophageal third at the level of the esophagogastric junction of approximately 16 x 11 mm in longitudinal and transverse diameters. Evolution Surgical removal of the device is decided by a multidisciplinary team. Laparoscopic release of the gastric band was performed with electrocautery following adhesions around the device. Complete withdrawal upon release. Intraoperative endoscopy was performed, showing significant esophageal dilation with retained fermented food remains, mucous membrane affected by esophageal candidiasis. After the esophagogastric junction, a gastric fibrous ring was evidenced at the place of location of the gastric band, with good passage without evidence of gastric or esophageal lesions. Favorable postoperative evolution, being discharged 24 hours after surgery. After the case we observed the failure of the safety mechanism of the gastric band that regulates the internal diameter of the device due to the formation of a fibrotic constriction ring. Removal of the device improves the symptoms without requiring, in this case, section of the constriction ring. Currently, the patient shows improvement in her symptoms 6 months after the bariatric revision surgery.

A damage rock model considering shear failure by modified logistic growth theory

Localized rock failures, like cracks or shear bands, demand specific attention in modeling for solids and structures. This is due to the uncertainty of conventional continuum-based mechanical models when localized inelastic deformation has emerged. In such scenarios, as macroscopic inelastic reactions are primarily influenced by deformation and microstructural alterations within the localized area, internal variables that signify these microstructural changes should be established within this zone. Thus, localized deformation characteristics of rocks are studied here by the preset angle shear experiment. A method based on shear displacement and shear stress differences is proposed to identify the compaction, yielding, and residual points for enhancing the model's effectiveness and minimizing subjective influences. Next, a mechanical model for the localized shear band is depicted as an elasto-plastic model outlining the stress-displacement relation across both sides of the shear band. Incorporating damage theory and an elasto-plastic model, a proposed damage model is introduced to replicate shear stress-displacement responses and localized damage evolution in intact rocks experiencing shear failure. Subsequently, a novel nonlinear mathematical model based on modified logistic growth theory is proposed for depicting the shear band's damage evolution pattern. Thereafter, an innovative damage model is proposed to effectively encompass diverse rock material behaviors, including elasticity, plasticity, and softening behaviors. Ultimately, the effects of the preset angles, temperature, normal stresses and the residual shear strength are carefully discussed. This discovery enhances rock research in the proposed damage model, particularly regarding shear failure mode.

Sand improvement by microbial-induced carbonate precipitation with casein micelles

This study explores the incorporation of casein micelles to improve the conventional microbial-induced carbonate precipitation technique used for soil improvement. With a single application of the proposed biocementing agent containing casein micelles, a mixed slurry of natural sand solidified to self-sustaining strength within 48 h at 37°C was obtained. The stress–strain curves of the biocemented specimens obtained from a consolidated drained triaxial compression test exhibited sharp peaks at less than 1% strain. Under effective confining pressures of 30, 50 and 100 kPa, the peak deviatoric stress registered 415, 479 and 536 kPa, respectively – representing 1·8–4·1 times the maximum strength of the original sand. Vaterite calcium carbonate crystals formed by the biocementing agent ensured bridging between sand particles, resulting in the improved cohesion. The cohesion-derived residual strength tended to increase at the critical state in biocemented sand under the lowest confining stress. The localised shear band formed by the crystals may control the movement of sand particles, resulting in a change in volumetric strain behaviour. The formation of casein micelles induced the nucleation and growth of spherical crystals, acting as a casein-mediated vaterite. This formation likely contributed to the improved cohesion of sand observed in this study.

Dynamic rupture modeling in a complex fault zone with distributed and localized damage

Active fault zones have complex structural and geometric features that are expected to affect earthquake nucleation, rupture propagation with shear and volumetric deformation, and arrest. Earthquakes, in turn, dynamically activate co-seismic off-fault damage that may be both distributed and localized, affecting fault zone geometry and rheology, and further influencing post-seismic deformation and subsequent earthquake sequences. Understanding this co-evolution of fault zones and earthquakes is a fundamental challenge in computational rupture dynamics with consequential implications for earthquake physics, seismic hazard and risk. Here, we implement a continuum damage-breakage (CDB) rheology model in our MOOSE-FARMS dynamic rupture simulator to investigate the interplay between bulk damage and fault motion on the evolution of dynamic rupture, energy partitioning, and ground motion characteristics. We demonstrate several effects of damage (accounting for distributed cracking) and breakage (accounting for granulation) on rupture dynamics in the context of two prototype problems addressed currently in the 2D plane-strain setting: (1) a single planar fault and (2) a fracture network. We quantify the spatio-temporal reduction in wave speeds associated with dynamic ruptures in each of these cases and track the evolution of the original fault zone geometry. The results highlight the growth and coalescence of localization bands as well as competition between localized slip on the pre-existing faults vs. inelastic deformation in the bulk. We analyze the differences between off-fault dissipation through damage-breakage vs. plasticity and show that damage-induced softening increases the slip and slip rate, suggesting enhanced energy radiation and reduced energy dissipation. These results have important implications for long-standing problems in earthquake and fault physics as well as near-fault seismic hazard, and they motivate continuing towards 3D simulations and detailed near-fault observations to uncover the processes occurring in earthquake rupture zones.

Hot Workability and Microstructure Evolution of Homogenized 2050 Al-Cu-Li Alloy during Hot Deformation.

For this article, hot compression tests were carried out on homogenized 2050 Al-Cu-Li alloys under different deformation temperatures and strain rates, and an Arrhenius-type constitutive model with strain compensation was established to accurately describe the alloy flow behavior. Furthermore, thermal processing maps were created and the deformation mechanisms in different working regions were revealed by microstructural characterization. The results showed that most of the deformed grains orientated toward <101>//CD (CD: compression direction) during the hot compression process, and, together with some dynamic recovery (DRV), dynamic recrystallization (DRX) occurred. The appearance of large-scale DRX grains at low temperatures rather than in high-temperature conditions is related to the particle-stimulated nucleation mechanism, due to the dynamic precipitation that occurs during the deformation process. The hot-working diagrams with a true strain of 0.8 indicated that the high strain-rate regions C (300 °C-400 °C, 0.1-1 s-1) and D (440 °C-500 °C, 0.1-1 s-1) are unfavorable for the processing of 2050 Al-Li alloys, owing to the flow instability caused by local deformation banding, microcracks, and micro-voids. The optimum processing region was considered to be 430 °C-500 °C and 0.1 s-1-0.001 s-1, with a dissipation efficiency of more than 30%, dominated by DRV and DRX; the DRX mechanisms are DDRX and CDRX.

Experimental study of rock fracture behavior under direct tension using three-dimensional digital image correlation

Understanding the mechanical characteristics of rocks when subjected to direct tension is crucial for assessing the stability of rock formations. Within the scope of this research, a series of tests was conducted using Tage tuff to assess the deformation behavior and crack extension of rock under direct tension. The axial, lateral, and shear strain fields as well as crack propagation, localized deformation behavior, and failure mode of the rocks were analyzed using three-dimensional digital image correlation method. The results showed that the axial strain fields on the specimen surface were heterogeneous, with different locations and localization occurring in the pre-peak stage, which was similar to the evolution of shear strain, whereas the lateral strain only showed slight changes. The crack extension direction was inferred, indicating that both tensile and shear stress occurred in the tests. Furthermore, different stress–strain responses were observed for the inside and outside of the localized bands. Then, the surface patterns of specimen failure were scanned and analyzed to assess the failure mode and residual strength of the specimen under direct tensile stress. Finally, the results of direct tension, uniaxial compression, and Brazilian split tests for Tage tuff were compared, and the complete stress–strain curve of uniaxial tension (UT) was simulated using a nonlinear-variable-compliance constitutive equation. This study provides a deeper understanding into the damage behavior of rocks under direct tension.

Copper-supported MOF-derived carbon materials for highly efficient antibiotics removal

Facing the escalating issue of antibiotic pollution and the emergence of bacterial resistance in water ecosystems, photocatalytic technology has been widely studied as one of the efficient methods to remove antibiotics in aquatic ecosystem. Herein, the bimetallic organic framework materials Cu/Zn-BTC were synthesized with varying proportions of copper and zinc as metal joints and 1,3,5-phthalic acid as organic ligands. Subsequently, the zinc elements within the MOF were eliminated through high pyrolysis to obtain carbon materials derived from Cu/Zn-BTC (referred to as 1.3CZC, 1.4CZC, and 1.5CZC based on the copper-to-zinc ratio). Notably, the presence of different valence copper species facilitated to form type II heterojunction within MOF-derived carbon materials, where internal Cu0/Cu+ species combined with oxygen vacancies to create localized bands that prolonged the lifetime of photogenerated carriers and enhanced photocatalytic activity. X-ray photoelectron spectroscopy, Brunauer-Emmett-Taylor and other characterization methods were used to analyze the difference in structure and performance of different catalysts. 1.4CZC showed excellent performance, upon exposure to visible light for 30 min, the removal rate of tetracycline significantly increased to an impressive 92.4 %, while extending the exposure time to 60 min further improved the removal rate of ciprofloxacin to approximately 82.6 %. It provides a highly efficient antibiotics removal pathway by MOF-derived carbon materials.

Unraveling the infrared spectrum of graphene oxide

The applicability of infrared spectroscopy toward graphene oxide (GO) and its derivatives is currently very limited, because the exact location of absorbance bands, originated by the main functional groups of GO, in the spectrum is still under debate. This obstacle leads to widespread misinterpretation of FTIR spectra in literature, and to invalid conclusions on attaining target functionalization reactions. In this work, by involving GO in four types of reactions, for the first time, we identify absorbance bands, originated by the main functional groups of GO: epoxides and tertiary alcohols. Also, we identify the bands, associated with carboxyl and carboxylate groups. In addition, we reconfirm the band assignment for absorbed water molecules (1619 cm−1) and covalent sulfates (1221 cm−1 and 1410 cm−1). Finally, we show conditions for appearance, and the exact position of the band of the C=C bond stretch. All together we accurately assign eight previously unidentified or incorrectly assigned absorbance bands in the fingerprint region of the spectrum, plus three bands which appear in the spectra of specific forms of GO. The assignment of the bands is independently confirmed by the 13C SSNMR spectroscopy. Summing up the newly assigned and the re-confirmed bands, for the first time, we report a complete library of the main absorbance bands in the FTIR spectrum of GO and GO derivatives.

Enlargement of the localized resonant band gap by using multi-layer structures

Multi-layer structures possess highly geometrically tunable optical resonances to change the surface plasmon frequencies in the wide range. A simple analytic model is presented to describe the plasmon hybridization of multi-layer metamaterial structures with multipole resonances. We theoretically demonstrate that the number of plasmon modes increases with the number of layers, which results in the enlargement of the localized resonant optical band gap. To explore the interaction between incident fields and multi-layer structures, we derive the closed-form perturbed field in terms of a generalized polarization matrix, whose dimension matches the number of layers. This enables us to obtain the eigenmode frequencies and their corresponding eigenfunctions for three-dimensional multi-layer concentric spheres and two-dimensional multi-layer concentric cylinders in a vacuum setting. These findings offer nanoscientists a general design principle that can be applied to facilitate the proper selection of the metamaterial parameters, thereby inducing the desired resonance and enabling customized applications to be realized.

Phononic crystals with incomplete line defects: applications in high-performance and broadband acoustic energy localization and harvesting

Using phononic crystals (PnCs) to enhance the electrical output performance of piezoelectric energy harvesting (PEH) devices and broaden the frequency range of harvesting energy is crucial to solving the self-energy of low-power devices such as wireless sensors. In this work, an ultra-wide full-band gap PnC was designed. The concept of a PnC with an incomplete line defect was proposed. The energy localization and harvesting of incomplete line defect PnCs and traditional point defect and line defect PnCs were studied by finite element analysis. The results show that compared with a point defect and a line defect, the output electric power of an incomplete line defect was increased by 31.88 times and 2.51 times, respectively, and the energy localization and harvesting frequency band were widened. By exploring the influence of the periodicity of the vertical incomplete line defect direction on the electrical output performance of the PnC-based PEH system, it is found that the electrical output performance of the 5 × 3 incomplete line defect PnC is the best, and the maximum output voltage and output electric power are 27.36 V and 17.29 mW, respectively. This work provides new insights and ideas for improving the energy localization and harvesting performance of PnC-based PEH systems.

Effects of local strain on the plastic deformation and fracture mechanism of heterogeneous multilayered aluminum

Elucidating the effect of local strain on the mechanical properties is of great significance for the design of high-performance layered metals. For this purpose, we conceived the present study, featured by tailoring the local strain by layer thickness design, and simultaneous monitoring of local strain and geometrically necessary dislocations (GNDs) via coupling in-situ electron backscatter diffraction (EBSD) and high-resolution digital image correlation (DIC). In addition, synchrotron X-ray micro-computed tomography (μCT) was employed to analyze the microcracks that serve as another form of strain localization. Such detailed experimental studies revealed that the interfacial strain gradient was rapidly elevated, and the strain localization band was effectively dispersed as the layer thickness decreased. This leads to two typical transitions, from grain-boundary-related to layer-interface-related plastic deformation mode, and from macroscopic shear to zig-zag fracture mode. Their influences on the mechanical properties, as well as underlying mechanisms, were discussed based on the relationship among the layer thickness, strain gradient, strain localization, GND density, and microcracks. Our work not only contributes to the fundamental understanding of the mechanical behavior of multilayered metals but also offers guidance for the structural design of high-performance metals aimed at achieving superior strength-ductility combinations.

Transformation pattern of shape-memory NiTi alloy during stress-biased thermal cycling

Despite the superelastic deformation of NiTi has been documented and analyzed elaborately, its shape-memory behavior during stress-biased thermal cycling has not been thoroughly unveiled. This paper examines the evolution of transformation pattern in NiTi upon thermal cycling over a wide range of biasing stress. For the present shape-memory NiTi, both forward and reverse transformations proceed via the growth of localized deformation band (LDB) under low biasing stress (σbias ≤ 150 MPa), while LDB only appears during forward transformation and reverse transformation is uniform under high biasing stress (σbias ≥ 200 MPa). This is the first time that delocalization (conversion of deformation mode from localization to homogeneity) is observed during stress-biased thermal cycling. We clarify that the intrinsic undercooling/overheating of martensitic transformation results in unstable thermomechanical response, and it is the origin of localization in shape-memory NiTi. It is found that transformation-induced plasticity (TRIP), which is dominated by dislocation slip and deformation twining, not only causes irreversibility in the present shape-memory NiTi but also leads to delocalization through stabilization of intrinsic thermomechanical response of reverse transformation.

Hydration of mafic crustal rocks at high temperature during brittle‐viscous deformation along a strike‐slip plate boundary

AbstractThe Poroshiri ophiolite (Hidaka metamorphic belt, Japan) occurs within a crustal‐scale network of high‐temperature, dextral shear zones that accommodated hundreds of kilometres of displacement due to the opening of the Japan Sea in the Neogene. The opholitic rocks comprise ultramafic, mafic and sedimentary protoliths that have been variably hydrated and metamorphosed. This work investigates the mechanisms and timing of fluid influx relative to viscous deformation in metagabbros and amphibolites deformed during exhumation from granulite‐ to amphibolite‐facies conditions. We consider a range of microstructures, from low strain domains and 1–2 mm thick shear bands to mylonites with a thickness of a few meters. Low strain domains of metagabbros exhibit corona textures with symplectites consisting of pargasitic amphibole (Ed0.7) ‐ anorthitic plagioclase (An80–92) ± orthopyroxene ± clinopyroxene forming around olivine and igneous pyroxene and with similar plagioclase–amphibole‐orthopyroxene ± clinopyroxene granoblastic aggregates in micrometric‐thick fractures. These textures result from hydration under low fluid‐rock ratio, with elevated H2O content only occurring locally (H2O &gt; 1–1.2 wt%). Igneous mineral replacement leads to grain size reduction from 1 mm to ~10 μm. Amphibole exhibits a strong core‐rim zonation primarily controlled by the high diffusivity of Fe, Mg and OH and the low diffusivity of Al. Mineral compositional equilibrium is achieved at the scale of 100–200 μm. In mm‐thick localized shear bands and in metric‐scale mylonitic amphibolites, the heterogeneous mineral composition of amphibole (Ed0.2–0.5) and plagioclase (An40−An80) indicates only partial re‐equilibration (at the scale of 200–500 μm) despite higher fluid‐rock ratios and more pervasive fluid percolation than in metagabbros. Plagioclase–amphibole thermometry and equilibrium phase diagrams indicate that the initial fluid infiltration and corona formation occurred at 800–850°C by fracturing and percolation along grain boundaries. This was followed by the main fluid percolation and mylonitization event, which occurred during exhumation and cooling at conditions of 720–580°C, ~4 kbar. Continuous hydration during retrogression was achieved by the influx of dominantly seawater‐derived fluid, as attested by the high chlorine (Cl) contents (&gt;300–400 ppm) of amphiboles in fractures. The heterogeneous distribution of fractures controls the distribution of fluid from the earliest stages of hydration, creating positive feedback where the growth of hydrous minerals as amphibole (up to +300 vol% of amphibole in high strain areas relative to the low‐strain ones) and the formation of fine‐grained mixed domains that led to further localization of viscous strain and mass transfer (variations of ± 30–40% in major elements). The Poroshiri ophiolite therefore represents a good fossil example of a former transpressional plate boundary where coupled metamorphic and deformation processes were triggered by seawater‐derived fluid that percolated to depths of ~15 km.

In-situ investigation of coordinated deformation behavior of Ti-6242S alloy with duplex microstructure

In this work, the coordinated deformation behavior related to slip activation, slip transfer and microcrack growth of Ti-6242S alloy with duplex microstructure was investigated through the in-situ tensile testing. It was found that the deformation process of duplex microstructure can be divided into three stages: slip deformation, the formation of slip band and microcrack nucleation, crack propagation and fracture. And single slip was the dominant slip mode, and multiple slip was the auxiliary slip mode. During the initial tensile stage, the slip lines appearing within colony α were shallower than those within primary α owing to the hindering of α/β interface. The slips penetrated across the entire colony region by straight line. This was because there existed a Burgers orientation relationship between lamellar α and β layer, and the orientation of lamellar α was similar. Meanwhile, the common crystal plane between adjacent grains can still provide good condition for slip transfer when the grain boundary was greater than 15°. Moreover, the slip transfer between adjacent slip systems was more prone to occur when there existed good geometric compatibility and high Schmid factor of exit slip system, which provided coordinated deformation between adjacent grains and avoided stress concentration. However, due to the existence of incompatible deformation, the cracks were generated at the stress concentration areas and then grew along the grain boundary or localized slip band.

New Insights into the Ingot Breakdown Mechanism of Near-β Titanium Alloy: An Orientation-Driven Perspective

The ingot breakdown behavior of a typical near-β titanium alloy, Ti-55511, was investigated by various multi-pass upsetting processes. Particular emphasis was placed on the breakdown mechanism of the ultra-large β grains. The results showed that the upsetting far above the β-transus yielded uniform and refined macrostructure with relatively coarse grain size. In contrast, subtransus deformation within the (α + β) dual-phase field caused severe strain localization and macroscale shear bands. It was found that the static recrystallization during the post-deformation annealing was determined by the preferential grain orientations, which were closely related to the processing conditions. During β-working, the stable &lt;001&gt;-oriented grains were predominant and fragmentized mainly via a so-called “low-angle grain boundary merging” mechanism, even under a fairly low deformation. However, the vast &lt;001&gt; grain area was unbeneficial for microstructural conversion since it provided minor nucleation sites for the subsequent annealing. In contrast, the α/β-working produced the majority &lt;111&gt;-orientated grains, which were strongly inclined to strain localization. Highly misoriented deformation/shear bands were massively produced within the &lt;111&gt; grains, providing abundant nucleation sites for static recrystallization and, hence, were favorable for microstructural refinement. Furthermore, the intrinsic causes for deformation nonuniformity were discussed in detail, as well as the competition between microstructural homogeneity and refinement.