Early Silurian Research Articles

Zircon U[sbnd]Pb ages, trace elements, and Hf isotopes establish a genetic link between volcanic ash beds and porphyritic intrusions during early Silurian in the South China Block

The provenance of the Late Ordovician to Early Silurian volcanic ash beds (VABs) in the South China Block (SCB) remains debated. In this study, we provide new zircon UPb age, trace element, and Hf isotope data of bentonites, crystal tuffs, and porphyritic intrusions from the Longmaxi Formation of the Dabashan area in the northern margin of the SCB with a view to investigate the composition, tectonic setting, and source of their parent magmas. The zircon UPb ages show that the volcanic eruption and magma emplacement occurred in the Early Silurian (ca. 440–434 Ma). The zircon trace element compositions are consistent with A-type parent magmas formed in intraplate extensional settings. The positive εHf(t) values (+1.7 to +6.9) of zircon indicate an enriched mantle source for the magma, with possible crustal input. The similar UPb ages, trace element compositions, and εHf(t) values of zircon grains from VABs and porphyritic intrusion in the Dabashan area suggest that their parent magmas shared similar sources. These A-type parent magmas could have originated in intraplate extension settings on the passive margin of the northern SCB during the subduction of the Proto-Tethys Ocean towards the North Qinling Terrane. Our results suggest that the Paleo-Tethys oceanic basin did not open before the Early Silurian (ca. 434 Ma) in the Dabashan area.

Temperature Controls Initial REE Enrichment in Peraluminous Granites: Implication from the Parent Granites in the Shangyou Ion-Adsorption Type REE Deposit

The initial enrichment of rare earth elements (REE) in granites plays an important role for the generation of ion-adsorption type REE deposits. It has been summarized that the mineralization-related granitoids are mostly peraluminous, but the enrichment mechanism of REE in this peraluminous granite is currently not well understood. In this study, we conducted geochronology, petrological, and geochemical investigations on the biotite granite and muscovite granite from the Shangyou complex in Ganzhou, Jiangxi Province. Zircon U-Pb dating indicates that both the biotite granite and muscovite granite generated in the Early Silurian (ca. 433–434 Ma). The high aluminum saturation index and occurrence of muscovite and old zircon cores indicate that they belong to the S-type granite and are derived from the melting of metagreywacke. The relatively higher FeOT contents, Mg# values, and zirconium saturation temperatures (760–873 °C) for the biotite granite resulted from hydrous melting with the involvement of mantle material. In contrast, the muscovite granite with low FeOT contents, Mg# values, Nb/Ta ratios, and zirconium saturation temperatures (748–761 °C) indicates a purely crust-derived melt formed by muscovite dehydration melting. There is a positive correlation of REE contents with the formation temperature and Th contents in both the Shangyou granites and the data collected from global peraluminous granites. This indicates that temperature plays a key role in the REE enrichment in peraluminous granites, as the high-temperature condition could promote the melting of REE-rich and Th-rich accessory minerals of allanite and REE-phosphate and result in the increases in both REE contents and Th contents in the melts. Given the fact that the parent granites for ion-adsorbing REE deposits are mostly peraluminous and generated in the extensional setting in South China, we concluded that peraluminous granite formed under high-temperature extensional tectonic settings favors initial REE enrichment, which further contributes to the formation of ion-adsorbing REE deposits in South China.

Waukeshaaspis eatonae n. gen. n. sp.: a specialized dalmanitid (Trilobita) from the Telychian of southeastern Wisconsin

Abstract A new dalmanitid trilobite is described from the early Silurian (Telychian) Waukesha Biota in Wisconsin, USA, best known for its variety of exceptionally preserved arthropods. Waukeshaaspis eatonae new genus new species is the most common trilobite found in the Waukesha Biota, numbering ~200 specimens, allowing a thorough description of the dorsal exoskeleton. This new taxon has a combination of characters unique to the Dalmanitidae, including a distinct embayment on the posterior margin of the pygidium. Embayments are rare for dalmanitids, most species having instead a caudal spine. The lengthening of the genal spines might have served a similar function to that which a caudal spine would have served, allowing the embayment to fulfill a different function, related to keeping an opening when enrolled. The abundance at the preservation site suggests physiological tolerance at the habitation site. UUID: http://zoobank.org/50a214e3-72f0-4ca2-b8f1-4ad4460bc1d4

Evolution of volcanism and geodynamic settings in the Sakmara zone of the Southern Urals in the early Paleozoic

Research subject. Northern part of the Sakmara zone of the Southern Urals, represented by the Krakinsko-Mednogorsk paleovolcanic belt, including the Mednogorsk ore district and the Blavinsko-Komsomolskoye ore field. Aim. To reconstruct the paleogeodynamic settings during the Cambrian–Early Devonian in the Sakmara zone. Methods. An analysis of geological, petrogeochemical, structural-tectonical, and paleovolcanological data obtained by the authors and those reported in literature using conventional and new petrogeochemical diagrams. Results. The following stages of tectono-magmatic evolution in the Sakmara zone were distinguished: (1) Cambrian–Early Ordovician, continental rifting; (2) Early–Middle Ordovician, oceanic spreading; (3) Early Silurian, suboceanic rifting, serpentinite protrusions, edaphogenic breccias, siliceous rocks (starting a subduction zone); (4) Late Silurian–Early Devonian, island-arc basalt-rhyolite volcanism and sulfide deposits, volcanism of the shoshonitic and alkaline series, formation of the rear island arc. The Sakmara zone features no analogues of boninite volcanism (D1e2) typical of the West Magnitogorsk zone, which indicates the absence of signs of the volcanogenic strata of the Voznesensk–Prisakmar zone being pushed into the Sakmara structural zone. Conclusions. (1) In the Cambrian–Early Devonian, volcanogenic and volcanogenic-sedimentary formations and strata of the Sakmara zone formed a megacycle, starting with the processes of continental and oceanic rifting, which led to the subduction process and generation of the frontal and rear island arcs. (2) The volcanism in the Sakmara and Voznesensk–Prisakmar zones developed autonomously, without tectonic transfers from east to west. (3) The partial coincidence of the formation age of the Chanchar (D1lh–e1) complex of the Sakmara zone and the Turin complex (S2p–D1lh) of the Tagil zone suggests the presence of a reduced continuation of the western wing of the Tagil zone in the Sakmara zone.

Silurian-devonian adakites and granitic pegmatitic dikes in North Qinling, China: Multi-stage magmatism and implications for the tectonic evolution

The petrogenesis and tectonic setting of early Paleozoic adakites and granitic pegmatites in the North Qinling orogenic belt are highly debated issues. Zircon UPb dating revealed that the Huichizi pluton is composed of the Early Silurian granodiorites, Late Silurian granodiorites, and Early Devonian granitic pegmatite dikes. The average εHf(t) value of pegmatite dikes was −2.8, which is lower than those of the Early Silurian (4.8) and Late Silurian granodiorites (5.1). It is worth noting that the Early Silurian and Late Silurian granodiorites exhibited adakitic characteristics and were formed through the partial melting of a thickened juvenile mafic lower crust. In addition, the Early Devonian pegmatite dikes displayed a substantial fractional crystallization. They were derived from the partial melting of mixed sources, including the crustal and mantle materials. The early Paleozoic adakitic rocks in the North Qinling orogenic belt can be categorized into four groups according to their c geochemical characteristics. The adakitic rocks of the first group (496–458 Ma) were rich in Na and exhibited extremely high εHf(t) values. They were formed by the partial melting of the Erlangping back-arc oceanic crust. The adakitic rocks of the second group (454–420 Ma) exhibited enriched Na or K contents and varying εHf(t) values. They were derived from the partial melting of a thickened lower crust with various mantle components, underplated by mafic magma formed during the subduction of the Shangdan Ocean. The adakites of the third (420–410 Ma) and fourth (410–400 Ma) groups were formed by the partial melting of a thickened lower crust under collisional and post-collisional settings, respectively.

Relationships between high-K magmas and Cu–Au porphyry deposits in the Macquarie Arc, Australia

The Macquarie Arc is a long-lived volcanic arc terrane which began in the latest Cambrian and continued until the early Silurian. Early Silurian high-K suites associated with Cu–Au porphyry mineralization are typically considered shoshonitic; however, comparisons with well-studied examples of shoshonites in continental arcs and associated settings suggest few Macquarie Arc rocks would classify as shoshonitic. Notably, the Au-rich Cadia Intrusive Complex, which is marginally shoshonitic, and most high-K to ‘shoshonitic’ Macquarie Arc rocks are essentially high-K calc-alkaline, analogous to ‘primitive’ shoshonites generated within intraoceanic arc settings. Arc magmatism in the Macquarie Arc is consistently primitive and mantle derived prior to an increase in siliciclastic input and crustal thickening during the Silurian Benambran Orogeny, consistent with prior isotopic studies. Magma source regions can thus be interpreted as varying spatially and temporally due to variable enrichment from slab and mantle derived components, reflecting a maturing and potentially migrating arc system.

Detrital Zircons From Lower Palaeozoic Metamorphic Complexes and Silurian–Devonian Strata in the South Kitakami Belt, Northeast Japan: Implications for the Northern Extension of the Terra Australis Orogen in Northeast Gondwana

ABSTRACTTo reconstruct the detailed location of proto‐Japan around northeastern Gondwana during the early Palaeozoic, this article presents detrital zircon U–Pb age spectra for lower Palaeozoic metamorphic complexes and Silurian–Devonian strata from the western margin of the South Kitakami belt in northeast Japan. Psammitic and siliceous schists have youngest age peaks ranging from the Ordovician (479–458 Ma) to early Silurian (ca. 439 Ma). Sandstones have youngest age peaks varying from the early Silurian (ca. 435 Ma) to Late Devonian (370–360 Ma). The U–Pb age spectra exhibit major peaks at 510–500, 480–470, and 450–440 Ma. Excluding the Upper Devonian sandstones, significant age peaks occur at 650–550 and 1300–900 Ma. These data can be interpreted as a Pacific Gondwana signature, indicating a tectonic association with the Terra Australis Orogen that developed along the northeastern Gondwanan margin and Paleo‐Pacific Ocean, extending from eastern Australia (i.e., the Thomson, Lachlan, and Delamerian orogens) to Antarctica (i.e., the Ross Orogen). In northeast Asia, the Pacific Gondwana detrital zircons and 480–470 Ma zircons occur in the Bainaimiao arc belt along the northern margin of the North China Craton and in the Jiangyu continental arc in the Jilin area. The magmatic arcs of proto‐Japan and these regions were part of the Terra Australis Orogen during the Ordovician–early Silurian. A decrease in the proportion of Pacific Gondwana detrital zircons in Upper Devonian strata may be due to multistage trench retreat, such as that recognized in the Tasmanides in eastern Australia, which corresponds to the northern Terra Australis Orogen.

Re-Os geochronology and geochemical evolution of late Cambrian to Middle Ordovician Alum and Tøyen shales, Sweden

The limited number of accurate and precise radiometric ages through the ∼100 Myr span of the Cambrian and Ordovician impedes reliable age determinations for stage boundaries in these periods. Here, we fill significant gaps in the early Paleozoic chronostratigraphy by providing precise Re-Os time-pins. Sample selection is linked to a firm biostratigraphic framework built on the appearance and distribution of trilobites, graptolites, and conodonts. A Furongian (upper Cambrian) Alum Shale section (Andrarum-3 drill core, Scania, Sweden) at the onset of the Steptoean Positive Carbon Isotopic Excursion (SPICE) yields highly non-isochronous Re-Os isotopic data from a section with wildly fluctuating δ13Corg; however, selected data from a narrow sediment band with steady carbon isotope stratigraphy provides an imprecise Re-Os age of 497 ± 28 Ma (2σ; Model 3; n = 3), with an initial 187Os/188Os ratio (Osi) of 0.74 ± 0.05. Organic-rich Alum Shale (Tomten-1 drill core, Västergötland, Sweden) from ∼120 cm below the Cambrian-Ordovician boundary yields a Model 1 age of 488.6 ± 5.1 Ma (2σ; MSWD = 1.5; n = 25) and an Osi of 0.82 ± 0.04 for Stage 10, uppermost Cambrian. Biostratigraphic data indicate the dated Alum Shale is from an interval slightly below the Top Of Cambrian Excursion (TOCE) and slightly above the First Appearance Datum (FAD) of the agnostoid Lotagnostus americanus. Organic-rich Tøyen Shale (Lerhamn drill core, Scania, Sweden) yields a precise Model 1 Re-Os age of 469.7 ± 1.4 Ma (2σ; MSWD = 1.0; n = 10) and Osi of 0.802 ± 0.002 for the maximum age of the Floian–Dapingian stage boundary (Lower–Middle Ordovician boundary). The Os isotopic composition of seawater from the latest Ediacaran through the Cambrian to Early-Middle Ordovician hovers around 0.8 but falls to 0.54 by early Silurian. This significant decrease in seawater 187Os/188Os is consistent with reduced chemical weathering and cooler seawater temperatures through the Middle–Late Ordovician. Overall, Redox Sensitive Element (RSE; Re, Os, Mo, U) abundances correlate positively with Total Organic Carbon (TOC), suggesting efficient removal of these elements from an anoxic water column by organic matter. However, these relationships break down for high TOC (>10%) shales depositing under euxinic conditions. The RSE-TOC relationship breakdown supports enhanced metal drawdown from the water column with local pyrite accumulation. Geochemical data suggest the deposition of Alum and Tøyen shales under hydrographically restricted settings with increased primary productivity along the Baltica's margin during the latest Cambrian to Early-Middle Ordovician.

Orogenic Gold Deposits of Northern Transbaikalia, Russia: Geology, Age, Sources, and Genesis

The paper presents newly obtained and summarizes preexisting data of long-term geochronological and isotope studies of orogenic mesothermal gold deposits in the world’s largest Lena metallogenic province and reviews interpretations of their genesis. Geochronologic data indicate that the gold mineralization was formed during three ore-forming Paleozoic events. The early Late Ordovician–Early Silurian (450–430 Ma) event produced the abundant veinlet—disseminated gold–sulfide mineralization in Neoproterozoic carbonaceous terrigenous–carbonate rocks of the Baikal–Patom foldbelt (BPB). The mineralization was formed simultaneously with regional metamorphic processes. The rejuvenation of hydrothermal activity in the BPB resulted in gold-bearing quartz veins, which was produced in the Middle Carboniferous (340–330 Ma) in relation to postcollisional granitoid magmatism. The latest ore-forming event occurred in the Early Permian (290–280 Ma) and affected exclusively in Precambrian structures of the Baikal-Muya foldbelt (BMB). It was synchronous with the development of intraplate alkaline and subalkaline magmatism in the region. Newly obtained and preexisting isotopic-geochemical (87Sr/86Sr, 143Nd/144Nd, Pb–Pb, and δ34S) data indicate that the mesothermal ore-forming systems of northern Transbaikalia were heterogeneous in their isotopic characteristics, which distinguishes them from the ore–magmatic (intrusion-related type) systems. Comparison of the Sr, Nd, and Pb isotopic composition of the ores and rocks, including magmatic rocks coeval with the gold mineralization, indicates that the Precambrian continental crust was the dominant source of mineral-forming components for the hydrothermal systems of the gold deposits. The contribution of the magmatic source to the genesis of the orogenic gold mineralization was limited and is identifiable only for the Early Permian ore-forming systems of the BMB, for which the input of metals from alkaline mafic melts was suggested.

Multiple Non-Destructive Approaches to Analysis of the Early Silurian Chain Coral Halysites from South China.

Cnidarians are among the most important diploblastic organisms, elucidating many of the early stages of Metazoan evolution. However, Cnidarian fossils from Cambrian deposits have been rarely documented, mainly due to difficulties in identifying early Cnidarian representatives. Halysites, a tabulate coral from Silurian reef systems, serves as a crucial taxon for interpreting Cambrian cnidarians. Traditionally, the biological characteristics of Halysites have been analyzed using methods limited by pretreatment requirements (destructive testing) and the chamber size capacity of relevant analytical instruments. These constraints often lead to irreversible information loss and inadequate data extraction. This means that, to date, there has been no high-resolution three-dimensional mineralization analysis of Halysites. This study aims to introduce novel, non-destructive techniques to analyze the internal structure and chemical composition of Halysites. Furthermore, it seeks to elucidate the relationship between coral organisms and biomineralization in reef settings and to compare Silurian Tabulata with putative Cambrian cnidarians. Techniques such as micro-X-ray fluorescence spectrometry (micro-XRF), micro-X-ray computed tomography (micro-CT), and scanning electron microscopy (SEM) were employed in this research. With the help of high-resolution micro-CT scanning, we identify the growth pattern of Halysites, showing both lateral and vertical development. The lateral multiple-branching growth pattern of Halysites corals is first established herein. The flaggy corallite at the initial stage of branching is also observed. The micro-XRF mapping results reveal the occurrence of septa spines for Halysites, a trait previously thought rare or absent. Additionally, the ratio of coral volume to the surrounding rock was assessed, revealing that Halysites reefs were relatively sparse (volume ratio = ~30%). The cavities between Halysites likely provided more space for other organisms (e.g., rugose corals and bryozoans) when compared to other coral reef types. Additionally, we provide a comparative analysis of post-Cambrian colonial calcareous skeletons, offering insights into the structural features and growth patterns of early skeletal metazoans across the Ediacaran-Cambrian boundary.

Geological setting and gold mineralisation characteristics at the Me Xi, Vinh Linh, Quang Tri, Vietnam

The Me Xi gold deposit is located in Vinh Linh, Quang Tri, Truong Son Fold Belt, Vietnam, about 45 km to the east of the Sepon Mineral District, Laos PDR. Gold mineralisation at Me Xi is predominantly hosted in siltstone and subordinate calcareous siltstone, sandstone, shale, black shale and calcareous shale of Ordovician - Early Silurian Long Dai formation that were metamorphosed at greenschist facies. The igneous rocks that are closest to Me Xi deposit include undated porphyritic dolerite and mafic dykes. Two gold mineralisation zones consisting of eight mineralised bodies have been recorded, in which the main zone is ~ 640 m long and ~10÷60 m wide. The largest gold mineralisation body has a length of ~220 m and a width of ~0.5÷3 m. Gold mineralisation occurred mainly as stockwork quartz-sulphide veins that were typically characterised by the brittle deformation of host rocks. At least four hydrothermal stages were observed at the deposit, of which gold was accumulated in the stage 2 veins and possibly stage 3 veins that has similar mineralogical assemblage and alteration patterns to those of the stage 2. These stockwork stages 2 and 3 veins predominantly consist of pyrite and minor chalcopyrite, gold, arsenopyrite, pyrrhotite and galena in association with strong silicification, chloritisation, sericitisation and subordinate decalcification. The pre-Au stage 1 veins are rarely observed, but this hydrothermal stage records an initial deformation of the host sequence. The post-Au stage 4 is characterised by carbonate-rich quartz stockwork veins with local patches of sulphides.

Geochemical Features, Origin, and Depositional Environment of Late Ordovician–Early Silurian Wufeng and Longmaxi Formation Cherts in the Southeastern Sichuan Basin

Geochemical Features, Origin, and Depositional Environment of Late Ordovician–Early Silurian Wufeng and Longmaxi Formation Cherts in the Southeastern Sichuan Basin

High resolution Ordovician carbon isotope chemostratigraphy in South China and its significance for global correlation

Based on the Shidi-1 drill core, this paper presents new and highly time resolved carbon isotope data (δ13Ccarb) for the Early Ordovician through Early Silurian of the Yangtze Platform, South China. Five carbon isotopic shifts (C1-C5) through the late Tremadocian to the Katian have been recognized in the Shidi-1 drill core recordings. Together with previously published isotope data, a composite carbon isotope curve for the Yangtze platform, permits the identification of a continuous Ordovician carbon isotope trend with five prominent carbon isotope shifts; including the TSICE, the Late Tremadocian positive Isotopic Carbon Excursion (LTICE, named herein), the Late Floian Rise, the MDICE and the Pagoda Isotopic Carbon Excursion (PICE, named herein). The identification and documentation of these anomalies further strengthen the regional and global correlation of the Ordovician succession on the Yangtze platform. The long-term trend in carbon isotopes indicates that organic carbon burial increased gradually throughout the Great Biodiversification Event (GOBE). A tipping point is also marked by the Dapingian-Darriwilian border, which is followed by a notable shift in the environment and creatures in the middle Darriwilian.

Elemental Geochemical Characteristics of Shales from Wufeng-Longmaxi Formations in the Southern Margin of the Qinling Orogenic Belt, China: Implications for Depositional Controls on Organic Matter.

The tectonic background and sedimentary environment during the transition period from the Ordovician to Silurian have been widely studied by many scholars. This study focuses on the Upper Ordovician Wufeng Formation and Lower Silurian Longmaxi Formation in the Bajiaokou profile at the southern margin of the Qinling Orogenic Belt in southern China. In order to study the aggregation mechanism of organic matter, geochemical proxies were proposed, including redox proxies (V, V/Al, U, U/Al, Mo, and Mo/Al), paleoproductivity proxies (P, P/Ti, Ba, Ba/Al, and SiXS), paleoclimate proxies (CIA), and terrigenous flux proxies (Al, Zr, and Zr/Al). In addition, Al-Co[EF] × Mn[EF] is used to provide information on paleoenvironmental parameters such as watermass restriction conditions. The redox proxies show that the Wufeng-Longmaxi shale is mainly accumulated under oxic-dysoxic conditions. During the shale deposition period of Wufeng-Longmaxi formations, the marine surface primary productivity in the southern Qinling area is generally low to moderate. The paleoclimate proxies show that from the Late Ordovician to the Early Silurian the southern Qinling area generally had a warm and humid climate. The upwelling current is widely developed in the northern margin of the Sichuan Basin and the southern margin of the Qinling area. Although the upwelling current was highly developed during the deposition of the Wufeng Formation in the Bajiaokou profile, the concentrated accumulation of a large amount of volcanic ash resulted in the low primary productivity of the ocean. During the sedimentary period of the Longmaxi Formation in the Bajiaokou profile, the development of seasonal upwelling currents and a small amount of volcanic ash supply increased the primary productivity to moderate, which provided a good material basis for the enrichment of organic matter, but the high detritus flux and the water body condition of oxic-dysoxic resulted in the slight enrichment of organic matter.

Zinc isotopic evidence for enhanced continental weathering and organic carbon burial in the Early Silurian

The Late Ordovician and Early Silurian periods experienced glaciation and mass extinctions. However, debates exist regarding the factors that initiated the glaciation and the subsequent delay in biotic recovery. To uncover the relationships between paleoclimate, marine redox states, and biotic recovery in the Early Silurian, temporal variations in Zinc (Zn) isotopic compositions along with other multi-geochemical proxies were analyzed for a carbonate-dominated section in South China. A stratigraphic δ66Zn trend was found in studied section, indicating a widespread disturbance to the marine Zn cycle. A significant negative shift in δ66Zn by up to ∼0.7 ‰ was observed immediately following the Hirnantian Glaciation and HICE, which can be attributed to a combination of reduced burial efficiency of organic carbon, fast weathering of large igneous provinces and increased riverine Zn input. This was followed by a ∼ 0.4 ‰ rise in δ66Zn values, alongside a sharp decrease in δ13C values, indicating an increase in sulfide precipitation (e.g., ZnS, FeS) due to expansions of euxinia. Subsequently, a notable rise in δ66Zn values by up to ∼1.1 ‰ is interpreted as an increase in organic carbon burial, given the concurrent variation of δ66Zn and δ13C during this period. The findings suggest that the increase in organic carbon burial, a reduction in reverse weathering, or a combination of them contributed to the glaciation in Silurian. Furthermore, the weathering-induced high primary productivity led to anoxic water conditions in the latest Hirnantian and Rhuddanian. This prolonged marine anoxia in seawater thus caused the deposition of organic-rich sediments and hindered biotic recovery in the Rhuddanian.

Two periods of magmatism in the Weishancheng ore concentration area, Henan Province: Evidences from zircon U‐Pb chronology, Hf isotopes and petrogeochemistry

The Weishancheng area of Tongbai County, Henan Province, is an important Au‐Ag polymetallic ore concentration area in China, characterized by a widespread distribution of plutons and frequent magmatic activities. To investigate the genetic relationship between magmatism and the mineralization of gold and silver polymetallic deposits in the area, this study focuses on the porphyritic monzogranite of the Liangwan pluton and the biotite granite of the Taoyuan pluton in detail. The zircon U‐Pb age of the Liangwan pluton is 128.5 ± 0.7 Ma, placing its intrusion age in the Early Cretaceous. Similarly, the zircon U‐Pb age of the Taoyuan pluton is 431.3 ± 2.7 Ma, indicating an intrusion age in the Early Silurian. Petrogeochemical analysis reveals that both the Liangwan and Taoyuan plutons exhibit high SiO2, Na2O and Al2O3 contents, along with low MgO, Fe2O3 and CaO contents, indicating a (high‐K) calc‐alkaline series, and have the properties of peraluminous I‐type granite. The total rare earth elements (REE) concentrations are low, with noticeable fractionation between light and heavy REE, and a negative Eu anomaly. High‐field‐strength elements (such as Nb, Ta, P, Ti) are depleted, while the large‐ion lithophile elements (such as Rb, K, Pb) are enriched. The εHf(t) values of the Liangwan and Taoyuan plutons range from −16.1 to −18.8 and from 11.0 to 14.6, respectively. The mean values of Hf two‐stage model ages (TDM2) are 603 Ma and 2230 Ma, respectively. These results suggest that the Liangwan pluton may have formed through partial melting of ancient crustal materials in the Palaeoproterozoic, during extensional tectonic events following the subduction of Izanagi Plate. It appears closely linked to Au‐Ag mineralization in the ore concentration area. The Taoyuan pluton likely originated from the depleted mantle and experienced some degree of crustal contamination. However, it is unrelated to regional mineralization.

A new post-LOME (Late Ordovician Mass Extinction) recovery brachiopod fauna from South China

AbstractFollowing the Late Ordovician Mass Extinction event, brachiopod faunas were in a phase of recovery during the late Rhuddanian (early Silurian), documented by a drastic turnover of Ordovician-type to Silurian-type faunas. In this study, we present a recovery brachiopod fauna, from the Niuchang Formation (late Rhuddanian-based graptolite zonation) at the Wanzi section of Zhenxiong in northeastern Yunnan Province, South China. The fossils include 26 species assigned to 25 genera, with a dominance of strophomenides and orthides, but also a diverse suite of atrypides and pentamerides, which exhibit compositional differences compared to the earlier Edgewood–Cathay fauna. The emergence of a more typical Silurian brachiopod fauna suggests a delayed community turnover after the Late Ordovician Mass Extinction event. The shallowing marine environment trend evinced in the brachiopod assemblages in the section indicates a balance between the global transgression and the regional Qianzhong Uplift, which provided a stable environment for the brachiopod recovery. The presence of diverse pentamerides, including the earliest species of the large-shelled genus Sinostricklandiella, suggests early diversification of this clade in South China.

Geochemical Characteristics of the Paleozoic Marine Source Rocks and Ultra-Deep Hydrocarbon Accumulation Mode of the Awati Sag

The Lower Paleozoic of the Awati Sag and its periphery is a region with relatively low levels of exploration and stands as a frontier for ultra-deep hydrocarbon exploration. Based on outcrop and core samples, this study integrated organic geochemical analysis, total organic carbon (TOC) logging interpretation, and one-dimensional and two-dimensional hydrocarbon accumulation simulations, to clarify the primary source rock of the Lower Paleozoic and its characteristics, as well as its hydrocarbon accumulation mode. The findings indicate the following: (1) The Lower Paleozoic features two sets of industrial source rocks. The Yuertusi Formation, with its considerable thickness (approximately 200 m), widespread distribution, and elevated TOC (averaging approximately 5% from experimental data and logging interpretation), stands out as the Lower Paleozoic’s most pivotal source rock. (2) The Yuertusi and Saergan Formations are in a high-to-over-mature stage, with the Yuertusi initiating oil generation in the early Silurian and transitioning to gas by the late Permian. The Saergan began producing oil in the Carboniferous, followed by gas in the late Permian. (3) The potential ultra-deep gas reservoirs in the Awati Sag are mainly distributed in the structural traps closer to the deep faults in five potential target formations. Deep natural gas typically exhibits mixed-source signatures, with the mixing notably pronounced along the Shajingzi Fault Belt due to influential basin-controlling faults.

Structural styles and chronological sequence of the Mianyuzui ductile strike-slip fault along the Shangdan suture Zone: Implications for the Paleozoic tectonic evolution of the Qinling Orogenic Belt, China

The Shangdan suture zone (SDSZ) subdivides the Qinling Orogenic Belt into North Qinling and South Qinling belts, marking the main tectonic boundary between the North China and South China Blocks. The Mianyuzi ductile strike-slip fault (MYZF) within the SDSZ separates the North China Block from the South China Block and contains valuable collisional information. This paper integrates the structural and geochronological data of the MYZF to investigate the Paleozoic tectonic evolution of the Qinling Orogenic Belt and the collision between the North China and South China Blocks. Two phases of deformation (D1-D2a-b) are identified along the southern boundary of the SDSZ. The metamorphic temperature of mylonites is ∼ 600–700 ℃ for the early stage and ∼ 300–500 ℃ for the late stage of shearing deformation. U-Pb zircon analysis of the mylonites and diabase dike in the ductile shear reveals that zircons have major younger protolith populations at 480–460 Ma, 450–430 Ma, and 405–425 Ma, which suggests that rocks were probably derived from the North Qinling belt. The metamorphism and deformation cooling age from the MYZF have been constrained to be 339–328 Ma and 259 ± 1.6 Ma using U-Pb and 40Ar/39Ar dating. Combined with previously published data, we concluded that the subduction of the Shangdan Ocean was active until the Early Silurian and subsequent collisions occurred during the Late Silurian. Meanwhile, the shearing might have been related to the intraplate extension-exhumation during the Carboniferous-Late Permian in the Qinling Orogenic Belt.

Metabasites from the Central East Kunlun Orogenic Belt Inform a New Suture Model for Subduction and Collision in the Early Paleozoic Proto-Tethys Ocean

The discovery of eclogite outcrops in the East Kunlun Orogen Belt (EKOB) has confirmed the existence of an Early Paleozoic HP-UHP metamorphic belt. However, the protoliths and metamorphic histories of widespread metabasites remain poorly constrained. We collected three types of metabasites from the central part of EKOB. We present an integrated study of petrography, whole-rock geochemistry, Sr-Nd isotopes, estimated P–T conditions, and zircon U-Pb isotope ages. The results show that amphibolites and retrograde eclogites have clockwise P–T paths with peak conditions of, respectively, 11–12 kbar and 675–695 °C, and 21.5–22.2 kbar and 715–750 °C. Zircon dating of metabasites from Dagele yields Late Ordovician (~449 Ma) to Early Silurian (~440 Ma) protolith ages and Early Devonian (~414 Ma) amphibolite facies metamorphic ages. Retrograde eclogites from east Nuomuhong have a protolith age of ~902 Ma and metamorphic ages of ~418 Ma, consistent with other eclogites from East Kunlun. Our data suggest that the protoliths of Dagele metabasites represent arc-type magmatism during the subduction of a small back-arc oceanic basin. Instead, the protoliths of retrograde eclogites are Neoproterozoic tholeiitic basalts emplaced into continental crust and subsequently deeply subducted. We develop a new model for Early Paleozoic subduction and collision in the East Kunlun region, emphasizing the role of ‘dominant’ and ‘secondary’ suture boundaries. This model helps explain the ages and metamorphic histories of the metabasites studied here and offers new perspectives on the evolution of the Proto-Tethys Ocean.