Lightweight, and broad and strong absorption are still a huge challenge for electromagnetic (EM) wave absorbers. Here, we propose a facile oxidative polymerization-carbonization strategy to synthesize O, S, N codoped carbon planar helixes for superior EM wave absorbers. The spiral cetyltrimethylammounium bromide crystallites act as a template for the in-situ oxidative polymerization of pyrroles into ordered PPy spiral nanowires. Sintering temperature (Ts) was used to adjust the defects, heteroatoms, graphitization degree, and properties of the carbonized products. With Ts varying from 400 °C to 800 °C, internal stress and heteroatom (N, O, S) content decreased, causing the decreased defect/dipole polarization and increased graphitization degree and conductivity loss. As a result, one broad high-frequency absorption band was exhibited by carbon planar helixes produced at 400 °C− 500 °C, two broad absorption bands were exhibited by those formed at 600 °C, and three absorption bands were exhibited by those formed at 700 °C − 800 °C. The carbon planar helix formed at 700 °C exhibited broader bandwidth (4.96 GHz), thinner sample thickness (1.4 mm), and stronger absorption (−35.44 dB) than those of other absorbers. The superior properties are attributed to a combination of dipole/defect polarization, interface polarization, conductivity loss, multiple scattering, and multiple LC-resonances generated from the unique planar helical structure, defects, heteroatoms, and local electric network.