Local Droplet Research Articles

Local Droplet Etching with Indium Droplets on InP(100) by Metal–Organic Vapor Phase Epitaxy

Local Droplet Etching with Indium Droplets on InP(100) by Metal–Organic Vapor Phase Epitaxy

High-Fidelity Sensing Modality for Anomaly Detection in Inkjet Printing

Abstract Inkjet three-dimensional (3D) printing has emerged as a transformative manufacturing technique, finding applications in diverse fields such as biomedical, metal fabrication, and functional materials production. It involves precise deposition of materials onto a moving substrate through a nozzle, achieving submillimeter scale resolution. However, the dynamic nature of droplet deposition introduces uncertainties, challenging consistent quality control. Current process monitoring, relying on image-based techniques, is slow and limited, hindering real-time feedback in erratic droplet ejection. In response to these challenges, we present the zero-dimensional ultrafast sensing (0-DUS) system, a novel, cost-effective, in situ monitoring tool designed to assess the quality of drop-on-demand inkjet printing. The 0-DUS system leverages the sensitivity of the light-beam field interference effect to rapidly and precisely detect and analyze localized droplets. Two core technical advancements drive this innovation: first, the exploration of integral sensing of the computational light-beam field, which allows for efficient extraction of temporal and spatial information about droplet evolution, introducing a novel in situ sensing modality; second, the establishment of a robust mapping mechanism that aligns sensor data with image-based data, facilitating accurate estimation of droplet characteristics. We successfully implemented the 0-DUS system within a commercial inkjet printer and conducted a comparative analysis with ground truth data. Our experimental results demonstrate a detection accuracy exceeding 95%, even at elevated speeds, allowing for an impressive in situ certification throughput of up to 500 Hz. Consequently, our proposed 0-DUS system meets the stringent quality assurance requirements, thereby expanding the potential applications of inkjet printing across a wide spectrum of industrial sectors.

Divergence of Critical Fluctuations on Approaching Catastrophic Phase Inversion in Turbulent Emulsions.

Catastrophic phase inversion, the breakdown of a concentrated emulsion characterized by the most puzzling sudden feature, is crucial in numerous industrial applications. Here we combine well-controlled experiments and fully resolved numerical simulations to study the critical dynamics of catastrophic phase inversion in oil-water emulsions under turbulent flow as the phase-inversion volume fraction is approached. We reveal that the phase inversion is characterized by the critical power-law divergence of fluctuations in the global drag force. We determine the enhanced dynamical heterogeneity in the local droplet structures at approaching the phase inversion, and tightly connect it to the diverging drag fluctuations. Moreover, we show that near to the critical point the phase inversion is triggered as a stochastic process by large fluctuations at both large and small scales. Our findings pave the way to modeling the phase inversion process as an out-of-equilibrium critical-like phenomena.

Local droplet etching of a vicinal InGaAs(111)A metamorphic layer

We demonstrated nanopit formation by Ga-assisted local droplet etching technique in InGaAs metamorphic layers grown on vicinal GaAs(111)A substrates. We studied nanopit formation depending on the substrate temperature, Ga flux and Ga amount. The etched pits show a highly symmetrical pyramidal shape with an equilateral triangular base and the edges of the triangle are along <11¯0> directions. The observed behavior, in terms of nanopit density, depth and, aspect ratio is well described by a model taking into account the dynamics of the droplet etching process.

A comprehensive analysis of uncertainties in warm rain parameterizations in climate models based on in situ measurements

Abstract Because of the coarse grid size of Earth system models (ESM), representing warm-rain processes in ESMs is a challenging task involving multiple sources of uncertainty. Previous studies evaluated warm-rain parameterizations mainly according to their performance in emulating collision-coalescence rates for local droplet populations over a short period of a few seconds. The representativeness of these local process rates comes into question when applied in ESMs for grid sizes on the order of 100 kilometers and time steps on the order of 20-30 minutes. We evaluate several widely used warm-rain parameterizations in ESM application scenarios. In the comparison of local and instantaneous autoconversion rates, the two parameterization schemes based on numerical fitting to stochastic collection equation (SCE) results perform best. However, because of Jessen’s inequality, their performance deteriorates when grid-mean, instead of locally-resolved, cloud properties are used in their simulations. In contrast, the effect of Jessen’s inequality partly cancels the overestimation problem of two semi-analytical schemes, leading to an improvement in the ESM-like comparison. In the assessment of uncertainty due to the large time step of ESMs, it is found that the rain-water tendency simulated by the SCE is roughly linear for time steps smaller than 10 minutes, but the nonlinearity effect becomes significant for larger time steps, leading to errors up to a factor of 4 for a time step of 20 minutes. After considering all uncertainties, the grid-mean and time-averaged rain-water tendency based on the parameterization schemes are mostly within a factor of 4 of the local benchmark results simulated by SCE.

Differential Acute Adipogenic Signaling Changes Following Neuromusculoskeletal Injuries

Following traumatic injury, neuromusculoskeletal tissue undergoes extensive plastic modification. Changes can be observed at the local and systemic levels and can involve tissue function, signaling, and local composition. Currently there is limited understanding of early adipogenic changes following some traumatic injuries, which is needed to understand the long-term lack of functional muscle recovery. The objective of this project was to examine plasticity after injury, namely systemic and local adipogenic signaling and fat droplet deposition following volumetric muscle loss (VML) and denervation injuries. We hypothesized there would be differential changes in local and systemic adipogenic signaling, specifically changes in fat droplet accumulation following neuromusculoskeletal injuries. Adult C57B1/6J mice (n=36; 6 male, 6 female/group): posterior compartment VML, tibial nerve denervation, and naïve control. Both injury models target plantarflexor muscles. Mice were euthanized 72-hrs post-injury. In vivo muscle function was assessed, and gastrocnemius, liver, and serum were saved for analysis. Whole gastrocnemius muscles from a subset (n=4/group) were saved for histology, and five standardized sections were systematically obtained 1.5mm apart; muscle sections were stained with H&amp;E and Oil-Red-O to evaluate total fiber number and fat droplet accumulation, respectively. Data were analyzed by two- and three-way ANOVA with Tukey’s HSD post hoc. Maximal torque declined ~81 and 98% following VML and denervation injury, respectively (main effect p&lt;0.001), and VML-injured muscle was more fatigable than injury naïve (main effect p=0.001). Following denervation, liver insulin-like growth factor 1 (IGF-1) was increased ~52% compared to other groups, and was most pronounced in males (main effect injury p&lt;0.001; sex p=0.021). VML injury resulted in a 4-fold higher muscle IGF-1 regardless of sex (interaction p=0.021), and greater muscle interleukin-6 (IL-6), which was more pronounced in females (main effect injury p=0.001; sex p=0.049). Platelet-derived factor growth receptor (PDFGRα) expression was diminished following VML injury in both sexes (interaction p=0.016); suggesting a decrease in fibro-adipogenic progenitors (FAPs) and an alternative origin responsible for increases in IGF-1 and IL-6 rather than FAPs. Serum leptin concentrations were blunted following both VML- and denervation-injury (main effect p=0.002), which may illicit alterations in the regenerative process, specifically the maintenance of muscle quality. Serum IGF-1 and IL-6 concentrations were not affected by injury (p≥0.164). Histological analysis revealed a significant decrease in total fiber number across the middle three sections of the VML-injured muscle (i.e., the section initially injured) compared to other groups (p≤0.034). Findings provide a foundation for characterizing adipocyte development in the muscle remaining after injury and identify therapeutic targets for rehabilitative and nutritional approaches to address contractile and metabolic impairments following injury. Future work should elucidate the time course of adipogenic signaling following these injuries, with particular interest in their relationship to changes in metabolic and contractile impairments. R01-AR078903 (JAC &amp; SMG); University of Minnesota UROP (BAC). This is the full abstract presented at the American Physiology Summit 2024 meeting and is only available in HTML format. There are no additional versions or additional content available for this abstract. Physiology was not involved in the peer review process.

Temperature-Enhanced Exciton Emission from GaAs Cone-Shell Quantum Dots.

The temperature-dependent intensities of the exciton (X) and biexciton (XX) peaks from single GaAs cone-shell quantum dots (QDs) are studied with micro photoluminescence (PL) at varied excitation power and QD size. The QDs are fabricated by filling self-assembled nanoholes, which are drilled in an AlGaAs barrier by local droplet etching (LDE) during molecular beam epitaxy (MBE). This method allows the fabrication of strain-free QDs with sizes precisely controlled by the amount of material deposited for hole filling. Starting from the base temperature T = 3.2 K of the cryostat, single-dot PL measurements demonstrate a strong enhancement of the exciton emission up to a factor of five with increasing T. Both the maximum exciton intensity and the temperature Tx,max of the maximum intensity depend on excitation power and dot size. At an elevated excitation power, Tx,max becomes larger than 30 K. This allows an operation using an inexpensive and compact Stirling cryocooler. Above Tx,max, the exciton intensity decreases strongly until it disappears. The experimental data are quantitatively reproduced by a model which considers the competing processes of exciton generation, annihilation, and recombination. Exciton generation in the QDs is achieved by the sum of direct excitation in the dot, plus additional bulk excitons diffusing from the barrier layers into the dot. The thermally driven bulk-exciton diffusion from the barriers causes the temperature enhancement of the exciton emission. Above Tx,max, the intensity decreases due to exciton annihilation processes. In comparison to the exciton, the biexciton intensity shows only very weak enhancement, which is attributed to more efficient annihilation processes.

Numerical analysis of impingement characteristics of supercooled large droplets on the surface of a rotating hood

The authors of this study numerically analyze the characteristics of impingement of supercooled large droplets on the surface of the rotating hood of an aircraft. We use the secondary development function of Fluent software to first compare the prevalent models of impinging supercooled large droplets and then develop a modified model to numerically simulate their characteristics of impingement on the surface of a rotating hood in order to examine the effects of the diameter of the droplets, the speed of rotation, and the corresponding velocity of inflow on them. The results showed that the efficiency of the loss of mass of the droplets caused by their splashing and rebounding was low on the top of the cone, while the efficiency of local droplet collection was the highest. The efficiency of mass loss quickly increased, while that of droplet collection sharply decreased in the area of transition from the top to the side. The efficiencies of mass loss and droplet collection were nearly constant on the side of the cone, while that of the latter decreased to zero on the tail of the cone. When the median volumetric diameter of the droplets was increased from 79 to 250 µm, the efficiency of the loss of mass increased by about 15% on the side of the cone, but that of local droplet collection changed only slightly. The efficiency of the loss of mass decreased by about 20%, while that of local droplet collection increased by about 2.6% on the top of the cone under this condition. When the speed of rotation was increased from 1200 to 4300 r/min and the corresponding velocity of inflow was increased from 30 to 140 m/s, the efficiency of mass loss increased by about 15% on the side of the cone, while that of local droplet collection changed little. The efficiency of mass loss on the top of the cone decreased by about 37.5%, while that of local droplet collection increased by about 8% in this case.

Characterization of Sprays Generated by the Expansion of Emulsions with Liquid Carbon Dioxide

AbstractExpanding emulsions with liquid CO2 facilitates the creation of aerosols with an average droplet diameter in the low micrometer size range, which is challenging with conventional atomizers. The droplet formation process of the expansion of high‐pressure emulsions was investigated using a plain‐orifice atomizer and different swirl nozzles. The local droplet size and droplet velocities were measured and used to estimate the local Weber number and thus infer the droplet size reduction. Measurements of the local mass concentration in the aerosol showed that, for the swirl nozzle, the highest concentration was found outside of the central axis, indicating radial momentum generated by the swirl nozzle. Furthermore, it was shown that the type of expansion nozzle used has an influence on the resulting median droplet size in the aerosol. For a water mass load of 0.01, the median droplet diameter was reduced from 8 to 3 μm by increasing the swirl number from 0.01 to 0.1.

Flexible Patterned Electrohydrodynamic Jet Printing Using Orthogonal Deflection Electrodes.

Electrohydrodynamic jet (E-Jet) printing technology provides unmatched advantages in the fabrication of patterned micro/nanostructures. However, the rapid jets generated during printing can lead to localized droplet accumulation on complex structures due to the relatively slow motion control achieved with motorized translation stages, resulting in distorted patterns. To address this challenge, we introduce two jet-deflecting electrodes orthogonally placed on each other, which can rapidly change the electric field in the vicinity of the jet and thus flexibly adjust the flight trajectory of the fast jet to avoid the region where droplets have been deposited. In this way, the jet droplets are precisely controlled to generate high-fidelity microstructures with arbitrary predefined patterns on the stationary substrate. The maximum deflection distance of the jet droplets reaches several hundred microns. Furthermore, the positioning error of the printed structure is less than 3%. Moreover, we successfully obtained a diverse range of complex patterns by combining this technique with stage motion. This innovative printing technology not only enables the fabrication of complex patterned structures with high fidelity but also opens up exciting possibilities for new applications that require complete control of fast droplet positioning.

Visual analysis of model parameter sensitivities along warm conveyor belt trajectories using Met.3D (1.6.0-multivar1)

Abstract. Numerical weather prediction models rely on parameterizations for subgrid-scale processes, e.g., for cloud microphysics, which are a well-known source of uncertainty in weather forecasts. Via algorithmic differentiation, which computes the sensitivities of prognostic variables to changes in model parameters, these uncertainties can be quantified. In this article, we present visual analytics solutions to analyze interactively the sensitivities of a selected prognostic variable to multiple model parameters along strongly ascending trajectories, so-called warm conveyor belt (WCB) trajectories. We propose a visual interface that enables us to (a) compare the values of multiple sensitivities at a single time step on multiple trajectories, (b) assess the spatiotemporal relationships between sensitivities and the trajectories' shapes and locations, and (c) find similarities in the temporal development of sensitivities along multiple trajectories. We demonstrate how our approach enables atmospheric scientists to interactively analyze the uncertainty in the microphysical parameterizations and along the trajectories with respect to the selected prognostic variable. We apply our approach to the analysis of WCB trajectories within extratropical Cyclone Vladiana, which occurred between 22–25 September 2016 over the North Atlantic. Peaks of sensitivities that occur at different times relative to a trajectory's fastest ascent reveal that trajectories with their fastest ascent in the north are more susceptible to rain sedimentation from above than trajectories that ascend further south. In contrast, large sensitivities to cloud condensation nuclei (CCN) activation and cloud droplet collision in the south indicate a local rain droplet formation. These large sensitivities reveal considerable uncertainty in the shape of clouds and subsequent rainfall. Sensitivities to cloud droplets' formation and subsequent conversion to rain droplets are also more pronounced along convective ascending trajectories than for slantwise ascents. The slantwise ascending trajectories are characterized by periods of slower ascent and even descent, during which the sensitivities to the formation of cloud droplets and rain droplets alternate. This alternating pattern leads to large-scale precipitation patterns, whereas convective ascending trajectories do not exhibit this pattern. Thus the primary source for uncertainty in large-scale precipitation patterns stems from slantwise ascents. The strong ascent of convective trajectories leads to large sensitivities of rain mass density to riming and freezing parameters at high altitudes, which are barely present in slantwise ascending trajectories. These sensitivities correspond to uncertainties concerning graupel and hail formation in convective ascents.

Tablet coating in lab-scale drum coaters: Combining DEM simulations and spray experiments to predict tablet coating

In pharmaceutical industry the coating of granulates or tablets is an essential production step, which is often realised in a rotating drum moving the tablet bed and a number of spray nozzles installed above this bed. The nozzles atomise the coating liquid through a high-velocity annular air-stream and apply steering air nozzles for producing an oval-shaped spray. The operational conditions determine the produced droplet size spectrum. The collision of the droplets with the solid particles or tablets in the drum and the resulting coating and film thickness strongly influences the product properties of granulates or tablets. In order to be able to predict the coating result, without running time-consuming lab-scale experiments, it is intended to numerically simulate the entire tablet coating process by combining Computational Fluid Dynamics (CFD), the Discrete Element Method (DEM) and the Lagrangian Parcel Concept (LPC) for simulating the spray propagation originating at the nozzle. For doing so, knowledge on the spray droplet properties produced by the two-fluid spray nozzles is indispensable. Therefore, it is necessary to characterise as a first step the local droplet size and velocity distributions in different spray cross-sections, which is the main focus of the present contribution. Such measurements are efficiently done by applying Phase Doppler Anemometry (PDA). It was found that the velocity of the spray emitted from the two-fluid nozzle exceeds almost 200 m/s and the number mean droplet diameter was well below 20 μm. In the initial spray region droplet break-up was observed whereas downstream of 50 mm a slight growth of the mean droplet size indicated further coalescence. Due to the applied pattern air, the spray flux distribution at the normally located tablet bed (i.e., 100–150 mm downstream the nozzle) has an oval shape and the mean droplet velocity still exceeds almost 50 m/s with a mean droplet diameter of about 10 μm. The cross-sectional measurements are used to provide proper inlet conditions for the spray simulations, while the other cross-sections are used for validating the computed spray expansion and dispersion. For demonstrating the effect of a real measured spray flux distribution on the tablet coating quality, additionally DEM simulations were conducted. Here, the measured spray flux data were mapped onto the temporarily evolving and moving tablet surface simulated for a lab-scale test drum by DEM. The uniformity of tablet coating (inter-tablet variability) was judged by calculating the Coefficient Of Variation (COV) for the considered different tablet shapes and operational conditions.

Telecom C-band photon emission from (In,Ga)As quantum dots generated by filling nanoholes in In0.52Al0.48As layers

We present the fabrication of strain-free quantum dots in the In0.53Ga0.47As/In0.52Al0.48As-system lattice matched to InP, as future sources for single and entangled photons for long-haul fiber-based quantum communication in the optical C-band. We achieved these quantum dots by local droplet etching via InAl droplets in an In0.52Al0.48As layer and subsequent filling of the holes with In0.53Ga0.47As. Here, we present detailed investigations of the hole morphologies measured by atomic force microscopy. Statistical analysis of a set of nanoholes reveals a high degree of symmetry for nearly half of them when etched at optimized temperatures. Overgrowth with 50–150 nm In0.52Al0.48As increases their diameter and elongates the holes along the [01̄1]-direction. By systematically scanning the parameter space, we were able to fill the holes with In0.53Ga0.47As, and by capping the filled holes and performing photoluminescence measurements, we observe photoluminescence emission in the O-band up into the C-band depending on the filling height of the nanoholes.

Strong Electric Polarizability of Cone–Shell Quantum Structures for a Large Stark Shift, Tunable Long Exciton Lifetimes, and a Dot-to-Ring Transformation

Strain-free GaAs cone-shell quantum structures (CSQS) with widely tunable wave functions (WF) are fabricated using local droplet etching (LDE) during molecular beam epitaxy (MBE). During MBE, Al droplets are deposited on an AlGaAs surface, which then drill low-density (about 1 × 107 cm-2) nanoholes with adjustable shape and size. Subsequently, the holes are filled with GaAs to form CSQS, where the size can be adjusted by the amount of GaAs deposited for hole filling. An electric field is applied in growth direction to tune the WF in a CSQS. The resulting highly asymmetric exciton Stark shift is measured using micro-photoluminescence. Here, the unique shape of the CSQS allows a large charge-carrier separation and, thus, a strong Stark shift of up to more than 16 meV at a moderate field of 65 kV/cm. This corresponds to a very large polarizability of 8.6 × 10-6 eVkV -2 cm2. In combination with simulations of the exciton energy, the Stark shift data allow the determination of the CSQS size and shape. Simulations of the exciton-recombination lifetime predict an elongation up to factor of 69 for the present CSQSs, tunable by the electric field. In addition, the simulations indicate the field-induced transformation of the hole WF from a disk into a quantum ring with a tunable radius from about 10 nm up to 22.5 nm.

Review of Oil–Water Flow Characteristics of Emptying by Water Displacing Oil in Mobile Pipelines

Water displacing oil is one of the main emptying methods for mobile pipelines. It has the advantages of being a simple process and highly safe. At present, the determination of a water displacing oil scheme of mobile pipelines is based on the oil–oil alternating transport theory of product oil pipelines. However, the insolubility of the oil phase and the water phase results in a great difference between the flow characteristics of water displacing oil and the oil–oil alternating transport of a product oil pipeline. In addition, due to the effect of buoyancy, the oil phase gathers at the high point of the pipeline and forms a liquid accumulation, which is difficult to carry away by water flow, resulting in the low emptying efficiency of the mobile pipeline. The essence of water displacing oil in a mobile pipeline is an oil–water two-phase unsteady displacement flow, involving liquid–liquid displacement flow, oil–water two-phase flow and water carrying oil. Aiming at such problems, domestic and foreign scholars have carried out a large number of theoretical and experimental studies, established the oil–water mixing model of water displacing oil and the relationship between macroscopic quantity (flow pattern, pressure drop and water content) and microscopic quantity (local flow field and droplet dispersion pattern, etc.) under each flow type, and explored the influence of pipeline diameter, oil phase velocity, pipeline inclination angle and other parameters on the capacity of carrying liquid accumulation. On this basis, this paper analyzes the shortcomings of the current research on the oil–water flow characteristics of water displacing oil in a mobile pipeline from three aspects: the formation mechanism of the oil–water mixture, displacing flow characteristics of immiscible fluids and flow characteristics of water carrying oil. Five future research directions are proposed, including the interface morphology and flow field characteristics of oil–water two-phase layered flow, local mixing characteristics of an oil–water two-phase dual continuous flow interface, droplet distribution and flow characteristics of oil–water two-phase dispersed flow, unsteady flow characteristics of the oil–water mixture of water displacing oil and oil accumulation and flow characteristics in topographic relief pipes.

A novel isothermal digital amplification system and its application for absolute quantification of respiratory infectious virus

Herein, we establish a novel isothermal digital amplification system termed digital nicking and extension chain reaction system-based amplification (dNESBA) by utilizing the isothermal NESBA technique and the newly developed miniaturized fluorescence monitoring system (mFMS). dNESBA enables parallel isothermal NESBA reactions in more than 10,000 localized droplet microreactors and read the fluorescence signals rapidly in 150 s by mFMS. This system could identify the genomic RNA (gRNA) extracted from target respiratory syncytial virus A (RSV A) as low as 10 copies with remarkable specificity. The practical applicability of dNESBA was also successfully verified by reliably detecting the gRNA in the artificial sputum samples with excellent reproducibility and accuracy. Due to the intrinsic advantages of isothermal amplifying technique including the elimination of the requirement of thermocycling device and the enhanced portability of the miniaturized read-out equipment, the dNESBA technique equipped with mFMS could serve as a promising platform system to achieve point-of-care (POC) digital molecular diagnostics, enabling absolute and ultra-sensitive quantification of various infectious pathogens even in an early stage.

On the mechanics of droplet surface crater during impact on immiscible viscous liquid pool

We study drop impacts on an immiscible viscous liquid pool and investigate the formation of droplet surface craters using experimental and theoretical analyses. We attribute the formation of air craters to the rapid deceleration of the droplet due to viscous drag force. The droplet response to the external impulsive decelerating force induces oscillatory modes on the surface exposed to the air forming capillary waves that superimpose to form air craters of various shapes and sizes. We introduce a non-dimensional parameter (${\varGamma }$), that is, the ratio of the drag force to the capillary force acting on the droplet. We show that${\varGamma }$is directly proportional to the capillary number. We show that droplets forming air craters of significant depths have${\varGamma }&gt;1$. Further, we demonstrate that Legendre polynomials can locally approximate the central air crater jet profile. We also decipher that the air crater response time scale ($T$) varies as the square root of impact Weber number ($T\sim We^{1/2}$). Further, we generalize the local droplet response with a global response model for low impact energies based on an eigenvalue problem. We represent the penetrating drop as a constrained Rayleigh drop problem with a dynamic contact line. The air–water interface dynamics is analysed using an inviscid droplet deformation model for small deformation amplitudes. The local and global droplet response theories conform with each other and depict that the deformation profiles could be represented as a linear superposition of eigenmodes in Legendre polynomial basis. We unearth that the droplet response in an immiscible impact system differs from the miscible impact systems due to the presence of such a dynamic contact line.

Experimental study on local droplet parameters in a deformed 2 × 2 Rod bundle under air-water annular-mist flow

During reflood conditions following a loss-of-coolant accident in pressurized water reactors, droplet flow affects the heat and mass transfer between liquid and steam phases. Flow behavior is further complicated by fuel rod cladding deformation. Accurate knowledge of the large interfacial area liquid droplets characteristics and the effect of rod deformation is essential for understanding the associated thermal-hydraulic process and guaranteeing nuclear safety. This study aims to investigate the effect of fuel rod deformation on the characteristics and distribution of local droplet parameters. Experiments were conducted in a vertical 2 × 2 deformed rod bundle with two deformed test sections with blockage ratios of 25% and 50%. Tests were performed under annular-mist flow conditions at atmospheric pressure over superficial liquid and gas velocities ranges of 0.020–0.040 m/s and 25–35 m/s, respectively. A double-sensor optical fiber probe was used to measure local droplet parameters downstream of the deformed region on the measuring planes. For a quantitative characterization of the effect of rod deformation on local droplet parameter distribution, the results of the deformed bundle tests were compared with those of the previous intact bundle tests. Furthermore, a prediction correlation for the bundle deformation-enhanced droplet mass flux ratio was proposed. The results of this study provide a better understanding of the complex reflood flow behavior and improve the predictability of numerical simulations.

Slag Flow in the Packed Bed With Varied Properties and Bed Conditions: Numerical Investigation

Molten slag, which is primarily generated in the blast furnace (BF) cohesive zone, trickles down through the coke packed bed in the form of films, rivulets, or droplets in the lower zone of the BF. During its downward flow, there are significant interactions occurring between slag and other phases such as gas, coke particles, hot metal, and fine powders. In terms of these interactions, slag flow behavior can greatly affect BF productivity and be associated with furnace irregularities such as channeling, hanging, and slipping. Hence, understanding the interactions between phases is useful to maximizing BF efficiency in terms of operating cost, reliability, and production capacity. In the current study, a Volume of Fluid (VOF) modeling technique was applied to track the movement of individual slag droplets in the packed bed at a mesoscopic level, considering various bed permeabilities, more wide-ranging slag properties, and different wettability between slag and packing particles. Results demonstrate the significant role of modeling at a mesoscopic level in understanding macroscopic slag flow behavior. Modeling work helps to visualize the trickling behavior of slag droplets in more realistic and complex conditions representing a BF, and clarify the mechanisms of the different flow patterns generated for variations in operating conditions. Transient flow characteristics such as localized slag accumulation and droplet morphology were identified and analyzed in relation to complex condition changes. The current modeling proved to be a valuable tool to provide a foundation for better understanding the slag flow behavior and its interactions with other phases in the BF lower zone.

Migration of non-Brownian particles localized inside sheared droplets

• Particles inside sheared droplets migrate along the vorticity direction. • The migration direction depends on the viscosity ratio. • The migration kinetics depends on Ca, interfacial tension and particle concentration. • VOF simulations provide velocity and shear rate distribution in a particle-free droplet. • Shear-induced migration plays a major role. The migration of non-Brownian particles inside a droplet subjected to shear flow is investigated. The viscosity ratio, particle concentration, particle to droplet size ratio and capillary number are systematically varied. It was observed that particles migrate in the vorticity direction either towards or away from the equatorial plane. The main factor determining the migration direction is the viscosity ratio. The particle concentration and applied capillary number have no influence on the equilibrium distribution and only affect the time necessary to reach this distribution. In order to identify the flow profile, both velocity and shear rate magnitudes to which the particles inside the droplet are subjected, are numerically simulated using the Volume-of-Fluid method in a particle-free droplet/matrix system. The numerical predictions of the flow are used to evaluate the presence of possible driving mechanisms for cross-streamline particle motion, such as particle inertia and shear rate gradients. Depending on the conditions, the simulations reveal significant differences in the streamline profiles and shear rate gradients within the droplet. The observed steady state particle distributions can partially be explained by shear-induced migration towards zones of low shear rates and/or low streamline curvature. However, in complex flows, such as inside a deformed droplet, different migration mechanisms can occur simultaneously. Hence, confinement inside the droplet and potential secondary flows may also play a role.